A Strategy to Improve O2 Gas Response of La-SnO2 Nanofibers Based Sensor through Temperature Modulation

2019 ◽  
Vol 944 ◽  
pp. 657-665
Author(s):  
Ya Xiong ◽  
Hui Li ◽  
Tian Chao Guo ◽  
Qing Zhong Xue
Keyword(s):  
Gas Sensors ◽  
Gas Sensing ◽  
Operation Mode ◽  
Temperature Modulation ◽  
Oxide Semiconductors ◽  
Oxygen Ions ◽  
Isothermal Test ◽  
Sensor Temperature ◽  
Heating Energy Consumption ◽  
Gas Response

Generally sensing mechanisms of gas sensors based on metal-oxide semiconductors greatly depend on temperature, suggesting temperature modulation can be applied as a vital method to effectively enhance the sensor response. In this paper, we reported a strategy of quick-cooling operating temperature mode in the course of gas sensing process to elevate the O2 gas response while maintaining low heating energy consumption. La-SnO2 nanofibers synthesized by electrospinning were chosen as gas sensing materials. The O2 gas responses by employing quick-cooling operation mode are significantly improved compared with those obtained by traditional isothermal test. The improved O2 response is contributed to a higher coverage of negatively charged oxygen ions as a result of quick cooling. Our research offers a facile route to detect gas at low temperature with high response. More importantly, the strategy demonstrated here could also be extended to other gas sensor as long as its gas response is related to the sensor temperature.

scholarly journals Enhancing Formaldehyde Selectivity of SnO2 Gas Sensors with the ZSM-5 Modified Layers

Sensors ◽  
2021 ◽  
Vol 21 (12) ◽  
pp. 3947
Author(s):  
Wei Wang ◽  
Qinyi Zhang ◽  
Ruonan Lv ◽  
Dong Wu ◽  
Shunping Zhang
Keyword(s):  
Gas Sensors ◽  
Indoor Air ◽  
High Performance ◽  
Screen Printing ◽  
Gas Sensing ◽  
Oxide Semiconductors ◽  
Screen Printing Method ◽  
Gas Sensing Properties ◽  
Zeolite Films ◽  
Insufficient Knowledge

High performance formaldehyde gas sensors are widely needed for indoor air quality monitoring. A modified layer of zeolite on the surface of metal oxide semiconductors results in selectivity improvement to formaldehyde as gas sensors. However, there is insufficient knowledge on how the thickness of the zeolite layer affects the gas sensing properties. In this paper, ZSM-5 zeolite films were coated on the surface of the SnO2 gas sensors by the screen printing method. The thickness of ZSM-5 zeolite films was controlled by adjusting the numbers of screen printing layers. The influence of ZSM-5 film thickness on the performance of ZSM-5/SnO2 gas sensors was studied. The results showed that the ZSM-5/SnO2 gas sensors with a thickness of 19.5 μm greatly improved the selectivity to formaldehyde, and reduced the response to ethanol, acetone and benzene at 350 °C. The mechanism of the selectivity improvement to formaldehyde of the sensors was discussed.

Effect of Au Doped WO3 Gas Sensors for NO2 Detection

2011 ◽  
Vol 492 ◽  
pp. 308-311 ◽  
Author(s):  
Wu Bin Gao ◽  
Cheng Dong ◽  
Xu Liu ◽  
Yun Han Ling ◽  
Jia Lin Sun
Keyword(s):  
Gas Sensors ◽  
Gas Sensing ◽  
Point Contact ◽  
X Ray ◽  
Sensing Properties ◽  
Gas Sensing Properties ◽  
Tungsten Filaments ◽  
Gas Response ◽  
Contact Sensors

Gas sensor based on point contact tungsten trioxide (WO3) was prepared by in-situ induction-heating thermal oxidation of tungsten filaments. X-ray diffractometry (XRD) and field emission scanning electron microscopy (FESEM) were employed to analyze the phase and the morphology of the fabricated thin films. The results showed that the WO3films exhibited a monoclinic phase and were composed of hierarchical micro and nano crystals. The NO2(1-8 ppm) sensing properties of the point contact sensors based on Pure and Au-sputtering doped (2.5 at%) WO3films were investigated. The results showed that the gas sensing properties of the Au (2.5 at%) doped WO3sensors were superior to those of the undoped. The obtained point contact WO3sensor exhibited the maximum NO2gas response at 100°C.

Enhanced Gas Sensing of Tin Dioxide Based Sensor for Indoor Formaldehyde Application

2021 ◽  
Vol 16 (2) ◽  
pp. 337-342
Author(s):  
Gaoqi Zhang ◽  
Fan Zhang ◽  
Kaifang Wang ◽  
Shanyu Liu ◽  
Ying Wang ◽  
...  
Keyword(s):  
Gas Sensors ◽  
Tin Dioxide ◽  
Gas Sensing ◽  
Fast Response ◽  
Sensing Material ◽  
Gas Sensing Properties ◽  
Recovery Times ◽  
Response And Recovery ◽  
Formaldehyde Sensing ◽  
Gas Response

Indoor formaldehyde detection is of great important at present. Using efficient solvothermal method, nanosheet-constructed and nanorod-constructed hierarchical tin dioxide (SnO2) microspheres were successfully synthesized in this work and used for the gas sensing material for indoor formaldehyde application. The as-prepared two kinds of SnO2 gas sensing materials were applied to fabricate the gas sensors and formaldehyde gas sensing experiments were carried out. The HCHO gas sensing tests indicate that the gas response of the nanosheet-constructed SnO2 microspheres is about 1.7 times higher than that of the nanorod-constructed SnO2 microspheres. In addition, both of the two SnO2 based gas sensors show almost fast response and recovery time to HCHO gas. For the nanosheet-constructed microspheres, the response value is estimated to be 32.0 at 350 °C to 60 ppm formaldehyde gas, while the response and recovery times are 7 and 5 s, respectively. The simple and efficient preparation method and improved gas sensing properties show that the as-synthesized hierarchical SnO2 microsphere that is constructed by a large amount of nanosheets exhibits significant potential application for the indoor formaldehyde sensing.

scholarly journals Nanostructured Materials Based on Thin Films and Nanoclusters for Hydrogen Gas Sensing

Proceedings ◽  
2021 ◽  
Vol 56 (1) ◽  
pp. 38
Author(s):  
Stanislav Haviar ◽  
Nirmal Kumar ◽  
Šárka Batková ◽  
Jiří Čapek
Keyword(s):  
Thin Films ◽  
Gas Sensors ◽  
Tungsten Trioxide ◽  
Gas Sensing ◽  
Cupric Oxide ◽  
Hydrogen Gas ◽  
Oxide Semiconductors ◽  
Copper Tungstate ◽  
Solid Film ◽  
Nanostructured Metal

In this paper, we present two approaches to synthesize nanostructured metal oxide semiconductors in a form of multi-layer thin films later assembled as a conductometric gas-sensors. The first approach produces a combination of thin solid film of tungsten trioxide (WO3) with nanoclusters of cupric oxide (CuO) prepared by a magnetron-based gas aggregation cluster source (GAS). The second method is a two-step reactive magnetron sputtering forming a nanostructured copper tungstate (CuWO4) on-top of a WO3 film. Both methods lead to synthesis of nanosized hetero-junctions. These greatly improve the sensorial response to hydrogen in comparison with a WO3 thin film alone.

scholarly journals ppb-Level Selective Hydrogen Gas Detection of Pd-Functionalized In2O3-Loaded ZnO Nanofiber Gas Sensors

Sensors ◽  
2019 ◽  
Vol 19 (19) ◽  
pp. 4276 ◽  
Author(s):  
Jae-Hyoung Lee ◽  
Jae-Hun Kim ◽  
Jin-Young Kim ◽  
Ali Mirzaei ◽  
Hyoun Woo Kim ◽  
...  
Keyword(s):  
Gas Sensors ◽  
Gas Sensing ◽  
Hydrogen Gas ◽  
Strong Response ◽  
Pd Nanoparticle ◽  
Highly Sensitive ◽  
Hydrogen Gas Sensors ◽  
Zno Nanofibers ◽  
Gas Response ◽  
Hydrogen Gas Detection

Pd nanoparticle-functionalized, xIn2O3 (x = 0.05, 0.1, and 0.15)-loaded ZnO nanofibers were synthesized by an electrospinning and ultraviolet (UV) irradiation method and assessed for their hydrogen gas sensing properties. Morphological and chemical analyses revealed the desired morphology and chemical composition of the synthesized nanofibers. The optimal gas sensor namely Pd-functionalized, 0.1In2O3-loaded ZnO nanofibers showed a very strong response to 172–50 ppb hydrogen gas at 350 °C, which is regarded as the optimal sensing temperature. Furthermore, the gas sensors showed excellent selectivity to hydrogen gas due to the much lower response to CO and NO2 gases. The enhanced gas response was attributed to the excellent catalytic activity of Pd to hydrogen gas, and the formation of Pd/ZnO and In2O3/ZnO heterojunctions, ZnO–ZnO homojunction, as well as the formation of PdHx. Overall, highly sensitive and selective hydrogen gas sensors can be produced based on a simple methodology using a synergistic effect from Pd functionalization and In2O3 loading in ZnO nanofibers.

Progress of Research on Preparation of Micro Gas Sensors of Metal Oxide Semiconductors

2011 ◽  
Vol 143-144 ◽  
pp. 562-566 ◽  
Author(s):  
Wen An ◽  
Chun Ying Yang
Keyword(s):  
Metal Oxide ◽  
Gas Sensors ◽  
Gas Sensing ◽  
Sol Gel ◽  
Dip Coating ◽  
Metal Oxide Semiconductors ◽  
Preparation Technique ◽  
Fabrication Technique ◽  
Oxide Semiconductors ◽  
Existing Problems

New progress of research on the preparation technique of micro gas sensors of metal oxide semiconductors is introduced, such as the chemical treatment of the gas sensing film, the deposited technique of gas sensing film in the oxygen radical assisted EB evaporation, the technique of the multilayered film, the fabrication technique of the thermally oxidized, the technique of the electrode configuration, the fabrication technique of the miniaturized arrays by micro-molding in capillaries, the dip-coating of the sol-gel. And their features will be analyzed respectively, and their existing problems and future development directions will be given.

scholarly journals New approaches for improving selectivity and sensitivity of resistive gas sensors: a review

Sensor Review ◽  
2015 ◽  
Vol 35 (4) ◽  
pp. 340-347 ◽  
Author(s):  
Janusz Marek Smulko ◽  
Maciej Trawka ◽  
Claes Goran Granqvist ◽  
Radu Ionescu ◽  
Fatima Annanouch ◽  
...  
Keyword(s):  
Gas Sensors ◽  
Gas Sensing ◽  
Experimental Studies ◽  
Low Frequency ◽  
Gas Detection ◽  
Temperature Modulation ◽  
Content Type ◽  
Practical Applications ◽  
Noise Data ◽  
Resistive Gas Sensors

Purpose – This paper aims to present the methods of improving selectivity and sensitivity of resistance gas sensors. Design/methodology/approach – This paper compares various methods of improving gas sensing by temperature modulation, UV irradiation or fluctuation-enhanced sensing. The authors analyze low-frequency resistance fluctuations in commercial Taguchi gas sensors and the recently developed tungsten trioxide (WO3) gas-sensing layers, exhibiting a photo-catalytic effect. Findings – The efficiency of using low-frequency fluctuations to improve gas detection selectivity and sensitivity was confirmed by numerous experimental studies in commercial and prototype gas sensors. Research limitations/implications – A more advanced measurement setup is required to record noise data but it will reduce the number of gas sensors necessary for identifying the investigated gas mixtures. Practical implications – Fluctuation-enhanced sensing can reduce the energy consumption of gas detection systems and assures better detection results. Originality/value – A thorough comparison of various gas sensing methods in resistance gas sensors is presented and supported by exemplary practical applications.

scholarly journals Effect of Growth Temperature and Time on Morphology and Gas Sensitivity of Cu2O/Cu Microstructures

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Ling Wu ◽  
Lun Zhang ◽  
Zhipeng Xun ◽  
Guili Yu ◽  
Liwei Shi
Keyword(s):  
Electron Microscopy ◽  
Gas Sensors ◽  
Gas Sensing ◽  
Spherical Particles ◽  
X Ray Diffraction ◽  
Gas Sensitivity ◽  
X Ray ◽  
Transmission Electron ◽  
Wide Range ◽  
Gas Response

A facile hydrothermal synthesis with CuSO4as the copper source was used to prepare micro/nano-Cu2O. The obtained samples have been characterized by X-ray diffraction, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). With increasing the reaction temperature and time, the final products were successively Cu2O octahedron microcrystals, Cu2O/Cu composite particles, and a wide range of Cu spherical particles. The gas sensitivity of products towards ethanol and acetone gases was studied. The results showed that sensors prepared with Cu2O/Cu composites synthesized at 65°C for 15 min exhibited optimal gas sensitivity. The gas sensing mechanism and the effect of Cu in the enhanced gas response were also elaborated. The excellent gas sensitivity indicates that Cu2O/Cu composites have potential application as gas sensors.

scholarly journals Graphene-enhanced metal oxide gas sensors at room temperature: a review

2018 ◽  
Vol 9 ◽  
pp. 2832-2844 ◽  
Author(s):  
Dongjin Sun ◽  
Yifan Luo ◽  
Marc Debliquy ◽  
Chao Zhang
Keyword(s):  
Metal Oxide ◽  
Gas Sensors ◽  
Room Temperature ◽  
Gas Sensing ◽  
Metal Oxide Semiconductors ◽  
Oxide Semiconductors ◽  
Sensing Material ◽  
Metal Oxide Gas Sensors ◽  
Low Sensitivity ◽  
Sensing Performance

Owing to the excellent sensitivity to gases, metal-oxide semiconductors (MOS) are widely used as materials for gas sensing. Usually, MOS gas sensors have some common shortages, such as relatively poor selectivity and high operating temperature. Graphene has drawn much attention as a gas sensing material in recent years because it can even work at room temperature, which reduces power consumption. However, the low sensitivity and long recovery time of the graphene-based sensors limit its further development. The combination of metal-oxide semiconductors and graphene may significantly improve the sensing performance, especially the selectivity and response/recovery rate at room temperature. In this review, we have summarized the latest progress of graphene/metal-oxide gas sensors for the detection of NO2, NH3, CO and some volatile organic compounds (VOCs) at room temperature. Meanwhile, the sensing performance and sensing mechanism of the sensors are discussed. The improved experimental schemes are raised and the critical research directions of graphene/metal-oxide sensors in the future are proposed.

scholarly journals Morphology-driven gas sensing by fabricated fractals: A review

2021 ◽  
Vol 12 ◽  
pp. 1187-1208
Author(s):  
Vishal Kamathe ◽  
Rupali Nagar
Keyword(s):  
Fractal Dimension ◽  
Gas Sensors ◽  
Fractal Geometry ◽  
Gas Sensing ◽  
Network Connectivity ◽  
Hybrid Structure ◽  
Controlled Growth ◽  
Length Scales ◽  
Comprehensive Review ◽  
Gas Response

Fractals are intriguing structures that repeat themselves at various length scales. Interestingly, fractals can also be fabricated artificially in labs under controlled growth environments and be explored for various applications. Such fractals have a repeating unit that spans in length from nano- to millimeter range. Fractals thus can be regarded as connectors that structurally bridge the gap between the nano- and the macroscopic worlds and have a hybrid structure of pores and repeating units. This article presents a comprehensive review on inorganic fabricated fractals (fab-fracs) synthesized in labs and employed as gas sensors across materials, morphologies, and gas analytes. The focus is to investigate the morphology-driven gas response of these fab-fracs and identify key parameters of fractal geometry in influencing gas response. Fab-fracs with roughened microstructure, pore-network connectivity, and fractal dimension (D) less than 2 are projected to be possessing better gas sensing capabilities. Fab-fracs with these salient features will help in designing the commercial gas sensors with better performance.

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