Fabrication and Properties of APS- and RTS-Sprayed TiB2/Mo2FeB2 Multiphase Ceramic Coating on Q235 Steel

2011 ◽  
Vol 704-705 ◽  
pp. 1244-1252 ◽  
Author(s):  
Xin Ling Guo ◽  
Wei Wang ◽  
Shao Jie Li
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Mass Loss ◽  
Thermal Shock ◽  
Steel Substrate ◽  
Ceramic Coatings ◽  
Atmospheric Plasma ◽  
Composite Powders ◽  
Q235 Steel ◽  
Sprayed Coatings

A kind of TiB2/Mo2FeB2 composite powders for reactive thermal spraying (RTS) and atmospheric plasma spraying (APS) were prepared using Mo powder, Fe-B alloy powder, Fe powder and TiB2 powder. The TiB2/Mo2FeB2 composite ceramic coatings were synthesized and deposited by APS and RTS on Q235 steel. Microstructure and phases were investigated by X-ray diffraction (XRD) and scanning electrical microscopy (SEM). The thermal shock resistance, wear resistance and corrosion resistance were characterized with the relevant lab testing equipment. The result indicates that the coatings are composed of the major phases Mo2FeB2, TiB2 and α-Fe, a little of Fe2O3, FeO, and B2O3.The thermal shock times of RTS-sprayed coatings is 44, the corrosion resistance is 6.07 times than those of the substrate, respectively, while those of APS-sprayed coatings are 55 and 15.5, respectively. The mass loss of Q235 steel is 138.6g/m2, while the mass loss of the coatings with 30% TiB2 which were prepared by RTS is 28.0952g/m2, the mass loss of the coatings with 30% which were prepared by APS is 15.4028g/m2, when the testing load was 400N. Therefore, the coatings with 30%TiB2 prepared by APS possess better wear resistance than the Q235 steel substrate.

The Research of Thermal Arc Sprayed Coatings Tribological Properties by Using Rubber Wheel Test

2015 ◽  
Vol 220-221 ◽  
pp. 693-697 ◽  
Author(s):  
Justinas Gargasas ◽  
Algirdas Vaclovas Valiulis ◽  
Irmantas Gedzevicius ◽  
Hanna Pokhmurska
Keyword(s):  
Wear Resistance ◽  
Mass Loss ◽  
Tribological Properties ◽  
Steel Substrate ◽  
High Wear Resistance ◽  
Tribological Behaviour ◽  
Oxide Inclusions ◽  
Porosity Of Coatings ◽  
Sprayed Coatings ◽  
Thermal Sprayed Coatings

This paper present the result obtained from new experimental STEIN-MESYFIL 953 V; STEIN-MESYFIL 954 V coatings. The surfacing material was wires of 1.6 mm diameter. The tests aimed at determining wear resistance of coatings sprayed on steel substrate. The investigation shows that the tribological behaviour of new experimental thermal arc sprayed coatings is greatly affected by its microstructural constituents such as porosity, oxide inclusions, and microhardness of coatings. Results show that increasing porosity of coatings twice, it doubles the mass loss. Results for thermal sprayed coatings of all experiments showed their high wear resistance and are discussed.

Determination of Abrasive Wear Resistance of Plasma Sprayed Coatings on Stainless Steel Substrate

2015 ◽  
Vol 766-767 ◽  
pp. 579-584 ◽  
Author(s):  
A. Anderson
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Abrasive Wear ◽  
Steel Substrate ◽  
Ceramic Coatings ◽  
Atmospheric Plasma ◽  
Wear Behaviour ◽  
Coating Materials ◽  
Plasma Sprayed Coatings ◽  
Plasma Sprayed

A relative study among various types of coating materials to develop wear resistance of stainless steel has been performed. Ceramic coatings with the thickness up to 250 μm were prepared by Atmospheric plasma spray technique on the stainless steel. Two different types of coating materials such that Yttria Stabilised Zirconia, Zirconia Ceria powder were used. The influence of Ceria powder on abrasive wear was determined. It was found that the addition of Ceria to Yttria Stabilised Zirconia in a sufficient amount helped in increasing its wear resistance compared to the wear behaviour of pure Yttria Stabilised Zirconia powder. Moreover, it was found that the lesser the surface roughness of the coating layer,.

Laser Sintering of Nano-Al2O3 Powders on Plasma Sprayed Ceramic Based Coatings

2007 ◽  
Author(s):  
Lida Shen ◽  
Yinhui Huang ◽  
Zongjun Tian ◽  
Guoran Hua
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Plasma Spraying ◽  
Bond Coat ◽  
Continuous Wave ◽  
Ceramic Coatings ◽  
Laser Sintering ◽  
Al2o3 Ceramic ◽  
Plasma Sprayed ◽  
Steel Substrates

This paper describes an investigation of nano-Al2O3 powders reinforced ceramic coatings, which has included NiCrAl and Al2O3+13%wt.TiO2 coats pre-produced by atmosphere plasma spraying, implemented by laser sintering. Commercial NiCrAl powders were plasma sprayed onto 45 Steel substrates to give a bond coat with thickness of ∼100μm. The 600μm thick Al2O3+13%wt.TiO2 based coating was also plasma sprayed on top of the NiCrAl bond coat. With 2.5kw continuous wave CO2 laser, nano-Al2O3 ceramic powders were laser sintered on the based Coatings. The micro structure and chemical composition of the modified Al2O3+13%wt.TiO2 coatings were analyzed by such detection devices as scanning electronic microscope (SEM) and x-ray diffraction (XRD). Microhardness, wear resistance and corrosion resistance of the modified coatings were also tested and compared with that of the unmodified. The results show that the crystal grain size of Al2O3 had no obvious growth. In addition, due to the nanostructured Al2O3 ceramic phases, the coatings exhibited higher microhardness, better wear resistance and corrosion resistance than those unmodified counterparts. The complex process of plasma spraying with laser sintering as a potential effective way of the application of ceramic nano materials was also simply discussed and summarized in the end.

scholarly journals Microstructural and Corrosion Behavior of High Velocity Arc Sprayed FeCrAl/Al Composite Coating on Q235 Steel Substrate

Coatings ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 542 ◽  
Author(s):  
Ndumia Joseph Ndiithi ◽  
Min Kang ◽  
Jiping Zhu ◽  
Jinran Lin ◽  
Samuel Mbugua Nyambura ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Composite Coating ◽  
High Velocity ◽  
Steel Substrate ◽  
Arc Spraying ◽  
Spray Parameters ◽  
Q235 Steel ◽  
Electrochemical Tests ◽  
Al Composite ◽  
Al Coating

High velocity arc spraying was used to prepare FeCrAl/Al composite coating on Q235 steel substrate by simultaneously spraying FeCrAl wire as the anode and Al wire as the cathode. The composite coating was sprayed with varying voltage and current to obtain optimum coating characteristics. FeCrAl coating was also prepared for comparison purposes. The surface microstructure of the coatings was characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The average microhardness of the coatings and the substrate was analyzed and compared. Corrosion resistance was investigated by means of electrochemical tests. The image results showed that a lamellar structure consisted of interwoven layers of FeCrAl and Al. Al and FeCr constituted the main phases with traces of oxides and AlFe intermetallic compounds. The average porosity was reduced and microhardness of the coatings was improved with increasing voltage and current. The FeCrAl/Al coating formed alternating layers of hard and ductile phases; the corrosion resistance of the coatings in the sodium chloride (NaCl) solution depended on the increase in Al content and spray parameters. The corrosion resistance tests indicated that FeCrAl/Al coating had a better corrosion resistance than the FeCrAl coating. FeCrAl/Al can be used to coat steel substrates and increase their corrosion resistance.

Development & Characterization of Alumina Coating by Atmospheric Plasma Spraying

2018 ◽  
Vol 877 ◽  
pp. 104-109 ◽  
Author(s):  
Jobin Sebastian ◽  
Abyson Scaria ◽  
Don George Kurian
Keyword(s):  
Plasma Spraying ◽  
Elevated Temperatures ◽  
Steel Substrate ◽  
Oxide Coating ◽  
Ceramic Coatings ◽  
Substrate Material ◽  
Atmospheric Plasma ◽  
Flame Spraying ◽  
Alumina Coating ◽  
Spray Process

Ceramic coatings are applied on metals to prevent them from oxidation and corrosion at room as well as elevated temperatures. The service environment, mechanisms of protection, chemical and mechanical compatibility, application method, control of coating quality and ability of the coating to be repaired are the factors that need to be considered while selecting the required coating. The coatings based on oxide materials provides high degree of thermal insulation and protection against oxidation at high temperatures for the underlying substrate materials. These coatings are usually applied by the flame or plasma spraying methods. The surface cleanliness needs to be ensured before spraying. Abrasive blasting can be used to provide the required surface roughness for good adhesion between the substrate and the coating. A pre bond coat like Nickel Chromium can be applied on to the substrate material before spraying the oxide coating to avoid chances of poor adhesion between the oxide coating and the metallic substrate. Plasma spraying produces oxide coatings of greater density, higher hardness, and smooth surface finish than that of the flame spraying process Inert gas is often used for generation of plasma gas so as to avoid the oxidation of the substrate material. The work focuses to develop, characterize and optimize the parameters used in Al2O3 coating on transition stainless steel substrate material for minimizing the wear rate and maximizing the leak tightness using plasma spray process. The experiment is designed using Taguchi’s L9 orthogonal array. The parameters that are to be optimized are plasma voltage, spraying distance and the cooling jet pressure. The characterization techniques includes micro-hardness and porosity tests followed by Grey relational analysis of the results

scholarly journals Selected Properties Of Thermally Sprayed Oxide Ceramic Coatings

2015 ◽  
Vol 15 (3) ◽  
pp. 17-32 ◽  
Author(s):  
A. Czupryński
Keyword(s):  
Wear Resistance ◽  
Abrasive Wear ◽  
Calcium Oxide ◽  
Zirconium Oxide ◽  
Steel Substrate ◽  
Ceramic Coatings ◽  
Abrasive Wear Resistance ◽  
Flame Spraying ◽  
Oxide Ceramic ◽  
Wide Range

Abstract The article presents the results of the study on exploitation properties of flame sprayed ceramic coatings produced by oxide ceramic material in the form of powder on the aluminum oxide Al2O3 matrix with 3% titanium oxide TiO2 addition and also on the zirconium oxide (ZrO2) matrix with 30% calcium oxide (CaO) on the substrate of unalloyed structural steel of S235JR grade. As a primer powder, metallic powder on the base of Ni-Al-Mo has been applied. Plates with dimensions of 5×200×300 mm and also front surfaces of ∅40×50 mm cylinders have been flame sprayed. Spraying of primer coating has been done using RotoTec 80 torch and external specific coating has been done with CastoDyn DS 8000 torch. Investigations of coating properties are based on metallography tests, phase composition research, measurement of microhardness, coating adhesion to the ground research (acc. to EN 582:1996 standard), abrasive wear resistance (acc. to ASTM G65 standard) and erosion wear resistance (acc. to ASTM G76-95 standard) and thermal stroke study. Performed tests have shown that the flame spraying with 97%Al2O3 powder containing 3% TiO2 and also by the powder based on zirconium oxide (ZrO2) containing 30% calcium oxide (CaO) performed in a wide range of technological parameters allow to obtain high quality ceramic coatings with thickness up to ca. 500 μm on a steel substrate. The primer coating sprayed with the Ni-Al-Mo powder to the steel substrate and external coatings sprayed has the of mechanical bonding character. The coatings are characterized by high adhesion to the substrate and also high erosion and abrasive wear resistance and the resistance for cyclic thermal stroke.

Structure and Property of Micro Arc Oxidation Ceramic Coatings on Al Alloy in K2ZrF6 Solution

2010 ◽  
Vol 105-106 ◽  
pp. 505-508 ◽  
Author(s):  
Zhen Dong Wu ◽  
Zhong Wen Yao ◽  
Fang Zhou Jia ◽  
Zhao Hua Jiang
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Aluminium Alloy ◽  
Friction And Wear ◽  
Ceramic Coatings ◽  
Al Alloy ◽  
Structure And Property ◽  
Micro Arc Oxidation ◽  
Disk Friction ◽  
Composition Structure

The coatings containing zirconia were produced on LY12 Aluminium alloy by micro-arc oxidation in K2ZrF6 and NaH2PO2 solution. The composition, structure, hardness, friction and wear resistance and corrosion resistance of the coating were studied by XRD, SEM, EDS, ball-on-disk friction tester and electrochemical analyzer, respectively. The results show that coating was composed of m-ZrO2 and t-ZrO2. There were a large amount of Zr and O and a little Al, P and K in the coating. The thickness of coating prepared for 3h was 168μm and the maximum value of the hardness was up to 16.75GPa. The friction and wear resistance and corrosion resistance were improved, compared with the LY12 aluminium alloy substrate.

Microstructure and Wear Resistance of TiC+Cr7C3 Reinforced Ceramal Composite Coating Produced by PTA Weld-Surfacing Process

2010 ◽  
Vol 97-101 ◽  
pp. 1377-1380 ◽  
Author(s):  
Jun Hai Liu ◽  
Ji Hua Huang ◽  
Jun Bo Liu ◽  
Gui Xiang Song
Keyword(s):  
Wear Resistance ◽  
Composite Coating ◽  
Steel Substrate ◽  
Wear Test ◽  
Primary Phase ◽  
Dry Sliding Wear ◽  
X Ray ◽  
Q235 Steel ◽  
High Microhardness ◽  
New Type

A new type in situ reinforcing phase TiC+Cr7C3 ceramal composite coating was fabricated on substrate of Q235 steel by plasma transferred arc (PTA) weld-surfacing process using the mixture of ferrotitanium, ferrochromium, ferroboron and ferrosilicium powders. Microstructure and wear performance of the coating were investigated by means of X-ray diffraction (XRD), scanning electron micrograph (SEM), energy dispersive X-ray analysis (EDS), microhardness tester and wear tester. Results show that the composite coating consists of TiC, primary phase Cr7C3 , (Cr,Fe)7C3 and austenite. The composite coating is metallurgically bonded to the Q235 steel substrate. TiC particles present cubic and “dendrite flower-like” shape in the composite coating. The coating has high microhardness and excellent wear resistance under dry-sliding wear test conditions.

scholarly journals Testing of Flame Sprayed Al2O3 Matrix Coatings Containing TiO2

2016 ◽  
Vol 61 (3) ◽  
pp. 1363-1370 ◽  
Author(s):  
A. Czupryński ◽  
J. Górka ◽  
M. Adamiak ◽  
B. Tomiczek
Keyword(s):  
Wear Resistance ◽  
Abrasive Wear ◽  
Steel Substrate ◽  
Aluminium Oxide ◽  
Ceramic Coatings ◽  
Abrasive Wear Resistance ◽  
Flame Spraying ◽  
Oxide Ceramic ◽  
Al2o3 Matrix ◽  
External Coating

Abstract The paper presents the results of the properties of flame sprayed ceramic coatings using oxide ceramic materials coating of a powdered aluminium oxide (Al2O3) matrix with 3% titanium oxide (TiO2) applied to unalloyed S235JR grade structural steel. A primer consisting of a metallic Ni-Al-Mo based powder has been applied to plates with dimensions of 5×200×300 mm and front surfaces of Ø40×50 mm cylinders. Flame spraying of primer coating was made using a RotoTec 80 torch, and an external coating was made with a CastoDyn DS 8000 torch. Evaluation of the coating properties was conducted using metallographic testing, phase composition research, measurement of microhardness, substrate coating adhesion (acc. to EN 582:1996 standard), erosion wear resistance (acc. to ASTM G76-95 standard), and abrasive wear resistance (acc. to ASTM G65 standard) and thermal impact. The testing performed has demonstrated that flame spraying with 97% Al2O3 powder containing 3% TiO2 performed in a range of parameters allows for obtaining high-quality ceramic coatings with thickness up to ca. 500 µm on a steel base. Spray coating possesses a structure consisting mainly of aluminium oxide and a small amount of NiAl10O16 and NiAl32O49 phases. The bonding primer coat sprayed with the Ni-Al-Mo powder to the steel substrate and external coating sprayed with the 97% Al2O3 powder with 3% TiO2 addition demonstrates mechanical bonding characteristics. The coating is characterized by a high adhesion to the base amounting to 6.5 MPa. Average hardness of the external coating is ca. 780 HV. The obtained coatings are characterized by high erosion and abrasive wear resistance and the resistance to effects of cyclic thermal shock.

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