Membrane Extraction and Electrodeposition of Zinc(II) and Lead(II) during Electrodialysis

2019 ◽  
Vol 800 ◽  
pp. 175-180 ◽  
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Sulfuric Acid ◽  
Complete Removal ◽  
Membrane Extraction ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Fine Grained ◽  
Platinum Cathode ◽  
Fine Grained Structure ◽  
Effective Transfer ◽  
Acetic Acids

The processes of Zn2+ and Pb2+ extraction by bulk liquid membranes containing di (2-ethylhexyl) phosphoric acid and tri-n-octylamine during galvanostatic electrodialysis accompanied by electrodeposition of the metals were studied. The effects of the current density as well as of composition of the liquid membranes and aqueous solutions on the rate of zinc (II) and lead (II) transport were determined. It was demonstrated that a practically complete removal of zinc (II) and more than 90 % extraction of lead (II) from the feed solutions containing 0.01 M ZnSO4 or 0.01 M Pb (NO3)2 was achieved during 1.0 − 5.0 h of electrodialysis. A possibility of effective transfer of zinc (II) into dilute solutions of sulphuric, hydrochloric, perchloric and acetic acids was shown. Adherent zinc and lead coatings with a fine-grained structure have been deposited on the platinum cathode. More than 75% of zinc (II) and about 60% of lead (II) was deposited from solutions of sulfuric acid and perchloric acid, respectively.

Electrodeposition of Cobalt and Lead in the Hybrid Liquid Membrane - Electrodialysis-Electrolysis Process

2016 ◽  
Vol 721 ◽  
pp. 399-403 ◽  
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Liquid Membrane ◽  
Nitric Acid Concentration ◽  
Feed Solution ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Dilute Solutions ◽  
Cathodic Electrodeposition ◽  
Fine Grained ◽  
Fine Grained Structure ◽  
Effective Transfer

A novel method for Co (II) and Pb (II) recovery from acidic solutions is presented. The extraction of Co (II) and Pb (II) ions using the bulk liquid membranes during a galvanostatic electrodialysis process accompanied by cathodic electrodeposition of the metals was studied. Solutions of di (2-ethylhexyl) phosphoric acid (D2EHPA) with admixtures of tri-n-octylamine (TOA) in 1,2-dichloroethane were used as the liquid membranes. Effects of current density, Co (II) and Pb (II) concentrations in the feed solution, sulfuric or nitric acid concentration in the feed solution, D2EHPA and TOA concentration in the liquid membrane, of the type and concentration of acid in the cathodic solution were studied, and optimal conditions were determined. It is demonstrated that a practically complete (98-99%) removal of Co (II) and Pb (II) from the feed solutions containing 0.01 mol∙L-1 CoSO4 or 0.01 mol∙L-1 Pb (NO3)2 is achieved during 1.0 − 4.0 h of electrodialysis. A possibility of effective transfer of Pb (II) into dilute solutions of perchloric and nitric acids was demonstrated. The liquid membranes ensure the recovery of Co (II) ions into dilute solutions of perchloric, sulphuric, hydrochloric and nitric acids. Adherent, compact cobalt and lead electrodeposits with a fine-grained structure were obtained in the studied systems.

Liquid Membrane System for Extraction and Electrodeposition of Copper(II)

2020 ◽  
Vol 850 ◽  
pp. 22-27
Author(s):  
Tatiana Sadyrbaeva
Keyword(s):  
Liquid Membrane ◽  
Complete Removal ◽  
Membrane System ◽  
Feed Solution ◽  
Hydrochloric Acid Concentration ◽  
Fine Grained ◽  
Fine Grained Structure ◽  
Membrane Type ◽  
Effective Transfer ◽  
Sulfuric Acid Solutions

The extraction of copper (II) ions using di (2-ethylhexyl) phosphoric acid – based liquid membranes during a galvanostatic electrodialysis-electrolysis process was studied. Effects of the current density, copper (II) and hydrochloric acid concentration in the feed solution, carrier and admixture concentration in the liquid membrane, type of acid in the catholyte were studied, and the optimal conditions were determined. A practically complete removal of copper (II) from the feed solution containing 0.01 M CuCl2 was achieved during 3.0 −4.0 h of electrodialysis. A possibility of effective transfer and electrodeposition of copper (II) from dilute solutions of sulfuric, hydrochloric, perchloric, nitric and acetic acids was shown. Adherent copper coatings with a fine-grained structure were obtained from dilute sulfuric acid solutions. A maximum stripping degree into the catholyte of 88 % and an electrodeposition degree of 73 % were achieved in the studied system.

Carrier‐Mediated Transport of Amino Acids Through Bulk Liquid Membranes

2004 ◽  
Vol 39 (16) ◽  
pp. 3821-3838 ◽  
Author(s):  
R. Bucci ◽  
S. Canepari ◽  
E. Cardarelli ◽  
A. M. Girelli ◽  
A. Pietrodangelo ◽  
...  
Keyword(s):  
Amino Acids ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Carrier Mediated Transport

scholarly journals Effect of Microstructure and Notches on the Fracture Toughness of Medium Carbon Steel

1970 ◽  
Vol 3 (1) ◽  
pp. 15-22 ◽  
Author(s):  
SK Nath ◽  
Uttam Kr Das
Keyword(s):  
Fracture Toughness ◽  
Carbon Steel ◽  
Tensile Specimen ◽  
Medium Carbon Steel ◽  
Notch Angle ◽  
Medium Carbon ◽  
Fine Grained ◽  
Keywords Fracture ◽  
Fine Grained Structure ◽  
Marine Engineering

Fracture toughness (K1C) of medium carbon steel (0.5% C) has been determined by round notched tensile specimen. Two notch diameters (5.6mm and 4.2mm) and three notch angles (α) namely 45°, 60° and 75° have been used to observe the effect of notch diameters and notch angle on fracture toughness of the steel. By heat treatment the microstructure of the steel is also varied and its effect on the fracture toughness is also observed. It has been found that fine grained structure improves fracture toughness. Lower notch diameter and higher notch angle show higher value of K1C. Keywords: Fracture toughness, microstructure, notch, heat treatmentDOI: 10.3329/jname.v3i1.925 Journal of Naval Architecture and Marine Engineering 3(2006) 15-22

A Study on Nanocrystalline Nickel Parts Prepared by Jet Electrodeposition

2010 ◽  
Vol 37-38 ◽  
pp. 64-67
Author(s):  
Jin Song Chen ◽  
Yin Hui Huang ◽  
Bin Qiao ◽  
Jian Ming Yang ◽  
Yi Qiang He
Keyword(s):  
Dimensional Accuracy ◽  
Processing Parameters ◽  
X Ray Diffraction ◽  
Scanning Microscope ◽  
Nanocrystalline Nickel ◽  
X Ray ◽  
Fine Grained ◽  
Average Grain Size ◽  
Jet Electrodeposition ◽  
Fine Grained Structure

The principles of jet electrodeposition orientated by rapid prototyping were introduced. The nanocrystalline nickel parts with simple shape were fabricated using jet electrodeposition. The microstructure and phase transformation of nanocrystalline nickel were observed under the scanning microscope and X-ray diffraction instrument. The results show that the jet electrodeposition can greatly enhance the limited current density, fine crystalline particles and improve deposition quality. The nickel parts prepared by jet electrodeposition own a fine-grained structure (average grain size 25.6nm) with a smooth surface and high dimensional accuracy under the optimum processing parameters.

Electrodeposited Nanocrystalline Nickel Parts

2012 ◽  
Vol 201-202 ◽  
pp. 1102-1105
Author(s):  
Jin Song Chen ◽  
Jian Ming Yang
Keyword(s):  
Rapid Prototyping ◽  
Dimensional Accuracy ◽  
Processing Parameters ◽  
Nanocrystalline Nickel ◽  
Fine Grained ◽  
Average Grain Size ◽  
Machined Parts ◽  
Jet Electrodeposition ◽  
Fine Grained Structure ◽  
Metallic Parts

The principles of jet electrodeposition orientated by rapid prototyping were introduced , The nanocrystalline nickel parts with simple shape were fabricated using jet electrodeposition oriented by rapid prototyping. The microstructure and phase transformation of nanocrystalline nickel were observed under the scanning microscope and X-ray diffraction instrument . The results show that the successful fabrication of metallic parts demonstrates the potential of the jet electrodeposition process for prototyping technology . The jet electrodeposition can greatly enhance the limited current density, fine crystalline particles and improve deposition quality. The nickel parts prepared by jet electrodeposition own a fine-grained structure( average grain size 25.6nm) with a smooth surface and high dimensional accuracy under the optimum processing parameters..The dimensional accuracy as well as the surface quality of metallic parts and tools manufactured using jet electrodeposition techniques still lag far behind those of conventionally machined parts.

Structure, Texture and Mechanical Properties through the Section of the Hot-Extruded Tube of Titanium Alloy PT-1M

2020 ◽  
Vol 989 ◽  
pp. 139-144 ◽  
Author(s):  
F.V. Vodolazskiy ◽  
N.A. Barannikova ◽  
Anatoly G. Illarionov
Keyword(s):  
Titanium Alloy ◽  
Extrusion Direction ◽  
Hot Extrusion ◽  
Tangential Direction ◽  
Primary Recrystallization ◽  
Recrystallization Temperature ◽  
Fine Grained ◽  
Surface Areas ◽  
Α Phase ◽  
Fine Grained Structure

The study considers the formation of the structure, texture, and hardness of hot extruded tube of titanium alloy PT-1M. It is shown that hot extrusion at 840 °C, which is higher than the α-phase recrystallization temperature, results to the development of dynamic and primary recrystallization processes and ensures the formation of homogeneous and fine-grained structure through-out the cross section with a two-component tangential texture (0001)TD<100>ED+(0001)TD<110>ED (TD – tangential direction, ED – extrusion direction) and hardness of 155 HV. It has been established that a higher cooling rate of the surface areas of the tube after extrusion results to a less active development of recrystallization processes, which lead to the formation of a finer granular structure near the outer surface. This weakens recrystallization component of (0001)TD<110>ED, compared to other areas of the tube.

The Effect of Preliminary Mechanical Activation on the Structure and Mechanical Properties of Ni3Al+B Material Obtained by SPS

2017 ◽  
Vol 743 ◽  
pp. 19-24 ◽  
Author(s):  
Lilia I. Shevtsova ◽  
Anatoliy A. Bataev ◽  
Vyacheslav I. Mali ◽  
Maksim A. Esikov ◽  
Veronika V. Sun Shin Yan ◽  
...  
Keyword(s):  
Mechanical Activation ◽  
Bending Strength ◽  
Stoichiometric Composition ◽  
Initial Mixture ◽  
Optical Microscope ◽  
Fine Grained ◽  
Plasma Sintering ◽  
Fine Grained Structure ◽  
Spark Plasma ◽  
Almost All

In the present study, a mixture of powders (87.9 at.% Ni, 12 at.% Al, 0.1 at.% B) was used as the initial material to produce sintered Ni3Al + B alloy. Spark Plasma Sintering (SPS) method was used to compact the powder. The powder mixtures were previously prepared in two ways: mixing the initial powders in a mortar (М1) and mechanical activation (М2). The microstructure was observed using optical microscope (OM). The addition of small amount of boron to the initial mixture of nickel and aluminum improves the density of the sintered Ni3Al intermetallic compound (98.8%). The results of density, bending and microhardness tests showed, that the provisional three-minute mechanical activation improves almost all properties of the sintered material. The compact obtained by SPS by M2 contributes to the formation of a homogeneous fine-grained structure of the material. It leads to further increase in flexural bending strength up to 2200 MPa. This value is almost 8 times the strength of the intermetallic Ni3Al stoichiometric composition obtained by SPS.

scholarly journals Transport and Separation of the Silver Ion with n–decanol Liquid Membranes Based on 10–undecylenic Acid, 10–undecen–1–ol and Magnetic Nanoparticles

Membranes ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 936
Author(s):  
Gheorghe Nechifor ◽  
Florentina Mihaela Păncescu ◽  
Paul Constantin Albu ◽  
Alexandra Raluca Grosu ◽  
Ovidiu Oprea ◽  
...  
Keyword(s):  
Magnetic Nanoparticles ◽  
Membrane Separation ◽  
Silver Ions ◽  
Silver Ion ◽  
Bulk Liquid ◽  
Liquid Membranes ◽  
Gravimetric Analysis ◽  
Undecylenic Acid ◽  
Scanning Calorimetry ◽  
Source Phase

This paper presents a transport and recovery of silver ions through bulk liquid membranes based on n–decanol using as carriers 10–undecylenic acid and 10–undecylenyl alcohol. The transport of silver ions across membranes has been studied in the presence of two types of magnetic oxide nanoparticles obtained by the electrochemical method with iron electrodes in the electrolyte with and without silver ions, which act as promoters of turbulence in the membrane. Separation of silver ions by bulk liquid membranes using 10–undecylenic acid and 10–undecylenyl alcohol as carriers were performed by comparison with lead ions. The configuration of the separation module has been specially designed for the chosen separation process. Convective-generating magnetic nanoparticles were characterized in terms of the morphological and structural points of view: scanning electron microscopy (SEM), high-resolution SEM (HR–SEM), energy dispersive spectroscopy analysis (EDAX), Fourier Transform InfraRed (FTIR) spectroscopy, thermal gravimetric analysis (TGA), differential scanning calorimetry and magnetization. The process performance (flux and selectivity) was tested were tested for silver ion transport and separation through n–decanol liquid membranes with selected carriers. Under the conditions of the optimized experimental results (pH = 7 of the source phase, pH = 1 of the receiving phase, flow rate of 30 mL/min for the source phase and 9 mL/min for the receiving phase, 150 rot/min agitation of magnetic nanoparticles) separation efficiencies of silver ions of over 90% were obtained for the transport of undecenoic acid and about 80% for undecylenyl alcohol.

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