Growth and Characterization of 13C Enriched 4H-SiC for Fundamental Materials Studies

2007 ◽  
Vol 556-557 ◽  
pp. 13-16 ◽  
Author(s):  
Yeon Suk Jang ◽  
Sakwe Aloysius Sakwe ◽  
Peter J. Wellmann ◽  
Sandrine Juillaguet ◽  
Hervé Peyre ◽  
...  

We have carried out the growth and basic characterization of isotopically enriched 4HSi 13C crystals. In recent years the growth of 13C enriched 6H-SiC has been performed in order to carry out fundamental materials studies (e.g. determination of phonon energies, fundamental bandgap shift, carbon interstitial defect study, analysis of the physical vapor transport (PVT) growth process). For electronic device applications, however, the 4H-SiC polytype is the favored material, because it offers greater electron mobility. In this paper we present the growth of 4H-Si13C single crystals with up to 60% of 13C concentration. From a physical point of view we present first results on phonons as well as the fundamental bandgap energy shift due to 13C incorporation into the SiC lattice.

Foods ◽  
2020 ◽  
Vol 9 (3) ◽  
pp. 310 ◽  
Author(s):  
Sofie Buhler ◽  
Ylenia Riciputi ◽  
Giuseppe Perretti ◽  
Maria Fiorenza Caboni ◽  
Arnaldo Dossena ◽  
...  

Parmigiano–Reggiano (PR) is a worldwide known Italian, long ripened, hard cheese. Its inclusion in the list of cheeses bearing the protected designation of origin (PDO, EU regulation 510/2006) poses restrictions to its geographic area of production and its technological characteristics. To innovate the Parmigiano–Reggiano (PR) cheese manufacturing chain from the health and nutritional point of view, the output of defatted PR is addressed. Two defatting procedures (Soxhlet, and supercritical CO2 extraction) were tested, and the obtained products were compared in the composition of their nitrogen fraction, responsible for their nutritional, organoleptic, and bioactive functions. Free amino acids were quantified, and other nitrogen compounds (peptides, proteins, and non-proteolytic aminoacyl derivatives) were identified in the extracts and the mixtures obtained after simulated gastrointestinal digestion. Moreover, antioxidant and angiotensin converting enzyme (ACE) inhibition capacities of the digests were tested. Results obtained from the molecular and biofunctional characterization of the nitrogen fraction, show that both the defatted products keep the same nutritional properties of the whole cheese.


1905 ◽  
Vol 3 (53) ◽  
pp. 217-228
Author(s):  
Emile Picard

Without restricting ourselves to the historical order, let us resume the development of mathematical physics in the last century, in so far as analysis is concerned. The problems of thermal equilibrium lead to the equation already known to Laplace in the study of attraction. There are few equations which have been the object of so many researches as this celebrated one. The conditions for the limits may assume various forms. The simplest case is that of the thermal equilibrium of a body, the elements of the surface of which are maintained at given temperatures. From the physical point of view, it may be regarded as evident that the temperature, assumed continuous in the interior since there is no source of heat, is determined when it is given at the surface. The more general case is that in which, the condition remaining permanent, there would be a radiation outward with an intensity • varying at the surface according to a given law ; in particular the temperature may be given over one portion, while there is radiation over the remainder. These questions, which are not yet solved in their widest generality, have largely contributed to the direction taken by the theory of partial differential equations. They have called attention to types of determination of the integrals which would never have presented themselves if we had been restricted to a purely abstract point of view. Laplace’s equation has been already met with in hydrodynamics, and in the study of attraction varying inversely as the square of the distance. The latter theory brought to light elements of the most essential nature, such as the potential of single and double layers. Here we meet with analytical combinations of the highest importance, which have since been notably generalised. Green’s formula is a case in point. The fundamental problems of electrostatics are of the same order of ideas, and certainly the celebrated theorem on electrical phenomena in the interior of a hollow conductor, which Faraday rediscovered at a later stage by experimental means, knowing nothing whatever of Green’s memoir, was a notable triumph for theory. This magnificent aggregate has remained the type of the classical theories of mathematical physics, which seem to us to have almost attained perfection, and which have exercised, and still exercise, so happy an influence on the progress of pure analysis by suggesting to it the most beautiful problems. The theory of functions again will afford us a notable comparison. The analytical transformations brought into play are not distinct from those we have met with in the steady movement of heat. Certain fundamental problems in the theory of functions of a complex variable have lost their abstract enunciation and assumed a physical form, as in the case of the distribution of temperature on a closed surface of any connectivity whatever and without radiation, in thermal equilibrium, with two sources of heat which necessarily correspond to equal and opposite flows. Interpreting this, we find a question on Abelian integrals of the third species in the theory of algebraical curves.


2018 ◽  
Vol 14 (18) ◽  
pp. 218
Author(s):  
Jean Claude N’zi ◽  
Mamadou Toure ◽  
N’goran Jean-Paul Yao ◽  
Rachelle Affouet Kouassi ◽  
Zeli Bruno Digbehi ◽  
...  

Analyzes carried out on 262 cuttings samples from two boreholes located in the coastal sedimentary basin of Abidjan (south-west of the lagoon fault) were aimed at the paleoenvironmental determination of tertiary-age deposits. Indeed, these sedimentological analyses allowed the characterization of the lithological nature of the formations encountered by AB and BM drilling. They also helped to determine the origin of the sedimented material as well as the hydrodynamic conditions that governed the placement of the various deposits. Moreover, the deposits medium of the studied formations was revealed. The formations consist of an alternation of sands and sandy clays in the AB drilling and essentially glauconous clays for BM drilling. In the clay intervals, there is a weak presence of calcium carbonates on the whole of the two boreholes. The sands analyzed are of different granulometric grades (very coarse, coarse, medium and fine) according to the intervals. This, therefore, shows the different variations in the energy of the current that transported the sediment. From a facies point of view, the granulometric facies is dominant in the study area, indicating the variation in watercourse competence during sedimentation. Mostly sub-angular to sub-rounded quartz grains suggest a relatively distal proving source while their shiny blunted appearance evokes an aquatic environment. The sediments of these wells are therefore sands of fluviatile origin, deposited in a shallow marine environment.


1982 ◽  
Vol 37 (11) ◽  
pp. 1304-1326 ◽  
Author(s):  
J. Doyne Farmer

The concepts of entropy and dimension as applied to dynamical systems are reviewed from a physical point of view. The information dimension, which measures the rate at which the information contained in a probability density scales with resolution, fills a logical gap in the classification of attractors in terms of metric entropy, fractal dimension, and topological entropy. Several examples are presented of chaotic attractors that have a self similar, geometrically scaling structure in their probability distribution; for these attractors the information dimension and fractal dimension are different. Just as the metric (Kolmogorov-Sinai) entropy places an upper bound on the information gained in a sequence of measurements, the information dimension can be used to estimate the information obtained in an isolated measurement. The metric entropy can be expressed in terms of the information dimension of a probability distribution constructed from a sequence of measurements. An algorithm is presented that allows the experimental determination of the information dimension and metric entropy.


Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 268 ◽  
Author(s):  
Luciana Randazzo ◽  
Michela Ricca ◽  
Silvestro Ruffolo ◽  
Marco Aquino ◽  
Barbara Davidde Petriaggi ◽  
...  

This paper aims to carry out an archaeometric characterization of mortar samples taken from an underwater environment. The fishpond of the archaeological site of Castrum Novum (Santa Marinella, Rome, Italy) was chosen as a pilot site for experimentation. The masonry structures reached the maximum thickness at the apex of the fishpond (4.70 m) and consisted of a concrete conglomerate composed of slightly rough stones of medium size bound with non-hydraulic mortar. After sampling, for a complete characterization of selected mortar fragments, different and complementary techniques (stereomicroscopy, polarizing optical microscopy, and X-ray powder diffraction analysis) were carried out in order to: a) define the minero-petrographic features; and b) investigate their state of conservation. The obtained data allowed the determination of the main constituents of mortars from a compositional point of view. The raw materials, in fact, were quite homogeneous, as well as the ratio in which they were mixed, confirming the typical "recipe" used in Roman times to manufacture hydraulic-type mortars by adding pozzolana. At the same time, it was possible to identify the various degradation processes we were interested in, namely, biological colonization (bio-fouling) that develops differently according to environmental conditions. Based on characterization phase results, the research will help to develop adequate techniques for intervention (innovative tools and methods for the protection of underwater cultural heritage) with particular regard to cleaning and consolidating procedures to be carried out directly in situ.


2013 ◽  
Vol 778 ◽  
pp. 690-697
Author(s):  
Maria Rosa Valluzzi ◽  
Antonino di Bella ◽  
Enrico Garbin

In the paper, the results of an experimental study aimed at evaluating the mutual influence among the intervention techniques normally employed to improve separately the acoustic or the mechanical performance of timber floors are provided. The superimposition of planks having different thickness and arrangement or connections is usually considered to improve the in-plane stiffness of floors, especially in case of interventions on existing buildings in seismic zone, to take into account, if possible, also preservation criteria. On the other hand, the improvement of acoustic comfort is addressed to the use of specific noise-abating materials, like insulating boards (OSB) or sheathings, whose contribution, in terms of mechanical stiffness/strength is often neglected. This work proposes a combined interpretation of the two abovementioned requirements, through the characterization of the main parameters governing the involved physical and mechanical phenomena. The first results obtained on simple unidirectional full-scale specimens of floors are presented; seven combinations among various solution of boards and noise-abating materials are compared, first from a structural and subsequently acoustic point of view. The results allow identifying the solution, which is able to optimize at best both the mechanical and acoustic requirements, to be proposed for the intervention on existing timber floors.


2001 ◽  
Vol 664 ◽  
Author(s):  
Roger Loo ◽  
Philippe Meunier-Beillard ◽  
Didier Dentel ◽  
Michael Goryll ◽  
Danielle Vanhaeren ◽  
...  

ABSTRACTSi based nanostructures such as Ge or Si1-xGex dots embedded in Si receive a lot of attention. This interest is driven by the reduction of device sizes as well as by their possible use in opto-electronic applications, as a possible solution to improve the radiative light emission. In this paper we give a detailed overview of the growth kinetics as observed for Ge growth in a standard production oriented chemical vapor deposition system. The island morphology and density are controlled by varying the growth conditions or by applying a thermal anneal after the island growth. Island densities up to 2.3x1010 cm−2 have been obtained for depositions at 650°C. With increasing deposition time, the usual change-over from monomodal to bimodal island distribution is pointed out and this change-over depends on the critical island diameter, which decreases with decreasing growth temperature. Applying a thermal budget after the island growth initiates Ge surface diffusion and Si diffusion from the substrate through the islands. This results in an enhancement of the island diameter and height, and also in a reduction of island density. Furthermore, depending on the island distribution after Ge deposition, a transition from pyramid to dome or visa versa is observed after the in-situ anneal. Optical device structures require a Si cap layer. However, Si capping at 700°C, leads to a nearly total dissolution of small islands and a truncation of bigger dome-shaped islands. This can be prevented by reducing the deposition temperature and by changing the Si gas source. Clear island luminescence, is observed up to 200K and lies in the spectral range of 1.35-1.50μm, which is interesting from the point of view of applications. In particular, this shows the potential of this material system for opto-electronic device applications. In spite of the fact that the observed PL intensity is comparable to the best reported values, we could further enhance it by a thermal treatment in a H2 plasma.


1989 ◽  
Vol 145 ◽  
Author(s):  
A. S. Jordan ◽  
S. J. Pearton ◽  
W. S. Hobson

AbstractWe review the growth of GaAs on Si by MO-CVD and MBE and discuss the relative merits of these techniques. Major emphasis is placed on the structural and optical characterization of the material that may be indicative of device performance. Typical GaAs layers on Si are free of anti- phase domains and the crystallinity at the surface for a 3-4μm thick deposit approaches that of bulk GaAs, as evidenced by the RBS backscattering yields and Si ion implantation profiles. The major drawbacks of GaAs heteroepitaxy on Si are the very large dislocation densities (106- 109cm−2), the relatively high unintentional doping concentration (>5 × 1014cm−3) that is partly attributable to Si outdiffusion, and the excessive bowing due to thermal expansion coefficient mismatch. While there are growth and processing techniques to overcome bowing or at least its influence, dislocations and low resistivity are hard to remedy. We discuss novel schemes to reduce dislocations (selective area growth, superlattices and thermal cycling) and efforts to improve the electrical properties (doping, optimization of V/III ratio). A variety of electronic devices and circuits have been fabricated using GaAs/Si. We shall present results on MESFETs, HBTs and HFETs processed in our laboratory and elsewhere. It is quite encouraging that HFETs with a transconductance of 220mS/mm are achievable. However, lasers in room temperature CW operation still have a very limited lifetime. Finally, we discuss the implications of GaAs/Si for a broader area of mismatched heteroepitaxy (InP/Si, InP/GaAs, etc.) and speculate on the future prospects for this new materials technology.


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