Study on Thermo-Mechanical Behaviors of Shape Memory Polymer

2009 ◽  
Vol 419-420 ◽  
pp. 497-500 ◽  
Author(s):  
Bo Zhou ◽  
Yan Ju Liu ◽  
Jin Song Leng ◽  
Tao Li
Keyword(s):  
Glass Transition ◽  
Shape Memory ◽  
Material Parameter ◽  
Shape Memory Polymer ◽  
Tensile Tests ◽  
Mechanical Analysis ◽  
New Material ◽  
Strain Relationship ◽  
Relationship Of ◽  
Parameter Function

Dynamic mechanical analysis (DMA) tests are conducted on styrene-based shape memory polymer(SMP) to investigate its glass transition behaviors. The tensile tests at various temperatures are operated to detect the stress-strain relationship of styrene-based SMP. The material elastic moduli and yielding limits at 25oC, 30oC, 40oC, and 50oC are determined according to the results of tensile test. A new material parameter function is supposed to express the glass transition behavior of styrene-based SMP. The shape memory thermo-mechanical cycle of styrene-based SMP is numerically simulated by Tobushi’s constitutive equation coupled with the new material parameter function. Numerical results show the new material parameter function can express the thermo-mechanical properties of styrene-based SMP effectively.

A GLASS TRANSITION MODEL FOR SHAPE MEMORY POLYMER AND ITS COMPOSITE

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1248-1253 ◽  
Author(s):  
BO ZHOU ◽  
YAN-JU LIU ◽  
XIN LAN ◽  
JIN-SONG LENG ◽  
SUNG-HO YOON
Keyword(s):  
Glass Transition ◽  
Shape Memory ◽  
Smart Materials ◽  
Shape Memory Polymer ◽  
Mechanical Analysis ◽  
Transition Model ◽  
Critical Temperatures ◽  
External Stimuli ◽  
Material Temperature ◽  
Fiber Fabric

As novel smart materials, shape memory polymer (SMP) and its composite (SMPC) have the ability to regain its original shape after undergoing significant deformation upon heating or other external stimuli such as light, chemic condition and so on. Their special behaviors much depends on the glass transitions due to the increasing of material temperature. Dynamic Mechanical Analysis (DMA) tests are performed on the styrene-based SMP and its carbon fiber fabric reinforced SMPC to investigate their glass transition behaviors. Three glass transition critical temperatures of SMP or SMPC are defined and a method to determine their values from DMA tests is supposed. A glass transition model is developed to describe the glass transition behaviors of SMP or SMPC based on the results of DMA tests. Numerical calculations illustrate the method determining the glass transition critical temperature is reasonable and the model can well predict the glass transition behaviors of SMP or SMPC.

Characterizing and Modeling the Free Recovery and Constrained Recovery Behavior of a Polyurethane Shape Memory Polymer

2010 ◽  
Author(s):  
Brent L. Volk ◽  
Dimitris C. Lagoudas ◽  
Duncan J. Maitland
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Shape Memory ◽  
Volume Fraction ◽  
Shape Memory Polymer ◽  
Tensile Tests ◽  
Stress Recovery ◽  
Shear Moduli ◽  
Recovery Experiment

In this work, tensile tests are performed on a polyurethane shape memory polymer for both free recovery (extension recovery at zero load) and constrained recovery (stress recovery at constant extension) conditions. The experimental characterization is conducted on an electromechanical screw driven test frame, and a laser extensometer is used in conjunction with the electromechanical frame to provide a non-contact technique for measuring the deformation of the material. The specimens are deformed, above the glass transition temperature, to 10% extension. The SMP is then cooled, at a constant value of extension, to below the glass transition temperature to ‘lock’ the temporary shape. The extension recovery at zero load as well as the stress recovery at a constant value of extension is measured during the first shape memory cycle as the SMP is heated to above its glass transition temperature. The material is observed to recover 93% of the applied deformation when heated at zero load. In addition, a stress recovery of 1.5 MPa is observed when heated while holding a constant value of deformation (10% extension). After performing the experiments, the Chen and Lagoudas model, implemented in 1-D by Volk, et al., is used to simulate and predict the experimental results. The material properties used in the model — namely the coefficients of thermal expansion, shear moduli, and frozen volume fraction — are calibrated from a single free recovery experiment. The calibrated model is then used to simulate the material response for the free recovery tests as well as predict the response for the constrained recovery condition. The model simulations agree well with the free recovery experimental data but predict a larger compressive stress than what is observed during the constrained recovery experiment.

scholarly journals Buckling and vibration analysis of shape memory laminated composite beams under axially heterogeneous in-plane loads in the glass transition temperature region

2021 ◽  
Vol 3 (4) ◽  
Author(s):  
Nilesh Tiwari ◽  
A. A. Shaikh
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Boundary Conditions ◽  
Shape Memory ◽  
Transition Region ◽  
Shape Memory Polymer ◽  
Shear Deformation Theory ◽  
Effect Of Temperature ◽  
Glass Transition Region

AbstractBuckling and vibration study of the shape memory polymer composites (SMPC) across the glass transition temperature under heterogeneous loading conditions are presented. Finite element analysis based on C° continuity equation through the higher order shear deformation theory (HSDT) is employed considering non linear Von Karman approach to estimate critical buckling and vibration for the temperature span from 273 to 373 K. Extensive numerical investigations are presented to understand the effect of temperature, boundary conditions, aspect ratio, fiber orientations, laminate stacking and modes of phenomenon on the buckling and vibration behavior of SMPC beam along with the validation and convergence study. Effect of thermal conditions, particularly in the glass transition region of the shape memory polymer, is considerable and presents cohesive relation between dynamic modulus properties with magnitude of critical buckling and vibration. Moreover, it has also been inferred that type of axial loading condition along with the corresponding boundary conditions significantly affect the buckling and vibration load across the glass transition region.

Origami-inspired shape memory dual-matrix composite structures

2019 ◽  
Vol 30 (17) ◽  
pp. 2639-2647
Author(s):  
O-Hyun Kwon ◽  
Jin-Ho Roh
Keyword(s):  
Shape Memory ◽  
Polymer Composite ◽  
Matrix Composite ◽  
Composite Structures ◽  
Shape Recovery ◽  
Shape Memory Polymer ◽  
Tensile Tests ◽  
Woven Fabrics ◽  
Morphing Structure ◽  
Composite Skins

A sandwiched morphing structure is developed using an Origami-inspired shape memory dual-matrix composite core and shape memory polymer composite skins. The geometric parameters of the morphing structure are designed to have a zero Poisson’s ratio. In addition, an analytical model is developed to analyze the three-dimensional morphing structure easily. The shape memory dual-matrix composites are fabricated with woven fabrics based on the shape memory polymers, and an epoxy matrix is used to ensure a flexible and shape-recoverable structure. The shape recoverability of the shape memory polymer composite skins is verified by measuring the shape recovery ratio at various temperatures. Based on the tensile tests for the shape memory polymer composite skins and shape memory polymer hinges, it is found that the morphing structure can be highly flexible depending on temperature. Finally, the bending and shape recovery behaviors of the morphing structure are demonstrated.

Carbon Fiber Reinforced Shape Memory Nanocomposites Incorporated With Highly Conductive Carbon Nanopaper for Electro Actuation

2013 ◽  
Author(s):  
Fei Liang ◽  
Jihua Gou ◽  
He Shen ◽  
Yunjun Xu ◽  
Bob Mabbott
Keyword(s):  
Carbon Fiber ◽  
Shape Memory ◽  
Smart Materials ◽  
Shape Memory Polymer ◽  
Flexural Modulus ◽  
Fiber Reinforcement ◽  
High Strength ◽  
Mechanical Analysis ◽  
Carbon Fiber Reinforcement ◽  
Continuous Carbon Fiber

Shape memory polymers (SMPs) are one of the most popular smart materials due to light weight and high elastic deformation capability. In this study, highly conductive carbon nanofibers paper (CNFP) was coated on the surface of SMP as a conductive layer for electro actuation of SMP. To overcome the drawback of low modulus and low strength of shape memory polymer (SMP), continuous carbon fiber reinforcement was also incorporated with SMP by autoclave processing. The dynamic mechanical analysis (DMA) result showed over 600% increase of storage modulus of SMP by introducing carbon fiber reinforcement. Also, the shape recovery time of SMP has been reduced over 150%, while the recovery ratio of SMP has been improved to 99% by incorporating with carbon fiber reinforcement. Additionally, the mechanical property degradation of SMP composites has been investigated after different electro actuation cycles. After 50 actuation cycles, the decrease of flexural modulus of SMP composites is negligible (< 2%), and the ultimate flexural strength of SMP composites only decreased 25%. The SMP composite shows high strength and modulus, and good durability.

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