Liquid Membrane System for Extraction and Electrodeposition of Copper(II)

2020 ◽  
Vol 850 ◽  
pp. 22-27
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Liquid Membrane ◽  
Complete Removal ◽  
Membrane System ◽  
Feed Solution ◽  
Hydrochloric Acid Concentration ◽  
Fine Grained ◽  
Fine Grained Structure ◽  
Membrane Type ◽  
Effective Transfer ◽  
Sulfuric Acid Solutions

The extraction of copper (II) ions using di (2-ethylhexyl) phosphoric acid – based liquid membranes during a galvanostatic electrodialysis-electrolysis process was studied. Effects of the current density, copper (II) and hydrochloric acid concentration in the feed solution, carrier and admixture concentration in the liquid membrane, type of acid in the catholyte were studied, and the optimal conditions were determined. A practically complete removal of copper (II) from the feed solution containing 0.01 M CuCl2 was achieved during 3.0 −4.0 h of electrodialysis. A possibility of effective transfer and electrodeposition of copper (II) from dilute solutions of sulfuric, hydrochloric, perchloric, nitric and acetic acids was shown. Adherent copper coatings with a fine-grained structure were obtained from dilute sulfuric acid solutions. A maximum stripping degree into the catholyte of 88 % and an electrodeposition degree of 73 % were achieved in the studied system.

Electrodeposition of Cobalt and Lead in the Hybrid Liquid Membrane - Electrodialysis-Electrolysis Process

2016 ◽  
Vol 721 ◽  
pp. 399-403 ◽  
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Liquid Membrane ◽  
Nitric Acid Concentration ◽  
Feed Solution ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Dilute Solutions ◽  
Cathodic Electrodeposition ◽  
Fine Grained ◽  
Fine Grained Structure ◽  
Effective Transfer

A novel method for Co (II) and Pb (II) recovery from acidic solutions is presented. The extraction of Co (II) and Pb (II) ions using the bulk liquid membranes during a galvanostatic electrodialysis process accompanied by cathodic electrodeposition of the metals was studied. Solutions of di (2-ethylhexyl) phosphoric acid (D2EHPA) with admixtures of tri-n-octylamine (TOA) in 1,2-dichloroethane were used as the liquid membranes. Effects of current density, Co (II) and Pb (II) concentrations in the feed solution, sulfuric or nitric acid concentration in the feed solution, D2EHPA and TOA concentration in the liquid membrane, of the type and concentration of acid in the cathodic solution were studied, and optimal conditions were determined. It is demonstrated that a practically complete (98-99%) removal of Co (II) and Pb (II) from the feed solutions containing 0.01 mol∙L-1 CoSO4 or 0.01 mol∙L-1 Pb (NO3)2 is achieved during 1.0 − 4.0 h of electrodialysis. A possibility of effective transfer of Pb (II) into dilute solutions of perchloric and nitric acids was demonstrated. The liquid membranes ensure the recovery of Co (II) ions into dilute solutions of perchloric, sulphuric, hydrochloric and nitric acids. Adherent, compact cobalt and lead electrodeposits with a fine-grained structure were obtained in the studied systems.

Membrane Extraction and Electrodeposition of Zinc(II) and Lead(II) during Electrodialysis

2019 ◽  
Vol 800 ◽  
pp. 175-180 ◽  
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Sulfuric Acid ◽  
Complete Removal ◽  
Membrane Extraction ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Fine Grained ◽  
Platinum Cathode ◽  
Fine Grained Structure ◽  
Effective Transfer ◽  
Acetic Acids

The processes of Zn2+ and Pb2+ extraction by bulk liquid membranes containing di (2-ethylhexyl) phosphoric acid and tri-n-octylamine during galvanostatic electrodialysis accompanied by electrodeposition of the metals were studied. The effects of the current density as well as of composition of the liquid membranes and aqueous solutions on the rate of zinc (II) and lead (II) transport were determined. It was demonstrated that a practically complete removal of zinc (II) and more than 90 % extraction of lead (II) from the feed solutions containing 0.01 M ZnSO4 or 0.01 M Pb (NO3)2 was achieved during 1.0 − 5.0 h of electrodialysis. A possibility of effective transfer of zinc (II) into dilute solutions of sulphuric, hydrochloric, perchloric and acetic acids was shown. Adherent zinc and lead coatings with a fine-grained structure have been deposited on the platinum cathode. More than 75% of zinc (II) and about 60% of lead (II) was deposited from solutions of sulfuric acid and perchloric acid, respectively.

Possibilities of chromium (III) separation from acid solution using the double-carrier supported liquid membrane (DCSLM)

2017 ◽  
Vol 75 (10) ◽  
pp. 2358-2368 ◽  
Author(s):  
Jakub Rajewski ◽  
Paulina Rajewska
Keyword(s):  
Aqueous Solutions ◽  
Liquid Membrane ◽  
Phosphinic Acid ◽  
Membrane System ◽  
Feed Solution ◽  
Supported Liquid Membrane ◽  
Acid Solutions ◽  
Membrane Phase ◽  
High Exhaustion ◽  
Effective Carrier

This paper describes the problem of recovery and reusing chromium from aqueous solutions. The authors studied a novel double-carrier supported liquid membrane system (DCSLM) with di(2-ethylhexyl) phosphoric acid (D2EHPA) and bis(2,4,4-trimethyl) phosphinic acid (Cyanex272) as a carrier of Cr(III) ions as a method to separate chromium (III) from acid solutions. As a result, they confirmed that the presence of two carriers in the DCSLM with the most effective carrier concentration ratios, leads to approximately three times shorter pertraction, compared to a process conducted with the D2EHPA only. It was found that synergistic effect is independent of the initial concentration of chromium in the feed solution. Higher initial concentrations of Cr(III) ≥ 0.01 mol dm−3 cause high ‘exhaustion’ of active carrier molecules at the interface. Moreover, the authors observed the increase in viscosity in the membrane phase and process inhibition. It was found that efficiency of separation of chromium ions from aqueous solutions using a liquid membrane depends on the transport rate for these ions in the membrane (ions pertraction). Therefore, it was concluded that the pertraction stage of the Cr(III) ions limits the efficiency of the whole separation process.

scholarly journals Removal of methylene blue dye from wastewater by using supported liquid memberane technology

2016 ◽  
Vol 18 (2) ◽  
pp. 26-30 ◽  
Author(s):  
Muhammad Waqar Ashraf
Keyword(s):  
Methylene Blue ◽  
Acid Concentration ◽  
Polyvinylidene Fluoride ◽  
Liquid Membrane ◽  
Feed Solution ◽  
Polymeric Films ◽  
Blue Dye ◽  
Hydrochloric Acid Concentration ◽  
Methylene Blue Dye ◽  
Strip Solution

Abstract The present work describes the application of Supported Liquid Membrane (SLM) technology towards the removal and recovery of a cationic dye (Methylene Blue) from aqueous solutions. Natural and non-toxic vegetable oils have been impregnated on microporous polymeric films of polyvinylidene fluoride (PVDF) to constitute a liquid membrane. Different parameters affecting the transport, like pH of feed solution, acid concentration in the strip solution, initial dye concentration, oil types and stirring speeds have been investigated. Highest value of flux (1.7 × 10−5 mg/cm2/sec1) for methylene blue dye was achieved with sunflower oil impregnated on the PVDF support, with pH maintained at 12 in the feed solution and 0.3 M hydrochloric acid concentration in the strip solution. It took 6 hours to transport maximum amount of dye under optimum conditions.

scholarly journals Effect of Microstructure and Notches on the Fracture Toughness of Medium Carbon Steel

1970 ◽  
Vol 3 (1) ◽  
pp. 15-22 ◽  
Author(s):  
SK Nath ◽  
Uttam Kr Das
Keyword(s):  
Fracture Toughness ◽  
Carbon Steel ◽  
Tensile Specimen ◽  
Medium Carbon Steel ◽  
Notch Angle ◽  
Medium Carbon ◽  
Fine Grained ◽  
Keywords Fracture ◽  
Fine Grained Structure ◽  
Marine Engineering

Fracture toughness (K1C) of medium carbon steel (0.5% C) has been determined by round notched tensile specimen. Two notch diameters (5.6mm and 4.2mm) and three notch angles (α) namely 45°, 60° and 75° have been used to observe the effect of notch diameters and notch angle on fracture toughness of the steel. By heat treatment the microstructure of the steel is also varied and its effect on the fracture toughness is also observed. It has been found that fine grained structure improves fracture toughness. Lower notch diameter and higher notch angle show higher value of K1C. Keywords: Fracture toughness, microstructure, notch, heat treatmentDOI: 10.3329/jname.v3i1.925 Journal of Naval Architecture and Marine Engineering 3(2006) 15-22

A Study on Nanocrystalline Nickel Parts Prepared by Jet Electrodeposition

2010 ◽  
Vol 37-38 ◽  
pp. 64-67
Author(s):  
Jin Song Chen ◽  
Yin Hui Huang ◽  
Bin Qiao ◽  
Jian Ming Yang ◽  
Yi Qiang He
Keyword(s):  
Dimensional Accuracy ◽  
Processing Parameters ◽  
X Ray Diffraction ◽  
Scanning Microscope ◽  
Nanocrystalline Nickel ◽  
X Ray ◽  
Fine Grained ◽  
Average Grain Size ◽  
Jet Electrodeposition ◽  
Fine Grained Structure

The principles of jet electrodeposition orientated by rapid prototyping were introduced. The nanocrystalline nickel parts with simple shape were fabricated using jet electrodeposition. The microstructure and phase transformation of nanocrystalline nickel were observed under the scanning microscope and X-ray diffraction instrument. The results show that the jet electrodeposition can greatly enhance the limited current density, fine crystalline particles and improve deposition quality. The nickel parts prepared by jet electrodeposition own a fine-grained structure (average grain size 25.6nm) with a smooth surface and high dimensional accuracy under the optimum processing parameters.

Electrodeposited Nanocrystalline Nickel Parts

2012 ◽  
Vol 201-202 ◽  
pp. 1102-1105
Author(s):  
Jin Song Chen ◽  
Jian Ming Yang
Keyword(s):  
Rapid Prototyping ◽  
Dimensional Accuracy ◽  
Processing Parameters ◽  
Nanocrystalline Nickel ◽  
Fine Grained ◽  
Average Grain Size ◽  
Machined Parts ◽  
Jet Electrodeposition ◽  
Fine Grained Structure ◽  
Metallic Parts

The principles of jet electrodeposition orientated by rapid prototyping were introduced , The nanocrystalline nickel parts with simple shape were fabricated using jet electrodeposition oriented by rapid prototyping. The microstructure and phase transformation of nanocrystalline nickel were observed under the scanning microscope and X-ray diffraction instrument . The results show that the successful fabrication of metallic parts demonstrates the potential of the jet electrodeposition process for prototyping technology . The jet electrodeposition can greatly enhance the limited current density, fine crystalline particles and improve deposition quality. The nickel parts prepared by jet electrodeposition own a fine-grained structure( average grain size 25.6nm) with a smooth surface and high dimensional accuracy under the optimum processing parameters..The dimensional accuracy as well as the surface quality of metallic parts and tools manufactured using jet electrodeposition techniques still lag far behind those of conventionally machined parts.

Transient peak membrane potential in a liquid membrane system generated by pH jump: Non-linear response to perturbation

1987 ◽  
Vol 17 (2) ◽  
pp. 193-203 ◽  
Author(s):  
Kazuo Nomura ◽  
Shao-Mu Ma ◽  
Hiroshi Kamaya ◽  
Issaku Ueda ◽  
Sheng H. Lin
Keyword(s):  
Membrane Potential ◽  
Linear Response ◽  
Liquid Membrane ◽  
Membrane System ◽  
Non Linear ◽  
Ph Jump
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