scholarly journals A review of the Effect of Calcination Temperature on the Properties of Calcined Clay Concrete

2021 ◽  
Vol 2 (3) ◽  

Naturally occurring clays can produce an amorphous siliceous material possessing pozzolanic properties if is heated at an appropriate temperature. Calcination at the right temperature is crucial since it affects the formation of relevant phases, pozzolanic reactivity, hydration kinetics and consequently, increase the strength and durability of concrete. This paper reviews the effect of calcination temperature on the properties of mortar and concrete corporating calcined clay as partial cement replacement. It is observed that calcination temperatures close to 900°C decrease the specific surface and represent the onset for the structural reorganization of aluminosilicates. Both factors limit the pozzolanic reactivity and can consequently compromise compressive strength. The results show that mortar containing 20% calcined clay obtained compressive strength of 63MPa when calcined at 800oC, surpassing the reference cement by about 8MPa.

2018 ◽  
Vol 59 (1) ◽  
pp. 1-12 ◽  
Author(s):  
Tobias Danner ◽  
Harald Justnes

Abstract Calcined clays are gaining increasing interest as future supplementary cementitious materials for the production of blended cements. Besides the mineralogy, the right production conditions can affect the pozzolanic activity of calcined clays. In this paper, the pozzolanic reactivity of two calcined natural clays in dependence of burning temperature, residence time in the furnace, cooling conditions and particle size of the final product is investigated. The highest pozzolanic reactivity was found at calcination temperatures between 600 and 800°C. While different cooling conditions had no identified effect on reactivity, decreased particle size and residence time increased the reactivity.


2020 ◽  
Vol 20 (2) ◽  
pp. 205
Author(s):  
Nurul Farhanah Mohd Kusaimi ◽  
Fazlena Hamzah ◽  
Junaidah Jai ◽  
Nurul Asyikin Md Zaki ◽  
Norliza Ibrahim

Eco Processed Pozzolan (EPP) is derived from Spent Bleaching Earth (SBE) by the calcination process via heat treatment in the palm oil refining industry. EPP can be used as a partial replacement of cement as it contains a high amount of silica and has pozzolanic properties. Besides its properties, the sustainable production of EPP in the palm oil industry, abundantly available, and cheaper raw material have opened an opportunity to explore it as a cement substitute in pavement industries. This research aimed to study the properties of pozzolanic EPP and discover its potential as a partial substitute of cement in the pavement block's development. The compressive strength and water absorption of the formulated pavement block using EPP were analyzed in this study. Two sets of paving blocks were developed, namely, Set A, EPP was added as a partial replacement of the cement in pavement formulation at 20% - 90%, while in Set B, integration of EPP and Fly Ash (FA) was used as a partial replacement of the cement. The results indicated that the maximum addition of EPP into pavement formulation was 20%. The increment of EPP as a cement substitute in a formulation of more than 20% has reduced the compressive strength and increased the water absorption of the pavement. Simultaneously, the addition of FA and EPP in the formulation of hybrid pavement in Set B shows that the addition of FA has improved the compressive strength of the pavement and less water absorption was detected. The pavement’s highest compressive strength by addition of FA was 36MPa at the EPP was added of 15 – 20%. The study indicated that EPP could be used as a partial substitute of the cement, but addition of FA might require to improve pavement compressive strength.


2014 ◽  
Vol 803 ◽  
pp. 288-293 ◽  
Author(s):  
Mustaqqim Abdul Rahim ◽  
Norlia Mohamad Ibrahim ◽  
Zulliza Idris ◽  
Zuhayr Md Ghazaly ◽  
Shahiron Shahidan ◽  
...  

The use of pozzolanic material from waste product as partial cement replacement in concrete contribute to reduce the environmental, economic problem through their waste and as well enhance the strength and properties of concrete. Rice husk ash (RHA) is one of the industrial waste that suitably used as a cement replacement due to its pozzolanic properties which can enhance the properties of concrete. In this study, the workability, compressive strength and water absorption of the concrete containg RHA is investigating. The chemical content of RHA also investigated by using X-ray Fluorescence Test (XRF). The different RHA percentage of 5%, 15% and 25% were used in this study with burning temperature 650°C. The concrete cube of size 100 mm x 100 mm x 100 mm were prepared and cured for 7, 14 and 28 days. Based on result, it was concluded that the optimum RHA replacement for cement in this report was 5 %, which provided the highest compressive strength at 28 days.


Author(s):  
Achraf Harrou ◽  
El Khadir Gharibi ◽  
Yassine Taha ◽  
Nathalie Fagel ◽  
Meriam El Ouahabi

The Black Steel slag (Ss) and phosphogypsum (PG) are industrial wastes produced in Morocco. In order to reduce these two wastes and to evaluate their pozzolanic reactivity in the presence of water, they were incorporated into bentonite (B) mixed with lime (L). The studied mixtures (BLW, BL-PG-W and BL-PG-Ss-W) were analyzed by X-ray diffraction, Infrared spectroscopy, Raman spectroscopy and SEM/EDX analysis. Compressive strength tests were performed on hardened specimens. The results obtained show that the hydration kinetics of the B-L-W and B-L-PG-W mixtures are slow. The addition of PG to a bentonite-lime mixture induces the formation of new microstructures such as hydrated calcium silicate (C-S-H) and ettringite, which increases the compressive strength of the cementitious specimens. The addition of the Ss to a mixture composed by 8%PG and 8%L-B accelerates the kinetics of hydration and activates the pozzolanic reaction. The presence of C2S in the slag helps to increase the mechanical strength of the mixture B-L-PG-Ss. The compressive strength of the mixtures BL-W, BL-PG-W and BL-PG-Ss-W increases from 15 to 28 days of setting. After 28 days of setting, 8% of Sc added to the mixture 8% PG-8%L-B is responsible for an increase of the compressive strength to 0.6 MPa.


Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1067
Author(s):  
Achraf Harrou ◽  
El Khadir Gharibi ◽  
Yassine Taha ◽  
Nathalie Fagel ◽  
Meriam El Ouahabi

The Black Steel slag (Ss) and phosphogypsum (PG) are industrial wastes produced in Morocco. In order to reduce these two wastes and to evaluate their pozzolanic reactivity in the presence of water, they were incorporated into bentonite (B) mixed with lime (L). The studied mixtures (BLW, BL–PG–W and BL–PG–Ss–W) were analyzed by X-ray diffraction, Infrared spectroscopy, Raman spectroscopy and SEM/EDX analysis. Compressive strength tests were performed on hardened specimens. The results obtained show that the hydration kinetics of the B–L–W and B–L–PG–W mixtures are slow. The addition of PG to a bentonite––lime mixture induces the formation of new microstructures such as hydrated calcium silicate (C–S–H) and ettringite, which increases the compressive strength of the cementitious specimens. The addition of the Ss to a mixture composed of 8%PG and 8%L–B accelerates the kinetics of hydration and activates the pozzolanic reaction. The presence of C2S in the slag helps to increase the mechanical strength of the mixture B–L–PG–Ss. The compressive strength of the mixtures BL–W, BL–PG–W and BL–PG–Ss–W increases from 15 to 28 days of setting. After 28 days of setting, 8% of Sc added to the mixture 8% PG–8%L–B is responsible for an increase of the compressive strength to 0.6 MPa.


2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Luigi Coppola ◽  
Denny Coffetti ◽  
Sergio Lorenzi

The paper focuses on the evaluation of the rheological and mechanical performances of cement-based renders manufactured with phase-change materials (PCM) in form of microencapsulated paraffin for innovative and ecofriendly residential buildings. Specifically, cement-based renders were manufactured by incorporating different amount of paraffin microcapsules—ranging from 5% to 20% by weight with respect to binder. Specific mass, entrained or entrapped air, and setting time were evaluated on fresh mortars. Compressive strength was measured over time to evaluate the effect of the PCM addition on the hydration kinetics of cement. Drying shrinkage was also evaluated. Experimental results confirmed that the compressive strength decreases as the amount of PCM increases. Furthermore, the higher the PCM content, the higher the drying shrinkage. The results confirm the possibility of manufacturing cement-based renders containing up to 20% by weight of PCM microcapsules with respect to binder.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2967
Author(s):  
Rokiah Othman ◽  
Ramadhansyah Putra Jaya ◽  
Khairunisa Muthusamy ◽  
MohdArif Sulaiman ◽  
Youventharan Duraisamy ◽  
...  

This study aims to obtain the relationship between density and compressive strength of foamed concrete. Foamed concrete is a preferred building material due to the low density of its concrete. In foamed concrete, the compressive strength reduces with decreasing density. Generally, a denser foamed concrete produces higher compressive strength and lower volume of voids. In the present study, the tests were carried out in stages in order to investigate the effect of sand–cement ratio, water to cement ratio, foam dosage, and dilution ratio on workability, density, and compressive strength of the control foamed concrete specimen. Next, the test obtained the optimum content of processed spent bleaching earth (PSBE) as partial cement replacement in the foamed concrete. Based on the experimental results, the use of 1:1.5 cement to sand ratio for the mortar mix specified the best performance for density, workability, and 28-day compressive strength. Increasing the sand to cement ratio increased the density and compressive strength of the mortar specimen. In addition, in the production of control foamed concrete, increasing the foam dosage reduced the density and compressive strength of the control specimen. Similarly with the dilution ratio, the compressive strength of the control foamed concrete decreased with an increasing dilution ratio. The employment of PSBE significantly influenced the density and compressive strength of the foamed concrete. An increase in the percentage of PSBE reduced the density of the foamed concrete. The compressive strength of the foamed concrete that incorporated PSBE increased with increasing PSBE content up to 30% PSBE. In conclusion, the compressive strength of foamed concrete depends on its density. It was revealed that the use of 30% PSBE as a replacement for cement meets the desired density of 1600 kg/m3, with stability and consistency in workability, and it increases the compressive strength dramatically from 10 to 23 MPa as compared to the control specimen. Thus, it demonstrated that the positive effect of incorporation of PSBE in foamed concrete is linked to the pozzolanic effect whereby more calcium silicate hydrate (CSH) produces denser foamed concrete, which leads to higher strength, and it is less pore connected. In addition, the regression analysis shows strong correlation between density and compressive strength of the foamed concrete due to the R2 being closer to one. Thus, production of foamed concrete incorporating 30% PSBE might have potential for sustainable building materials.


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 579
Author(s):  
Sang-Ho Chung ◽  
Adrian Ramirez ◽  
Tuiana Shoinkhorova ◽  
Ildar Mukhambetov ◽  
Edy Abou-Hamad ◽  
...  

The Lebedev process, in which ethanol is catalytically converted into 1,3-butadiene, is an alternative process for the production of this commodity chemical. Silica–magnesia (SiO2–MgO) is a benchmark catalyst for the Lebedev process. Among the different preparation methods, the SiO2–MgO catalysts prepared by wet-kneading typically perform best owing to the surface magnesium silicates formed during wet-kneading. Although the thermal treatment is of pivotal importance as a last step in the catalyst preparation, the effect of the calcination temperature of the wet-kneaded SiO2–MgO on the Lebedev process has not been clarified yet. Here, we prepared and characterized in detail a series of wet-kneaded SiO2–MgO catalysts using varying calcination temperatures. We find that the thermal treatment largely influences the type of magnesium silicates, which have different catalytic properties. Our results suggest that the structurally ill-defined amorphous magnesium silicates and lizardite are responsible for the production of ethylene. Further, we argue that forsterite, which has been conventionally considered detrimental for the formation of ethylene, favors the formation of butadiene, especially when combined with stevensite.


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