Fully Biodegradable Films Based on Functionalized Natural Polyphenol/Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) as a Potential Material for Food Packaging

2017 ◽  
Vol 898 ◽  
pp. 2279-2285
Author(s):  
Heng Xue Xiang ◽  
Zi Ye Chen ◽  
Wei Chen ◽  
Zhe Zhou ◽  
Bin Sun ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Food Packaging ◽  
Composite Films ◽  
Optical Microscope ◽  
Uniaxial Tensile ◽  
Biodegradable Films ◽  
Biodegradable Composite ◽  
Natural Polyphenol ◽  
New Type ◽  
Hydroxy Groups

As a potential material for food packaging, fully biodegradable composite films based on novel functionalized natural polyphenol/Poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) were successfully fabricated by solution casting, and also the functionalized natural polyphenol (C18TAx) was synthesized by grafting fatty acid onto natural polyphenol Tannic Acid (TA). The resultant C18TAx with better hydrophobicity was uniformly dispersed into a PHBV matrix. The influence of C18TAx dosage on the mechanical behavior, crystallization behavior and thermal properties of the C18TAx/PHBV composite films was investigated by uniaxial tensile mechanical testing, Differential Scanning Calorimeter (DSC), Polarizing Optical Microscope (POM) and Wide Angle X-ray Diffractometry (WAXD). The results revealed that the x value was about 0.09, showing that about 11/20 phenol hydroxy groups in TA molecules were replaced with fatty acid chains. Compared with those of neat PHBV, the tensile strength and elongation at break of the C18TA0.09/PHBV composite films with 10 wt.% C18TA0.09 content were enhanced by 121%, and 458%, respectively. This improvement was primarily ascribed to intermolecular hydrogen bonding interactions in composite films. This new type of fully biodegradable bio-based composite films shows great potential for food packaging.

Antimicrobial Activity of Allyl Isothiocyanate Used To Coat Biodegradable Composite Films as Affected by Storage and Handling Conditions†

2012 ◽  
Vol 75 (12) ◽  
pp. 2234-2237 ◽  
Author(s):  
WEILI LI ◽  
LINSHU LIU ◽  
TONY Z. JIN
Keyword(s):  
Antimicrobial Activity ◽  
Polylactic Acid ◽  
Food Packaging ◽  
Storage Time ◽  
Storage Temperature ◽  
Composite Films ◽  
Antimicrobial Properties ◽  
Allyl Isothiocyanate ◽  
Microbial Reduction ◽  
Biodegradable Composite

We evaluated the effects of storage and handling conditions on the antimicrobial activity of biodegradable composite films (polylactic acid and sugar beet pulp) coated with allyl isothiocyanate (AIT). Polylactic acid and chitosan were incorporated with AIT and used to coat one side of the film. The films were subjected to different storage conditions (storage time, storage temperature, and packed or unpacked) and handling conditions (washing, abrasion, and air blowing), and the antimicrobial activity of the films against Salmonella Stanley in tryptic soy broth was determined. The films (8.16 μl of AIT per cm2 of surface area) significantly (P < 0.05) inhibited the growth of Salmonella during 24 h of incubation at 22°C, while the populations of Salmonella in controls increased from ca. 4 to over 8 log CFU/ml, indicating a minimum inactivation of 4 log CFU/ml on films in comparison to the growth on controls. Statistical analyses indicated that storage time, storage temperature, and surface abrasion affected the antimicrobial activity of the films significantly (P < 0.05). However, the differences in microbial reduction between those conditions were less than 0.5 log cycle. The results suggest that the films' antimicrobial properties are stable under practical storage and handling conditions and that these antimicrobial films have potential applications in food packaging.

Design of biodegradable composite films for food packaging

Desalination ◽  
2006 ◽  
Vol 199 (1-3) ◽  
pp. 331-333 ◽  
Author(s):  
Victor Alves ◽  
Nuno Costa ◽  
Loic Hilliou ◽  
Fábio Larotonda ◽  
Maria Gonçalves ◽  
...  
Keyword(s):  
Food Packaging ◽  
Composite Films ◽  
Biodegradable Composite

Edible Bioactive Fatty Acid−Cellulosic Derivative Composites Used in Food-Packaging Applications

2002 ◽  
Vol 50 (15) ◽  
pp. 4290-4294 ◽  
Author(s):  
Issam Sebti ◽  
Frédérique Ham-Pichavant ◽  
Véronique Coma
Keyword(s):  
Fatty Acid ◽  
Food Packaging

scholarly journals Battery-free radio frequency wireless sensor for bacteria based on their degradation of gelatin-fatty acid composite films

2021 ◽  
Vol 381 ◽  
pp. 138275
Author(s):  
Palraj Kalimuthu ◽  
Juan F. Gonzalez-Martinez ◽  
Dainius Jakubauskas ◽  
Marité Cárdenas ◽  
Tautgirdas Ruzgas ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Radio Frequency ◽  
Composite Films ◽  
Wireless Sensor

scholarly journals Trends in Chitosan as a Primary Biopolymer for Functional Films and Coatings Manufacture for Food and Natural Products

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 767
Author(s):  
Elsa Díaz-Montes ◽  
Roberto Castro-Muñoz
Keyword(s):  
Food Packaging ◽  
Composite Films ◽  
Edible Films ◽  
Biological Properties ◽  
Food Preservation ◽  
Environmental Damage ◽  
Biodegradable Packaging ◽  
Product Consumption ◽  
New Concepts ◽  
Processed Products

Some of the current challenges faced by the food industry deal with the natural ripening process and the short shelf-life of fresh and minimally processed products. The loss of vitamins and minerals, lipid oxidation, enzymatic browning, and growth of microorganisms have been the main issues for many years within the innovation and improvement of food packaging, which seeks to preserve and protect the product until its consumption. Most of the conventional packaging are petroleum-derived plastics, which after product consumption becomes a major concern due to environmental damage provoked by their difficult degradation. In this sense, many researchers have shown interest in edible films and coatings, which represent an environmentally friendly alternative for food packaging. To date, chitosan (CS) is among the most common materials in the formulation of these biodegradable packaging together with polysaccharides, proteins, and lipids. The good film-forming and biological properties (i.e., antimicrobial, antifungal, and antiviral) of CS have fostered its usage in food packaging. Therefore, the goal of this paper is to collect and discuss the latest development works (over the last five years) aimed at using CS in the manufacture of edible films and coatings for food preservation. Particular attention has been devoted to relevant findings in the field, together with the novel preparation protocols of such biodegradable packaging. Finally, recent trends in new concepts of composite films and coatings are also addressed.

Natural polyphenol tannic acid reinforced poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) composite films with enhanced tensile strength and fracture toughness

2014 ◽  
Vol 36 (12) ◽  
pp. 2303-2308 ◽  
Author(s):  
Hengxue Xiang ◽  
Lili Li ◽  
Shichao Wang ◽  
Renlin Wang ◽  
Yanhua Cheng ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Tensile Strength ◽  
Tannic Acid ◽  
Composite Films ◽  
Natural Polyphenol

Enhanced functional properties of biodegradable Polyvinyl alcohol /carboxymethyl cellulose (PVA/CMC) composite films reinforced with L-alanine surface modified CuO nanorods

2021 ◽  
Author(s):  
Yamanappagouda Amaregouda ◽  
Kantharaju Kamanna ◽  
Tilak Gasti ◽  
Vijay Kumbar
Keyword(s):  
Polyvinyl Alcohol ◽  
Carboxymethyl Cellulose ◽  
Food Packaging ◽  
Composite Films ◽  
Nanocomposite Films ◽  
Soil Burial ◽  
High Antibacterial Activity ◽  
Active Food Packaging ◽  
Surface Modified ◽  
Cuo Nanorods

Abstract Herein, we described novel biogenic preparation of the CuO nanorods and its surface modification with L-alanine amino acid accelerated by microwave irradiation. The effect of surface functionalized CuO nanorods on the polyvinyl alcohol/carboxymethyl cellulose film physico-mechanical properties were investigated through various characterization techniques. The tensile strength was improved from 28.58 ± 0.73 MPa to 43.40 ± 0.93 MPa, UV shielding ability and barrier to the water vapors were highly enhanced when PVA/CMC matrices filled with 8 wt% of CuO-L-alanine. In addition, the prepared films exhibited acceptable overall migration limit and readily undergoes soil burial degradation. Nevertheless, CuO-L-alanine incorporated films showed potent antioxidant activity against DPPH radicals and had high antibacterial activity against Staphylococcus aureus and Escherichia coli, and antifungal activity against Candida albicans and Candida tropicalis. Furthermore, the nanocomposite films showed negligible cytotoxic effect on HEK293 and Caco-2 cell lines. In these contexts, the developed nanocomposite films can be implementing as an active food packaging material.

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