Comparison of Porous Ceramic Materials with Low Thermal Expansion Coefficient Prepared with SiC and Black-Al2O3

2008 ◽  
Vol 569 ◽  
pp. 321-324
Author(s):  
Isaías Juárez-Ramírez ◽  
Koji Matsumaru ◽  
Kozo Ishizaki ◽  
Leticia M. Torres-Martínez
Keyword(s):  
Thermal Expansion ◽  
Room Temperature ◽  
Raw Materials ◽  
Porous Ceramic ◽  
Ceramic Materials ◽  
X Ray Diffraction ◽  
Low Thermal Expansion ◽  
New Phase ◽  
Porous Ceramic Materials ◽  
Made In

Porous ceramic materials with low thermal expansion (LTE) at room temperature were prepared by heating a mixture of SiC or black-Al2O3, vitrified bonding material (VBM) and LiAlSiO4 at temperatures from 850°C to 1100°C. The mixture was prepared in adequate proportions to obtain a material with LTE according to previous works made in our laboratory. It was observed that a change in temperature provoked the formation of a new phase, LiAlSi3O8, which appears above 900°C. The presence of this new phase did not affect the thermal expansion value, keeping LTE at room temperature. All compounds showed around 40% of porosity, and Young’s modulus values of 30 GPa using black-Al2O3 or SiC. X-ray diffraction analysis (XRD) revealed that above 900°C the phase LiAlSi3O8 starts to appear as a consequence of the melting of VBM, which is reacting with the raw materials. SEM micrographs showed the presence of SiC or black-Al2O3 grains joined by VBM, which is acting as a bridge between them.

Preparation and Characterization of Quartz Porous Ceramic Materials Using the Yangtze River Sand

2013 ◽  
Vol 804 ◽  
pp. 52-56
Author(s):  
Yan Ping Feng ◽  
Zhi Wen Qiu ◽  
Xiao Bin Ma ◽  
Lei Zhao ◽  
Xin Chao Chen ◽  
...  
Keyword(s):  
Yangtze River ◽  
Raw Materials ◽  
Porous Ceramic ◽  
Ceramic Materials ◽  
Porous Ceramics ◽  
Low Grade ◽  
The Yangtze River ◽  
Insulation Property ◽  
River Sand ◽  
Porous Ceramic Materials

In order to lay raw materials foundation for increasing the performance of insulating brick with the low grade quartz sand along the Yangtze River, the quartz porous ceramic materials was researched in this paper. The results show the porosity of the porous quartz ceramics decreased with an increase in the sintering temperature. The pore is like the bowl shape, and the pore is closed pore, which is help to improve the heat insulation property of quartz porous ceramics. The CaSiO4 is produced in the ceramics after sintering processing. The shape is better, and the microstructure is circular and symmetrical pore, which is help to improve the mechanical property of quartz porous ceramics.

Hydrothermal Slag/Glass Chemistry for Porous Materials Production

2012 ◽  
Vol 521 ◽  
pp. 35-45 ◽  
Author(s):  
Masanori Suzuki ◽  
Toshihiro Tanaka
Keyword(s):  
Raw Materials ◽  
Porous Ceramic ◽  
Hydrothermal Process ◽  
Value Added ◽  
Ceramic Materials ◽  
Hydrothermal Conditions ◽  
Conventional Sintering ◽  
Slag Glass ◽  
Sintering Processes ◽  
Porous Ceramic Materials

Hydrothermal treatment has been conducted to create porous glass or ceramics as value-added materials for the recycling of slag and glass. Under hydrothermal conditions, slag and glass react with a high pressurized H2O and hydrate glass phase containing plenty of H2O is formed to connect raw materials particles to make ceramic materials. The hydrothermal process takes advantages of energy costs, because it can be operated at a low temperature compared to conventional sintering processes. Since the hydrothermal process uses H2O to fabricate ceramic materials, it can be regarded as energy-saving, eco-friendly, and spontaneous materials processing. In the present study, we introduce some applications of hydrothermal treatments to slag / glass to produce functional porous ceramic materials.

Use of Kaolin Processing Waste for the Production of Mullite Bodies

2008 ◽  
Vol 591-593 ◽  
pp. 799-804 ◽  
Author(s):  
Maria Isabel Brasileiro ◽  
Romualdo Rodrigues Menezes ◽  
M.O. Farias ◽  
Hélio Lucena Lira ◽  
Gelmires Araújo Neves ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Flexural Strength ◽  
Raw Materials ◽  
Processing Waste ◽  
X Ray Diffraction ◽  
Mullite Ceramic ◽  
Processing Industry ◽  
X Ray ◽  
Three Point Bending ◽  
Low Thermal Expansion

Mullite is a versatile material used in traditional and advanced ceramic, due to low thermal expansion, high thermal shock and creep resistance. The production of waste from ore industry is a problem that is increasing nowadays. The kaolin processing industry produces residue rich in Al2O3 and SiO2. These oxides are good precursors to produce mullite. The aim of this work is to use the residue from kaolin industry to produce mullite ceramic bodies. It was studied alumina, clay and residue from kaolin processing as raw materials. The material was dried and pressing in uniaxial press (30MPa). The samples were sintered at temperatures of 1450oC, 1500oC, 1550oC and 1600oC. The ceramic bodies were characterized by X-ray diffraction. The density was measured by Archimedes method and the flexural strength by the three point bending technique. The results showed that is possible to produce mullite with high amount of waste from kaolin processing.

scholarly journals An Investigation of Thermal Shock in Porous Clay Ceramics

2011 ◽  
Vol 2011 ◽  
pp. 1-9 ◽  
Author(s):  
F. W. Nyongesa ◽  
N. Rahbar ◽  
S. K. Obwoya ◽  
J. Zimba ◽  
B. O. Aduda ◽  
...  
Keyword(s):  
Thermal Shock ◽  
Residual Strength ◽  
Room Temperature ◽  
Porous Ceramic ◽  
Ceramic Materials ◽  
Shock Resistance ◽  
Bend Tests ◽  
Clay Ceramics ◽  
Porous Ceramic Materials

The thermal shock resistance of porous ceramic materials is often characterized by the Hasselman parameters. However, in other scenarios, the room-temperature residual strengths after thermal shock are also used to quantify the damage due to thermal shock. This paper attempts to link the measured residual strengths to the dominant crack features that are introduced due to thermal shock in porous clay ceramics produced by the sintering of clay powders with well-controlled size ranges. Residual strength estimates from bend tests are compared with fracture mechanics predictions. The implications of the residual strength results are then discussed for the characterization of damage due to thermal shock.

scholarly journals Sintering Behavior, Thermal Expansion, and Environmental Impacts Accompanying Materials of the Al2O3/ZrO2 System Fabricated via Slip Casting

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3365
Author(s):  
Justyna Zygmuntowicz ◽  
Magdalena Gizowska ◽  
Justyna Tomaszewska ◽  
Paulina Piotrkiewicz ◽  
Radosław Żurowski ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Life Cycle ◽  
Coefficient Of Thermal Expansion ◽  
Raw Materials ◽  
Slip Casting ◽  
Ceramic Materials ◽  
Sintering Behavior ◽  
Environmental Loads ◽  
Practical Applications ◽  
Technical Ceramics

This work focuses on research on obtaining and characterizing Al2O3/ZrO2 materials formed via slip casting method. The main emphasis in the research was placed on environmental aspects and those related to the practical use of ceramic materials. The goal was to analyze the environmental loads associated with the manufacturing of Al2O3/ZrO2 composites, as well as to determine the coefficient of thermal expansion of the obtained materials, classified as technical ceramics. This parameter is crucial in terms of their practical applications in high-temperature working conditions, e.g., as parts of industrial machines. The study reports on the four series of Al2O3/ZrO2 materials differing in the volume content of ZrO2. The sintering process was preceded by thermogravimetric measurements. The fabricated and sintered materials were characterized by dilatometric study, scanning electron microscopy, X-ray diffraction, and stereological analysis. Further, life cycle assessment was supplied. Based on dilatometric tests, it was observed that Al2O3/ZrO2 composites show a higher coefficient of thermal expansion than that resulting from the content of individual phases. The results of the life cycle analysis showed that the environmental loads (carbon footprint) resulting from the acquisition and processing of raw materials necessary for the production of sinters from Al2O3 and ZrO2 are comparable to those associated with the production of plastic products such as polypropylene or polyvinyl chloride.

scholarly journals Substitutions of Zr4+/V5+ for Y3+/Mo6+ in Y2Mo3O12 for Less Hygroscopicity and Low Thermal Expansion Properties

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3945 ◽  
Author(s):  
Qiang Ma ◽  
Lulu Chen ◽  
Heng Qi ◽  
Qi Xu ◽  
Baohe Yuan ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Expansion ◽  
Crystal Structures ◽  
Room Temperature ◽  
Crystal Water ◽  
Thermal Expansion Property ◽  
Expansion Property ◽  
Low Thermal Expansion ◽  
Substitution Content ◽  
Structure And Microstructure

In this investigation, ZrxY2−xVxMo3−xO12 (0 ≤ x ≤ 1.4) is developed and the effects of the substitutions of Zr4+/V5+ for Y3+/Mo6+ in Y2Mo3O12 on the hygroscopicity and thermal expansion property are investigated. For the smaller substitution content (x ≤ 0.5), their crystal structures remain orthorhombic, while there is crystal water still in the lattice. The linear coefficients of thermal expansions (CTEs), for x = 0.1, 0.3, 0.5, and 0.7, are about −4.30 × 10−6, −0.97 × 10−6, 0.85 × 10−6, and 0.77 × 10−6 K−1, respectively, from 476 to 773 K, which means that the linear CTE could be changed linearly with the substitution content of Zr4+/V5+ for Y3+/Mo6+ in Y2Mo3O12. As long as the substitution content reaches x = 1.3/1.4, almost no hygroscopicity and low thermal expansion from room temperature are obtained and are discussed in relation to the crystal structure and microstructure.

scholarly journals Preparation and Characterization of Porous Ceramic Membranes for Micro-Filtration from Clay/CuZn Using Extrusion Methods

2018 ◽  
Vol 156 ◽  
pp. 08015 ◽  
Author(s):  
Muh Amin ◽  
Muhammad Subri
Keyword(s):  
Porous Ceramic ◽  
Ceramic Materials ◽  
Ceramic Membranes ◽  
Extrusion Process ◽  
X Ray Diffraction ◽  
Percentage Composition ◽  
X Ray ◽  
Ceramic Support ◽  
Fabrication And Characterization

In this study, fabrication and characterization of ceramic membranes preparation was carried out. Porous ceramic membranes were fabricated by extrusion process from different percentage composition of CuZn on (80 wt% Clay, 10 wt% TiO2, 5 wt% Carbon and 5 wt% PVA). The fabricated membranes were sintered at 900°C for 1 hour in an electrical box furnace with heating rate 1oC/min and holding time for 1 hour. Apparent density and porosity were determined by standar methods for ceramic materials. Phase composition of the ceramic support was established by X-Ray Diffraction analysis. SEM studies of the membranes added at different CuZn were carried out.

scholarly journals Centrifugal Infiltration of Porous Ceramic Preforms by the Liquid Al Alloy – Theoretical Background and Experimental Verification

2016 ◽  
Vol 61 (1) ◽  
pp. 411-418 ◽  
Author(s):  
A.J. Dolata
Keyword(s):  
Heat Exchange ◽  
Liquid Metal ◽  
Experimental Verification ◽  
Porous Ceramic ◽  
Specific Area ◽  
Ceramic Materials ◽  
Theoretical Background ◽  
Al Alloy ◽  
Ceramic Preform ◽  
Porous Ceramic Materials

The goal of this work is the description of phenomena occurring during centrifugal infiltration of porous ceramic materials by liquid Al alloy. In this method, the pressure required to infiltration of liquid metal into pores of ceramic is generated by centrifugal force. From the beginning it was assumed that the porous ceramic material will create reinforcement layer in specific area of the casting. The forces that influence on the liquid metal during mould centrifugation and heat exchange between ceramic preform and metal alloy within the area of the front of infiltration were considered in the analysis. The paper presents also selected experiment results.

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