Pressure Assisted Sintering of an Aluminium Alloy

2009 ◽  
Vol 618-619 ◽  
pp. 627-630
Author(s):  
Stephen J. Bonner ◽  
Graham B. Schaffer ◽  
Ji Yong Yao

An aluminium alloy was sintered using a conventional press and sinter process, at various gas pressures, to observe the effect of sintering gas pressure on the densification rate. Compacts of aluminium alloy 2712 (Al-3.8Cu-1Mg-0.7Si-0.1Sn) were prepared from elemental powders and sintered in a horizontal tube furnace under nitrogen or argon at 590°C for up to 60 minutes, and air cooled. The gas flow was adjusted to achieve specific gas pressures in the furnace. It has been found that increasing the nitrogen pressure at the start of the isothermal holding stage to 160kPa increased the densification rate compared to standard atmospheric pressure sintering. Increasing the nitrogen pressure further, up to 600kPa, had no additional benefit. The densification rate was increased significantly by increasing the gas pressure to 600kPa during both heating and isothermal holding. Under argon the elevated pressure did not increase the densification rate. Results seem to suggest that the beneficial effect of the elevated pressure on the rate of densification is related to nitride formation.

2019 ◽  
Vol 6 (3) ◽  
pp. 227-230
Author(s):  
M. E. Pinchuk ◽  
A. V. Budin ◽  
N. K. Kurakina ◽  
A. G. Leks

The paper presents some results concerning electrophysical and gas-dynamics parameters of high-curent arc in axial blast discharge chamber. The experimental stand and numerical model were modified for axial gas flow type. Some design changes are described in the paper. The experiments were carried out for gas pressures of 1.0-6.0 MPa with current amplitude of 25-150 kA. The current half-period was of 1.0-10.0 ms. The contacts moved apart to the distance of 3-4 cm due to gas pressure boost in the chamber. OpenFOAM package with the library swak4foam was used for numerical simulation.


2003 ◽  
Vol 807 ◽  
Author(s):  
Stephen T. Horseman ◽  
Jon F. Harrington ◽  
P. Sellin

ABSTRACTThis paper describes a long-term laboratory test designed to examine the sensitivity of gas flow in Mx80 buffer bentonite subject to a constant volume boundary condition. A constant volume and radial flow (CVRF) apparatus was designed to enable gas flow from a centrally located injection filter to be independently monitored at three sink-filter arrays mounted around the circumference of the clay specimen. Axial and radial total stresses and internal porewater pressure were continuously monitored. Gas entry, breakthrough and peak gas pressures were found to be systematically higher under constant volume boundary conditions than under previously reported constant stress and radially-constrained test conditions [6, 9, 10]. The observation that gas pressures are sensitive to test boundary conditions supports the hypothesis that gas entry is accompanied by dilation of the bentonite fabric. Gas penetration of the clay caused a substantial increase in total stress and internal porewater pressure. Abrupt drops in gas pressure, accompanied by similar drops in total stress, were interpreted as fracture propagation events. The outflow of gas was always non-uniformly distributed between the sinks. Furthermore, the distribution of flow between sinks often changed abruptly during the course of an experiment indicating that gas pathways were very unstable. When gas injection stopped, the gas pressure and rate of outflow spontaneously declined with time. Under constant volume conditions, the gas pressure at the asymptote exceeded the internal porewater pressure by an amount equal to the capillary pressure. In constant volume tests on clay with high water saturation, capillary pressure has a value close to the measured swelling pressure of the clay.


Author(s):  
Nathaniel Metzger ◽  
Archana Sekar ◽  
Jun Li ◽  
Xianglin Li

Abstract The gas flow of carbon dioxide from the catalyst layer (CL) through the microporous layer (MPL) and gas diffusion layer (GDL) has great impacts on the water and fuel management in direct methanol fuel cells (DMFCs). This work has developed a liquid–vapor two-phase model considering the counter flow of carbon dioxide gas, methanol, and water liquid solution in porous electrodes of DMFC. The model simulation includes the capillary pressure as well as the pressure drop due to flow resistance through the fuel cell components. The pressure drop of carbon dioxide flow is found to be about two to three orders of magnitude higher than the pressure drop of the liquid flow. The big difference between liquid and gas pressure drops can be explained by two reasons: volume flowrate of gas is three orders of magnitude higher than that of liquid; only a small fraction of pores (<5%) in hydrophilic fuel cell components are available for gas flow. Model results indicate that the gas pressure and the mass transfer resistance of liquid and gas are more sensitive to the pore size distribution than the thickness of porous components. To buildup high gas pressure and high mass transfer resistance of liquid, the MPL and CL should avoid micro-cracks during manufacture. Distributions of pore size and wettability of the GDL and MPL have been designed to reduce the methanol crossover and improve fuel efficiency. The model results provide design guidance to obtain superior DMFC performance using highly concentrated methanol solutions or even pure methanol.


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Xiao Fukun ◽  
Meng Xin ◽  
Li Lianchong ◽  
Liu Jianfeng ◽  
Liu Gang ◽  
...  

Based on gas seepage characteristics and the basic thermo-solid-gas coupling theory, the porosity model and the dynamic permeability model of coal body containing gas were derived. Based on the relationship between gas pressure, principal stress and temperature, and gas seepage, the thermo-solid-gas coupling dynamic model was established. Initial values and boundary conditions for the model were determined. Numerical simulations using this model were done to predict the gas flow behavior of a gassy coal sample. By using the thermo-solid-gas coupling model, the gas pressure, temperature, and principal stress influence, the change law of the pressure field, displacement field, stress field, temperature field, and permeability were numerically simulated. Research results show the following: (1) Gas pressure and displacement from the top to the end of the model gradually reduce, and stress from the top to the end gradually increases. The average permeability of the Y Z section of the model tends to decrease with the rise of the gas pressure, and the decrease amplitude slows down from the top of the model to the bottom. (2) When the principal stress and temperature are constant, the permeability decreases first and then flattens with the gas pressure. The permeability increases with the decrease of temperature while the gas pressure and principal stress remain unchanged.


2019 ◽  
Vol 13 (27) ◽  
pp. 76-82
Author(s):  
Kadhim A. Aadim

Low-pressure capacitively coupled RF discharge Ar plasma has been studied using Langmuir probe. The electron temperature, electron density and Debay length were calculated under different pressures and electrode gap. In this work the RF Langmuir probe is designed using 4MHz filter as compensation circuit and I-V probe characteristic have been investigated. The pressure varied from 0.07 mbar to 0.1 mbar while electrode gap varied from 2-5 cm. The plasma was generated using power supply at 4MHz frequency with power 300 W. The flowmeter is used to control Argon gas flow in the range of 600 standard cubic centimeters per minute (sccm). The electron temperature drops slowly with pressure and it's gradually decreased when expanding the electrode gap. As the gas pressure increases, the plasma density rises slightly at low gas pressure while it drops little at higher gas pressure. The electron density decreases rapidly with expand distances between electrodes.


2021 ◽  
Vol 25 (6 Part B) ◽  
pp. 4651-4658
Author(s):  
Teng Teng ◽  
Xiaoyan Zhu ◽  
Yu-Ming Wang ◽  
Chao-Yang Ren

Gas-flow in coal or rock is hypersensitive to the changes of temperature, confin?ing pressure and gas pressure. This paper implemented a series of experiments to observe the seepage behavior, especially the permeability evolution of CO2 in naturally fractured coal sample under coupled hydro-thermal-mechanical conditions. The experimental results show that coal permeability increases exponentially with the increasing gas pressure, and tends to be linear when the confining pressure is high. Coal permeability decreases exponentially with the increasing confining pressure. Coal permeability decreases with the increasing temperature generally, but it may bounce up when the temperature rises to high. The results provide reference for the projects of coal gas extraction and carbon dioxide geological sequestration.


Author(s):  
Patrick Magee ◽  
Mark Tooley

The physics of pressure, flow and the gas laws have been discussed in Chapter 7 in relation to the behaviour of gas and vapour. This section will focus on the physical principles of the measurement of gas pressure, volume and flow. Unlike a liquid, a gas is compressible and the relationship between pressure, volume and flow depends on the resistance to gas flow (or impedance if there is a frequency dependence between pressure and flow in alternating flow, see Chapter 4 for the electrical analogy of this) in conduits (bronchi, anaesthetic tubing); it also depends on the compliance of structures being filled and emptied (alveoli, reservoir bags, tubing or bellows). Normal breathing occurs by muscular expansion of the thorax, thus lowering the intrathoracic pressure, allowing air or anaesthetic gas to flow towards the alveoli down a pressure gradient from atmospheric pressure. When positive pressure ventilation occurs, gas is ‘pushed’ under pressure into the alveoli. Depending on the exact relationship between the ventilator and the lungs, different relationships exist between airway pressure (rather than alveolar pressure, which cannot easily be measured) and gas flow and volume. Gas pressure measurement devices were traditionally in the form of an aneroid barometer, a hollow metal bellows calibrated for pressure and temperature, which contracts when the external pressure on it increases, and expands when it decreases. The movement is linked to a pointer and indicator dial. It is often more convenient to make the device in the shape of part of a circular section, but the principle is the same. This is what the Bourdon gauge, which commonly measures pressure in gas cylinders, looks like. The detection of movement of the diaphragm of an aneroid barometer can take several forms. The movement can either be linked via a direct mechanical linkage to a pointer, or diaphragm movement can be linked to a capacitative or inductive element in an electrical circuit, such as a Wheatstone bridge. Airway pressure during spontaneous breathing or artificial ventilation is low. The preferred units of measurement are cm H2O and the range of values is between −20 and +20 cmH2O. The aneroid barometer to measure this will therefore be of light construction, using thin copper for the bellows material.


Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2387 ◽  
Author(s):  
Bo Zhang ◽  
Yong Li ◽  
Nicholas Fantuzzi ◽  
Yuan Zhao ◽  
Yan-Bao Liu ◽  
...  

Coal contains a large number of fractures, whose characteristics are difficult to describe in detail, while their spatial distribution patterns may follow some macroscopic statistical laws. In this paper, several fracture geometric parameters (FGPs) were used to describe a fracture, and the coal seam was represented by a two-dimensional stochastic fracture network (SFN) which was generated and processed through a series of methods in MATLAB. Then, the processed SFN image was able to be imported into COMSOL Multiphysics and converted to a computational domain through the image function. In this way, the influences of different FGPs and their distribution patterns on the permeability of the coal seam were studied, and a finite element model to investigate gas flow properties in the coal seam was carried out. The results show that the permeability of the coal seam increased with the rising of fracture density, length, aperture, and with the decrease of the angle between the fracture orientation and the gas pressure gradient. It has also been found that large-sized fractures have a more significant contribution to coal reservoir permeability. Additionally, a numerical simulation of CBM extraction was carried out to show the potential of the proposed approach in the application of tackling practical engineering problems. According to the results, not only the connectivity of fractures but also variations of gas pressure and velocity can be displayed explicitly, which is consistent well with the actual situation.


1996 ◽  
Vol 13 (2) ◽  
pp. 71-84 ◽  
Author(s):  
Adam Nodzeński

During the liberation of gas from a coal bed, the temperature of the system is decreased because desorption is an endothermic process and heat exchange with the surroundings is difficult. A method for measuring gas desorption in the elevated pressure range, enabling investigations under isothermal and quasi-adiabatic conditions, was described. The results of carbon dioxide desorption from Polish coal were presented. The study was carried out using different rates of decrease in the external gas pressure for different coal grain sizes. The non-isothermal desorption curves thus obtained were described using empirical equations. Extrapolation of the equation constants obtained enabled the desorption curves to be calculated for the limit of decrease in rate of the external gas pressure and of grain size. It was found experimentally that the dependence of the decrease in coal temperature on the amount of desorbed gas is linear provided that heat exchange with the surroundings is limited.


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