scholarly journals Determination of Heavy Metals in Selected Tissues of Cattle Slaughtered across Nasarawa State, Nigeria

2021 ◽  
Vol 40 (4) ◽  
pp. 254-262
Author(s):  
Muktar A.B. Sabuwa ◽  
Wesley Daniel Nafarnda ◽  
Salihu Danlami Mohammed ◽  
Abdulaziz Bello

This study was conducted to determine the concentrations of some toxic heavy metals in cattle slaughtered from the three agricultural zones of Nasarawa State, Nigeria. Selected tissues of muscle, intestine, skin, kidney and liver were analyzed for the presence of  Cadmium (Cd), Chromium (Cr), Lead (Pb), Copper (Cu) and Nickel (Ni) using Atomic Absorption Spectrophotometer (AAS). Thirty cattle were used for sampling. Five samples of the tissues were collected from each of the cattle, making a total of one hundred and fifty samples. Values obtained were compared with that of FAO/WHO guidelines. Statistical analysis was done using descriptive statistics, t-test and ANOVA. The mean concentrations (mg/kg) of Ni, Cd, Pb and Cu in all the sampled tissues were generally low and below the codex standards. Cr was detected above permissible limit with mean concentrations (mg/kg) of 1.19±5.94, 1.07±4.42, 3.01±6.65, 1.18±5.56 and 1.35±6.94 in intestine, kidney, liver, muscle and skin respectively. There was a significant (P < 0.05) difference in the level of Ni and Cd across two agricultural zones. Government and private sectors should establish cattle ranch and colonies across Nigeria so  as to reduce pasture contamination. Public enlightenment on the grazing of cattle in heavy metals prone areas such as automobile workshops, construction sites and paint factory premises should be advocated. Measures should be put in place for continuous monitoring of heavy metals in Nasarawa state in order to curtail their potential negative effect in human and animal tissues. Key words: cattle, heavy metals, AAS, Nasarawa state.

2017 ◽  
Vol 68 (10) ◽  
pp. 2363-2366
Author(s):  
Delia Nica Badea

The paper evaluates the presence and content of traces of heavy metals Hg, Pb, Ni, Cd (total forms) from coal and solid combustion products, the degree of transfer and accessibility in the area of influence of a lignite power plant. The content of toxic heavy metals in residues are characterized by RE Meiji [ 1 (Pb and Hg) and REMeij �1 (Ni and Cd) for the filter ash. Pb and Ni content in the soil exceeds normal values, and Pb exceeds and alert value for sensitive soils around the residue deposit (70.20 mg.Kg-1). The degree of accessibility of the metals in plants (TF), reported at the Khan reference value (0.5), indicates a significant bioaccumulation level for the metals: Cd (1.9) and Hg (0.6) inside the deposit; Cd (0.39) at the base of the deposit, Hg (0.8) in the area of the thermal power plant. The trace levels of heavy metals analyzed by GFAAS and CVAAS (Hg), indicates a moderate risk potential for food safety and quality of life in the studied area.


2017 ◽  
Vol 2 (1) ◽  
pp. 39
Author(s):  
Rahmi Nurhaini ◽  
Arief Affandi

Iron (Fe) is one of many heavy metals that is corrosive resistant, dense, and has a low melting point. If accumulated in the body, the metal can cause some medical conditions, such as irritation to skin and eyes, breathing problems, and in the long term, cancer. This research aims to know generally the spread of metallic iron (Fe) in the river Pasar in Belangwetan, Klaten. This study was conducted using an observational method in which researchers did not examine the effects of interventions. Sampling was done using purposive sampling method taken from three points, namely the upper, middle, lower. Determination of iron levels by Atomic Absorption Spectrophotometer (AAS) obtained a positive result, and the data was processed using SPSS to determine the Mean and Standard Deviation. Of the research result, it could be known the Mean score was 2.33 ppm and SD was 0.0352. The result of this research indicated that the levels of iron in the river Pasar in Belangwetan were 2.33 ppm. It means that the levels violate the regulation of the Minister of Health of the Republic of Indonesia, which is not more than 1mg/L (1ppm) in the clean water


2014 ◽  
Vol 7 (4) ◽  
pp. 295-301 ◽  
Author(s):  
Ji Yeon Choi ◽  
Girum Habte ◽  
Naeem Khan ◽  
Eun Yeong Nho ◽  
Joon Ho Hong ◽  
...  

Water ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 3405
Author(s):  
Yahia A. Othman ◽  
Amani Al-Assaf ◽  
Maher J. Tadros ◽  
Abeer Albalawneh

Wastewater is actively used for irrigation of vegetable and forage crops in arid lands due to water scarcity and cost advantages. The objective of this review was to assess the effect of wastewater (mixture sources) reuse in irrigation on soil, crop (vegetable and forage crops), animal products, and human health. The metadata analysis of 95 studies revealed that the mean of toxic heavy metals including nickel (Ni), chromium (Cr), cadmium (Cd), lead (Pb), and zinc (Zn) in untreated wastewater were higher than the world standard limits in wastewater-irrigated regions. Although heavy metals in treated wastewater were within the standard limits in those areas, the concentration of those toxic elements (Pb, Cd, Ni, Cr, and As) exceeded the allowable limits in both soil and vegetables’ edible parts. In fact, the concentration of heavy metals in vegetables’ edible parts increased by 3–9 fold when compared with those irrigated with fresh water. Escherichia coli in wastewater-irrigated soil was about 2 × 106 (CFU g−1) and about 15 (CFU g−1) in vegetables’ edible parts (leaf, bulb, tuber and fruit) while the mean total coliforms was about 1.4 × 106 and 55 (CFU g−1) in soil and vegetables’ edible parts, respectively. For human health risk assessment, the estimated daily intake (EDI) and human health risk index (HRI) ranged from 0.01 to 8 (EDI and HRI > 1.0 associated with adverse health effects). Although the mean of EDI for heavy metals from wastewater-irrigated vegetables were less than 1, the HRI for Cd and Pb were above the limits for safe consumption. Overall, heavy metal levels in wastewater that used for irrigation of agricultural crops could be within the recommended levels by the world standards, but the long-term use of this reused water will contaminate soil and crops with several toxic heavy metals leading to potential carcinogenic risks to humans. Therefore, rigorous and frequent testing (wastewater, soil, and plant) is required in cultivated farms to prevent the translocation of heavy metals in the food chain.


Author(s):  
Austin A. Okwelle ◽  
Tamunosisi F. Mac- Pepple

This study analysed the levels of some heavy metals like copper (Cu), cadmium (Cd), chromium(Cr), nickel (Ni) and lead (Pb) present in selected food spices widely used in Port Harcourt, Rivers State, Nigeria. The Atomic Absorption Spectroscopy (AAS) and wet digestion was used for analysis. The results revealed different concentrations of heavy metals in the food spices analysed. The mean and standard deviation of heavy metals across the samples revealed that copper had the highest concentration in tomatoes (15.45±5.09 mg/Kg), curry (10.30±2.03 mg/Kg), garlic (8.65±2.08 mg/Kg), onions (6.50±2.52 mg/Kg) and uda (6.15±3.75 mg/Kg) respectively. Chromium was only detected in curry (2.75±1.00 mg/Kg), pepper (0.65±0.02 mg/Kg) and salt (0.05±0.00 mg/kg). The detected level of nickel was high in tomatoes (6.90±4.89 mg/Kg), curry (4.09±1.90 mg/Kg), salt (6.15±3.70 mg/Kg) and onions (3.09±2.10 mg/Kg). Lead occurred more in uda (3.08±2.87 mg/Kg), tomatoes (3.80±1.28 mg/Kg), curry (2.86±1.34 mg/Kg) and salt (2.60±0.76 mg/Kg) respectively. Cadmium was not detected in any of the food spices, while in chilles spice no heavy metals was detected. The daily intake limit was calculated and compared with minimum risk level (MRL) values. The concentrations of lead in some of the food spices were much larger than those of MRL values. The regular consumption of the spices can lead to accumulation of these toxic heavy metals in human beings.


2011 ◽  
Vol 94 (4) ◽  
pp. 1297-1303 ◽  
Author(s):  
Mustafa Soylak ◽  
Yunus Emre Unsal

Abstract A multiwalled carbon nanotube disk was used for the SPE of some toxic heavy metals from environmental samples. Metal ions were adsorbed on the disk as 8-hydroxquinoline complexes, then quantitatively desorbed from the disk by using 10 mL 2 M HNO3. The effects of analytical parameters, including pH, sample volume, and flow rates, on the recoveries of Cd(II), Co(II), Ni(II), Pb(II), Fe(III), Cu(II), and Zn(II) were investigated. The influences of some 1A and 2A group elements and some other ions as concomitant ions on the recoveries of analyte ions were also examined. The LODs of the presented preconcentration-separation system for the analyte ions were found to be in the range of 1.0–5.2 µg/L. In order to validate the procedure, SRM 1577B Bovine Liver, IAEA 336 Lichen, and HR-1 Humber river sediment certifed reference materials were analyzed. The proposed method has been applied to the determination of understudy elements in some pharmaceutical samples and natural water samples from different sites in Turkey.


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