Effect of Temperature Synthesize on the Crystalline Structures and Magnetic Properties in Co-Precipitated Cobalt Ferrite Bismuth Nanoparticles

2020 ◽  
Vol 855 ◽  
pp. 3-8
Author(s):  
Santi Pratiwi ◽  
Utari ◽  
Budi Purnama
Keyword(s):  
Magnetic Properties ◽  
Fourier Transform ◽  
Saturation Magnetization ◽  
Cobalt Ferrite ◽  
Effect Of Temperature ◽  
Vibrating Sample Magnetometer ◽  
Magnetic Characterization ◽  
X Ray ◽  
Bismuth Nanoparticles ◽  
Infra Red

The synthesis of CoBi0.15Fe1.85O4 obtained from cobalt ferrite doped by bismuth using the coprecipitation method was successfully carried out by varying the temperature of the titration. In this study the temperature of titration was used at 65°C, 75°C, 85°C, and 95°C. Annealing was then carried out at a temperature of 800°C for 5 hours. The results of the synthesis were then characterized using X-Ray Diffractometer (XRD), Fourier Transform Infra-Red (FTIR) and Vibrating Sample Magnetometer (VSM). The increase of the magnetic characterization i.e. the saturation magnetization increases and coercivity attribute the increase of the anisotropy crystalline.

Comparison of the Crystalline Structure and Magnetic Properties in Coprecipitated CoFe2O4 and CoLa0.1Fe1.9O4

2020 ◽  
Vol 855 ◽  
pp. 16-21
Author(s):  
Riyana Indah Setiyani ◽  
Utari ◽  
Yofentina Iriani ◽  
Budi Purnama
Keyword(s):  
Magnetic Properties ◽  
Fourier Transform ◽  
Crystalline Structure ◽  
Atomic Radius ◽  
Nano Particles ◽  
Vibrating Sample Magnetometer ◽  
X Ray ◽  
Bonding Structure ◽  
Previous Discussion ◽  
Lanthanum Cation

Comparison of the crystalline structure and magnetic properties in CoFe2O4 and CoLa0.1Fe1.9O4 nanoparticles have been studied. The obtained samples are characterized by using X-Ray Diffractometer (XRD), Fourier Transform InfraRed (FTIR) and Vibrating Sample Magnetometer (VSM). The XRD results show that the crystallite size of the samples are 24.539 nm and 28.772 nm for the CoFe2O4 and CoLa0.1Fe1.9O4 nano particles, respectively. Furthermore, the crystalline strain is 0.00460 and lightly decreases to 0.00392 with the presence of lanthanum. The different of the atomic radius for both Fe3+ (1.26 Å) and La3+ (1.87 Å) should attribute to the change of the crystalline strain. FTIR results show that the absorption peak of the CoFe2O4 occur at k = 591.21/cm and the CoLa0.1Fe1.9O4 is 594.10/cm. This indicate that the lanthanum cation successfully substitutes to the original bonding-structure of the CoFe2O4. VSM results show that the HC are 1.02 kOe and 0.705 kOe for the samples without and with La3+ cations. Moreover, the MS is equal 69.625 emu/g and decrease of 55.70 emu/g with the present of the La3+ cations. Finally, the strains-induce-magnetism should contribute to the changes of the MS that associated with changes in crystalline strains at the previous discussion.

Structural and Magnetic Properties of CoFe2O4 / Si (001) Thin Films via Sol-Gel Method

2013 ◽  
Vol 744 ◽  
pp. 315-318
Author(s):  
Wei Rao ◽  
Ding Guo Li ◽  
Hong Chun Yan
Keyword(s):  
Thin Films ◽  
Magnetic Properties ◽  
Exchange Coupling ◽  
Cobalt Ferrite ◽  
Sol Gel ◽  
Magnetic Hysteresis ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Calcined Temperature

Cobalt ferrite (CoFe2O4) thin films have been prepared on Si (001) substrates, with different calcined temperatures (Tcal=400°C~800°C). The films structure was studied by X-ray diffraction (XRD) and their surface was examined by scanning electron microscopy (SEM). The magnetic properties were measured with a vibrating sample magnetometer (VSM). For low calcined temperatures, the films presented a mixture of a CoFe2O4phase, with the cubic spinel structure, and cobalt and iron antiferromagnet oxides with CoO and FeO stoichiometries. As the calcined temperature increased, the CoO and FeO relative content strongly decreased, so that for Tcal=800°Cthe films were composed mainly by polycrystalline CoFe2O4. The magnetic hysteresis cycles measured in the films were horizontally shifted due to an exchange coupling field originated by the presence of the antiferromagnetic phases.

scholarly journals Magnetic Properties of Co0.5Zn0.5Fe2O4Nanoparticles Synthesized by a Template-Assisted Hydrothermal Method

2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
H. Y. He
Keyword(s):  
Electron Microscopy ◽  
Saturation Magnetization ◽  
Hydrothermal Method ◽  
Cobalt Ferrite ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Templating Agent ◽  
Nickel Cobalt ◽  
Scanning Electron

In the present paper, nickel cobalt ferrite (Co0.5Zn0.5Fe2O4) nanoparticles were synthesized using a template-assisted hydrothermal method. Carboxymethyl cellulose was used as the templating agent for controlling the morphology of the Co0.5Zn0.5Fe2O4nanoparticles. The synthesized nanoparticles were characterized using X-ray diffraction, scanning electron microscopy, and a vibrating sample magnetometer. The results indicated that the morphology of the nanoparticles changed from granular and superparamagnetic to platelike and ferromagnetic with the addition of the template. The Co0.5Zn0.5Fe2O4nanoparticles synthesized without the template exhibited a saturation magnetization and coercivity 2.81 T and 0.2 kA⋅m−1, while when the template was used, the saturation magnetization and coercivity increased to 3.13 T and 76.6 kA⋅m−1as the template proportion increased to 0.3.

scholarly journals Pengaruh Konsentrasi Polyethylene glycol (PEG) pada Sifat Kemagnetan Nanopartikel Magnetik PEG-Coated Fe3O4 (Halaman 35 s.d. 40)

2014 ◽  
Vol 17 (51) ◽  
Author(s):  
Seveny Nuzully ◽  
Takeshi Kato ◽  
Edi Suharyadi
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Fourier Transform ◽  
Polyethylene Glycol ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Peg 4000 ◽  
Infra Red

Nanopartikel magnetit (Fe3O4) telah berhasil disintesis menggunakan metode kopresipitasi dengan penambahan Polyethylene Glycol (PEG-4000) sebagai coating. Distribusi ukuran partikel dan sifat magnetik dari nanopartikel ini diteliti berdasarkan perbandingan massa Fe3O4 dan PEG, yaitu 1:1, 2:1, 3:1, 4:1, 1:2, dan 1:3. Distribusi ukuran partikel dikarakteristik dengan Transmission Electron Microscopy (TEM) sedangkan pengujian awal untuk mengetahui struktur kristal yang terkandung dalam sampel hasil sintesis dikarakteristik dengan X-Ray Diffraction (XRD), kemudian untuk mengetahui keberhasilan coating PEG dapat dikarakterisasi dengan menggunakan Fourier Transform Infra Red (FTIR) serta sifat magnetiknya dapat dikarakterisasi menggunakan Vibrating Sample Magnetometer (VSM). Sampel 1:1, 2:1, 3:1, 4:1, 1:2, 1:3 berturut-turut meiliki nilai Ms 37,2; 49,7; 55,2; 61,7; 27,7; 33,7 dan nilai Mr 4,8; 6,4; 6,6; 8,0; 3,3; 4,7. Hasil karakterisasi menunjukkan bahwa penambahan konsentrasi PEG mengakibatkan nilai saturation magnetic (Ms) dan remanence magnetic (Mr) turun, kecuali pada sampel dengan perbandingan 1:3.

scholarly journals Pengaruh Konsentrasi Polyethylene glycol (PEG) pada Sifat Kemagnetan Nanopartikel Magnetik PEG-Coated Fe3O4 (Halaman 35 s.d. 40)

2014 ◽  
Vol 17 (51) ◽  
Author(s):  
Seveny Nuzully ◽  
Takeshi Kato ◽  
Edi Suharyadi
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Fourier Transform ◽  
Polyethylene Glycol ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Peg 4000 ◽  
Infra Red

Nanopartikel magnetit (Fe3O4) telah berhasil disintesis menggunakan metode kopresipitasi dengan penambahan Polyethylene Glycol (PEG-4000) sebagai coating. Distribusi ukuran partikel dan sifat magnetik dari nanopartikel ini diteliti berdasarkan perbandingan massa Fe3O4 dan PEG, yaitu 1:1, 2:1, 3:1, 4:1, 1:2, dan 1:3. Distribusi ukuran partikel dikarakteristik dengan Transmission Electron Microscopy (TEM) sedangkan pengujian awal untuk mengetahui struktur kristal yang terkandung dalam sampel hasil sintesis dikarakteristik dengan X-Ray Diffraction (XRD), kemudian untuk mengetahui keberhasilan coating PEG dapat dikarakterisasi dengan menggunakan Fourier Transform Infra Red (FTIR) serta sifat magnetiknya dapat dikarakterisasi menggunakan Vibrating Sample Magnetometer (VSM). Sampel 1:1, 2:1, 3:1, 4:1, 1:2, 1:3 berturut-turut meiliki nilai Ms 37,2; 49,7; 55,2; 61,7; 27,7; 33,7 dan nilai Mr 4,8; 6,4; 6,6; 8,0; 3,3; 4,7. Hasil karakterisasi menunjukkan bahwa penambahan konsentrasi PEG mengakibatkan nilai saturation magnetic (Ms) dan remanence magnetic (Mr) turun, kecuali pada sampel dengan perbandingan 1:3.

PREPARATION, STRUCTURAL CHARACTERIZATION AND MAGNETIC PROPERTIES OF La-SUBSTITUTED Co FERRITES VIA A MODIFIED CITRATE PRECURSOR ROUTE

2009 ◽  
Vol 23 (27) ◽  
pp. 3289-3297 ◽  
Author(s):  
LUNHONG AI ◽  
JING JIANG
Keyword(s):  
Particle Size ◽  
Magnetic Properties ◽  
Fourier Transform ◽  
Thermal Evolution ◽  
Vibrating Sample Magnetometer ◽  
X Ray ◽  
Thermogravimetric Analyzer ◽  
Ftir Spectrometer ◽  
Precursor Route ◽  
Citrate Precursor

CoLa x Fe 2-x O 4 (x = 0.00, 0.05 and 0.1) nanoparticles were prepared simply by a modified citrate precursor route. Effects of La -substituting level on the their magnetic properties were investigated on the basis of the structural analysis. The thermal evolution of the precursor, as well as the microstructure of as-prepared products were studied by means of a thermogravimetric analyzer (TGA), X-ray diffractometer (XRD) and Fourier transform infrared (FTIR) spectrometer. The magnetic properties of the as-prepared samples were measured using a vibrating sample magnetometer (VSM). It was found that the magnetic properties were dependent on many factors such as La -substituting level, particle size and microstructure. The observed saturation magnetization decreased with increasing La content, whereas coercivity exhibited reverse behavior.

Structural and Magnetic Properties of CoFe2O4 Thin Films via Sol-Gel Method

2014 ◽  
Vol 716-717 ◽  
pp. 159-162 ◽  
Author(s):  
Shao Hua Yang ◽  
Ding Guo Li ◽  
Hai Bin Yang ◽  
Hong Chun Yan
Keyword(s):  
Thin Films ◽  
Magnetic Properties ◽  
Exchange Coupling ◽  
Cobalt Ferrite ◽  
Sol Gel ◽  
Magnetic Hysteresis ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Calcined Temperature

Cobalt ferrite (CoFe2O4) thin films have been prepared on Si (001) substrates, with different calcined temperatures (Tcal=400°C~800°C). The films structure was studied by X-ray diffraction (XRD) and their surface was examined by scanning electron microscopy (SEM). The magnetic properties were measured with a vibrating sample magnetometer (VSM). For low calcined temperatures, the films presented a mixture of a CoFe2O4phase, with the cubic spinel structure, and cobalt and iron antiferromagnet oxides with CoO and FeO stoichiometries. As the calcined temperature increased, the CoO and FeO relative content strongly decreased, so that for Tcal=800°Cthe films were composed mainly by polycrystalline CoFe2O4. The magnetic hysteresis cycles measured in the films were horizontally shifted due to an exchange coupling field originated by the presence of the antiferromagnetic phases.

scholarly journals Synthesis of nano Co1-xNixFe2O4 by sol-gel method and its properties

2016 ◽  
Vol 19 (3) ◽  
pp. 123-128
Author(s):  
Minh Truong Xuan Nguyen ◽  
Oanh Le Kieu Pham ◽  
Ha Ky Phuong Huynh ◽  
Vien Minh Le
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Cobalt Ferrite ◽  
Sol Gel ◽  
Vibrating Sample Magnetometer ◽  
Gel Method ◽  
Sol Gel Method ◽  
Nickel Cobalt ◽  
Ni Content ◽  
Higher Temperature

Nano ferrites have received considerable attentions due to their various applications such as magnetic or catalyst materials. In this work, nickel-cobalt ferrite (Co1-xNixFe2O4) was synthesized by sol-gel method using stearic acid. The effects of calcination temperature and nickel/cobalt ratios on the formation of structure were also investigated. XRD results show that all samples which were calcined from 6000C to higher temperature for 1 hour were in single cubic spinel phases. The magnetic properties include saturation magnetization (Ms) and coercivity (Hc) have been also investigated by using vibrating sample magnetometer (VSM). The saturation magnetization and coercivity of CoFe2O4 calcined at 6000C for 1hour is 74.4 emu/g and 1519.13 Oe, respectively. The saturation magnetization and coercivety of substituted materials decrease with increasing Ni content.

PENGGUNAAN TiO2 PARTIKEL NANO HASIL SINTESIS BERBASIS AIR MENGGUNAKAN METODA SOL-GEL PADA BAHAN KAPAS SEBAGAI APLIKASI UNTUK TEKSTIL ANTI UV

Arena Tekstil ◽  
2013 ◽  
Vol 28 (1) ◽  
Author(s):  
Maya Komalasari ◽  
Bambang Sunendar
Keyword(s):  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Sol Gel ◽  
Crosslinking Agent ◽  
X Ray Diffraction ◽  
Nano Tio2 ◽  
X Ray ◽  
Infra Red ◽  
Scanning Electron

Partikel nano TiO2 berbasis air dengan pH basa telah berhasil disintesis dengan menggunakan metode sol-gel dan diimobilisasi pada kain kapas dengan menggunakan kitosan sebagai zat pengikat silang. Sintesis dilakukan  dengan prekursor TiCl4 pada konsentrasi 0,3 M, 0,5 M dan 1 M, dan menggunakan templat kanji dengan proses kalsinasi pada suhu 500˚C selama 2 jam. Partikel nano TiO2 diaplikasikan ke kain kapas dengan metoda pad-dry-cure dan menggunakan kitosan sebagai crosslinking agent. Berdasarkan hasil Scanning Electron Microscope (SEM),diketahui bahwa morfologi partikel TiO2 berbentuk spherical dengan ukuran nano (kurang dari 100 nm). Karakterisasi X-Ray Diffraction (XRD) menunjukkan adanya tiga tipe struktur kristal utama, yaitu (100), (101) dan (102) dengan fasa kristal yang terbentuk adalah anatase dan rutile. Pada karakterisasi menggunakan SEM terhadap serbuk dari TiO2 yang telah diaplikasikan ke permukaan kain kapas, terlihat adanya imobilisasi partikel nano TiO2 melalui ikatan hidrogen silang dengan kitosan pada kain kapas. Hasil analisa tersebut kemudian dikonfirmasi dengan FTIR (Fourier Transform Infra Red) yang hasilnya memperlihatkan puncak serapan pada bilangan gelombang 3495 cm-1, 2546 cm-1, dan 511 cm-1,  yang masing-masing diasumsikan sebagai adanya vibrasi gugus fungsi O-H, N-H dan Ti-O-Ti. Hasil SEM menunjukkan pula bahwa kristal nano yang terbentuk diantaranya adalah fasa rutile , yang berdasarkan literatur terbukti dapatberfungsi sebagai anti UV.

Effect of Temperature on Fe3O4 Magnetic Nanoparticles Prepared by Coprecipitation Method

2014 ◽  
Vol 900 ◽  
pp. 172-176 ◽  
Author(s):  
Ji Mei Niu ◽  
Zhi Gang Zheng
Keyword(s):  
Magnetic Nanoparticles ◽  
Coprecipitation Method ◽  
Effect Of Temperature ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
X Ray ◽  
Magnetic Carriers ◽  
Average Grain Size ◽  
Or Gene ◽  
Block Temperature

The Fe3O4 magnetic nanoparticles obtained by the aqueous coprecipitation method are characterized systematically using scanning electron microscope, X-ray diffraction and vibrating sample magnetometer. These magnetic nanoparticles are spheric, dispersive, and have average grain size of 50 nm. The size and magnetic properties of Fe3O4 nanoparticles can be tuned by the reaction temperature. All samples exhibit high saturation magnetization (Ms=53.4 emu·g-1) and superparamagnetic behavior with a block temperature (TB) of 215K. These properties make such Fe3O4 magnetic nanoparticles worthy candidates for the magnetic carriers of targeted-drug or gene therapy in future.

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