Processing and Thermoelectric Properties of New Si-/ Se-/ Sn-Based Intermetallics

2016 ◽  
Vol 879 ◽  
pp. 2131-2137
Author(s):  
Wilfried Wunderlich ◽  
Masashi Sato ◽  
Yoshihito Matsumura
Keyword(s):  
Thermoelectric Properties ◽  
Driving Force ◽  
Intermetallic Phase ◽  
Intermetallic Alloys ◽  
Arc Melting ◽  
The Earth ◽  
Earth Abundant ◽  
First Time ◽  
New Si ◽  
Powder In Tube

Global warming is the driving force for developing new functional thermoelectric generators based on new materials which contain at least one of the elements Si, Se, or Sn. We describe four processing methods and their characterization by SEM and thermoelectric properties. The earth-abundant Mg2Si requires the method of cyclic hydrogen loading, which has two advantages: It suppresses the oxide formation, and promotes the driving force for formation of the intermetallic phase. While the clathrate BaCuSi and the Half-Heusler alloy (TiZr)NiSn, as most intermetallic alloys, can economically be produced by arc-melting, the Se-alloys CuTiSe and CuFeSe need to be processed by the powder-in-tube method and their Seebeck-voltage measurements up to +/- 0.04 mV/K and output power of 4 μW at ΔT= 400 K are reported here for the first time.

Alexander and the Mongols

1979 ◽  
Vol 111 (2) ◽  
pp. 123-136 ◽  
Author(s):  
John Andrew Boyle
Keyword(s):  
Eighth Century ◽  
Alexander The Great ◽  
The Caucasus ◽  
The North ◽  
The Earth ◽  
Four Corners ◽  
Book Of Genesis ◽  
First Time

The association of Alexander the Great with the Mongols begins with the identification of the latter with the peoples of Gog and Magog. The evolution of this legend, which has its origin in the Book of Genesis, is curious in the extreme. In Genesis Magog is mentioned as one of the sons of Japhet, his name occurring between those of Gomer and Madai. Since Madai is clearly intended as the eponym of the Medes and Gomer has been located in Cappadocia and Phrygia it has been plausibly suggested that Magog at this stage corresponded to the territory in between, i.e. the region immediately south of the Caucasus in Eastern and Northern Armenia. In Ezekiel we hear for the first time of Gog “of the land of Magog”, who will come from his place out of the uttermost parts of the north, he and many peoples with him, “all of them riding on horses, a great company and a mighty army.” It will be seen that the “land of Magog” can no longer be located south of the Caucasus, and indeed Ezekiel's prophecy of the invasion of Gog has been interpreted as an echo of the invasions of the Cimmerians, who came southwards from the steppes through the Darial pass towards the end of the eighth century B.C.; or more probably of the invasion of the Scythians which took place in the following century by way of Darband. Finally we are told in Revelation that “when the thousand years are finished, Satan shall be loosed out of his prison, and shall come forth to deceive the nations which are in the four corners of the earth, Gog and Magog, to gather them together to the war; the number of whom is as the sand of the sea”.

scholarly journals Evolutionary economics: Crisis, transformation and metamorphosis

2021 ◽  
pp. 1-8
Author(s):  
Milan Zeleny
Keyword(s):  
Growth Rate ◽  
Productivity Growth ◽  
Driving Force ◽  
Evolutionary Economics ◽  
Regional Economies ◽  
Economic Evolution ◽  
Economic Sectors ◽  
Advanced Economies ◽  
First Time

Most world economies are undergoing fundamental transformations of economic sectors, shifting their employed workforce through the secular sequence of (1. Agriculture⟶2. Industry⟶3. Services⟶4. Government). The productivity growth rate is the driving force. Most advanced economies have reached the final stages of the sequence. Assorted recessions, crises and stagnations are simply cofluent, accompanying phenomena. Crises might be cyclical, but economic evolution is unidirectional. Traditional economics can hardly distinguish phenomena of crisis from those of the transformation. Because there is no “fifth sector”, some economies are entering the phase of metamorphosis, for the first time in history. Metamorphosis is manifested through deglobalization, relocalization and autonomization of local and regional economies. We are entering the Age of Entrepreneurship.

scholarly journals Mechanical and Thermoelectric Properties of Bulk AlSb Synthesized by Controlled Melting, Pulverizing and Subsequent Vacuum Hot Pressing

2019 ◽  
Vol 9 (8) ◽  
pp. 1609 ◽  
Author(s):  
A. K. M. Ashiquzzaman Shawon ◽  
Soon-Chul Ur
Keyword(s):  
Mechanical Properties ◽  
Intermetallic Compound ◽  
Thermoelectric Properties ◽  
Hot Pressing ◽  
Single Phase ◽  
Aluminum Antimonide ◽  
Simple Method ◽  
Group Iii ◽  
Indirect Band Gap ◽  
First Time

Aluminum antimonide is a semiconductor of the Group III-V order. With a wide indirect band gap, AlSb is one of the least discovered of this family of semiconductors. Bulk synthesis of AlSb has been reported on numerous occasions, but obtaining a single phase has always proven to be extremely difficult. This work reports a simple method for the synthesis of single-phase AlSb. Subsequently, consolidation was done into a near single-phase highly dense semiconductor in a form usable for thermoelectric applications. Further, the thermoelectric properties of this system are accounted for the first time. In addition, the mechanical properties of the intermetallic compound are briefly discussed for a possibility of further use.

On the Electrochemical Insertion of Mg2+in Na7V4(P2O7)4(PO4) and Na3V2(PO4)3 Host Materials

2021 ◽  
Author(s):  
Saustin Dongmo ◽  
Fabio Maroni ◽  
Cornelius Gauckler ◽  
Mario Marinaro ◽  
Margret Wohlfahrt-Mehrens
Keyword(s):  
Energy Storage ◽  
Research And Development ◽  
Cathode Materials ◽  
Fast Kinetics ◽  
The Earth ◽  
Host Materials ◽  
High Potentials ◽  
Phosphate Phase ◽  
Storage Technologies ◽  
First Time

Abstract Next generation energy storage technologies need to be more sustainable and cheaper. Among Post-Li chemistries, Mg batteries are emerging as a possible alternative with desirable features like abundance of Mg on the Earth`s crust and a doubled volumetric capacity with respect to the current Li metal. However, research and development of Mg-batteries is still in its infancy stage and still many hurdles are to be understood and solved. For instance, cathode materials showing high capacities, operating at high potentials and with sufficient fast kinetics need to be designed and developed. Polyanionic materials are a class of sustainable and environmentally friendly materials that emerged as possible Mg2+ hosts. In this work the insertion of Mg cations inside the NASICON Na3V2(PO4)3 and, for the first time, in the mixed phosphate phase Na7V4(P2O7)4(PO4), is reported, structurally and electrochemically characterized.

Experimental and computational investigations of TiIrB: a new ternary boride with Ti1+x Rh2−x+y Ir3−y B3-type structure

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jan P. Scheifers ◽  
Kate A. Gibson ◽  
Boniface P. T. Fokwa
Keyword(s):  
Density Functional ◽  
Ternary Phase ◽  
Structure Type ◽  
X Ray Diffraction ◽  
Functional Theory ◽  
Arc Melting ◽  
Ternary Boride ◽  
Charge Analysis ◽  
First Time ◽  
Bader Charge Analysis

Abstract A new ternary phase, TiIrB, was synthesized by arc-melting of the elements and characterized by powder X-ray diffraction. The compound crystallizes in the orthorhombic Ti1+x Rh2−x+y Ir3−y B3 structure type, space group Pbam (no. 55) with the lattice parameters a = 8.655(2), b = 15.020(2), and c = 3.2271(4) Å. Density Functional Theory (DFT) calculations were carried out to understand the electronic structure, including a Bader charge analysis. The charge distribution of TiIrB in the Ti1+x Rh2−x+y Ir3−y B3-type phase has been evaluated for the first time, and the results indicate that more electron density is transferred to the boron atoms in the zigzag B4 units than to isolated boron atoms.

From the Formation of the Earth to the Establishment of Luka

2021 ◽  
Vol 30 (5) ◽  
pp. 497-520
Author(s):  
Zdravka Kostova ◽  
Keyword(s):  
Natural Selection ◽  
Driving Force ◽  
Prokaryotic Cell ◽  
The Earth ◽  
Evolution Of Life ◽  
A Cell ◽  
Organic Precursors ◽  
Biotic Environment

The article discusses successive stages in the evolution of life up to the establishment of the prokaryotic cell emphasizing the transitions from pre-biotic environment to organic precursors, pre-RNA-RNA, RNA-proteins-DNA, DNA-LUCA. They are paired with the development of pre-biotic structural progenitors of a cell - micelles, vesicles, protocells, prokaryotic ancestor, two prokaryotic branches – Eubacteria and Archaebacteria. The driving force is the natural selection (chemical, biochemical and biological), maintaining the correspondence between the emerging structures and their environment.

Cosmic Deer as an Archaic Symbol in the Narratives and Rituals of the Tungus-Manchus

2020 ◽  
pp. 112-121
Author(s):  
Татьяна Юрьевна Сем
Keyword(s):  
Bronze Age ◽  
The Sun ◽  
Time Model ◽  
Space And Time ◽  
The Earth ◽  
Cosmic Scale ◽  
First Time ◽  
The Universe ◽  
The Bronze Age

Статья посвящена мифологическому образу космического оленя в традиционной культуре тунгусо-маньчжуров. В работе рассматриваются материалы фольклора, шаманства, промысловых и календарных ритуалов, а также искусства. Впервые систематизированы материалы по всем тунгусо-маньчжурским народам. Образ космического оленя в фольклоре эвенов имеет наиболее близкие аналогии с амурскими народами, которые представляют его с рогами до небес. Он сохранился в сказочном фольклоре с мифологическими и эпическими элементами. В эвенском мифе образ оленя имеет космические масштабы: из тела его происходит земля и всё живущее на ней. У народов Амура образ оленя нашел отражение в космогенезе, отделении неба от земли. Своеобразие сюжета космической охоты характеризует общесибирскую мифологию, относящуюся к ранней истории. В ней наиболее ярко проявляется мотив смены старого и нового солнца, хода времени, смены времен года, календарь тунгусо-маньчжуров. В результате анализа автор пришел к выводу, что олень в тунгусо-маньчжурской традиции моделирует пространство и время Вселенной, характеризует образ солнца и хода времени. Космический олень является архетипичным символом культуры тунгусо-маньчжуров, сохранившим свое значение до настоящего времени в художественной культуре This article is devoted to the mythological image of cosmic deer in traditional Tungus-Manchu culture. It examines materials of folklore, shamanism, trade and calendar rituals as well as art and for the first time systematizes materials from all of the Tungus-Manchu peoples. The image of cosmic deer in the folklore of the Evens has its closest analogy in that of the Amur peoples, reflected in the image of a deer with horns reaching up to the sky. This image is preserved in fairytales with mythological and epic elements. In the Even myth, the image of a deer is on a cosmic scale, as the cosmos issues from its body. Among the Amur peoples, the image of a deer is also related to cosmogenesis, to the separation of the earth from the sky. The plot of a cosmic hunt is reflected in pan-Siberian mythology, dating back to the Bronze Age. It clearly illustrates the motif of the change of the old and new sun, the passage of time, the change of seasons, the Tungus-Manchu calendar. The author comes to the conclusion that deer in the Tungus-Manchu tradition, in depicting the image of the sun and the passage of time, model the space and time of the Universe. The cosmic deer is an archetypal symbol of Tungus-Manchu culture, which has retained its significance in artistic culture to the present day.

The Strait of Magellan—a Gateway to New Worlds

2021 ◽  
Author(s):  
Mauricio Onetto Pavez
Keyword(s):  
Global Scale ◽  
Modern World ◽  
American Continent ◽  
The Earth ◽  
Starting Point ◽  
Strait Of Magellan ◽  
The World ◽  
The Strait Of Magellan ◽  
History Of ◽  
First Time

The year 2020 marks the five hundredth anniversary of the “discovery” of the Strait of Magellan. The unveiling of this passage between 1519 and 1522 allowed the planet to be circumnavigated for the first time in the history of humanity. All maritime routes could now be connected, and the idea of the Earth, in its geographical, cosmographic, and philosophical dimensions, gained its definitive meaning. This discovery can be considered one of the founding events of the modern world and of the process of globalization that still continues today. This new connectivity awoke an immediate interest in Europe that led to the emergence of a political consciousness of possession, domination, and territorial occupation generalized on a global scale, and the American continent was the starting point for this. This consciousness also inspired a desire for knowledge about this new form of inhabiting the world. Various fields of knowledge were redefined thanks to the new spaces and measurements produced by the discovery of the southern part of the Americas, which was recorded in books on cosmography, natural history, cartography, and manuscripts, circulating mainly between the Americas and Europe. All these processes transformed the Strait of Magellan into a geopolitical space coveted by Europeans during the 16th century. As an interoceanic connector, it was used to imagine commercial routes to the Orient and political projects that could sustain these dynamics. It was also conceived as a space to speculate on the potential wealth in the extreme south of the continent. In addition, on the Spanish side, some agents of the Crown considered it a strategic place for imperial projections and the defense of the Americas.

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