Effect of Growth Time on the Structural and Morphological Properties of MoS2 Synthesized via Hydrothermal Method

2021 ◽  
Vol 1028 ◽  
pp. 162-167
Author(s):  
Tengku Emrinaldi ◽  
Cuk Imawan ◽  
Riski Titian Ginting ◽  
Vivi Fauzia
Keyword(s):  
Phase Transformation ◽  
Hydrothermal Method ◽  
Molybdenum Disulfide ◽  
Structural Properties ◽  
Hydrothermal Process ◽  
Sodium Molybdate ◽  
Diffraction Peak ◽  
Morphological Properties ◽  
Growth Time ◽  
Simple Hydrothermal Process

Recently, molybdenum disulfide (MoS2), have been explored as photothermal materials for solar evaporation. However, the optimum phase for photothermal material, 1T-MoS2 or 2H-MoS2, is still debatable. In this work, we observed the morphological and structural properties of MoS2 prepared by a simple hydrothermal process at 200 °C in three different growth times (16, 20, and 24 hours) using Na2MoO4·2H2O (sodium molybdate) as a Mo precursor, and CS(NH2)2 (thiourea) as S precursor. MoS2 nanoflowers were successfully prepared with nanosheets petals and its diameter increased from 0.4 to 2.8 and 4.5 as the growth time increased from 16 to 20 and 24 hours. The increase in growth time also led to improve the Mo:S ratio from 1:8 to 1:5 and facilitate the phase transformation from 1T to 2H as indicated by the shifting of (002) diffraction peak from 9.25° to higher degrees (12.98°, and 14.12°).

A simple hydrothermal process to grow MoS2 nanosheets with excellent dielectric loss and microwave absorption performance

2016 ◽  
Vol 4 (28) ◽  
pp. 6816-6821 ◽  
Author(s):  
Xiaohui Liang ◽  
Xingmiao Zhang ◽  
Wei Liu ◽  
Dongming Tang ◽  
Baoshan Zhang ◽  
...  
Keyword(s):  
Dielectric Loss ◽  
Hydrothermal Method ◽  
Microwave Absorption ◽  
Hydrothermal Process ◽  
Two Dimensional ◽  
Mos2 Nanosheets ◽  
Absorption Performance ◽  
Microwave Absorbing ◽  
Microwave Absorption Performance ◽  
Simple Hydrothermal Process

In this study, two-dimensional MoS2 nanosheets synthesized by a hydrothermal method were firstly investigated for microwave absorbing performance.

scholarly journals Thermal Conductivity of Epoxy Composites Modified by Microspheric Molybdenum Disulfide

2021 ◽  
Author(s):  
Zhen Liu ◽  
Yuan Jia ◽  
Juxiang Yang ◽  
Ruifeng Shi
Keyword(s):  
Thermal Conductivity ◽  
Dielectric Properties ◽  
Molybdenum Disulfide ◽  
Hydrothermal Process ◽  
Sodium Dodecyl ◽  
Sodium Molybdate ◽  
X Ray Diffraction ◽  
X Ray ◽  
Uniform Dispersion ◽  
Ep Matrix

Abstract In order to improve the thermal conductivity of epoxy resins (EP) without reducing their dielectric properties, a kind of molybdenum disulfide with microspheres structure (S-MoS2) was prepared via surfactant promoting hydrothermal process based on the sodium molybdate, thiosemicarbazide, and sodium dodecyl sulfate. The S-MoS2 was then used as modifiers to add into EP matrix to prepare a new kind of S-MoS2/EP composites. The morphology of the prepared S-MoS2 was observed by X-ray diffraction (XRD) scanning electron microscopy (SEM), while the influence of different S-MoS2 loading on the dielectric properties, thermal conductivity and thermal resistance of S-MoS2/EP composites was also researched. The results suggested that the reasonable content of S-MoS2 can highly improve the thermal conductivity of S-MoS2/EP, which can be attributed to the excellent thermal resistant and uniform dispersion of S-MoS2 in EP matrix.

scholarly journals In Situ Thermal-Stage Fitted-STEM Characterization of Spherical-Shaped Co/MoS2 Nanoparticles for Conversion of Heavy Crude Oils

Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1239
Author(s):  
Manuel Ramos ◽  
Félix Galindo-Hernández ◽  
Brenda Torres ◽  
José Manuel Domínguez-Esquivel ◽  
Martin Heilmaier
Keyword(s):  
Molybdenum Disulfide ◽  
Sodium Molybdate ◽  
Interlayer Spacing ◽  
Scanning Transmission Electron Microscope ◽  
Interplanar Distance ◽  
Scanning Transmission ◽  
Heavy Crude ◽  
C 50 ◽  
Nano Catalysts

We report the thermal stability of spherically shaped cobalt-promoted molybdenum disulfide (Co/MoS2) nano-catalysts from in-situ heating under electron irradiation in the scanning transmission electron microscope (STEM) from room temperature to 550 °C ± 50 °C with aid of Fusion® holder (Protochip©, Inc.). The catalytic nanoparticles were synthesized via a hydrothermal method using sodium molybdate (Na2MoO4·2H2O) with thioacetamide (CH3CSNH2) and cobalt chloride (CoCl2) as promoter agent. The results indicate that the layered molybdenum disulfide structure with interplanar distance of ~0.62 nm remains stable even at temperatures of 550 °C, as observed in STEM mode. Subsequently, the samples were subjected to catalytic tests in a Robinson Mahoney Reactor using 30 g of Heavy Crude Oil (AGT-72) from the golden lane (Mexico’s east coast) at 50 atm using (ultrahigh purity) UHP hydrogen under 1000 rpm stirring at 350 °C for 8 h. It was found that there is no damage on the laminar stacking of Co/MoS2 with temperature, with interlayer spacing remaining at 0.62 nm; these sulfided catalytic materials led to aromatics rise of 22.65% and diminution of asphaltenes and resins by 15.87 and 3.53%, respectively.

Selective oxidation of cyclopentene to glutaraldehyde by H2O2 over Nb-SBA-15

2021 ◽  
Author(s):  
yingmeng qi ◽  
Qi Han ◽  
li wu ◽  
Jun Li
Keyword(s):  
Structural Properties ◽  
Selective Oxidation ◽  
Mesoporous Materials ◽  
Hydrothermal Process ◽  
X Ray Diffraction ◽  
X Ray

A series of niobium-containing mesoporous materials Nb-SBA-15 have been prepared by sonication–impregnation and hydrothermal process. The dispersion and structural properties of niobium-containing species were systematically characterized by X-ray diffraction, scanning...

Facile synthesis of monodispersed yolk-shelled molybdenum disulfide microspheres with enhanced photocatalytic properties

2018 ◽  
Vol 5 (12) ◽  
pp. 3082-3090 ◽  
Author(s):  
Yongxing Zhang ◽  
Yuanyuan Zhao ◽  
Jia Li ◽  
Li Li ◽  
Yi Liu ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Molybdenum Disulfide ◽  
Photocatalytic Properties ◽  
Facile Synthesis

Monodispersed yolk-shelled MoS2 microspheres with outstanding photocatalytic properties have been synthesized by the hydrothermal method with the assistance of P123.

scholarly journals Synthesis and characterization of one-dimensional titanate structure

2008 ◽  
Vol 2 (2) ◽  
pp. 109-114 ◽  
Author(s):  
Ljubica Nikolic ◽  
Marija Maletin ◽  
Paula Ferreira ◽  
Paula Vilarinho
Keyword(s):  
Heat Treatment ◽  
Structural Characteristics ◽  
Hydrothermal Process ◽  
Synthesis And Characterization ◽  
One Dimensional ◽  
Treatment Conditions ◽  
Alkaline Conditions ◽  
The Stability ◽  
Simple Hydrothermal Process

One-dimensional titania structures were synthesized trough a simple hydrothermal process in a highly alkaline conditions. The aim of this work was to elucidate the effect of time on the formation of 1D titanates as well on its structural characteristics (morphology, phase composition, surface area). Apart from that, the effect of heat treatment conditions on the stability of titanate based 1D samples has been investigated. The results have revealed that it is possible to form one-dimensional titanates already after 1 hour of hydrothermal synthesis. Although the composition of titanates is still under debate, the results probably correspond to the layered sodium titanates. The 1D prepared structures show a remarkable stability during heating, remaining the basic morphology and composition even up to 700?C.

scholarly journals Hydrothermal Transformation of Natural Zeolite from Ende-NTT and Its Application as Adsorbent of Cationic Dye

2018 ◽  
Vol 16 (2) ◽  
pp. 138 ◽  
Author(s):  
Yulius Dala Ngapa ◽  
Sri Sugiarti ◽  
Zaenal Abidin
Keyword(s):  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Natural Zeolite ◽  
Hydrothermal Process ◽  
Exchange Capacity ◽  
Synthetic Zeolite ◽  
Crystal Formation ◽  
Isothermal Adsorption ◽  
Hydrothermal Transformation ◽  
Equilibrium Process

A synthetic zeolite was produced from natural zeolite from Ende-Nusa Tenggara Timur (NTT) by hydrothermal method. This study aims to produce synthetic zeolite from Ende natural zeolite to remove cation dye through the adsorption process. Temperature of crystal formation (ageing) was performed at 60 °C for 6 h and hydrothermal process was at 100 °C for 24 h. The natural zeolite produced synthetic NaP1 and synthetic Faujasite. Based on the research results, the synthesis of zeolite by the hydrothermal method can enhance the adsorption capacity and Cation Exchange Capacity (CEC). The adsorption capacity in the natural zeolites of type ZG, ZL and ZC before the hydrothermal process were 17.289, 17.276, and 16.483 mg/g, respectively, and after hydrothermal they increased to 37.398, 37.369 and 37.362 mg/g, respectively. In addition, the CEC increased from 84.154, 81.042, and 77.474 cmol/kg, respectively, to 244.063, 216.354, and 211.432 cmol/kg, respectively. The Langmuir model most closely matched the isothermal adsorption equilibrium process.

Sign in / Sign up

Export Citation Format

Share Document