Case Histories and Ratings vs Corrosives of Polyester Fiber Glass Equipment★

CORROSION ◽  
1959 ◽  
Vol 15 (12) ◽  
pp. 29-35 ◽  
Author(s):  
ROBERT E. BARNETT ◽  
THOMAS F. ANDERSON
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Fish Oil ◽  
Boiling Point ◽  
Chemical Resistance ◽  
Polyester Fiber ◽  
Case Histories ◽  
Fiber Glass ◽  
Fair Poor

Abstract Polyesters used in situations where their chemical resistance is important are grouped into five types for convenience in considering their value under attack by industrial corrosives at varying temperatures. Data were compiled from information supplied by four of the major producers on polyester ducts, hoods and tanks as were 17 illustrations of equipment. Pictured equipment is described, environment indicated and durability reported. Corrodents involved include sulfonated fish oil, acidified oils, HCl containing benzene, nitric acid, hydrochloric acid and fumes, plating solutions, sulfuric acid and others at varying temperatures. Some of the characteristics of and reasons for using lined equipment are given. The appendix consists of four tables in which polyesters are rated for service as open hoods and connecting ductwork and for tanks against a wide variety of industrial corrosives, plating solutions pickling and dipping solutions and stripping solutions. Over 5000 ratings are given as excellent, good, fair, poor and not recommended at temperatures of 80 F or less, 212 F or boiling point of solution, if lower: 160 F. 180 F. 6.6.8

scholarly journals Effect of Surface Modification with Different Acids on the Functional Groups of AF 5 Catalyst and Its Catalytic Effect on the Atmospheric Leaching of Enargite

2019 ◽  
Vol 3 (2) ◽  
pp. 45 ◽  
Author(s):  
Jahromi ◽  
Ghahreman
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Functional Groups ◽  
Photoelectron Spectroscopy ◽  
Elemental Sulfur ◽  
Catalytic Properties ◽  
Copper Recovery ◽  
Pre Treatment ◽  
Sulfur Adsorption

Carbon-based catalysts can assist the oxidative leaching of sulfide minerals. Recently, we presented that AF 5 Lewatit® is among the catalysts with superior enargite oxidation capacity and capability to collect elemental sulfur on its surface. Herein, the effect of acid pre-treatment of the AF 5 catalyst was studied on the AF 5 surface, to further enhance the catalytic properties of AF 5. The AF 5 catalyst was pretreated by hydrochloric acid, nitric acid and sulfuric acid. The results showed that the acid treatment drastically changes the surface properties of AF 5. For instance, the concentration of quinone-like functional groups, which are ascribed to the catalytic properties of AF 5, is 45.4% in the sulfuric acid pre-treatment AF 5 and only 29.8% in the hydrochloric acid-treated AF 5. Based on the C 1s X-ray photoelectron spectroscopy (XPS) results the oxygenated carbon is 30.6% in the sulfuric acid-treated AF 5, 29.2% in the nitric acid-treated AF 5 and 28.3% in the hydrochloric acid-treated AF 5. The nitric acid pre-treated AF 5 resulted in the highest copper recovery during the oxidative enargite leaching process, recovering 98.8% of the copper. The sulfuric acid-treated AF 5 recovered 97.1% of the enargite copper into the leach solution. Among different leaching media and pre-treatment the lowest copper recovery was achieved with the HCl pre-treated AF 5 which was 88.6%. The pre-treatment of AF 5 with acids also had modified its elemental sulfur adsorption capacity, where the sulfur adsorption on AF 5 was increased from 30.9% for the HCl treated AF 5 to 51.1% for the sulfuric acid-treated AF 5.

scholarly journals THE INACTIVATION OF DILUTE SOLUTIONS OF CRYSTALLINE TRYPSIN BY X-RADIATION

1955 ◽  
Vol 38 (5) ◽  
pp. 581-598 ◽  
Author(s):  
Margaret R. McDonald
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Radiation Effects ◽  
Reaction Yield ◽  
X Rays ◽  
Dilute Solutions ◽  
Experimental Conditions ◽  
Ph Range ◽  
Ph Curve

The proteolytic activity of dilute solutions of clystalline trypsin is destroyed by x-rays, the amount of inactivation being an exponential function of the radiation dose. The reaction yield increases steadily with increasing concentration of trypsin, varying, as the concentration of enzyme is increased from 1 to 300 µM, from 0.068 to 0.958 micromole of trypsin per liter inactivated per 1000 r with 0.005 N hydrochloric acid as the solvent, from 0.273 to 0.866 with 0.005 N sulfuric acid as the solvent, and from 0.343 to 0.844 with 0.005 N nitric acid as the solvent. When the reaction yields are plotted as a function of the initial concentration of trypsin, they fall on a curve given by the expression Y α XK, in which Y is the reaction yield, X is the concentration of trypsin, and K is a constant equal to 0.46, 0.20, and 0.16, respectively, with 0.005 N hydrochloric, sulfuric, and nitric acids as solvents. The differences between the reaction yields found with chloride and sulfate ions in I to 10 µM trypsin solutions are significant only in the pH range from 2 to 4. The amount of inactivation obtained with a given dose of x-rays depends on the pH of the solution being irradiated and the nature of the solvent. The reaction yield-pH curve is a symmetrical one, with minimum yields at about pH 7. Buffers such as acetate, citrate, borate and barbiturate, and other organic molecules such as ethanol and glucose, in concentrations as low as 20 µM, inhibit the inactivation of trypsin by x-radiation. Sigmoid inactivation-dose curves instead of exponential ones are obtained in the presence of ethanol. The reaction yields for the inactivation of trypsin solutions by x-rays are approximately 1.5 times greater when the irradiation is done at 26°C. than when it is done at 5°C., when 0.005 N hydrochloric acid is the solvent. The dependence on temperature is less when 0.005 N sulfuric acid is used, and is negligible with 0.005 N nitric acid. The difficulties involved in interpreting radiation effects in aqueous systems, and in comparing the results obtained under different experimental conditions, are discussed.

Background Spectral Features in Inductively Coupled Plasma/Mass Spectrometry

1986 ◽  
Vol 40 (4) ◽  
pp. 445-460 ◽  
Author(s):  
S. H. Tan ◽  
G. Horlick
Keyword(s):  
Mass Spectrometry ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Inductively Coupled Plasma ◽  
Mass Spectra ◽  
Mass Range ◽  
Spectral Features ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

Basic background mass spectra of the inductively coupled plasma are presented in this report. The background spectral features were measured for the nebulization of water and for 5% solutions of nitric acid, hydrochloric acid, and sulfuric acid. Background spectra are presented for all these solutions for the mass range 1 to 84 amu, and extensive tables are presented for observed species and their isotopic combinations.

The Inhibitor Exploration Test of Collophane Reverse Flotation in Yunnan

2014 ◽  
Vol 722 ◽  
pp. 22-24
Author(s):  
Bo Wen Yang ◽  
Ping Zhou ◽  
Wan Chao Jin
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Reverse Flotation ◽  
One Stage ◽  
Phosphate Product ◽  
Test Process

The phosphate is low silicon carbonate collophane, gangue mainly dolomite. determine one-stage roughing and one-stage scavenging reverse flotation test process,the grinding fineness of 92.86% -200 mesh.Collector with paraffin soap oxidated,Three acid of sulfuric acid, hydrochloric acid, nitric acid as an inhibitor for contrast test,With concentration of 10% sulfuric acid 10000 g/t can research qualified phosphate product with content of 33.95% in concentration and recovery of 62.06%.

scholarly journals A Study on the Leaching of Rare Earth Elements from Waste Phosphor Powder

2021 ◽  
Vol 59 (7) ◽  
pp. 459-468
Author(s):  
Gee Hun Lee ◽  
Chang Kwon Kim ◽  
Dong Hoon Lee ◽  
Young Jun Song
Keyword(s):  
Rare Earth ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Rare Earth Elements ◽  
Nitric Acid Solution ◽  
Reaction Rate ◽  
Phosphor Powder ◽  
Leaching Reaction

This study was carried out to obtain data to design a process to recover rare earth elements, specifically Y(Yttrium), La(Lanthanum), Ce(Cerium), Eu(Europium), Tb(Terbium) from waste phosphor powder. For this purpose, we investigated the effect of temperature, concentration, time and acids on leaching of the rare earth elements. The effect of roasting temperature, roasting time, roasting agent and its dosage on the leaching of rare earth elements were also investigated. 92% of the Yttrium, 70% of the Europium and 8% of the Cerium contained in the waste phosphor powder was leached at the condition of 50 oC and 0.3N HCl solution for 3hours. However, Terbium and Lanthanum were never leached at this condition. The leaching ratio increased to 100% of Yttrium and Europium, 98% of Cerium, 92% of Terbium and 89% of Lanthanum by leaching after soda ash roasting. In the leaching experiment with unroasted phosphor at 80 oC, the initial leaching reaction rate of Yttrium was 0.035 mol/L·s in 0.3N sulfuric acid solution, 0.033 mol/L·s in nitric acid solution and 0.028 mol/L·s in 0.3N hydrochloric acid solution. And the initial leaching reaction rate of Europium was 0.0017 mol/L·s in 0.3N sulfuric acid solution, 0.00114 mol/L·s in nitric acid solution and 0.00113 mol/L·s in 0.3N hydrochloric acid solution. For Cerium, the initial leaching reaction rate was 0.00019 mol/L·s in 0.3N sulfuric acid solution, 0.00025 mol/L·s in nitric acid solution and 0.00014 mol/L·s in 0.3N hydrochloric acid solution.

The Salt Makers

2019 ◽  
Author(s):  
Peter Wothers
Keyword(s):  
Organic Matter ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Periodic Table ◽  
Dilute Hydrochloric Acid ◽  
Common Salt ◽  
Distilled Water ◽  
Metal Sulfate

This chapter looks at the elements from the penultimate group of the periodic table—the halogens (‘salt-formers’). We shall see that the first of these elements was discovered by Scheele during his investigations of the mineral pyrolusite. Lavoisier knew of the element but he failed to recognize it as such since he was convinced the gas had to contain oxygen and so must be a compound. It was left to Davy to prove that this was not so, which led to the English chemist naming this element that had been discovered (but not properly named) over thirty years before by the great Scheele. Davy’s choice was to influence the names given to all the members of this group, including the most recent member named in 2016. There are three common acids known as mineral acids, since they may all be obtained by heating combinations of certain minerals. Their modern names are nitric acid, sulfuric acid, and hydrochloric acid. Of these three, hydrochloric was probably the last to be discovered. Nitric and sulfuric acids were obtained in the thirteenth or early fourteenth centuries, but the earliest unambiguous preparation of relatively pure hydrochloric acid is from a hundred years later, in a manuscript from Bologna which translates as Secrets for Colour. It gives a curious recipe for a water to soften bones: ‘Take common salt and Roman vitriol in equal quantities, and grind them very well together; then distil them through an alembic, and keep the distilled water in a vessel well closed.’ As we saw in Chapter 3, ‘Roman vitriol’ is a hydrated metal sulfate, probably iron or copper sulfate; its mixture with salt, when heated, produces water and hydrogen chloride, which together form the acid solution. Later texts from the sixteenth and seventeenth centuries include similar methods to prepare this so-called spirit of salt, or ‘oyle of salt’. The first mentioned use, to soften bones, is indeed best achieved with hydrochloric acid, which readily dissolves the minerals from bone to leave only the organic matter largely intact. Leave a chicken bone in dilute hydrochloric acid for a few hours, and it may easily be bent without breaking.

HASTELLOY C-2000 ALLOY

Alloy Digest ◽  
1996 ◽  
Vol 45 (9) ◽  
Keyword(s):  
Thermal Stability ◽  
Corrosion Resistance ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
High Resistance ◽  
Localized Corrosion ◽  
Good Thermal Stability ◽  
High Concentrations ◽  
Corrosive Environments

Abstract Hastelloy C-2000 has a broad capability range for handling corrosive environments. The alloy has high resistance to reagent grade sulfuric acid, hydrochloric acid to high concentrations, and nitric acid. The alloy has outstanding localized corrosion resistance, excellent stress-corrosion cracking resistance, and good thermal stability. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on corrosion resistance. Filing Code: Ni-516. Producer or source: Haynes International Inc.

Contributions to the Analysis of Rubber. IV. Determination of Manganese in Crude Rubber; in Rubber Mixtures and in Fillers

1940 ◽  
Vol 13 (2) ◽  
pp. 430-436
Author(s):  
P. Dekker
Keyword(s):  
Sulfuric Acid ◽  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Reliable Method ◽  
Orthophosphoric Acid ◽  
Manganese Ions ◽  
Potassium Periodate ◽  
Mineral Fillers ◽  
Manganese Compounds

Abstract A scheme for the determination of manganese in mineral fillers, compounding ingredients, crude rubber, rubber mixtures and rubberized materials is described. It is shown that with this method the use of potassium persulfate and two drops of orthophosphoric acid, as proposed by Kehren for the oxidation of colorless manganese ions to red permanganate ions, is advisable. When potassium periodate is used, small quantities of manganese escape detection. It is further shown that there is no appreciable difference between concentration with nitric acid and evaporation with hydrochloric acid and a little sulfuric acid. If, however, the ash is decomposed by soda-potash mixture, the manganese contents are considerably higher. Doubtless these higher values can be accounted for by manganese compounds which are occluded in silicates, and which can be regarded as harmless. A reliable method for the decomposition of the manganese compounds is therefore desirable. The results of analyses of the manganese contents of a large number of various materials are tabulated, and the maximum manganese contents of various materials allowed by the Netherlands Government Rubber Institute are given.

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