Magnetic Properties Variations in Iron Complexes with Benzimidazole Derivatives Depending on the System Spin State

2012 ◽  
Vol 190 ◽  
pp. 633-636
Author(s):  
L.V. Khenkin ◽  
Alla A. Novakova ◽  
Nikolai S. Perov ◽  
A. A. Vompe
Keyword(s):  
Magnetic Properties ◽  
Transition Temperature ◽  
Magnetic Moment ◽  
Valence State ◽  
High Field ◽  
Alkyl Radical ◽  
Spin Transition ◽  
Chloride Ion ◽  
Benzimidazole Derivatives ◽  
Iron Ions

Complexes of bivalent and trivalent iron with ligands based on benzimidazole derivatives have been synthesized and investigated. Chloride-ion was used as anion. Samples ligands differed from each other in the length of alkyl radical. Some samples were found in a mix-valence state, that complicated spin transition observation. Combination of Mossbauer spectroscopy and magnetic moment in high field (15kOe) measurements in the temperatures range 130K - 350K allowed us to establish the valence of iron ions under spin transition in our samples and spin transition temperature frameworks for these mix-valence compounds.

MAGNETIC PROPERTIES OF GdxY1-xLaAl4 SYSTEM

2005 ◽  
Vol 19 (03) ◽  
pp. 113-117
Author(s):  
ILEANA LUPSA
Keyword(s):  
Magnetic Properties ◽  
Transition Temperature ◽  
Structural Study ◽  
Magnetic Moment ◽  
Random Distribution ◽  
Exchange Interactions ◽  
Atomic Disorder ◽  
Gadolinium Concentration ◽  
Ferromagnetic Order ◽  
Temperature Range

The magnetic and structural study of Gd x Y 1-x LaAl 4 system was performed. The magnetic properties investigated in the 4–600 K temperature range and fields up to 80 kOe showed the ferromagnetic order for x≤0.8. For low gadolinium concentration, x≤0.4, the magnetic moment and the transition temperature values are lower than expected for Gd 3+ ion. It is considered that the dilution allows the formation of substitutional and atomic disorder, leading to modifications in the exchange interactions and determining a random-distribution configuration for gadolinium moments.

Abrupt spin crossover in iron(iii) complexes with aromatic anions

2019 ◽  
Vol 48 (41) ◽  
pp. 15515-15520 ◽  
Author(s):  
Sharon E. Lazaro ◽  
Adil Alkaş ◽  
Seok J. Lee ◽  
Shane G. Telfer ◽  
Keith S. Murray ◽  
...  
Keyword(s):  
Transition Temperature ◽  
Spin Crossover ◽  
Spin Transition ◽  
Halogen Bonds ◽  
Aromatic Anions

Two iron(iii) complexes, [Fe(qsal-X)2]OTs·nH2O, are found to exhibit abrupt spin crossover with the spin transition temperature substituent dependent, and X⋯O halogen bonds linking the spin centres.

Magnetic properties of PbO–Sb2O3–As2O3 glasses containing iron ions

2004 ◽  
Vol 284 ◽  
pp. 363-368 ◽  
Author(s):  
B.V. Raghavaiah ◽  
D. Krishna Rao ◽  
N. Veeraiah
Keyword(s):  
Magnetic Properties ◽  
Iron Ions

MAGNETIC BEHAVIOR OF IRON IONS IN THE P2O5·CaO GLASS MATRIX

2003 ◽  
Vol 17 (24) ◽  
pp. 1271-1275 ◽  
Author(s):  
I. ARDELEAN ◽  
C. ANDRONACHE ◽  
P. PǍŞCUŢǍ
Keyword(s):  
Magnetic Susceptibility ◽  
High Temperature ◽  
Magnetic Moment ◽  
Glass Matrix ◽  
Magnetic Behavior ◽  
Iron Ions ◽  
Ion Content ◽  
Dipole Interactions ◽  
Valence States ◽  
Temperature Susceptibility

The temperature dependence of the magnetic susceptibility of x Fe 2 O 3·(100-x)-[ P 2 O 5· CaO ] glasses with 0<x≤50 mol % have been investigated. These data revealed that the valence states and the distribution of iron ions in the glass matrix depend on the Fe 2 O 3 content. For the glasses with x≤1 mol % only Fe 3+ ions are evidenced. In the case of the glasses with 3≤x≤35 mol % both Fe 3+ and Fe 2 ions co-exist in the P 2 O 5· CaO glass matrix, the Fe 2+ ion content is higher than that of the Fe 3+ ions for glasses with x≥10 mol %. For the glasses with x>35 mol %, the evaluated values of the μ eff indicate either the presence of Fe + ions or the coordination influence on the magnetic moment of iron ions, but the presence of small quantities of the antiferromagnetic or ferrimagnetic interactions between iron ions in studied temperature range cannot be excluded. The high temperature susceptibility results indicate that the iron ions are isolated or participate in dipole-dipole interactions for glasses with x≤35 mol % and are antiferromagnetically coupled for higher contents of Fe 2 O 3.

scholarly journals Stability and magnetic properties of isomorphous substituted Si7-xMnx+

2018 ◽  
Vol 56 (1) ◽  
pp. 64
Author(s):  
Nguyen Thanh Tung ◽  
Nguyen Thi Mai ◽  
Ngo Tuan Cuong
Keyword(s):  
Density Functional Theory ◽  
Magnetic Properties ◽  
Magnetic Moment ◽  
Density Functional ◽  
Basis Set ◽  
Pentagonal Bipyramid ◽  
Functional Theory ◽  
Electronic Configurations ◽  
Method Of Density Functional ◽  
Optimized Geometries

The optimized geometries, stability, and magnetic properties of cationic clusters Si7+, Si6Mn+, and Si5Mn2+ have been determined by the method of density functional theory using the B3P86/6-311+G(d) functional/basis set. Their electronic configurations have been analyzed to understand the influence of substituting Si atoms by Mn atoms on the structural and magnetic aspects of Si7+. It is shown that the manganese dopant does not alter the structure of the silicon host but significantly changes its stability and magnetism. In particular, while the magnetic moment of Si7+ is 1 mB, Si5Mn2+ exhibits a strong magnetic moment of 9 mB and that of Si6Mn+ takes a relatively high value of 4 mB. Among studied clusters, the pentagonal bipyramid Si5Mn2+ is assigned as the most stable one.

Ab initio calculation of magnetic properties of p-block element doped ZnO

RSC Advances ◽  
2014 ◽  
Vol 4 (85) ◽  
pp. 45598-45602 ◽  
Author(s):  
Palash Nath ◽  
Anirban Chakraborti ◽  
D. Sanyal
Keyword(s):  
Magnetic Properties ◽  
Ab Initio ◽  
Magnetic Moment ◽  
Ab Initio Calculation ◽  
Effective Magnetic Moment ◽  
Block Element ◽  
System P ◽  
Doped Zno

Effective magnetic moment for Zn54O53X (X = B, C, N, F, Al, Si, P, Cl, Ga, Ge, As) system.

scholarly journals Magnetic properties of the non-stoichiometric TbCo2Nix alloys

2018 ◽  
Vol 185 ◽  
pp. 04021
Author(s):  
Alexander Inishev ◽  
Evgeny Gerasimov ◽  
Nikolay Mushnikov ◽  
Pavel Terentev ◽  
Vasily Gaviko
Keyword(s):  
Magnetic Properties ◽  
Curie Temperature ◽  
Concentration Dependence ◽  
Magnetic Moment ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Thermodynamic Relation ◽  
Temperature Dependences

The magnetic and magnetothermal properties of the non-stoichiometric TbCo2Nix (0 ≤ x ≤ 0.2) alloys were studied. It was found that the concentration dependence of the Curie temperature and magnetic moment of the 3d-sublattice have a maximum at x = 0.025. The obtained experimental magnetic properties of the TbCo2Nix alloys were discussed under assumption that the Co magnetic moment in the compounds changes with increasing x. The magnetic entropy change was determined using the temperature dependences of the magnetization and Maxwell’s thermodynamic relation. The obtained results for TbCo2Nix were compared with those for the ErCo2Mnx alloys.

Influence of Gd Addition on the Structure and Capability of Ni-Mn-In Metamagnetic Shape Memory Alloys

2012 ◽  
Vol 535-537 ◽  
pp. 950-953
Author(s):  
Li Na Bai ◽  
Gui Xing Zheng ◽  
Zhi Jian Duan ◽  
Jian Jun Zhang
Keyword(s):  
Differential Scanning Calorimetry ◽  
Magnetic Properties ◽  
Magnetic Property ◽  
Transition Temperature ◽  
Martensitic Transformation ◽  
Room Temperature ◽  
Vibrating Sample Magnetometry ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray

The influences of Gd concentration on martensitic transformation and magnetic properties of NiMnIn alloys were investigated by differential scanning calorimetry (DSC) , vibrating sample magnetometry (VSM), X-ray diffraction (XRD) and etc. It is Observed through the experiment: the addition of Gd enhances martensite transition temperature;X-ray diffraction analysis of experimental alloys is revealed that to the mixture is martensite and austenite at room temperature; content of Gd is not proportional to the improvement of magnetic property.

Structure, Electrical and Magnetic Properties of Thin Films of La1−xMxMnO3 on Si

1999 ◽  
Vol 562 ◽  
Author(s):  
N. N. Mateeva ◽  
P. C. Hogan ◽  
K. H. Dahmen
Keyword(s):  
Thin Films ◽  
Magnetic Properties ◽  
Transition Temperature ◽  
Buffer Layers ◽  
Ferromagnetic Transition ◽  
Electrical And Magnetic Properties ◽  
Insulator Metal Transition ◽  
Composition Structure

ABSTRACTThin films of lanthanum manganates doped with Ca2+, Sr2+, Ba2+ and Pb2+ have been deposited on Si(100) substrate and their electrical and magnetic properties were discussed with respect to the composition, structure and nature of the dopant. Buffer layers of YSZ and La0.8Al0.2O3 were employed and their effect on the materials was studied. Interesting magnetotransport properties were found in some of the films, where there is a large difference between the insulator-metal transition temperature and a ferromagnetic transition temperature.

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