Study on Utilization of Silica-Calcium Tailings in Concrete

2014 ◽  
Vol 599 ◽  
pp. 93-97
Author(s):  
Xiao Wu Tian ◽  
Wei Guo Shen ◽  
Lai Shan ◽  
Liang Hong Cao ◽  
Qing Lan ◽  
...  

The large production of tailings has caused soil, water and air pollution and serious potential safety hazard. The composition, particle morphology, particle size distribution of the silica-calcium tailings are investigated to assess the feasibility of using it in concrete in this paper. The silica-calcium tailings are mainly composed of quartz, calcite and dolomite. The results show that the tailings powder can stimulate the hydration of cement and fill the gradation gap between fine aggregate and cementitious materials in concrete as micronized sand to meet the requirements of concrete. The incorporation of silica-calcium tailings in concrete reduces the ultimate total shrinkage, autogenous shrinkage and drying shrinkage at early age.

2021 ◽  
Author(s):  
Oorkalan A ◽  
Chithra S

Abstract The present study investigates the properties of RPC developed using low cost eco-friendly materials such as pyrogenic silica (PS) and coir pith (CP) fine aggregates. This study investigates the effects of PS as silica fume replacement which is the main constituent for the production of reactive powder concrete which contained coir pith as a fine aggregate replacement instead of quartz sand up to 25%. The use of silica fume increases the particle packing density of RPC but increases the shrinkage phenomenon in RPC due to the minimum w/b ratio adopted. Therefore, in this research PS is used as a partial substitute for SF up to 30% and its effect on the mechanical and durability properties of coir pith containing RPC is studied. The test results showed that the mechanical strength values decreased with an increase in the addition of CP aggregate beyond 5% whereas the decrement in compressive strength was partially reduced when PS is used as silica fume replacement up to a maximum of 30%. The chloride penetration resistance was also improved with increasing PS substitution in RPC containing CP aggregates. The autogenous shrinkage and drying shrinkage were also significantly reduced due to the internal curing ability of the CP aggregates in combination with PS. The development of dense CSH gels from hydration is also evident from low CaO/ SiO2 ratio obtained from the EDS analysis. Hence the combination of PS with CP aggregates can reduce the shrinkage characteristics of RPC thereby providing eco-friendly sustainable concrete at low cost.


2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Shuncheng Xiang ◽  
Yingli Gao ◽  
Caijun Shi

Three polycarboxylates with different comb structures (i.e., the same degree of polymerization in side chains but different main chains) were synthesized via radical polymerization reaction at room temperature. The effect of polycarboxylates on the surface tension and the flowability in cement pastes was determined. The best product was selected to study its effects on the hydration heat evolution, compressive strength, autogenous shrinkage, and drying shrinkage of cement pastes with different kinds and contents of supplementary cementitious materials. The results showed that with the increase of molar ratio between AA and TPEG to 6 : 1, we could synthesis the best product. When the water-binder ratio was 0.4, with the increase of polycarboxylates, the cement hydration heat evolution had been slowed down, and the more the dosage was, the more obvious the effect was. Adding supplementary cementitious materials to cement under the same experimental conditions also played a mitigation role in slowing down the hydration heat. When the water-binder ratio was 0.3, supplementary cementitious materials could increase the strength of cement by 24.5% in maximum; its autogenous shrinkage and drying shrinkage could be decreased, respectively, by 60.1% and 21.9% in the lowest.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5614
Author(s):  
Zhiqiang Zhang ◽  
Zhilu Zhang ◽  
Shaoning Yin ◽  
Linwen Yu

The increasing annual emissions of iron ore tailings have proved a great threat to the natural environment, and the shortage of natural river sand, as well as the pursuit of sustainable development materials, provides motivation to reuse iron ore tailings as a fine aggregate in concrete. Due to the significantly different properties of iron tailings sand compared with natural river sand—such as the higher density, higher content of limestone particles smaller than 75 μm and its rough and angular shape—concretes prepared with iron tailings sand show remarkably higher shrinkage. This study presents the shrinkage characterization and shrinkage-reducing efficiency of three different methods on iron tailings, sand concrete and river sand concrete. The internal humidity was also monitored to reveal the shrinkage-reducing mechanism. The obtained results indicated that the autogenous and total shrinkage of iron tailings sand concrete were 9.8% and 13.3% higher than the river sand concrete at the age of 90 d, respectively. The shrinkage reducing agent (SRA) was the most effective shrinkage reducing method for river sand concrete, while for iron tailings sand concrete, super absorbent polymer (SAP) and controlled permeable formwork liner (CPFL) it worked best on autogenous shrinkage and drying shrinkage, respectively. Furthermore, the shrinkage mitigation strategies worked earlier for the drying shrinkage behavior of iron tailings sand concrete, while no such condition could be found for autogenous shrinkage.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Dongsheng Zhang ◽  
Pengfei Han ◽  
Qiuning Yang ◽  
Mingjie Mao

China is the world’s largest emitter of fly ash, an industrial by-product of coal combustion. Motivated towards greener development, China’s engineering industries must determine how to effectively utilize this by-product, while ensuring environmental and public safety protections. This study investigated the use of fly ash instead of fine aggregate in concrete mixtures with a focus on concrete shrinkage. A series of experiments were performed in which fly ash substitution levels, water-binder ratios, and ambient humidities were each respectively and exclusively varied to determine changes in the concrete’s drying and autogenous shrinkages. Experimental results indicated that the substitution of fly ash consistently decreased the drying shrinkage relative to ordinary concrete; a substitution level of 25% optimally reduced the drying shrinkage by 20.81%. A substitution level of 15% decreased the autogenous shrinkage relative to ordinary concrete, whereas higher levels (25, 35, and 45%) increased it. Ambient humidities also affected the concrete shrinkage, but the water-to-binder ratio effects were negligible. Drying shrinkage largely occurred before 28 d, whereas autogenous shrinkage continued after 28 d. Based on these experimental results, we evaluated common theoretical shrinkage models and subsequently developed a modified shrinkage model for application to concrete containing fly ash as fine aggregate.


Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3312 ◽  
Author(s):  
Sung Choi ◽  
Gum-Sung Ryu ◽  
Kyeong-Taek Koh ◽  
Gi-Hong An ◽  
Hyeong-Yeol Kim

In this study, a calcium sulfoaluminate-based expansive additive (0%, 2.5%, 5.0%, and 7.5% by the mass of the binder) was added to compensate for the shrinkage of alkali-activated material (AAM) mortar. Modulus of elasticity curves based on the ACI 209 model were derived for the AAM mortar mixed with the additive by measuring the compressive strength and modulus of elasticity. Moreover, autogenous shrinkage and total shrinkage were measured for 150 days, and drying shrinkage was calculated by excluding autogenous shrinkage from total shrinkage. For the autogenous and drying shrinkage of AAM mortar, shrinkage curves by age were obtained by deriving material constants using the exponential function model. Finally, shrinkage stress was calculated using the modulus of elasticity of the AAM mortar and the curves obtained using the shrinkage model. The results showed that the calcium sulfoaluminate-based expansive additive had an excellent compensation effect on the drying shrinkage of AAM mortar, but the effect was observed only at early ages when the modulus of elasticity was low. From a long-term perspective, the shrinkage compensation effect was low when the modulus of elasticity was high, and thus, shrinkage stress could not be reduced.


2017 ◽  
Vol 726 ◽  
pp. 521-526
Author(s):  
Di Zou ◽  
Lian Zhen Xiao ◽  
Wen Chong Shi

The cement-silica fume blended pastes were prepared with different silica fume (SF) dosages of 0%, 5%, 10%, and 15% at different water-binder ratios (W/B) of 0.4 and 0.5. The autogenous shrinkage (AS) and the drying shrinkage (DS) of the paste samples in the hydration period of 7d (168 hours) were measured by a new measurement technique to explore the influence of W/B and silica fume incorporation on the shrinkage in early age. The study results can provide reference for high performance concrete mix design.It is found that ether the AS or the DS of the paste samples shows a similar pattern, and the AS development with hydration time appeared a temporary expansion period after a rapid growth, especially in the samples at a higher W/B or with a lower SF content. However, the DS development did not occur obvious expansion period.Three development trends were obtained for the factors of W/B and SF content. 1) the AS and DS of the pastes mainly occurred in early ages. The lower W/B, the shorter the rapid growth periods, and the higher the shrinkage ratio of 1d to 7d. For the pastes with W/B of 0.4, the AS grew rapidly in 1d and the DS grew rapidly in the first 10h, and the AS value in 1d reached to 63.6% of 7d, and the DS value reached to 62.1% of 7d in the paste with SF of 10%. For the pastes with W/B of 0.5, the rapid growth periods of the AS and DS respectively extended to 30~33h and 12h, and the AS value in 1d reached to 60.0% of 7d, and the DS value reached to 57.2% of 7d in the paste with SF of 10%. 2) The lower W/B, the higher the shrinkage ratio of the AS to the DS. When the SF dosage is 10%, the ratio of the AS value to the DS value of 7d is 21.66%~21.15% for W/B of 0.4, and only 6.06%~5.78% for the W/B of 0.5. 3) the higher SF content results in the higher AS in cement-SF blended pastes. For the pastes with W/B of 0.4, the ratio of the AS to the DS increased from 6.98% to 30.16% with the increase of content of SF from 5% to 15% in 1d, from 15.1% to 28.19% in 3d, from 16.78% to 26.16% in 7d.


Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 979
Author(s):  
Jung Heum Yeon

This study reports the results of a series of experiments, particularly paying attention to the early-age behavior and response of hardening mortars incorporating different types and contents of superabsorbent polymer (SAP) under autogenous (sealed) and drying shrinkage (unsealed) conditions. To achieve this primary aim, the effects of SAP type (i.e., cross-linking density and grain size) and content on the internal relative humidity (IRH) changes and corresponding free shrinkage behavior, restrained stress development, and cracking potential of the mortar were extensively measured and analyzed, along with their strength and set time properties. The results of this study have shown that the internal curing (IC) via SAP effectively counteracted the early-age residual stress build-up due to autogenous shrinkage, as many other former studies described. No or little tensile residual stresses due to autogenous shrinkage took place when more than 0.4% SAP was added, regardless of the SAP type. However, it should be mentioned that the addition of SAP, irrespective of its content and type, hardly improved the shrinkage cracking resistance of the mortar when directly exposed to drying environment at early ages.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1647
Author(s):  
Xiaofeng Han ◽  
Hua Fu ◽  
Gege Li ◽  
Li Tian ◽  
Chonggen Pan ◽  
...  

In order to better predict the development of shrinkage deformation of steam-cured concrete mixed with slag, a deformation-temperature-humidity integrated model test, a hydration heat test, and an elastic modulus test were performed. The effects of the steam-curing process and the content of slag on shrinkage deformation, hydration degree and elastic modulus of concrete were studied. The results indicate that during the steam-curing process, the concrete has an “expansion-shrinkage” pattern. After the steam curing, the deformation of concrete is dominated by drying shrinkage. After the addition of slag, the shrinkage deformation of steam-cured concrete is increased. The autogenous shrinkage increases by 0.5–12%, and the total shrinkage increases by 1.5–8% at 60 days. At the same time, slag reduces the hydration degree of steam-cured concrete and modulus of elasticity. A prediction model for the hydration degree of steam-cured concrete is established, which can be used to calculate the degree of hydration at any curing age. Based on the capillary tension generated by the capillary pores in concrete, an integrated model of autogenous shrinkage and total shrinkage is established with the relative humidity directly related to the water loss in the concrete as the driving parameter. Whether the shrinkage deformation is caused by hydration reaction or the external environment, this model can better predict the shrinkage deformation of steam-cured concrete.


Author(s):  
Andina Sprince ◽  
Leonids Pakrastinsh

The aim of this paper was to study the behaviour of new high-performance fibre-reinforced cement composite materials (FRCC) that are reinforced with polyvinyl alcohol (PVA) fibres. The shrinkage deformations at early age, the compressive strength and modulus of elasticity of the new compositions had been determined. Test results shows that the addition of PVA fiber 1.10% and 0.55% by weight of the cement has negligible influence on concrete drying shrinkage, however, it is affect the concrete plastic and autogenous shrinkage. The results of the experiments permitted the prediction of long-term deformations of the concrete. Wider use of this material permit the construction of sustainable next generation structures with thin walls and large spans that cannot be built using the traditional concrete.


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