scholarly journals Hydrothermal Transformation of Natural Zeolite from Ende-NTT and Its Application as Adsorbent of Cationic Dye

2018 ◽  
Vol 16 (2) ◽  
pp. 138 ◽  
Author(s):  
Yulius Dala Ngapa ◽  
Sri Sugiarti ◽  
Zaenal Abidin
Keyword(s):  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Natural Zeolite ◽  
Hydrothermal Process ◽  
Exchange Capacity ◽  
Synthetic Zeolite ◽  
Crystal Formation ◽  
Isothermal Adsorption ◽  
Hydrothermal Transformation ◽  
Equilibrium Process

A synthetic zeolite was produced from natural zeolite from Ende-Nusa Tenggara Timur (NTT) by hydrothermal method. This study aims to produce synthetic zeolite from Ende natural zeolite to remove cation dye through the adsorption process. Temperature of crystal formation (ageing) was performed at 60 °C for 6 h and hydrothermal process was at 100 °C for 24 h. The natural zeolite produced synthetic NaP1 and synthetic Faujasite. Based on the research results, the synthesis of zeolite by the hydrothermal method can enhance the adsorption capacity and Cation Exchange Capacity (CEC). The adsorption capacity in the natural zeolites of type ZG, ZL and ZC before the hydrothermal process were 17.289, 17.276, and 16.483 mg/g, respectively, and after hydrothermal they increased to 37.398, 37.369 and 37.362 mg/g, respectively. In addition, the CEC increased from 84.154, 81.042, and 77.474 cmol/kg, respectively, to 244.063, 216.354, and 211.432 cmol/kg, respectively. The Langmuir model most closely matched the isothermal adsorption equilibrium process.

scholarly journals Study of The Acid-Base Effect on Zeolite Activation and Its Characterization as Adsorbent of Methylene Blue Dye

2017 ◽  
Vol 2 (2) ◽  
pp. 90 ◽  
Author(s):  
Yulius Dala Ngapa
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Natural Zeolite ◽  
Blue Dye ◽  
Activation Process ◽  
Acid Base ◽  
Isothermal Adsorption ◽  
Naoh Solution ◽  
Equilibrium Process

<p>Activation is one of the processes by which are mostly done to improve the quality of natural zeolite. Activation process by zeolite will change the ratio of the Si/Al and can increase the formation of empty cavities so that the capability of zeolite as an adsorbent be optimal. In this research, natural zeolite from the district of Ende, Nusa Tenggara Timur. Activation Ende natural zeolite done chemically using HCl and NaOH solution, with variations concentrate 0,5 M; 1,5 M; and 3,0 M. Next, zeolite which has activated used to adsorb dye methylene blue. Based on the research results, chemically of activation from natural zeolite can increase the adsorption capacity to substance methylene blue. The adsorption capacity in the Ende natural and after activation is 17,289 mg/g and 19,98 mg/g respectively. The Langmuir model most closely matched the isothermal adsorption of equilibrium process.</p>

scholarly journals Utilization of Natural Zeolites as Cu (Ii) and Zn (Ii) Adsorbent

2017 ◽  
Vol 21 (3) ◽  
pp. 153
Author(s):  
Evi Mutiara Dewi ◽  
. Suwardi ◽  
Dyah Tjahyandari Suryaningtyas ◽  
Syaiful Anwar
Keyword(s):  
Natural Zeolite ◽  
Data Interpretation ◽  
Exchange Capacity ◽  
Natural Zeolites ◽  
Saturation Point ◽  
Isothermal Adsorption ◽  
Zn Content ◽  
System Data ◽  
Physical And Chemical ◽  
Adsorption Capability

This research was aimed to determine the differences of physical and chemical characteristics from three natural zeolites from Tasikmalaya, Bayah and Lampung areas and to examine the characteristics of the natural zeolite adsorption capability to the micro-nutrients. The zeolite characterization analysis included some variables i.e. mineral types, morphologyand pH, CEC (Cation Exchange Capacity), BSP (Base Saturation Point), Cu and Zn content of zeolite.&nbsp; Analysis of natural zeolite adsorption characteristics were done by Batch System. Data interpretation were done by&nbsp; using the isothermal adsorption equation of Langmuir, Freundlich and Brunauer-Emmett-Teller (BET).The results showed that zeolite from Bayah and Tasikmalaya had a similiar morphology and it was categorized as mordenite types and platy structure, while zeolite from Lampung was a clinoptilolite type and tabular structure. The CEC of Tasikmalaya zeolite (137.58 cmol(-)kg-1) was higher than Bayah (96.75 cmol(-)kg-1) and Lampung (87.72 cmol(-)kg-1). Adsorption capability at the Langmuir equation of Cu by Bayah zeolite (47.619 mg g-1) was higher than Lampung (33.333 mgg-1) and Tasikmalaya (28.571 mg g-1). Effective adsorption of Zn by Bayah zeolite 19.417 mg g-1 was higher than&nbsp; Lampung (16.949 mg g-1) and Tasikmalaya (1.395 mg g-1).

scholarly journals Utilization of Natural Zeolites as Cu (Ii) and Zn (Ii) Adsorbent

2017 ◽  
Vol 21 (3) ◽  
pp. 153-160 ◽  
Author(s):  
Evi Mutiara Dewi ◽  
. Suwardi ◽  
Dyah Tjahyandari Suryaningtyas ◽  
Syaiful Anwar
Keyword(s):  
Natural Zeolite ◽  
Data Interpretation ◽  
Exchange Capacity ◽  
Natural Zeolites ◽  
Saturation Point ◽  
Isothermal Adsorption ◽  
Zn Content ◽  
System Data ◽  
Physical And Chemical ◽  
Adsorption Capability

This research was aimed to determine the differences of physical and chemical characteristics from three natural zeolites from Tasikmalaya, Bayah and Lampung areas and to examine the characteristics of the natural zeolite adsorption capability to the micro-nutrients. The zeolite characterization analysis included some variables i.e. mineral types, morphologyand pH, CEC (Cation Exchange Capacity), BSP (Base Saturation Point), Cu and Zn content of zeolite.  Analysis of natural zeolite adsorption characteristics were done by Batch System. Data interpretation were done by  using the isothermal adsorption equation of Langmuir, Freundlich and Brunauer-Emmett-Teller (BET).The results showed that zeolite from Bayah and Tasikmalaya had a similiar morphology and it was categorized as mordenite types and platy structure, while zeolite from Lampung was a clinoptilolite type and tabular structure. The CEC of Tasikmalaya zeolite (137.58 cmol(-)kg-1) was higher than Bayah (96.75 cmol(-)kg-1) and Lampung (87.72 cmol(-)kg-1). Adsorption capability at the Langmuir equation of Cu by Bayah zeolite (47.619 mg g-1) was higher than Lampung (33.333 mgg-1) and Tasikmalaya (28.571 mg g-1). Effective adsorption of Zn by Bayah zeolite 19.417 mg g-1 was higher than  Lampung (16.949 mg g-1) and Tasikmalaya (1.395 mg g-1).

scholarly journals The removal of lead by natural zeolite

2020 ◽  
Vol 200 ◽  
pp. 06012
Author(s):  
Wawan Budianta ◽  
Adinda Ardiana ◽  
Norma Dian Andriyani
Keyword(s):  
Grain Size ◽  
Adsorption Capacity ◽  
Natural Zeolite ◽  
Exchange Capacity ◽  
Batch Test ◽  
Mineralogical Characterization ◽  
Zeolite Sample ◽  
Initial Concentration ◽  
Mineral Components ◽  
Batch Testing

This study aimed to evaluate the ability of natural zeolite samples obtained from Gunungkidul, Yogyakarta, Indonesia in the removal of lead (Pb) in solutions. This study included mineralogical characterization as well as a batch test in the laboratory with parameters including grain size, the mass of natural zeolite sample, pH, and initial concentration of the solution. The results of mineralogical characterization showed that the natural zeolite sample have varied constituent on mineral components and relatively have high cation exchange capacity (CEC). The results of the batch test showed that the adsorption behavior depends on the mass of the zeolite sample which the increasing of the sample mass will increase the adsorption capacity. The results of the following batch testing showed that the variations in grain size had a limited effect on the adsorption capacity and the effect of the pH of the solution being a significant parameter. The results of the following batch test also showed that the increasing initial concentration of Pb solution caused a decrease in adsorption capacity. In general, natural zeolite samples in the study area have sufficient adsorption capacity as adsorbent material for Pb solution.

Few-Layered MoS2 Synthesized by Hydrothermal Method with Improved Adsorption Capacity for Methylene Blue Than Active Carbon

2018 ◽  
Vol 18 (11) ◽  
pp. 7948-7951 ◽  
Author(s):  
Cuiqing Zhang ◽  
Xiaoyu Li ◽  
Chengjiang Lian ◽  
Changyuan Hu ◽  
Shuwang Duo ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Active Carbon ◽  
Layered Mos2

scholarly journals Performance Evaluation of Small Sized Powdered Ferric Hydroxide as Arsenic Adsorbent

Water ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 957 ◽  
Author(s):  
Muhammad Usman ◽  
Ioannis Katsoyiannis ◽  
Manassis Mitrakas ◽  
Anastasios Zouboulis ◽  
Mathias Ernst
Keyword(s):  
Adsorption Capacity ◽  
Tap Water ◽  
Ferric Hydroxide ◽  
Equilibrium Concentration ◽  
Arsenic Species ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Isothermal Adsorption ◽  
Water Matrix ◽  
The Impact

The small sized powdered ferric oxy-hydroxide, termed Dust Ferric Hydroxide (DFH), was applied in batch adsorption experiments to remove arsenic species from water. The DFH was characterized in terms of zero point charge, zeta potential, surface charge density, particle size and moisture content. Batch adsorption isotherm experiments indicated that the Freundlich model described the isothermal adsorption behavior of arsenic species notably well. The results indicated that the adsorption capacity of DFH in deionized ultrapure water, applying a residual equilibrium concentration of 10 µg/L at the equilibrium pH value of 7.9 ± 0.1, with a contact time of 96 h (i.e., Q10), was 6.9 and 3.5 µg/mg for As(V) and As(III), respectively, whereas the measured adsorption capacity of the conventionally used Granular Ferric Hydroxide (GFH), under similar conditions, was found to be 2.1 and 1.4 µg/mg for As(V) and As(III), respectively. Furthermore, the adsorption of arsenic species onto DFH in a Hamburg tap water matrix, as well as in an NSF challenge water matrix, was found to be significantly lower. The lowest recorded adsorption capacity at the same equilibrium concentration was 3.2 µg As(V)/mg and 1.1 µg As(III)/mg for the NSF water. Batch adsorption kinetics experiments were also conducted to study the impact of a water matrix on the behavior of removal kinetics for As(V) and As(III) species by DFH, and the respective data were best fitted to the second order kinetic model. The outcomes of this study confirm that the small sized iron oxide-based material, being a by-product of the production process of GFH adsorbent, has significant potential to be used for the adsorptive removal of arsenic species from water, especially when this material can be combined with the subsequent application of low-pressure membrane filtration/separation in a hybrid water treatment process.

scholarly journals REDUCTION OF METAL CATIONS CONTENT FROM THE AQUEOUS SOLUTIONS BY SORBENTS

2021 ◽  
Vol 2021 (6) ◽  
pp. 5307-5311
Author(s):  
IVETA PANDOVA ◽  
◽  
MIROSLAV RIMAR ◽  
Keyword(s):  
Heavy Metals ◽  
Aqueous Solutions ◽  
Natural Zeolite ◽  
Metal Cations ◽  
Sorption Kinetics ◽  
Synthetic Zeolite ◽  
Natural Zeolites ◽  
Chemically Treated ◽  
Synthetic Zeolites

The article presents the results of research on reducing the concentration of heavy metals, such as copper and nickel, on natural zeolite in comparison with synthetic zeolite and chemically treated natural zeolite. The reduction of the content of specific types of heavy metals from aqueous solutions was investigated by the method of sorption kinetics. The results indicate the ability of natural zeolites to compete with synthetic zeolites.

scholarly journals Preparation of MoS2 nano-corals by hydrothermal method for adsorption of tartrazine in the aqueous medium

2020 ◽  
Vol 9 (4) ◽  
pp. 93-99
Author(s):  
Hung Mac Van ◽  
Tuan Vu Anh
Keyword(s):  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Adsorption Kinetics ◽  
Organic Dyes ◽  
Nile Blue ◽  
High Surface ◽  
High Surface Area ◽  
Optimal Dosage ◽  
Solution Ph ◽  
Intra Particle Diffusion

Corals-like molybdenum disulfide (MoS2) have been successfully synthesized via the hydrothermal method. The as-prepared MoS2 material with a high surface area of 83.9 m2.g-1 was used for the removal of tartrazine from an aqueous solution. The effects of parameters including contact time, MoS2 dosage, and solution pH on adsorption capacity were studied. The optimal dosage of MoS2 for removing tartrazine was 0.08 g and the removal efficiency of tartrazine reached 81.5 % for 100 min of adsorption. The adsorption kinetics studies were carried out using pseudo-first-order, pseudo-second-order, and intra-particle diffusion models. The results showed that the pseudo-second-kinetic model better described the adsorption kinetics of tartrazine on MoS2 and film diffusion was the rate-limiting step. In addition, the adsorption capacity of MoS2 was also performed with various organic dyes such as nile blue, janus green B, and congo red.

Synthesis of PZT Disks by a Hydrothermal Method

2012 ◽  
Vol 174-177 ◽  
pp. 592-595
Author(s):  
Lin Lin Yang ◽  
Yong Gang Wang ◽  
Yu Jiang Wang ◽  
Xiao Feng Wang
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Hydrothermal Method ◽  
Formation Mechanism ◽  
Powder Diffraction ◽  
Self Assembly ◽  
Hydrothermal Process ◽  
X Ray ◽  
Extended Length ◽  
Scanning Electron

The organization of nanostructures across extended length scales is a key challenge in the design of integrated materials with advanced functions. PbZr0.52Ti0.48O3multilayer disks which were constructed by oriented rectangle nanoparticles were easily prepared by a simple surfactant-free hydrothermal process. The as-prepared powders were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the as-prepared PZT disks were constructed by self-assembly of rectangle nanoparticles by a perfect manner. The formation mechanism of the products was discussed.

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