scholarly journals Persistence of ozone anomalies in the Arctic stratospheric vortex in autumn

2012 ◽  
Vol 12 (11) ◽  
pp. 4817-4823 ◽  
Author(s):  
D. Blessmann ◽  
I. Wohltmann ◽  
R. Lehmann ◽  
M. Rex
Keyword(s):  
Potential Temperature ◽  
Initial Perturbation ◽  
Vortex Formation ◽  
Polar Vortex ◽  
Quantitative Measure ◽  
The Arctic ◽  
Early Winter ◽  
Dynamical Processes ◽  
Vertical Range ◽  
Formation Phase

Abstract. Dynamical processes during the formation phase of the Arctic stratospheric vortex in autumn (from September to December) can introduce considerable interannual variability in the amount of ozone that is incorporated into the vortex. Chemistry in autumn tends to remove part of this variability because ozone relaxes towards equilibrium. As a quantitative measure of how important dynamical variability during vortex formation is for the winter ozone abundances above the Arctic we analyze which fraction of an ozone anomaly induced during vortex formation persists until early winter (3 January). The work is based on the Lagrangian Chemistry Transport Model ATLAS. In a case study, model runs for the winter 1999–2000 are used to assess the fate of an ozone anomaly artificially introduced during the vortex formation phase on 16 September. In addition, runs with reduced resolution explore the sensitivity of the results to interannual changes in transport, mixing, temperatures and NOx. The runs provide information about the persistence of the induced ozone anomaly as a function of time, potential temperature and latitude. The induced ozone anomaly survives longer inside the polar vortex than outside the vortex. Half of the initial perturbation survives until 3 January at 550 K inside the polar vortex, with a rapid fall off towards higher levels, mainly due to NOx induced chemistry. Above 750 K the signal falls to values below 0.5%. Hence, dynamically induced ozone variability from the early vortex formation phase cannot significantly contribute to early winter variability above 750 K. At lower levels increasingly larger fractions of the initial perturbation survive, reaching 90% at 450 K. In this vertical range dynamical processes during the vortex formation phase are crucial for the ozone abundance in early winter.

scholarly journals Interaction of chemical and transport processes during the formation of the Arctic stratospheric polar vortex

2011 ◽  
Vol 11 (12) ◽  
pp. 32283-32300
Author(s):  
D. Blessmann ◽  
I. Wohltmann ◽  
R. Lehmann ◽  
M. Rex
Keyword(s):  
Initial Perturbation ◽  
Vortex Formation ◽  
Polar Vortex ◽  
Quantitative Measure ◽  
Transport Processes ◽  
The Arctic ◽  
Dynamical Processes ◽  
Stratospheric Polar Vortex ◽  
Relevant Variable ◽  
Formation Phase

Abstract. Dynamical processes during the formation phase of the Arctic polar vortex can introduce considerable interannual variability in the amount of ozone that is incorporated into the vortex. Chemistry in autumn and early winter tends to remove part of that variability because ozone relaxes towards equilibrium. As a quantitative measure of how relevant variable dynamical processes during vortex formation are for the winter ozone abundances above the Arctic we analyze which fraction of an ozone anomaly induced dynamically during vortex formation persists until mid-winter. The work is based on the Lagrangian Chemistry Transport Model ATLAS. Model runs for the winter 1999–2000 are used to assess the fate of an ozone anomaly artificially introduced during the vortex formation phase. From these runs we get detailed information about the persistence of the induced ozone variability over time, height and latitude. Induced ozone variability survives longer inside the polar vortex compared to outside. At 540 K inside the polar vortex half of the initial perturbation survives until mid-winter (3 January) with a rapid fall off towards higher levels, mainly due to NOx induced chemistry. At 660 K 10% of the initial perturbation survives. Above 750 K the signal falls to values below 0.5%. Hence, dynamically induced ozone variability from the vortex formation phase can not significantly contribute to mid-winter variability at levels above 750 K. At lower levels increasingly larger fractions of the initial perturbation survive, reaching 90% at 450 K. In this vertical range dynamical processes during the vortex formation phase are crucial for the ozone abundance in mid-winter.

scholarly journals Influence of transport and mixing in autumn on stratospheric ozone variability over the Arctic in early winter

2012 ◽  
Vol 12 (17) ◽  
pp. 7921-7930
Author(s):  
D. Blessmann ◽  
I. Wohltmann ◽  
M. Rex
Keyword(s):  
Transport Model ◽  
Stratospheric Ozone ◽  
Vortex Formation ◽  
Polar Vortex ◽  
The Arctic ◽  
Early Winter ◽  
Mixing Ratios ◽  
Ozone Amount ◽  
High Fraction ◽  
Transport And Mixing

Abstract. Early winter ozone mixing ratios in the Arctic middle stratosphere show an interannual variability of about 10%. We show that ozone variability in early January is caused by dynamical processes during Arctic polar vortex formation in autumn (September to December). Observational data from satellites and ozone sondes are used in conjunction with simulations of the chemistry and transport model ATLAS to examine the relationship between the meridional and vertical origin of air enclosed in the polar vortex and its ozone amount. For this, we use a set of artificial model tracers to deduce the origin of the air masses in the vortex in January in latitude and altitude in September. High vortex mean ozone mixing ratios are correlated with a high fraction of air from low latitudes enclosed in the vortex and a high fraction of air that experienced small net subsidence (in a Lagrangian sense). As a measure for the strength of the Brewer-Dobson circulation and meridional mixing in autumn, we use the Eliassen-Palm flux through the mid-latitude tropopause averaged from September to November. In the lower stratosphere, this quantity correlates well with the origin of air enclosed in the vortex and reasonably well with the ozone amount in early winter.

scholarly journals Influence of transport and mixing in autumn on stratospheric ozone variability over the Arctic in early winter

2012 ◽  
Vol 12 (6) ◽  
pp. 15083-15113
Author(s):  
D. Blessmann ◽  
I. Wohltmann ◽  
M. Rex
Keyword(s):  
Transport Model ◽  
Stratospheric Ozone ◽  
Vortex Formation ◽  
Polar Vortex ◽  
The Arctic ◽  
Early Winter ◽  
Mixing Ratios ◽  
Ozone Amount ◽  
High Fraction ◽  
Transport And Mixing

Abstract. Early winter ozone mixing ratios in the Arctic middle stratosphere show a fair amount of interannual variability. We show that ozone variability in early January is caused by dynamical processes during Arctic polar vortex formation in autumn (September to December). Observational data from satellites and ozone sondes are used in conjunction with simulations of the Chemistry and Transport Model ATLAS to examine the relationship between the meridional and vertical origin of air enclosed in the polar vortex and its ozone amount. For this, we use a set of artificial model tracers to deduce the origin of the air masses in the vortex in January in latitude and altitude in September. High vortex mean ozone mixing ratios are related to a high fraction of air from low latitudes enclosed in the vortex and a high fraction of air that experienced small net subsidence. As a measure for the strength of the Brewer-Dobson circulation and meridional mixing in autumn, we use the Eliassen-Palm flux through the mid-latitude tropopause averaged from August to November. In the lower stratosphere, this quantity correlates well with both the ozone amount in early winter and the origin of air enclosed in the vortex.

scholarly journals Polar processing in a split vortex: early winter Arctic ozone loss in 2012/13

2015 ◽  
Vol 15 (4) ◽  
pp. 4973-5029 ◽  
Author(s):  
G. L. Manney ◽  
Z. D. Lawrence ◽  
M. L. Santee ◽  
N. J. Livesey ◽  
A. Lambert ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Lower Stratosphere ◽  
Polar Vortex ◽  
The Arctic ◽  
Early Winter ◽  
Sudden Stratospheric Warming ◽  
Ozone Loss ◽  
Chlorine Monoxide ◽  
Polar Stratospheric Cloud ◽  
Vortex Split

Abstract. A sudden stratospheric warming (SSW) in early January 2013 caused the polar vortex to split. After the lower stratospheric vortex split on 8 January, the two offspring vortices – one over Canada and the other over Siberia – remained intact, well-confined, and largely at latitudes that received sunlight until they reunited at the end of January. As the SSW began, temperatures abruptly rose above chlorine activation thresholds throughout the lower stratosphere. The vortex was very disturbed prior to the SSW, and was exposed to much more sunlight than usual in December 2012 and January 2013. Aura Microwave Limb Sounder (MLS) nitric acid (HNO3) data and observations from CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) indicate extensive polar stratospheric cloud (PSC) activity, with evidence of PSCs containing solid nitric acid trihydrate particles during much of December 2012. Consistent with the sunlight exposure and PSC activity, MLS observations show that chlorine monoxide (ClO) became enhanced early in December. Despite the cessation of PSC activity with the onset of the SSW, enhanced vortex ClO persisted until mid-February, indicating lingering chlorine activation. The smaller Canadian offspring vortex had lower temperatures, lower HNO3, lower hydrogen chloride (HCl), and higher ClO in late January than the Siberian vortex. Chlorine deactivation began later in the Canadian than in the Siberian vortex. HNO3 remained depressed within the vortices after temperatures rose above the PSC existence threshold, and passive transport calculations indicate vortex-averaged denitrification of about 4 ppbv; the resulting low HNO3 values persisted until the vortex dissipated in mid-February. Consistent with the strong chlorine activation and exposure to sunlight, MLS measurements show rapid ozone loss commencing in mid-December and continuing through January. Lagrangian transport estimates suggest ~ 0.7–0.8 ppmv (parts per million by volume) vortex-averaged chemical ozone loss by late January near 500 K (~ 21 km), with substantial loss occurring from ~ 450 to 550 K. The surface area of PSCs in December 2012 was larger than that in any other December observed by CALIPSO. As a result of denitrification, HNO3 abundances in 2012/13 were among the lowest in the MLS record for the Arctic. ClO enhancement was much greater in December 2012 through mid-January 2013 than that at the corresponding time in any other Arctic winter observed by MLS. Furthermore, reformation of HCl appeared to play a greater role in chlorine deactivation than in more typical Arctic winters. Ozone loss in December 2012 and January 2013 was larger than any previously observed in those months. This pattern of exceptional early winter polar processing and ozone loss resulted from the unique combination of dynamical conditions associated with the early January 2013 SSW, namely unusually low temperatures in December 2012 and offspring vortices that remained well-confined and largely in sunlit regions for about a month after the vortex split.

scholarly journals Temporal evolution of chlorine and minor species related to ozone depletion observed with ground-based FTIR at Syowa Station, Antarctica and satellites during austral fall to spring in 2007 and 2011

2018 ◽  
Author(s):  
Hideaki Nakajima ◽  
Isao Murata ◽  
Yoshihiro Nagahama ◽  
Hideharu Akiyoshi ◽  
Kosuke Saeki ◽  
...  
Keyword(s):  
Temporal Variation ◽  
Negative Correlation ◽  
Temporal Evolution ◽  
Polar Vortex ◽  
The Arctic ◽  
Early Winter ◽  
Syowa Station ◽  
Ozone Destruction ◽  
Reservoir Species ◽  
Satellite Sensor

Abstract. To understand and project future ozone recovery, understanding of mechanisms related to polar ozone destruction is crucial. For polar stratospheric ozone destruction, chlorine species play an important role, but detailed temporal evolution of chlorine species in the Antarctic winter is not well understood. We retrieved lower stratospheric vertical profiles of O3, HNO3, and HCl from solar spectra taken with a ground-based Fourier-Transform infrared spectrometer (FTIR) installed at Syowa Station, Antarctica (69.0º S, 39.6º E) from March to December 2007 and September to November 2011. We analyzed temporal variation of these species combined with ClO, HCl, and HNO3 data taken with the Aura/MLS (Microwave Limb Sounder) satellite sensor, and ClONO2 data taken with the Envisat/MIPAS (The Michelson Interferometer for Passive Atmospheric Sounding) satellite sensor at 18 and 22 km over Syowa Station. When the stratospheric temperature over Syowa Station fell below polar stratospheric cloud (PSC) saturation temperature in early winter, PSCs started to form and heterogeneous reaction on PSCs convert chlorine reservoirs into reactive chemical species. HCl and ClONO2 decrease occurred at both 18 and 22 km, and soon ClONO2 was almost depleted in early winter. When the sun returned to Antarctica in spring, enhancement of ClO and gradual O3 destruction were observed. During the ClO enhanced period, negative correlation between ClO and ClONO2 was observed in the time-series of the data at Syowa Station. This negative correlation was associated with the distance between Syowa Station and the inner edge of the polar vortex. Temporal variation of chlorine species over Syowa Station was affected by both heterogeneous chemistry related to PSC occurrence deep inside the polar vortex, and transport of an NONOx-rich airmass from lower latitudinal polar vortex boundary region which can produce additional ClONO2 by reaction between ClO and NO2. We used MIROC3.2 Chemistry-Climate Model (CCM) results to see the comprehensive behavior of chlorine and related species inside the polar vortex and the edge region in more detail. Rapid conversion of chlorine reservoir species (HCl and ClONO2) into Cl2, gradual conversion of Cl2 into Cl2O2, increase of ClO when sunlight became available, and conversion of ClO into HCl, was successfully reproduced by the CCM. HCl decrease in the winter polar vortex core continued to occur due to the transport of ClONO2 from the subpolar region (55–65º S) to higher latitudes (65–75º S), providing a flux of ClONO2 from more sunlit latitudes into the polar vortex. The deactivation pathways from active ClO into reservoir species (HCl and/or ClONO2) were found to be highly dependent on the availability of ambient O3 and NOx. At an altitude where most ozone was depleted in Antarctica, most ClO was converted to HCl. However, when there were some O3 and NOx available, super-recovery of ClONO2 can occur, similar to the case in the Arctic.

scholarly journals A Match-based approach to the estimation of polar stratospheric ozone loss using Aura Microwave Limb Sounder observations

2015 ◽  
Vol 15 (17) ◽  
pp. 9945-9963 ◽  
Author(s):  
N. J. Livesey ◽  
M. L. Santee ◽  
G. L. Manney
Keyword(s):  
Stratospheric Ozone ◽  
Potential Temperature ◽  
Polar Vortex ◽  
Rate Of Change ◽  
The Arctic ◽  
Air Mass ◽  
Ozone Loss ◽  
Chemical Destruction ◽  
Induced Changes ◽  
The Impact

Abstract. The well-established "Match" approach to quantifying chemical destruction of ozone in the polar lower stratosphere is applied to ozone observations from the Microwave Limb Sounder (MLS) on NASA's Aura spacecraft. Quantification of ozone loss requires distinguishing transport- and chemically induced changes in ozone abundance. This is accomplished in the Match approach by examining cases where trajectories indicate that the same air mass has been observed on multiple occasions. The method was pioneered using ozonesonde observations, for which hundreds of matched ozone observations per winter are typically available. The dense coverage of the MLS measurements, particularly at polar latitudes, allows matches to be made to thousands of observations each day. This study is enabled by recently developed MLS Lagrangian trajectory diagnostic (LTD) support products. Sensitivity studies indicate that the largest influence on the ozone loss estimates are the value of potential vorticity (PV) used to define the edge of the polar vortex (within which matched observations must lie) and the degree to which the PV of an air mass is allowed to vary between matched observations. Applying Match calculations to MLS observations of nitrous oxide, a long-lived tracer whose expected rate of change is negligible on the weekly to monthly timescales considered here, enables quantification of the impact of transport errors on the Match-based ozone loss estimates. Our loss estimates are generally in agreement with previous estimates for selected Arctic winters, though indicating smaller losses than many other studies. Arctic ozone losses are greatest during the 2010/11 winter, as seen in prior studies, with 2.0 ppmv (parts per million by volume) loss estimated at 450 K potential temperature (~ 18 km altitude). As expected, Antarctic winter ozone losses are consistently greater than those for the Arctic, with less interannual variability (e.g., ranging between 2.3 and 3.0 ppmv at 450 K). This study exemplifies the insights into atmospheric processes that can be obtained by applying the Match methodology to a densely sampled observation record such as that from Aura MLS.

scholarly journals Nitric acid in the stratosphere based on Odin observations from 2001 to 2009 – Part 1: A global climatology

2009 ◽  
Vol 9 (18) ◽  
pp. 7031-7044 ◽  
Author(s):  
J. Urban ◽  
M. Pommier ◽  
D. P. Murtagh ◽  
M. L. Santee ◽  
Y. J. Orsolini
Keyword(s):  
Nitric Acid ◽  
Potential Temperature ◽  
Polar Vortex ◽  
Data Sets ◽  
High Latitudes ◽  
Vertical Range ◽  
Spatial And Seasonal Variation ◽  
Antarctic Polar Vortex ◽  
Different Characteristics ◽  
The Antarctic

Abstract. The Sub-Millimetre Radiometer (SMR) on board the Odin satellite, launched in February 2001, observes thermal emissions of stratospheric nitric acid (HNO3) originating from the Earth limb in a band centred at 544.6 GHz. Height-resolved measurements of the global distribution of nitric acid in the stratosphere were performed approximately on two observation days per week. An HNO3 climatology based on more than 7 years of observations from August 2001 to April 2009 covering the vertical range between typically ~19 and 45 km (~1.5–60 hPa or ~500–1800 K in terms of potential temperature) was created. The study highlights the spatial and seasonal variation of nitric acid in the stratosphere, characterised by a pronounced seasonal cycle at middle and high latitudes with maxima during late fall and minima during spring, strong denitrification in the lower stratosphere of the Antarctic polar vortex during winter (the irreversible removal of NOy by the sedimentation of cloud particles containing HNO3), as well as large quantities of HNO3 formed every winter at high-latitudes in the middle and upper stratosphere. A strong inter-annual variability is observed in particular at high latitudes. A comparison with a stratospheric HNO3 climatology, based on over 7 years of UARS/MLS (Upper Atmosphere Research Satellite/Microwave Limb Sounder) measurements from the 1990s, shows good consistency and agreement of the main morphological features in the potential temperature range ~465 to ~960 K, if the different characteristics of the data sets such as the better altitude resolution of Odin/SMR as well as the slightly different altitude ranges are considered. Odin/SMR reaches higher up and UARS/MLS lower down in the stratosphere. An overview from 1991 to 2009 of stratospheric nitric acid is provided (with a short gap between 1998 and 2001), if the global measurements of both experiments are taken together.

scholarly journals Dynamical and chemical processes contributing to ozone loss in exceptional Arctic stratosphere winter-spring of 2020

2021 ◽  
Author(s):  
Sergei P. Smyshlyaev ◽  
Pavel N. Vargin ◽  
Alexander N. Lukyanov ◽  
Natalia D. Tsvetkova ◽  
Maxim A. Motsakov
Keyword(s):  
Polar Vortex ◽  
Reanalysis Data ◽  
Chemical Processes ◽  
Western Hemisphere ◽  
The Arctic ◽  
Spring Season ◽  
Dynamical Processes ◽  
Stratospheric Polar Vortex ◽  
Ozone Loss ◽  
Eastern Hemisphere

Abstract. The features of dynamical processes and changes in the ozone layer in the Arctic stratosphere during the winter-spring season 2019–2020 are analyzed using ozonesondes, reanalysis data and numerical experiments with a chemistry-transport model (CTM). Using the trajectory model of the Central Aerological Observatory (TRACAO) and the ERA5 reanalysis ozone mixing ratio data, a comparative analysis of the evolution of stratospheric ozone averaged along the trajectories in the winter-spring seasons of 2010–2011, 2015–2016, and 2019–2020 was carried out, which demonstrated that the largest ozone loss at altitudes of 18–20 km within stratospheric polar vortex in the Arctic in winter-spring 2019–2020 exceeded the corresponding values of the other two winter-spring seasons 2010–2011 and 2015–2016 with the largest decrease in ozone content in recent year. The total decrease in the column ozone inside the stratospheric polar vortex, calculated using the vertical ozone profiles obtained based on the ozonesondes data, in the 2019–2020 winter-spring season was more than 150 Dobson Units, which repeated the record depletion for the 2010–2011 winter-spring season. At the same time, the maximum ozone loss in winter 2019–2020 was observed at lower levels than in 2010–2011, which is consistent with the results of trajectory analysis and the results of other authors. The results of numerical calculations with the CTM with dynamical parameters specified from the MERRA-2 reanalysis data, carried out according to several scenarios of accounting for the chemical destruction of ozone, indicated that both dynamical and chemical processes make contributions to ozone loss inside the polar vortex. In this case, dynamical processes predominate in the western hemisphere, while in the eastern hemisphere chemical processes make an almost equal contribution with dynamical factors, and the chemical depletion of ozone is determined not only by heterogeneous processes on the surface of the polar stratospheric clouds, but by the gas-phase destruction in nitrogen catalytic cycles as well.

scholarly journals Spatial, temporal, and vertical variability of polar stratospheric ozone loss in the Arctic winters 2004/2005–2009/2010

2010 ◽  
Vol 10 (20) ◽  
pp. 9915-9930 ◽  
Author(s):  
J. Kuttippurath ◽  
S. Godin-Beekmann ◽  
F. Lefèvre ◽  
F. Goutail
Keyword(s):  
Transport Model ◽  
Stratospheric Ozone ◽  
Polar Vortex ◽  
The Arctic ◽  
Model Calculations ◽  
Ozone Loss ◽  
Vertical Range ◽  
Column Ozone ◽  
Catalytic Cycles ◽  
Good Agreement

Abstract. The polar stratospheric ozone loss during the Arctic winters 2004/2005–2009/2010 is investigated by using high resolution simulations from the chemical transport model Mimosa-Chim and observations from Aura Microwave Limb Sounder (MLS), by applying the passive tracer technique. The winter 2004/2005 shows the coldest temperatures, highest area of polar stratospheric clouds and strongest chlorine activation in 2004/2005–2009/2010. The ozone loss diagnosed from both simulations and measurements inside the polar vortex at 475 K ranges from 0.7 ppmv in the warm winter 2005/2006 to 1.5–1.7 ppmv in the cold winter 2004/2005. Halogenated (chlorine and bromine) catalytic cycles contribute to 75–90% of the ozone loss at this level. At 675 K the lowest loss of 0.3–0.5 ppmv is computed in 2008/2009, and the highest loss of 1.3 ppmv is estimated in 2006/2007 by the model and in 2004/2005 by MLS. Most of the ozone loss (60–75%) at this level results from nitrogen catalytic cycles rather than halogen cycles. At both 475 and 675 K levels the simulated ozone and ozone loss evolution inside the vortex is in reasonably good agreement with the MLS observations. The ozone partial column loss in 350–850 K deduced from the model calculations at the MLS sampling locations inside the polar vortex ranges between 43 DU in 2005/2006 and 109 DU in 2004/2005, while those derived from the MLS observations range between 26 DU and 115 DU for the same winters. The partial column ozone depletion derived in that vertical range is larger than that estimated in 350–550 K by 19±7 DU on average, mainly due to NOx chemistry. The column ozone loss estimates from both Mimosa-Chim and MLS in 350–850 K are generally in good agreement with those derived from ground-based ultraviolet-visible spectrometer total ozone observations for the respective winters, except in 2010.

scholarly journals The impact of model grid zooming on tracer transport in the 1999/2000 Arctic polar vortex

2003 ◽  
Vol 3 (5) ◽  
pp. 1833-1847 ◽  
Author(s):  
M. M. P. van den Broek ◽  
M. K. van Aalst ◽  
A. Bregman ◽  
M. Krol ◽  
J. Lelieveld ◽  
...  
Keyword(s):  
Transport Model ◽  
Potential Temperature ◽  
Polar Vortex ◽  
Vertical Gradient ◽  
The Arctic ◽  
Strong Mixing ◽  
Tropical Region ◽  
Tracer Transport ◽  
Model Experiments ◽  
The Impact

Abstract. We have used a 3D chemistry transport model to evaluate the transport of HF and CH4 in the stratosphere during the Arctic winter of 1999/2000. Several model experiments were carried out with the use of a zoom algorithm to investigate the effect of different horizontal resolutions. Balloon-borne and satellite-borne observations of HF and CH4 were used to test the model. In addition, air mass descent rates within the polar vortex were calculated and compared to observations. Outside the vortex the model results agree well with the observations, but inside the vortex the model underestimates the observed vertical gradient in HF and CH4, even when the highest available resolution (1º x 1º) is applied. The calculated diabatic descent rates agree with observations above potential temperature levels of 450 K. These model results suggest that too strong mixing through the vortex edge could be a plausible cause for the model discrepancies, associated with the calculated mass fluxes, although other reasons are also discussed. Based on our model experiments we conclude that a global 6º x 9º resolution is too coarse to represent the polar vortex, whereas the higher resolutions, 3º x 2º and 1º x 1º, yield similar results, even with a 6º x 9º resolution in the tropical region.

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