Study on Improving Biodegradability of Straw Pulp Papermaking Wastewater by Coagu-Flocculation and Nuclear-Flocculation

2014 ◽  
Vol 926-930 ◽  
pp. 4361-4364
Author(s):  
Xiao Qiao Song
Keyword(s):  
Molecular Weight ◽  
Organic Pollutants ◽  
Aromatic Hydrocarbons ◽  
Removal Rate ◽  
Activated Sludge Process ◽  
Test Results ◽  
Combination Process ◽  
Coagulation And Flocculation ◽  
Flocculation Process ◽  
Papermaking Wastewater

When straw pulp papermaking wastewater was treated by the process of coagu-flocculation and nuclear-flocculation, there were still high CODCr. UV254 can reflect organic pollutants and organic pollutants of unsaturated aromatic ring, carbon-carbon double bond. With the decrease of molecular weight of organic pollutants, absorption of ultraviolet light will decrease. Indirectly, it reflectd that the combination process had a good removal effect on high molecular aromatic hydrocarbons difficult to be biodegraded. Meanwhile it can improve the the biodegradability. It used the activated sludge process as subsequent process of coagulation and-flocculation process. The test results showed that the removal rate of CODCr was 24.1%, CODCr was the 88.1mg/L. It reached effluent standard.

scholarly journals Combined Application of UV Photolysis and Ozonation with Biological Aerating Filter in Tertiary Wastewater Treatment

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Zhaoqian Jing ◽  
Shiwei Cao
Keyword(s):  
Molecular Weight ◽  
Wastewater Treatment ◽  
Organic Pollutants ◽  
Wastewater Treatment Plants ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Secondary Effluent ◽  
Uv Photolysis ◽  
Combined Application

To enhance the biodegradability of residual organic pollutants in secondary effluent of wastewater treatment plants, UV photolysis and ozonation were used in combination as pretreatment before a biological aerating filter (BAF). The results indicated that UV photolysis could not remove much COD (chemical oxygen demand), and the performance of ozonation was better than the former. With UV photolysis combined with ozonation (UV/O3), COD removal was much higher than the sum of that with UV photolysis and ozonation alone, which indicated that UV photolysis could efficiently promote COD removal during ozonation. This pretreatment also improved molecular weight distribution (MWD) and biodegradability greatly. Proportion of organic compounds with molecular weight (MW) <3 kDalton was increased from 51.9% to 85.9%. COD removal rates with BAF and O3/BAF were only about 25% and 38%, respectively. When UV/O3oxidation was combined with BAF, the average COD removal rate reached above 61%, which was about 2.5 times of that with BAF alone. With influent COD ranging from 65 to 84 mg/L, the effluent COD was stably in the scope of 23–31 mg/L. The combination of UV/O3oxidation with BAF was quite efficient in organic pollutants removal for tertiary wastewater treatment.

scholarly journals Modelling PAHs removal in activated sludge process: effect of disintegration

2019 ◽  
Vol 80 (4) ◽  
pp. 794-805
Author(s):  
I. Mozo ◽  
M. Bounouba ◽  
E. Mengelle ◽  
N. Lesage ◽  
M. Sperandio ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Activated Sludge ◽  
Aromatic Hydrocarbons ◽  
Suspended Matter ◽  
Activated Sludge Process ◽  
Mass Balances ◽  
Colloidal Matter ◽  
Main Driver ◽  
Polycyclic Aromatic

Abstract The removal of polycyclic aromatic hydrocarbons (PAHs) in activated sludge was evaluated using two laboratory-scale bioreactors, coupled or not with a disintegration system (sonication). Mass balances performed on each system underlined that PAHs removal was significantly improved after sludge disintegration, especially for the higher molecular weight PAHs studied, which tended to adsorb to suspended matter. A model was developed in order to study the effect of sludge disintegration on the content of dissolved and colloidal matter (DCM), and to predict the potential impacts on PAHs availability and degradation. Results showed that this new model was efficient for capturing apparent degradation improvement trends and for discriminating between the involved mechanisms. This study showed that DCM content increased after sludge disintegration, and proved to be the main driver for improving PAHs apparent degradation.

Biodegradation rates of aromatic contaminants in biofilm reactors

1995 ◽  
Vol 31 (1) ◽  
pp. 117-128 ◽  
Author(s):  
Jean-Pierre Arcangeli ◽  
Erik Arvin
Keyword(s):  
Aromatic Hydrocarbons ◽  
Competitive Inhibition ◽  
Removal Rate ◽  
First Order ◽  
Biofilm Reactors ◽  
First Order Kinetics ◽  
Reducing Conditions ◽  
Low Concentrations ◽  
Degradation Rates ◽  
Order Surface

This study has shown that microorganisms can adapt to degrade mixtures of aromatic pollutants at relatively high rates in the μg/l concentration range. The biodegradation rates of the following compounds were investigated in biofilm systems: aromatic hydrocarbons, phenol, methylphenols, chlorophenols, nitrophenol, chlorobenzenes and aromatic nitrogen-, sulphur- or oxygen-containing heterocyclic compounds (NSO-compounds). Furthermore, a comparison with degradation rates observed for easily degradable organics is also presented. At concentrations below 20-100 μg/l the degradation of the aromatic compounds was typically controlled by first order kinetics. The first-order surface removal rate constants were surprisingly similar, ranging from 2 to 4 m/d. It appears that NSO-compounds inhibit the degradation of aromatic hydrocarbons, even at very low concentrations of NSO-compounds. Under nitrate-reducing conditions, toluene was easily biodegraded. The xylenes and ethylbenzene were degraded cometabolically if toluene was used as a primary carbon source; their removal was influenced by competitive inhibition with toluene. These interaction phenomena are discussed in this paper and a kinetic model taking into account cometabolism and competitive inhibition is proposed.

EDM with USM Combination Process of Sintered NdFeB Permanent Magnet

2010 ◽  
Vol 44-47 ◽  
pp. 1066-1069
Author(s):  
Li Li ◽  
Li Ling Qi ◽  
Zong Wei Niu
Keyword(s):  
Permanent Magnet ◽  
Material Removal ◽  
Removal Rate ◽  
Surface Characteristics ◽  
Dielectric Fluid ◽  
Machined Surface ◽  
Combination Process ◽  
Electro Discharge Machining ◽  
Ndfeb Permanent Magnet ◽  
Machining Characteristics

This paper presents an experimental investigation of the machining characteristics of sintered NdFeB permanent magnet using a combination process of electro-discharge machining (EDM) with ultrasonic machining (USM). Concentration of abrasive in the dielectric fluid is changed to explore its effect on the material removal rate (MRR). MRR of EDM /USM, conventional EDM are compared, machined surface characteristics are also compared between them. It is concluded that the combination EDM/USM process can increase the MRR and decrease the thickness of the recast layer. In the combination process, an appropriate abrasive concentration can improve its machining efficiency.

scholarly journals Enhanced Wastewater Treatment by Immobilized Enzymes

2021 ◽  
Author(s):  
Jakub Zdarta ◽  
Katarzyna Jankowska ◽  
Karolina Bachosz ◽  
Oliwia Degórska ◽  
Karolina Kaźmierczak ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Process Optimization ◽  
Organic Pollutants ◽  
Large Scale ◽  
Removal Rate ◽  
Immobilized Enzymes ◽  
Future Research ◽  
Process Conditions ◽  
Removal Rates ◽  
Catalytic Cycles

Abstract Purpose of Review In the presented review, we have summarized recent achievements on the use of immobilized oxidoreductases for biodegradation of hazardous organic pollutants including mainly dyes, pharmaceuticals, phenols, and bisphenols. In order to facilitate process optimization and achievement of high removal rates, effect of various process conditions on biodegradation has been highlighted and discussed. Recent Findings Current reports clearly show that immobilized oxidoreductases are capable of efficient conversion of organic pollutants, usually reaching over 90% of removal rate. Further, immobilized enzymes showed great recyclability potential, allowing their reuse in numerous of catalytic cycles. Summary Collected data clearly indicates immobilized oxidoreductases as an efficient biocatalytic tools for removal of hazardous phenolic compounds, making them a promising option for future water purification. Data shows, however, that both immobilization and biodegradation conditions affect conversion efficiency; therefore, process optimization is required to achieve high removal rates. Nevertheless, we have demonstrated future trends and highlighted several issues that have to be solved in the near-future research, to facilitate large-scale application of the immobilized oxidoreductases in wastewater treatment.

scholarly journals Multi-Response Optimization of Coagulation and Flocculation of Olive Mill Wastewater: Statistical Approach

2021 ◽  
Vol 11 (5) ◽  
pp. 2344
Author(s):  
Srikanth Vuppala ◽  
Riyaaz Uddien Shaik ◽  
Marco Stoller
Keyword(s):  
Grey Relational Analysis ◽  
Research Work ◽  
Olive Mill Wastewater ◽  
Relational Analysis ◽  
Coagulation And Flocculation ◽  
Coagulant Dosage ◽  
Response Optimization ◽  
Grey Relational ◽  
Flocculation Process ◽  
Olive Mill

Olive oil production is one of the important industrial sectors within the agro-food framework of the Mediterranean region, economically important to the people working in this sector, although there is also a threat to the environment due to residues. The main wastes of the olive oil extraction process are olive mill wastewater (OMW) and olive husks which also require proper treatment before dismissal. In this research work, the main goal is to introduce grey relational analysis, a technique for multi-response optimization, to the coagulation and flocculation process of OMW to select the optimum coagulant dosage. The coagulation and flocculation process was carried out by adding aluminum sulfate (Alum) to the waste stream in different dosages, starting from 100 to 2000 mg/L. In previous research work, optimization of this process on OMW was briefly discussed, but there is no literature available that reports the optimal coagulant dosage verified through the grey relational analysis method; therefore, this method was applied for selecting the best operating conditions for lowering a combination of multi-responses such as chemical oxygen demand (COD), total organic carbon (TOC), total phenols and turbidity. From the analysis, the 600 mg/L coagulant dosage appears to be top ranked, which obtained a higher grey relational grade. The implementation of statistical techniques in OMW treatment can enhance the efficiency of this process, which in turn supports the preparation of waste streams for further purification processes in a sustainable way.

scholarly journals Remediation of Anthracene-Contaminated Soil with Sophorolipids-SDBS-Na2SiO3 and Treatment of Eluting Wastewater

Water ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 2188
Author(s):  
Wei Li ◽  
Xiaofeng Wang ◽  
Lixiang Shi ◽  
Xianyuan Du ◽  
Zhansheng Wang
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Organic Pollutants ◽  
Aromatic Hydrocarbons ◽  
Contaminated Soil ◽  
Ring Opening ◽  
Single Factor ◽  
Elution Time ◽  
Factor B ◽  
Ring Opening Reaction ◽  
Polycyclic Aromatic

The soil pollution of polycyclic aromatic hydrocarbons (PAHs) is serious in China, which not only affects the living and growing environment of plants and animals but also has a great impact on people’s health. The use of hydrophobic organic compounds to make use of surfactant ectopic elution processing is more convenient and cheaper as a repair scheme and can effectively wash out the polycyclic aromatic hydrocarbons in the soil. Therefore, we mixed sophorolipids:sodium dodecylbenzene sulfonate (SDBS):Na2SiO3 according to the mass ratio of 1:15:150. We explored the influencing factors of high and low concentrations of PAH-contaminated soil using a single factor test and four factors at a two-level factorial design. Then, the elution wastewater was treated by ultrasonic oxidation technology and the alkali-activated sodium persulfate technology. The results showed that: (1) In the single factor test, when the elution time is 8 h, the concentration of the compounded surfactant is 1200 mg/L, the particle size is 60 mesh, the concentration of NaCl is 100 mmol/L, and the concentration of KCl is 50 mmol/L, and the effect of the PAH-contaminated soil eluted by the composite surfactant is the best. Externally added NaCl and KCl salt ions have a more obvious promotion effect on the polycyclic aromatic hydrocarbon-contaminated soil; (2) in the interaction experiment, single factor B (elution time) and D (NaCl concentration) have a significant main effect. There is also a certain interaction between factor A (concentration agent concentration) and factor D, factor B, and factor C (KCl concentration); (3) the treatment of anthracene in the eluate by ultrasonic completely mineralizes the organic pollutants by the thermal and chemical effects produced by the ultrasonic cavitation phenomenon, so that the organic pollutants in the eluate are oxidized and degraded into simple environmentally friendly small molecular substances. When the optimal ultrasonic time is 60 min and the ratio of oxidant to activator is 1:2, the removal rate of contaminants in the eluent can reach 63.7%. At the same time, the turbidity of the eluent is significantly lower than that of the liquid after centrifugal separation, indicating that oxidants can not only remove the pollutants in elution water but also remove the residual soil particulate matter; and (4) by comparing the infrared spectrum of the eluted waste liquid before and after oxidation, it can be seen that during the oxidation process, the inner part of eluent waste liquid underwent a ring-opening reaction, and the ring-opening reaction also occurred in the part of the cyclic ester group of the surfactant, which changed from a ring to non-ring.

scholarly journals Effect of WC/Ni–Cr additive on changes in the composition of an atmospheric residue in the course of cracking

2019 ◽  
Vol 17 (2) ◽  
pp. 499-508 ◽  
Author(s):  
Galina S. Pevneva ◽  
Natalya G. Voronetskaya ◽  
Nikita N. Sviridenko ◽  
Anatoly K. Golovko
Keyword(s):  
Molecular Weight ◽  
Tungsten Carbide ◽  
Aromatic Hydrocarbons ◽  
Aromatic Compounds ◽  
Low Molecular Weight ◽  
Nickel Chromium ◽  
Atmospheric Residue ◽  
Sulfur Containing ◽  
Catalytic Additive ◽  
Sulfur Containing Compounds

AbstractThe paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide–nickel–chromium (WC/Ni–Cr) catalytic additive and without it. The cracking is carried out in an autoclave at 500 °C for 30 min. The addition of the WC/Ni–Cr additive promotes the deepening of reactions of destruction not only of resins and asphaltenes, but also high molecular weight naphthene-aromatic compounds of the atmospheric residue. It is shown that the content of low molecular weight C9–C17 n-alkanes and C9–C10 alkylbenzenes rose sharply in the products of cracking with addition of WC/Ni–Cr in comparison with those produced without the additive. Alkyl- and naphthene-substituted aromatic hydrocarbons of benzene, naphthalene, phenanthrene series, polyarenes, benzo- and dibenzothiophenes are identified.

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