Influence of HLB Parameters of Surfactants on Properties of Magneto-Rheological Fluid

2010 ◽  
Vol 97-101 ◽  
pp. 843-847 ◽  
Author(s):  
Cheng Bin Du ◽  
Wei Qing Chen ◽  
Fa Xue Wan
Keyword(s):  
Magnetic Properties ◽  
Oleic Acid ◽  
Polyethylene Glycol ◽  
Rheological Properties ◽  
Magnetic Particles ◽  
Hydrophilic Lipophilic Balance ◽  
The Stability ◽  
Magneto Rheological

The hydrophilic-lipophilic balance (HLB) parameters of surfactants have a significant effect on properties of surfactants and determine the effects of surfactants. The magneto-rheological fluid (MRF) is prepared by using the two typical HLB parameters of surfactants including Polyethylene Glycol and oleic acid in order to improve the property of MRF. Polyethylene Glycol (PEG) whose HLB parameter is 20 has strong hydrophilic. Oleic acid whose HLB parameter is 1 has strong lipophilic. The results indicate that magnetic properties of magnetic particles and rheological properties of MRF can hardly be changed by adding surfactants. The sedimentary stability of MRF adding lipophilic surfactants is superior to that of MRF adding hydrophilic surfactants, and the stability of MRF adding two surfactants increases significantly.

Study of the Performance of Practical Magneto-Rheological Elastomers

2012 ◽  
Vol 430-432 ◽  
pp. 1979-1983
Author(s):  
Wei Bang Feng ◽  
Xue Yang ◽  
Zhi Qiang Lv
Keyword(s):  
Magnetic Field ◽  
Mechanical Properties ◽  
Mechanical Property ◽  
Magnetic Properties ◽  
External Magnetic Field ◽  
Magnetic Particles ◽  
Poor Performance ◽  
Electrical And Magnetic Properties ◽  
Intelligent Material ◽  
Magneto Rheological

Magneto-rheological elastomer( MR elastomer) is an emerging intelligent material made up of macromolecule polymer and magnetic particles. While a promising wide application it has in the fields of warships vibration controlling for its controllable mechanical, electrical and magnetic properties by external magnetic field, design and application of devices based on it are facing great limitations imposed by its poor performance in mechanical properties and magneto effect. Aiming at developing a practical MR elastomer, a new confecting method was proposed in this paper. Then, following this new method and using a specificly designed solidifying matrix, an amido- polyester MR elastomer was developed with its mechanical property systemically explored.

Synthesis and Characterization of Innovative Type Magneto-Rheological Fluid

2018 ◽  
Vol 18 (06) ◽  
pp. 1850041 ◽  
Author(s):  
Shreedhar Kolekar ◽  
Rajshekar V. Kurahatti ◽  
Vikram G. Kamble ◽  
Seung-Bok Choi
Keyword(s):  
Rheological Properties ◽  
Low Cost ◽  
Research Work ◽  
Suspension Systems ◽  
Carrier Liquid ◽  
Field Dependent ◽  
Electrolytic Iron Powder ◽  
Automotive Suspension ◽  
The Stability ◽  
Magneto Rheological

This research work is concerned with synthesis of an innovative type of magneto-rheological fluid (MRFluid) using edible low-cost soya bean oil as a carrier liquid with three different concentrations of electrolytic iron powder as a suspended medium and additives as a commercial grease. The field-dependent rheological properties of MRFluid samples were tested under different magnetic field conditions using rheometer. The results of the field-dependent-rheological properties of the prepared MRFluid samples show good agreement with commercial MRFluid. This directly indicates that the proposed innovative type of MRFluid can be used in automotive suspension systems, dampers, vibration control devices and so forth. Sedimentation test is also carried out in order to know the stability of the MRFluids.

scholarly journals Aqueous dispersions of epoxy oligomers: Stability and rheological properties

Chemija ◽  
2021 ◽  
Vol 32 (3-4) ◽  
Author(s):  
D. A. Busel ◽  
V. D. Koshevar ◽  
A. Zarkov ◽  
V. G. Shkadrecova ◽  
A. Kareiva
Keyword(s):  
Polyethylene Glycol ◽  
Rheological Properties ◽  
Epoxy Resins ◽  
Glycol Ether ◽  
Ionic Surfactant ◽  
Aqueous Dispersions ◽  
Epoxy Oligomers ◽  
The Stability ◽  
Epoxy Groups

In this study, the stability of the aqueous dispersions of epoxy oligomers was investigated. The following epoxy oligomers with various numbers of epoxy groups were used for the characterization: NPEL 127, NPEL 128, NPEL 134, NPPN 631, EPOXY 520 and DEG-1. A non-ionic surfactant Emulsogen LCN-287 based on alkyl polyethylene glycol ether was used as an emulsifier. The dispersions of epoxy resins were fabricated by changing the content of a non-ionic surfactant (emulsifier) in a range from 2 to 6 wt.%. It was demonstrated that the stability of aqueous emulsions depends not only on the type of resin, but also on the content of the oil phase and the concentration of the emulsifier. The rheological properties of the aqueous dispersions of epoxy oligomers were investigated as well.

Phase Change and Magneto-Rheology of a Suspension Composed of Magnetic Rod-Like Particles

2015 ◽  
Author(s):  
Akira Satoh
Keyword(s):  
Magnetic Field ◽  
Field Strength ◽  
Phase Change ◽  
Rheological Properties ◽  
Magnetic Field Strength ◽  
Magnetic Particles ◽  
Magnetic Particle ◽  
Magneto Rheological ◽  
Aggregate Structures ◽  
The Magnetic Field

Magnetic particle suspensions have a great potential as an application in engineering fields and therefore a variety of studies on these functional fluid have been conducted in various fields, including the traditional fluid engineering field and the recent bioengineering field such as an application to a drug delivery system. The main application target in the fluid engineering field may be mechanical dampers and actuators. Magneto-rheological properties significantly depend on the formation of aggregates of magnetic particles. In the present study, we focus on a ferromagnetic rod-like particle suspension to discuss the phase change of aggregate structures of magnetic rod-like particles and the magneto-rheological properties that are strongly dependent on the formation of aggregate structures. The characteristics of the phase change are mainly investigated by Monte Carlo simulations for thermodynamic equilibrium and the magneto-rheological properties are done by Brownian dynamics simulations in a simple shear flow situation. From the latter simulations, we discuss mainly the dependence of the magneto-rheological effect on the phase change of aggregate structures. In a weak applied magnetic field, magnetic rod-like particles tend to aggregate to form raft-like clusters if the magnetic particle-particle interaction is much stronger than thermal energy. If the magnetic field strength is increased, these raft-like clusters drastically dissociate into single-moving particles at a certain value of the magnetic field strength, that is, the phase change in aggregate structures arises. The net viscosity and viscosity components exhibit complex dependence on the magnetic field strength, which is mainly due to the raft-like cluster formation of magnetic particles.

A magnetic super lattice

1987 ◽  
Vol 45 ◽  
pp. 360-361 ◽  
Author(s):  
M.D. Bentzon ◽  
J. v. Wonterghem ◽  
A. Thölén
Keyword(s):  
Thermal Decomposition ◽  
Oleic Acid ◽  
Magnetic Fluid ◽  
Magnetic Particles ◽  
Carbon Film ◽  
Thick Layer ◽  
Amorphous Iron ◽  
Super Lattice ◽  
Carrier Liquid ◽  
Median Diameter

We report on the oxidation of a magnetic fluid. The oxidation results in magnetic super lattice crystals. The “atoms” are hematite (α-Fe2O3) particles with a diameter ø = 6.9 nm and they are covered with a 1-2 nm thick layer of surfactant molecules.Magnetic fluids are homogeneous suspensions of small magnetic particles in a carrier liquid. To prevent agglomeration, the particles are coated with surfactant molecules. The magnetic fluid studied in this work was produced by thermal decomposition of Fe(CO)5 in Declin (carrier liquid) in the presence of oleic acid (surfactant). The magnetic particles consist of an amorphous iron-carbon alloy. For TEM investigation a droplet of the fluid was added to benzine and a carbon film on a copper net was immersed. When exposed to air the sample starts burning. The oxidation and electron irradiation transform the magnetic particles into hematite (α-Fe2O3) particles with a median diameter ø = 6.9 nm.

Analysis of magneto rheological elastomers for energy harvesting systems

2020 ◽  
Vol 64 (1-4) ◽  
pp. 439-446
Author(s):  
Gildas Diguet ◽  
Gael Sebald ◽  
Masami Nakano ◽  
Mickaël Lallart ◽  
Jean-Yves Cavaillé
Keyword(s):  
Magnetic Field ◽  
Energy Harvesting ◽  
Shear Strain ◽  
Magnetic Induction ◽  
Magnetic Particles ◽  
Homogeneous Magnetic Field ◽  
Electrical Signal ◽  
Harvesting Systems ◽  
Dc Bias ◽  
Magneto Rheological

Magneto Rheological Elastomers (MREs) are composite materials based on an elastomer filled by magnetic particles. Anisotropic MRE can be easily manufactured by curing the material under homogeneous magnetic field which creates column of particles. The magnetic and elastic properties are actually coupled making these MREs suitable for energy conversion. From these remarkable properties, an energy harvesting device is considered through the application of a DC bias magnetic induction on two MREs as a metal piece is applying an AC shear strain on them. Such strain therefore changes the permeabilities of the elastomers, hence generating an AC magnetic induction which can be converted into AC electrical signal with the help of a coil. The device is simulated with a Finite Element Method software to examine the effect of the MRE parameters, the DC bias magnetic induction and applied shear strain (amplitude and frequency) on the resulting electrical signal.

scholarly journals Effect of Photoinitiator on Precursory Stability and Curing Depth of Thiol-Ene Clickable Gelatin

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1877
Author(s):  
Kai-Hung Yang ◽  
Gabriella Lindberg ◽  
Bram Soliman ◽  
Khoon Lim ◽  
Tim Woodfield ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Visible Light ◽  
Rheological Properties ◽  
Swelling Ratio ◽  
Sodium Persulfate ◽  
Photo Polymerization ◽  
Gelation Kinetics ◽  
The Stability ◽  
Over Time

Recent advances highlight the potential of photopolymerizable allylated gelatin (GelAGE) as a versatile hydrogel with highly tailorable properties. It is, however, unknown how different photoinitiating system affects the stability, gelation kinetics and curing depth of GelAGE. In this study, sol fraction, mass swelling ratio, mechanical properties, rheological properties, and curing depth were evaluated as a function of time with three photo-initiating systems: Irgacure 2959 (Ig2959; 320–500 nm), lithium phenyl-2,4,6-trimethylbenzoylphosphinate (LAP; 320–500 nm), and ruthenium/sodium persulfate (Ru/SPS; 400–500 nm). Results demonstrated that GelAGE precursory solutions mixed with either Ig2959 or LAP remained stable over time while the Ru/SPS system enabled the onset of controllable redox polymerization without irradiation during pre-incubation. Photo-polymerization using the Ru/SPS system was significantly faster (<5 s) compared to both Ig2959 (70 s) and LAP (50 s). Plus, The Ru/SPS system was capable of polymerizing a thick construct (8.88 ± 0.94 mm), while Ig2959 (1.62 ± 0.49 mm) initiated hydrogels displayed poor penetration depth with LAP (7.38 ± 2.13 mm) in between. These results thus support the use of the visible light based Ru/SPS photo-initiator for constructs requiring rapid gelation and a good curing depth while Ig2959 or LAP can be applied for photo-polymerization of GelAGE materials requiring long-term incubation prior to application if UV is not a concern.

scholarly journals Buffer Additives and Packaging Differentially Influence the Stability of Dyes Commonly Used in Chromovitrectomy

2016 ◽  
Vol 1 (3) ◽  
pp. 1-10
Author(s):  
Begoña Parrado Aliod ◽  
Wilfried Kugler ◽  
Tim Häring
Keyword(s):  
Polyethylene Glycol ◽  
Chemical Stability ◽  
Deuterium Oxide ◽  
Oxidative Degradation ◽  
Bromophenol Blue ◽  
Physiological Range ◽  
Vis Spectroscopy ◽  
The Stability ◽  
Acid Violet ◽  
Dye Solutions

Purpose: This study was performed to investigate the chemical stability of different dyes used in chromovitrectomy and the influence of various product parameters on it. Methods: Buffered dye solutions were prepared containing 1.5 g/L acid violet 17, 0.25 g/L brilliant blue G, 1.3 g/L bromophenol blue, and 1.5 g/L trypan blue, combined with deuterium oxide, polyethylene glycol 3350, and D-mannitol as additives. For accelerated storage testing, samples were incubated for 400 h at 80°C corresponding to 2 years according to the Van ‘t Hoff equation. After different incubation times samples were taken for UV/Vis spectroscopy, pH measurement, and osmometry. Results: Depending on dye, additive, and packaging, different solutions exhibit differences in chemical stability and hence shelf life. Packaging in syringes instead of vials increases dye stability. Additives may negatively influence important parameters, e.g. polyethylene glycol 3350 increases osmolality beyond the physiological range. Notably, acid violet 17 is chemically unstable except in D-mannitol-containing buffer, packed in syringes. However, simultaneously, D-mannitol leads to a pH shift below 7.0. Conclusion: In summary, dye solutions filled in syringes should be preferred to vials to slow down oxidative degradation. Especially acid violet 17 solutions should be used with caution because the addition of D-mannitol may contribute to pH values beyond the physiological range.

scholarly journals Assessment of Fennel Oil Microfluidized Nanoemulsions Stabilization by Advanced Performance Xanthan Gum

Foods ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 693
Author(s):  
Rubén Llinares ◽  
Pablo Ramírez ◽  
José Antonio Carmona ◽  
Luis Alfonso Trujillo-Cayado ◽  
José Muñoz
Keyword(s):  
Essential Oil ◽  
Rheological Properties ◽  
Xanthan Gum ◽  
Mechanical Energy ◽  
Physical Stability ◽  
Processing Condition ◽  
Oil In Water ◽  
Mechanical Spectra ◽  
The Stability ◽  
Fennel Oil

In this work, nanoemulsion-based delivery system was developed by encapsulation of fennel essential oil. A response surface methodology was used to study the influence of the processing conditions in order to obtain monomodal nanoemulsions of fennel essential oil using the microchannel homogenization technique. Results showed that it was possible to obtain nanoemulsions with very narrow monomodal distributions that were homogeneous over the whole observation period (three months) when the appropriate mechanical energy was supplied by microfluidization at 14 MPa and 12 passes. Once the optimal processing condition was established, nanoemulsions were formulated with advanced performance xanthan gum, which was used as both viscosity modifier and emulsion stabilizer. As a result, more desirable results with enhanced physical stability and rheological properties were obtained. From the study of mechanical spectra as a function of aging time, the stability of the nanoemulsions weak gels was confirmed. The mechanical spectra as a function of hydrocolloid concentration revealed that the rheological properties are marked by the biopolymer network and could be modulated depending on the amount of added gum. Therefore, this research supports the role of advanced performance xanthan gum as a stabilizer of microfluidized fennel oil-in-water nanoemulsions. In addition, the results of this research could be useful to design and formulate functional oil-in-water nanoemulsions with potential application in the food industry for the delivery of nutraceuticals and antimicrobials.

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