Synthesis and Characterization of Delafossite CuLaO2 for Thermoelectric Application
2007 ◽
Vol 534-536
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pp. 1081-1084
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Keyword(s):
X Ray
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The preparation of single-phase CuLaO2 with delafossite-type structure by means of the solid-state reaction method was investigated using X-ray diffraction. The results showed that notwhistanding the fact that there was a trace of metallic copper, nearly single-phase CuLaO2 was obtained by using La(OH)3 as a lanthanum source and by firing the mixed powder with nonstoichiometric composition ratio of La(OH)3:Cu2O =1:1.425 in a vacuum at 1273 K for 10 h. The measurement of electrical conductivity and Seebeck coefficient showed that CuLaO2 thus obtained was a p-type semiconductor and had a Seebeck coefficient of approximately 70 /V/K.