scholarly journals Technical Note: Fast two-dimensional GC-MS with thermal extraction for anhydro-sugars in fine aerosols

2010 ◽  
Vol 10 (9) ◽  
pp. 4331-4341 ◽  
Author(s):  
Y. Ma ◽  
M. D. Hays ◽  
C. D. Geron ◽  
J. T. Walker ◽  
M. J. Gatari Gichuru
Keyword(s):  
Biomass Burning ◽  
Atmospheric Aerosols ◽  
Analytical Techniques ◽  
Technical Note ◽  
Two Dimensional ◽  
Relative Standard ◽  
The Us ◽  
Thermal Extraction ◽  
Biomass Burning Aerosol ◽  
The Stability

Abstract. A fast two-dimensional gas chromatography (GC-MS) method that uses heart-cutting and thermal extraction (TE) and requires no chemical derivatization was developed for the determination of anhydro-sugars in fine aerosols. Evaluation of the TE-GC-GC-MS method shows high average relative accuracy (≥90%), reproducibility (≤10% relative standard deviation), detection limits of less than 3 ng/μL, and negligible carryover for levoglucosan, mannosan, and galactosan markers. TE-GC-GC-MS- and solvent extraction (SE)-GC-MS-measured levoglucosan concentrations correlate across several diverse types of biomass burning aerosols. Because the SE-GC-MS measurements were taken 8 years prior to the TE-GC-GC-MS ones, the stability of levoglucosan is established for quartz filter-collected biomass burning aerosol samples stored at ultra-low temperature (−50 °C). Levoglucosan concentrations (w/w) in aerosols collected following atmospheric dilution near open fires of varying intensity are similar to those in biomass burning aerosols produced in a laboratory enclosure. An average levoglucosan-mannosan-galactosan ratio of 15:2:1 is observed for these two aerosol sets. TE-GC-GC-MS analysis of atmospheric aerosols from the US and Africa produced levoglucosan concentrations (0.01–1.6 μg/m3) well within those reported for aerosols collected globally and examined using different analytical techniques (0.004–7.6 μg/m3). Further comparisons among techniques suggest that fast TE-GC-GC-MS is among the most sensitive, accurate, and precise methods for compound-specific quantification of anhydro-sugars. In addition, an approximately twofold increase in anhydro-sugar determination may be realized when combining TE with fast chromatography.

scholarly journals Fast two-dimensional GC-MS with thermal extraction for anhydro-sugars in fine aerosols

2010 ◽  
Vol 10 (1) ◽  
pp. 153-182 ◽  
Author(s):  
Y. Ma ◽  
M. D. Hays ◽  
C. D. Geron ◽  
J. T. Walker ◽  
M. J. Gatari Gichuru
Keyword(s):  
Biomass Burning ◽  
Atmospheric Aerosols ◽  
Analytical Techniques ◽  
Aerosol Sample ◽  
Two Dimensional ◽  
Relative Standard ◽  
The Us ◽  
Thermal Extraction ◽  
Biomass Burning Aerosol ◽  
The Stability

Abstract. A fast two-dimensional gas chromatography (GC-MS) method that uses heart-cutting and thermal extraction (TE) and requires no chemical derivatization was developed for the determination of anhydro-sugars in fine aerosols. Evaluation of the TE-GC-GC-MS method shows high average relative accuracy (≥90%), reproducibility (≤10% relative standard deviation), detection limits of less than 3 ng/μL, and negligible carryover for levoglucosan, mannosan, and galactosan markers. TE-GC-GC-MS- and solvent extraction (SE)-GC-MS-measured levoglucosan concentrations correlate across several diverse types of biomass burning aerosols. Because the SE-GC-MS measurements were taken 8 years prior to the TE-GC-GC-MS ones, the stability of levoglucosan is established for quartz filter-collected biomass burning aerosol samples stored at ultra-low temperature (–45°C). Levoglucosan concentrations (w/w) in aerosols collected following atmospheric dilution near open fires of varying intensity are similar to those in biomass burning aerosols produced in a laboratory enclosure. An average levoglucosan-mannosan-galactosan ratio of 15:2:1 is observed for these two aerosol sets. TE-GC-GC-MS analysis of atmospheric aerosols from the US and Africa produced levoglucosan concentrations (0.01–1.6 μg/m3) well within those reported for aerosols collected globally and examined using different analytical techniques (0.004–7.6 μg/m3). Further comparisons among techniques suggest that fast TE-GC-GC-MS is among the most sensitive, accurate, and precise methods for compound-specific quantification of anhydro-sugars. In addition, an approximately twofold increase in aerosol sample throughput may be realized when combining TE with fast chromatography for anhydro-sugar determination.

Chemical markers of biomass burning: Determination of levoglucosan, and potassium in size-classified atmospheric aerosols collected in Buenos Aires, Argentina by different analytical techniques

2018 ◽  
Vol 139 ◽  
pp. 181-187 ◽  
Author(s):  
Mariana Achad ◽  
Sofía Caumo ◽  
Pérola de Castro Vasconcellos ◽  
Héctor Bajano ◽  
Darío Gómez ◽  
...  
Keyword(s):  
Biomass Burning ◽  
Atmospheric Aerosols ◽  
Buenos Aires ◽  
Analytical Techniques ◽  
Chemical Markers

scholarly journals Improved Algorithms for Remote Sensing-Based Aerosol Retrieval during Extreme Biomass Burning Events

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 403
Author(s):  
Sonoyo Mukai ◽  
Itaru Sano ◽  
Makiko Nakata
Keyword(s):  
Biomass Burning ◽  
Atmospheric Aerosols ◽  
Large Scale ◽  
Near Infrared ◽  
Global Climate ◽  
Simulation Method ◽  
Near Ultraviolet ◽  
Aerosol Retrieval ◽  
Aerosol Classification ◽  
Biomass Burning Aerosol

This study proposed an aerosol characterization process using satellites for severe biomass burning events. In general, these severely hazy cases are labeled as “undecided” or “hazy.” Because atmospheric aerosols are significantly affected by factors such as air quality, global climate change, local environmental risk, and human and biological health, efficient and accurate algorithms for aerosol retrieval are required for global satellite data processing. Our previous classification of aerosol types was based primarily on near-ultraviolet (UV) data, which facilitated subsequent aerosol retrieval. In this study, algorithms for aerosol classification were expanded to events with serious biomass burning aerosols (SBBAs). Once a biomass burning event is identified, the appropriate radiation simulation method can be applied to characterize the SBBAs. The second-generation global imager (SGLI) on board the Japanese mission JAXA/Global Change Observation Mission-Climate contains 19 channels, including red (674 nm) and near-infrared (869 nm) polarization channels with a high resolution of 1 km. Using the large-scale wildfires in Kalimantan, Indonesia in 2019 as an example, the complementarity between the polarization information and the nonpolarized radiance measurements from the SGLI was demonstrated to be effective in radiation simulations for biomass burning aerosol retrieval. The retrieved results were verified using NASA/AERONET ground-based measurements, and then compared against JAXA/SGLI/L2-version-1 products, and JMA/Himawari-8/AHI observations.

scholarly journals Aerosol Characterization during the Summer 2017 Huge Fire Event on Mount Vesuvius (Italy) by Remote Sensing and In Situ Observations

2021 ◽  
Vol 13 (10) ◽  
pp. 2001
Author(s):  
Antonella Boselli ◽  
Alessia Sannino ◽  
Mariagrazia D’Emilio ◽  
Xuan Wang ◽  
Salvatore Amoruso
Keyword(s):  
Remote Sensing ◽  
Biomass Burning ◽  
Ground Level ◽  
Large Area ◽  
Fire Event ◽  
Near Surface ◽  
Mean Values ◽  
Microphysical Properties ◽  
Observational Site ◽  
Biomass Burning Aerosol

During the summer of 2017, multiple huge fires occurred on Mount Vesuvius (Italy), dispersing a large quantity of ash in the surrounding area ensuing the burning of tens of hectares of Mediterranean scrub. The fires affected a very large area of the Vesuvius National Park and the smoke was driven by winds towards the city of Naples, causing daily peak values of particulate matter (PM) concentrations at ground level higher than the limit of the EU air quality directive. The smoke plume spreading over the area of Naples in this period was characterized by active (lidar) and passive (sun photometer) remote sensing as well as near-surface (optical particle counter) observational techniques. The measurements allowed us to follow both the PM variation at ground level and the vertical profile of fresh biomass burning aerosol as well as to analyze the optical and microphysical properties. The results evidenced the presence of a layer of fine mode aerosol with large mean values of optical depth (AOD > 0.25) and Ångstrom exponent (γ > 1.5) above the observational site. Moreover, the lidar ratio and aerosol linear depolarization obtained from the lidar observations were about 40 sr and 4%, respectively, consistent with the presence of biomass burning aerosol in the atmosphere.

scholarly journals Development of TLC Chromatographic-Densitometric Procedure for Qualitative and Quantitative Analysis of Ceftobiprole

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 708
Author(s):  
Żaneta Binert-Kusztal ◽  
Małgorzata Starek ◽  
Joanna Żandarek ◽  
Monika Dąbrowska
Keyword(s):  
High Sensitivity ◽  
Biologically Active ◽  
Fifth Generation ◽  
Ich Guidelines ◽  
Relative Standard ◽  
Lipophilicity Parameter ◽  
Alkaline Environments ◽  
Acetic Acid Water ◽  
Cephalosporin Antibiotics ◽  
The Stability

Currently, there is still a need for broad-spectrum antibiotics. The new cephalosporin antibiotics include, among others, ceftobiprole, a fifth-generation gram-positive cephalosporin, active against Staphylococcus aureus methicillin agonist (MRSA). The main focus of the work was to optimize the conditions of ceftobiprole qualitative determination and to validate the developed procedure according to ICH guidelines. As a result of the optimization process, HPTLC Cellulose chromatographic plates as a stationary phase and a mixture consisting of ethanol:2-propanol: glacial acetic acid: water (4:4:1:3, v/v/v/v) as a mobile phase were chosen. The densitometric detection was carried out at maximum absorbance of ceftobiprole (λ = 232 nm). Next, the validation process of the developed procedure was carried out. The relative standard deviation (RSD) for precision was less than 1.65%, which proves the high compatibility of the results, as well as the LOD = 0.0257 µg/spot and LOQ = 0.0779 µg/spot values, which also confirm the high sensitivity of the procedure. The usefulness of the developed method for the stability studies of ceftobiprole was analyzed. Study was carried out under stress conditions, i.e., acid and alkaline environments, exposure to radiation imitating sunlight and high temperature (40–60 °C). It was found that cefotbiprole is unstable in an alkaline environment and during exposure to UV-VIS radiation. Moreover, the lipophilicity parameter, as a main physicochemical property of the biologically active compound, was determined using experimental and computational methods.

scholarly journals The two-dimensional hydrodynamical theory of moving aerofoils. IV

1947 ◽  
Vol 188 (1015) ◽  
pp. 439-463
Keyword(s):  
Stability Problem ◽  
Two Dimensional ◽  
Centre Of Gravity ◽  
First Approximation ◽  
Von Karman ◽  
Moving Cylinder ◽  
Period Equation ◽  
The Stability ◽  
Von Kármán ◽  
Hydrodynamical Theory

In the first part of this paper opportunity has been taken to make some adjustments in certain general formulae of previous papers, the necessity for which appeared in discussions with other workers on this subject. The general results thus amended are then applied to a general discussion of the stability problem including the effect of the trailing wake which was deliberately excluded in the previous paper. The general conclusion is that to a first approximation the wake, as usually assumed, has little or no effect on the reality of the roots of the period equation, but that it may introduce instability of the oscillations, if the centre of gravity of the element is not sufficiently far forward. During the discussion contact is made with certain partial results recently obtained by von Karman and Sears, which are shown to be particular cases of the general formulae. An Appendix is also added containing certain results on the motion of a vortex behind a moving cylinder, which were obtained to justify certain of the assumptions underlying the trail theory.

scholarly journals 3D sub-nanometer analysis of glucose in an aqueous solution by cryo-atom probe tomography

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
T. M. Schwarz ◽  
C. A. Dietrich ◽  
J. Ott ◽  
E. M. Weikum ◽  
R. Lawitzki ◽  
...  
Keyword(s):  
Atom Probe Tomography ◽  
Density Functional ◽  
Chemical Characterization ◽  
Analytical Techniques ◽  
Atom Probe ◽  
Characterization Methods ◽  
Signal Deconvolution ◽  
The Stability ◽  
Frozen Solutions ◽  
3D Volume

AbstractAtom Probe Tomography (APT) is currently a well-established technique to analyse the composition of solid materials including metals, semiconductors and ceramics with up to near-atomic resolution. Using an aqueous glucose solution, we now extended the technique to frozen solutions. While the mass signals of the common glucose fragments CxHy and CxOyHz overlap with (H2O)nH from water, we achieved stoichiometrically correct values via signal deconvolution. Density functional theory (DFT) calculations were performed to investigate the stability of the detected pyranose fragments. This paper demonstrates APT’s capabilities to achieve sub-nanometre resolution in tracing whole glucose molecules in a frozen solution by using cryogenic workflows. We use a solution of defined concentration to investigate the chemical resolution capabilities as a step toward the measurement of biological molecules. Due to the evaporation of nearly intact glucose molecules, their position within the measured 3D volume of the solution can be determined with sub-nanometre resolution. Our analyses take analytical techniques to a new level, since chemical characterization methods for cryogenically-frozen solutions or biological materials are limited.

The great Chinese surprise: the rupture with the United States is real and is happening

2020 ◽  
Vol 96 (2) ◽  
pp. 419-437
Author(s):  
Xiangfeng Yang
Keyword(s):  
United States ◽  
The United States ◽  
Donald Trump ◽  
Ample Evidence ◽  
Pendulum Swing ◽  
The Us ◽  
Methodological Problems ◽  
Trade War ◽  
The Stability ◽  
The Individual

Abstract Ample evidence exists that China was caught off guard by the Trump administration's onslaught of punishing acts—the trade war being a prime, but far from the only, example. This article, in addition to contextualizing their earlier optimism about the relations with the United States under President Trump, examines why Chinese leaders and analysts were surprised by the turn of events. It argues that three main factors contributed to the lapse of judgment. First, Chinese officials and analysts grossly misunderstood Donald Trump the individual. By overemphasizing his pragmatism while downplaying his unpredictability, they ended up underprepared for the policies he unleashed. Second, some ingrained Chinese beliefs, manifested in the analogies of the pendulum swing and the ‘bickering couple’, as well as the narrative of the ‘ballast’, lulled officials and scholars into undue optimism about the stability of the broader relationship. Third, analytical and methodological problems as well as political considerations prevented them from fully grasping the strategic shift against China in the US.

Distributed learning and mutual adaptation

2006 ◽  
Vol 14 (2) ◽  
pp. 313-332 ◽  
Author(s):  
Daniel L. Schwartz ◽  
Taylor Martin
Keyword(s):  
Distributed Cognition ◽  
Dimensional Space ◽  
Distributed Learning ◽  
Early Learning ◽  
Learning Technologies ◽  
Two Dimensional ◽  
Present Evidence ◽  
Mutual Adaptation ◽  
Initial Learning ◽  
The Stability

If distributed cognition is to become a general analytic frame, it needs to handle more aspects of cognition than just highly efficient problem solving. It should also handle learning. We identify four classes of distributed learning: induction, repurposing, symbiotic tuning, and mutual adaptation. The four classes of distributed learning fit into a two-dimensional space defined by the stability and adaptability of individuals and their environments. In all four classes of learning, people and their environments are highly interdependent during initial learning. At the same time, we present evidence indicating that certain types of interdependence in early learning, most notably mutual adaptation, can help prepare people to be less dependent on their immediate environment and more adaptive when they confront new environments. We also describe and test examples of learning technologies that implement mutual adaptation.

Sign in / Sign up

Export Citation Format

Share Document