scholarly journals Efecto del dióxido de titanio en las propiedades mecánicas y autolimpiantes del mortero

2021 ◽  
Vol 25 (109) ◽  
pp. 88-97
Author(s):  
Carlos Magno Chavarry Vallejos ◽  
Liliana Janet Chavarría Reyes ◽  
Xavier Antonio Laos Laura ◽  
Andrés Avelino Valencia Gutiérrez ◽  
Enriqueta Pereyra Salardi ◽  
...  

El presente artículo tiene como objetivo determinar la influencia de la adición del dióxido de titanio (TiO2) en el mortero de cemento Pórtland Tipo I. La investigación es descriptiva, correlacional, explicativo, con diseño experimental, longitudinal, prospectivo y estudio de cohorte. Se elaboró una mezcla patrón y tres mezclas de mortero con 5%, 7.5% y 10% de contenido de TiO2 como reemplazo del volumen de cemento para las propiedades autolimpiantes se realizó el ensayo de rodamina e intemperismo. La incorporación de dióxido de titanio disminuyó la resistencia a la compresión, incrementó la fluidez y tasa de absorción de agua; la prueba de rodamina dio que el mortero sin actividad fotocatalítico no contenía TiO2 porque no cumple con los factores de fotodegradación R4 y R26. Mediante la exposición de paneles al intemperismo favoreciendo la propiedad autolimpiante de los morteros con adición de TiO2 (5%). Palabras Clave: Actividad foto catalítico, dióxido de titanio, factores de fotodegradación, propiedades mecánicas y autolimpiante. Referencias [1]E. Medina and H. Pérez, “Influencia del fotocatalizador dióxido de titanio en las propiedades autolimpiables y mecánicas del mortero de cemento - arena 1:4 - Cajamarca,” Universidad Nacional de Cajamarca, 2017. [2]G. Abella, “Mejora de las propiedades de materiales a base de cemento que contienen TiO 2 : propiedades autolimpiantes,” Universidad Politécnica de Madrid, 2015. [3]J. Gonzalez, “El Dióxido de titanio como material fotocatalitico y su influencia en la resistencia a la compresión en Morteros,” Universidad de San Buenaaventura Seccional Bello, 2015. [4]D. Jimenez and J. Moreno, “Efecto del reemplazo de cemento portland por el dioido de titanio en las propiedades mecanicas del mortero,” Pontificia Universidad Javeriana, 2016. [5]L. Wang, H. Zhang, and Y. Gao, “Effect of TiO2 nanoparticles on physical and mechanical properties of cement at low temperatures,” Adv. Mater. Sci. Eng., 2018, doi: 10.1155/2018/8934689. [6]Comisión de Normalización y de Fiscalización de Barreras Comerciales no Arancelares, Norma Técnica Peruana. Perú, 2013, p. 29. [7]ASTM Internacional, “ASTM C150,” 2021. https://www.astm.org/Database.Cart/Historical/C150-07-SP.htm. [8]M. Issa, “( current astm c150 / aashto m85 ) with limestone and process addition ( ASTM C465 / AASHTO M327 ) on the performance of concrete for pavement and Prepared By,” 2014. [9]S. Zailan, N. Mahmed, M. Abdullah, A. Sandu, and N. Shahedan, “Review on characterization and mechanical performance of self-cleaning concrete,” MATEC Web Conf., vol. 97, pp. 1–7, 2017, doi: 10.1051/matecconf/20179701022. [10]C. Chavarry, L. Chavarría, A. Valencia, E. Pereyra, J. Arieta, and C. Rengifo, “Hormigón reforzado con vidrio molido para controlar grietas y fisuras por contracción plástica,” Pro Sci., vol. 4, no. 31, pp. 31–41, 2020, doi: 10.29018/issn.2588-1000vol4iss31.2020pp31-41. [11]D. Tobaldi, “Materiali ceramici per edilizia con funzionalità fotocatalitica,” Università di Bologna, 2009. [12]Norme UNI, “Norma Italiana UNI 11259,” 2016. http://store.uni.com/catalogo/uni-11259-2008?josso_back_to=http://store.uni.com/josso-security-check.php&josso_cmd=login_optional&josso_partnerapp_host=store.uni.com. [13]E. Grebenisan, H. Szilagyi, A. Hegyi, C. Mircea, and C. Baera, “Directory lines regarding the desing and production of self-cleaning cementitious composites,” Sect. Green Build. Technol. Mater., vol. 19, no. 6, 2019. [14]M. Kaszynska, “The influence of TIO2 nanoparticles on the properties of self-cleaning cement mortar,” Int. Multidiscip. Sci. GeoConference SGEM, pp. 333–341, 2018.

2021 ◽  
pp. 073168442110140
Author(s):  
Hossein Ramezani-Dana ◽  
Moussa Gomina ◽  
Joël Bréard ◽  
Gilles Orange

In this work, we examine the relationships between the microstructure and the mechanical properties of glass fiber–reinforced polyamide 6,6 composite materials ( V f = 54%). These materials made by thermocompression incorporate different grades of high fluidity polyamide-based polymers and two types of quasi-UD glass fiber reinforcement. One is a classic commercial fabric, while the other specially designed and manufactured incorporates weaker tex glass yarns (the spacer) to increase the planar permeability of the preform. The effects of the viscosity of the polymers and their composition on the wettability of the reinforcements were analyzed by scanning electron microscopy observations of the microstructure. The respective influences of the polymers and the spacer on the mechanical performance were determined by uniaxial tensile and compression tests in the directions parallel and transverse to the warp yarns. Not only does the spacer enhance permeability but it also improves physical and mechanical properties: tensile longitudinal Young’s modulus increased from 38.2 GPa to 42.9 GPa (13% growth), tensile strength increased from 618.9 MPa to 697 MPa (3% growth), and decrease in ultimate strain from 1.8% to 1.7% (5% reduction). The correlation of these results with the damage observed post mortem confirms those acquired from analyses of the microstructure of composites and the rheological behaviors of polymers.


2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Li Wang ◽  
Hongliang Zhang ◽  
Yang Gao

Low temperature negatively affects the engineering performance of cementitious materials and hinders the construction productivity. Previous studies have already demonstrated that TiO2 nanoparticles can accelerate cement hydration and enhance the strength development of cementitious materials at room temperature. However, the performance of cementitious materials containing TiO2 nanoparticles at low temperatures is still unknown. In this study, specimens were prepared through the replacement of cement with 1 wt.%, 2 wt.%, 3 wt.%, 4 wt.%, and 5 wt.% TiO2 nanoparticles and cured under temperatures of 0°C, 5°C, 10°C, and 20°C for specific ages. Physical and mechanical properties of the specimens were evaluated through the setting time test, compressive strength test, flexural strength test, hydration degree test, mercury intrusion porosimetry (MIP), X-ray diffraction (XRD) analysis, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) in order to examine the performance of cementitious materials with and without TiO2 nanoparticles at various curing temperatures. It was found that low temperature delayed the process of cement hydration while TiO2 nanoparticles had a positive effect on accelerating the cement hydration and reducing the setting time in terms of the results of the setting time test, hydration degree test, and strength test, and the specimen with the addition of 2 wt.% TiO2 nanoparticles showed the superior performance. Refined pore structure in the MIP tests, more mass loss of CH in TGA, intense peak appearance associated with the hydration products in XRD analysis, and denser microstructure in SEM demonstrated that the specimen with 2 wt.% TiO2 nanoparticles exhibited preferable physical and mechanical properties compared with that without TiO2 nanoparticles under various curing temperatures.


Author(s):  
J. Criollo Barahona ◽  
D. Román Robalino ◽  
E. Cabezas ◽  
E. Salazar Castañeda

The present investigation aims to determine the physical and mechanical properties in three-layer boards of Teak (Tectona grandis), Seike (Cedrelinga catenaeformis) and Mascarey (Hieronima alchorneoides), from the PISMADE S.A. Company, Canton Riobamba, province of Chimborazo. The three specimens used for each of the species in each of the tests performed were worked on using the ASTM D143-94 standard for the tests of parallel compression, perpendicular compression and flexion, and the DIN-52182 standard, with the main variation in thickness measurements caused by the commercial use established by the company. Mechanical tests showed that Seike had the best results, being superior in two tests: perpendicular compression and flexion. Teak tests gave us results that were superior in the perpendicular compression test. Mascarey, unlike the two species mentioned above, had complications during the trials due to problems with the glue between layers. Keywords: physical and mechanical properties of wood, three-layer boards. Resumen La presente investigación pretende: Determinar las propiedades físicas y mecánicas en tableros tricapa de Teca, Seike (Cedrelinga catenaeformis) y Mascarey (Hyeronima alchorneoides), Empresa PISMADE S.A., cantón Riobamba, provincia de Chimborazo; para lo cual se utilizaron 3 probetas por cada una de las especies en cada uno de los ensayos realizados, las mismas fueron trabajadas con base a la Norma ASTM D143-94 para las pruebas de compresión paralela, compresión perpendicular y flexión y la Norma DIN-52182, teniendo como principal variación en las medidas de espesor debido al uso comercial establecido por la empresa. Las pruebas mecánicas mostraron que Seike tuvo los mejores resultados al ser superior en dos ensayos: Compresión perpendicular y flexión. Los ensayos con Teca nos dieron como resultados que es superior en el ensayo de compresión perpendicular. Mascarey a diferencia de las dos especies mencionadas anteriormente tuvo complicaciones con los ensayos debido a problemas con el pegamento entre capas. Palabras clave: propiedades físicas y mecánicas de la madera, tableros tricapa.


2021 ◽  
Vol 1043 ◽  
pp. 133-139
Author(s):  
Tolya Khezhev ◽  
Artur Zhurtov ◽  
Alim Kazharov ◽  
Tamerlan Zrumov ◽  
Asharbek Samgurov

The research results on the development of fire-retardant composite cement mortar mixtures on exfoliated vermiculite and volcanic ash with the use of a multifunctional additive are presented D-5. Compositions of fire-retardant composite mortars, which make it possible to significantly improve the physical and mechanical properties of mortar mixtures and mortars, are proposed. Introduction of a multifunctional supplement D-5 in mortar mixtures makes it possible to improve the composite mortar mixtures properties and improve the solution characteristics. Replacement of finely dispersed fraction of exfoliated vermiculite d<0,63 mm volcanic ash by volume in mortar mixtures does not cause a noticeable increase in the solution density, while their strength characteristics increase. The developed composite mortar mixtures meet the requirements of GOST 28013–98 and have a low-cost price due to volcanic ash use.


2015 ◽  
Vol 815 ◽  
pp. 164-169
Author(s):  
Ng Hooi Jun ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamarudin Husin ◽  
Soo Jin Tan ◽  
Mohd Firdaus Omar

Utilization and suitability of bottom ash in Portland cement have been increasing significantly in recent year. Bottom ash has substantial effects on mechanical properties with different composition of replacement in mixture of bottom ash and Portland cement. Bottom ash was used to determine the feasibility of the substitution as recycling product from industry depending on the percentage of the bottom ash. On the other hand, bottom ash offers a better solution for maintaining materials characteristic of Portland cement mortar and also provide beneficial mechanical performance. The result of using bottom ash in Portland cement mortar showed that it could make better the mechanical properties and hence disposed bottom ash wastes safely in technical, economic and environmental methods.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6970
Author(s):  
Paweł Niewiadomski ◽  
Anna Karolak ◽  
Damian Stefaniuk ◽  
Aleksandra Królicka ◽  
Jacek Szymanowski ◽  
...  

Recently, the research of innovative building materials is focused on applying supplementary materials in the form of micro- and nanopowders in cementitious composites due to the growing insistence on sustainable development. Considering above, in paper, a research on the effect of microsilica and SiO2 nanoparticles addition to cement paste, designed with Andreasen and Andersen (AA) packing density model (PDM), in terms of its physical and mechanical properties was conducted. Density, porosity, compressive strength, hardness, and modulus of indentation were investigated and compared regarding different amount of additives used in cement paste mixes. Microstructure of the obtained pastes was analyzed. The possibility of negative influence of alkali-silica reaction (ASR) on the mechanical properties of the obtained composites was analyzed. The results of the conducted investigations were discussed, and conclusions, also practical, were presented. The obtained results confirmed that the applied PDM may be an effective tool in cement paste design, when low porosity of prepared composite is required. On the other hand, the application of AA model did not bring satisfactory results of mechanical performance as expected, what was related, as shown by SEM imaging, with inhomogeneous dispersion of microsilica, and creation of agglomerates acting as reactive aggregates, what as a consequence caused ASR reaction, crack occurrence and lowered mechanical properties. Finally, the study found that the use of about 7.5% wt. of microsilica is the optimum in regards to obtain low porosity, while, to achieve improved mechanical properties, the use of 4 wt. % of microsilica seems to be optimal, in the case of tested cement pastes.


2018 ◽  
Vol 27 (3) ◽  
pp. 348-354 ◽  
Author(s):  
Jakub Jura ◽  
Małgorzata Ulewicz

The article presents the results of research aimed at using glass waste and ash from biomass. The tests were carried out for cement mortars samples with using glass cullet, ash from biomass and using both wastes in 50/50 proportions. The physical and mechanical properties of the standard mortar and modified mortars were tested. Standard mortar and cement mortar samples were made in which 10, 20 and 30% of the cement mass was used as part of the standard sand. The samples were made of CEM I 42.5R. Mortars containing fly ash addition had an increased compressive strength and a smaller drop in compressive strength after frost resistance tests than standard mortar. The use of glass cullet in the amount of up to 20% did not reveal any changes in the mechanical properties of mortars, but using them in a larger amount resulted in unfavorable results. The use of a mixture of these two waste materials did not improve the results. The research has shown the possibility of using this waste to modify cement mortars.


Sign in / Sign up

Export Citation Format

Share Document