scholarly journals Why does surface ozone peak before a typhoon landing in southeast China?

2015 ◽  
Vol 15 (23) ◽  
pp. 13331-13338 ◽  
Author(s):  
Y. C. Jiang ◽  
T. L. Zhao ◽  
J. Liu ◽  
X. D. Xu ◽  
C. H. Tan ◽  
...  
Keyword(s):  
Large Scale ◽  
Lower Stratosphere ◽  
Surface Ozone ◽  
High Surface ◽  
Ambient Air ◽  
Ambient Air Quality ◽  
Substantial Impact ◽  
Upper Troposphere ◽  
Horizontal Transport ◽  
Surface O3

Abstract. A high O3 episode with the large increases in surface ozone by 21–42 ppbv and the nocturnal surface O3 levels exceeding 70 ppbv was observed in the region between Xiamen and Quanzhou over the southeastern coast of China during 12–14 June 2014, before the Typhoon Hagibis landing. Variations in the surface O3, NO2, CO and meteorology during the Typhoon Hagibis event clearly suggest a substantial impact of the peripheral downdrafts in the large-scale typhoon circulation on such an O3 episode excluding the contributions of photochemical production and the horizontal transport. The influence of vertical O3 transport from the upper troposphere and lower stratosphere (UTLS) region on high surface O3 levels is further confirmed by a negative correlation between surface O3 and CO concentrations as well as dry surface air observed during the O3 episode. This study provides observational evidence of typhoon-driven intrusion of O3 from the UTLS region to surface air, revealing a significant effect of such a process of stratosphere–troposphere exchange (STE) of O3 on tropospheric O3 and ambient air quality.

scholarly journals Why does surface ozone peak before a typhoon landing in southeast China?

2015 ◽  
Vol 15 (17) ◽  
pp. 24623-24642 ◽  
Author(s):  
Y. C. Jiang ◽  
T. L. Zhao ◽  
J. Liu ◽  
X. D. Xu ◽  
C. H. Tan ◽  
...  
Keyword(s):  
Large Scale ◽  
Lower Stratosphere ◽  
Surface Ozone ◽  
High Surface ◽  
Ambient Air ◽  
Ambient Air Quality ◽  
Substantial Impact ◽  
Upper Troposphere ◽  
Horizontal Transport ◽  
Surface O3

Abstract. A high O3 episode with the large increases in surface ozone by 21–42 ppbv and the nocturnal surface O3 levels exceeding 70 ppbv was observed in the region between Xiamen and Quanzhou over the southeastern coast of China during 12–14 June 2014, before Typhoon Hagibis landing. Variations in the surface O3, NO2, CO and meteorology during Typhoon Hagibis event clearly suggest a substantial impact of the peripheral downdrafts in the large scale typhoon circulation on such an O3 episode with excluding the contributions of photochemical production and the horizontal transport. The influence of vertical O3 transport from the upper troposphere and lower stratosphere (UTLS) region on high surface O3 levels is further confirmed by a negative correlation between surface O3 and CO concentrations as well as dry surface air observed during the O3 episode. This study provides observational evidence of typhoon-driven intrusion of O3 from the UTLS region to surface air, revealing a significant effect of such a process of stratosphere–troposphere exchange (STE) of O3 on tropospheric O3 and ambient air quality.

scholarly journals Characterizing sources of high surface ozone events in the southwestern U.S. with intensive field measurements and two global models

2019 ◽  
Author(s):  
Li Zhang ◽  
Meiyun Lin ◽  
Andrew O. Langford ◽  
Larry W. Horowitz ◽  
Christoph J. Senff ◽  
...  
Keyword(s):  
Large Scale ◽  
Las Vegas ◽  
Surface Ozone ◽  
Field Measurements ◽  
Ambient Air ◽  
Daily Maximum ◽  
Global Models ◽  
High Background ◽  
Stratospheric Intrusions ◽  
Surface O3

Abstract. The detection and attribution of high background ozone (O3) events in the southwestern U.S. is challenging but relevant to the effective implementation of the lowered National Ambient Air Quality Standard (NAAQS; 70 ppbv). Here we leverage intensive field measurements from the Fires, Asian, and Stratospheric TransportLas Vegas Ozone Study (FAST-LVOS) in MayJune 2017, alongside high-resolution simulations with two global models (GFDL-AM4 and GEOS-Chem), to pinpoint the sources of O3 during high-O3 events. We show stratospheric influence on four out of the ten events with daily maximum 8-hour average (MDA8) surface O3 above 65 ppbv in the greater Las Vegas region. While O3 produced from regional anthropogenic emissions dominates pollution in the Las Vegas Valley, stratospheric intrusions can mix with regional pollution to push surface O3 above 70 ppbv. GFDL-AM4 captures the key characteristics of deep stratospheric intrusions consistent with ozonesondes, lidar profiles, and co-located measurements of O3, CO, and water vapor at Angel Peak, whereas GEOS-Chem has difficulty simulating the observed features and underestimates observed O3 by ~ 20 ppbv at the surface. The two models also differ substantially during a wildfire event, with GEOS-Chem estimating ~ 15 ppbv greater O3, in better agreement with lidar observations. At the surface, the two models bracket the observed MDA8 O3 values during the wildfire event. Both models capture the large-scale transport of Asian pollution, but neither resolves some fine-scale pollution plumes, as evidenced from aerosol backscatter, aircraft, and satellite measurements. U.S. background O3 estimates from the two models differ by 5 ppbv on average and up to 15 ppbv episodically. Our multi-model approach tied closely to observational analysis yields process insights, suggesting that elevated background O3 may pose challenges to achieving a potentially lower NAAQS level (e.g., 65 ppbv) in the southwestern U.S.

scholarly journals The relative importance of various source regions on East Asian surface ozone

2010 ◽  
Vol 10 (22) ◽  
pp. 11305-11322 ◽  
Author(s):  
T. Nagashima ◽  
T. Ohara ◽  
K. Sudo ◽  
H. Akimoto
Keyword(s):  
East Asia ◽  
Korean Peninsula ◽  
Transport Model ◽  
Surface Ozone ◽  
Ambient Air ◽  
Large Contribution ◽  
Chemical Production ◽  
Substantial Impact ◽  
Source Regions ◽  
Surface O3

Abstract. We estimated the source-receptor relationship for surface O3 in East Asia during the early 2000s using a method that tags O3 tracers according to their region of chemical production (tagged tracer method) with a global chemical transport model. The estimation demonstrated the importance of intracontinental transport of O3 inside East Asia as well as of the transport of O3 from distant source regions. The model well simulated the absolute concentration and seasonal variation of surface O3 in East Asia and demonstrated significant seasonal differences in the origin of surface O3. In the cold season (October to March), more than half of surface O3 in East Asia is attributable to the O3 transported from distant sources outside of East Asia. In the warm season (April to September), most of the surface O3 is attributable to O3 created within East Asia in most areas of East Asia. In spring the contribution of domestically created O3 accounted for 20% of the surface O3 in Japan and the Korean Peninsula, 40% in the North China Plain, and around 50% in the southern part of China, and the domestic contribution increased greatly in summer. The contributions of O3 created in China and the Korean Peninsula to O3 in Japan were estimated at about 10% and 5%, respectively. We also demonstrated a large contribution (20%) from China to the Korean Peninsula. In the northern and southern parts of China, large contributions of over 10% from East Siberia and the Indochina Peninsula, respectively, were identified. The contribution from intercontinental transport increased with latitude; it was 21% in Northeast China and 13% in Japan and the Korean Peninsula in spring. As for the hourly mean of surface O3, domestically created O3 was the main contributor in most areas of East Asia, except for the low O3 class (<30 ppbv), and accounted for more than 50% in the very high O3 class (>90 ppbv). The mean relative contribution of O3 created in China to O3 in central Japan was about 10% in every class, but that created in the Korean Peninsula was significant in all except the low O3 class. We identified the substantial impact of foreign sources on Japan's ambient air quality standard in the high O3 class (60–90 ppbv) in spring.

scholarly journals Average versus high surface ozone levels over the continental U.S.A.: Model bias, background influences, and interannual variability

2018 ◽  
Author(s):  
Jean J. Guo ◽  
Arlene M. Fiore ◽  
Lee T. Murray ◽  
Daniel A. Jaffe ◽  
Jordan L. Schnell ◽  
...  
Keyword(s):  
Interannual Variability ◽  
Transport Model ◽  
Surface Ozone ◽  
High Surface ◽  
Anthropogenic Sources ◽  
Pollution Transport ◽  
Natural Sources ◽  
Model Biases ◽  
Regional Sources ◽  
Surface O3

Abstract. U.S. background ozone (O3) includes O3 produced from anthropogenic O3 precursors emitted outside of the U.S.A., from global methane, and from any natural sources. Using a suite of sensitivity simulations in the GEOS-Chem global chemistry-transport model, we estimate the influence from individual background versus U.S. anthropogenic sources on total surface O3 over ten continental U.S. regions from 2004–2012. Evaluation with observations reveals model biases of +0–19 ppb in seasonal mean maximum daily 8-hour average (MDA8) O3, highest in summer over the eastern U.S.A. Simulated high-O3 events cluster too late in the season. We link these model biases to regional O3 production (e.g., U.S. anthropogenic, biogenic volatile organic compounds (BVOC), and soil NOx, emissions), or coincident missing sinks. On the ten highest observed O3 days during summer (O3_top10obs_JJA), U.S. anthropogenic emissions enhance O3 by 5–11 ppb and by less than 2 ppb in the eastern versus western U.S.A. The O3 enhancement from BVOC emissions during summer is 1–7 ppb higher on O3_top10obs_JJA days than on average days, while intercontinental pollution is up to 2 ppb higher on average vs. on O3_top10obs_JJA days. In the model, regional sources of O3 precursor emissions drive interannual variability in the highest observed O3 levels. During the summers of 2004–2012, monthly regional mean U.S. background O3 MDA8 levels vary by 10–20 ppb. Simulated summertime total surface O3 levels on O3_top10obs_JJA days decline by 3 ppb (averaged over all regions) from 2004–2006 to 2010–2012 in both the observations and the model, reflecting rising U.S. background (+2 ppb) and declining U.S. anthropogenic O3 emissions (−6 ppb). The model attributes interannual variability in U.S. background O3 on O3_top10obs days to natural sources, not international pollution transport. We find that a three-year averaging period is not long enough to eliminate interannual variability in background O3.

scholarly journals Modeling the transport of very short-lived substances into the tropical upper troposphere and lower stratosphere

2009 ◽  
Vol 9 (5) ◽  
pp. 18511-18543 ◽  
Author(s):  
J. Aschmann ◽  
B. M. Sinnhuber ◽  
E. L. Atlas ◽  
S. M. Schauffler
Keyword(s):  
Large Scale ◽  
Lower Stratosphere ◽  
Transport Model ◽  
Three Dimensional ◽  
Chemical Transport Model ◽  
Heating Rates ◽  
Model Calculations ◽  
Upper Troposphere ◽  
Mass Fluxes ◽  
Tropical Upper Troposphere

Abstract. The transport of very short-lived substances into the tropical upper troposphere and lower stratosphere is investigated by a three-dimensional chemical transport model using archived convective updraft mass fluxes (or detrainment rates) from the European Centre for Medium-Range Weather Forecast's ERA-Interim reanalysis. Large-scale vertical velocities are calculated from diabatic heating rates. With this approach we explicitly model the large scale subsidence in the tropical troposphere with convection taking place in fast and isolated updraft events. The model calculations agree generally well with observations of bromoform and methyl iodide from aircraft campaigns and with ozone and water vapor from sonde and satellite observations. Using a simplified treatment of dehydration and bromine product gas washout we give a range of 1.6 to 3 ppt for the contribution of bromoform to stratospheric bromine, assuming a uniform source in the boundary layer of 1 ppt. We show that the most effective region for VSLS transport into the stratosphere is the West Pacific, accounting for about 55% of the bromine from bromoform transported into the stratosphere under the supposition of a uniformly distributed source.

scholarly journals High-resolution large-eddy simulations of sub-kilometer-scale turbulence in the upper troposphere lower stratosphere

2013 ◽  
Vol 13 (12) ◽  
pp. 31891-31932 ◽  
Author(s):  
R. Paoli ◽  
O. Thouron ◽  
J. Escobar ◽  
J. Picot ◽  
D. Cariolle
Keyword(s):  
Large Scale ◽  
Lower Stratosphere ◽  
Atmospheric Model ◽  
Large Eddy Simulations ◽  
Stratified Flows ◽  
Flow Topology ◽  
Upper Troposphere ◽  
Large Eddy ◽  
Scale Turbulence ◽  
The Impact

Abstract. Large-eddy simulations of sub-kilometer-scale turbulence in the upper troposphere lower stratosphere (UTLS) are carried out and analyzed using the mesoscale atmospheric model Méso-NH. Different levels of turbulence are generated using a large-scale stochastic forcing technique that was especially devised to treat atmospheric stratified flows. The study focuses on the analysis of turbulence statistics, including mean quantities and energy spectra, as well as on a detailed description of flow topology. The impact of resolution is also discussed by decreasing the grid spacing to 2 m and increasing the number of grid points to 8×109. Because of atmospheric stratification, turbulence is substantially anisotropic, and large elongated structures form in the horizontal directions, in accordance with theoretical analysis and spectral direct numerical simulations of stably stratified flows. It is also found that the inertial range of horizontal kinetic energy spectrum, generally observed at scales larger than a few kilometers, is prolonged into the sub-kilometric range, down to the Ozmidov scales that obey isotropic Kolmorogov turbulence. The results are in line with observational analysis based on in situ measurements from existing campaigns.

scholarly journals Study of Clear Air Turbulence Related to Tropopause Folding over the Romanian Airspace

Atmosphere ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 1099
Author(s):  
Sabina Ștefan ◽  
Bogdan Antonescu ◽  
Ana Denisa Urlea ◽  
Livius Buzdugan ◽  
Meda Daniela Andrei ◽  
...  
Keyword(s):  
Large Scale ◽  
Lower Stratosphere ◽  
Meteorological Data ◽  
Horizontal Temperature Gradient ◽  
Jet Streams ◽  
Mountain Waves ◽  
Upper Troposphere ◽  
Air Turbulence ◽  
Upper Level ◽  
Tropopause Folding

Clear air turbulence (CAT) poses a significant threat to aviation. CAT usually occurs in the lower stratosphere and the upper troposphere. It is generally associated with large scale waves, mountain waves, jet streams, upper-level fronts and tropopause folds. Aircraft can experience CAT when flying in proximity of a tropopause fold. To better understand and diagnose tropopause fold- associated CAT we selected a series of cases from among those reported by pilots between June 2017 and December 2018 in the Romanian airspace. Data on turbulence were used in conjunction with meteorological data, satellite imagery, and vertical profiles. Additionally, a set of indices as Ellrod, horizontal temperature gradient, Dutton, and Brown were computed to diagnose CAT associated with tropopause folding. These indices were also analyzed to test the physics mechanisms that may explain the occurrence of severe turbulence. Results show that out of the 420 cases announced by pilots, severe turbulence was reported in 80 cases of which 13 were associated with tropopause folding.

scholarly journals Impacts of different characterizations of large-scale background on simulated regional-scale ozone over the continental United States

2018 ◽  
Vol 18 (5) ◽  
pp. 3839-3864 ◽  
Author(s):  
Christian Hogrefe ◽  
Peng Liu ◽  
George Pouliot ◽  
Rohit Mathur ◽  
Shawn Roselle ◽  
...  
Keyword(s):  
Air Quality ◽  
Boundary Conditions ◽  
Large Scale ◽  
Surface Ozone ◽  
Regional Scale ◽  
Model Performance ◽  
Lower Troposphere ◽  
Substantial Impact ◽  
Mixing Ratios ◽  
Scale Models

Abstract. This study analyzes simulated regional-scale ozone burdens both near the surface and aloft, estimates process contributions to these burdens, and calculates the sensitivity of the simulated regional-scale ozone burden to several key model inputs with a particular emphasis on boundary conditions derived from hemispheric or global-scale models. The Community Multiscale Air Quality (CMAQ) model simulations supporting this analysis were performed over the continental US for the year 2010 within the context of the Air Quality Model Evaluation International Initiative (AQMEII) and Task Force on Hemispheric Transport of Air Pollution (TF-HTAP) activities. CMAQ process analysis (PA) results highlight the dominant role of horizontal and vertical advection on the ozone burden in the mid-to-upper troposphere and lower stratosphere. Vertical mixing, including mixing by convective clouds, couples fluctuations in free-tropospheric ozone to ozone in lower layers. Hypothetical bounding scenarios were performed to quantify the effects of emissions, boundary conditions, and ozone dry deposition on the simulated ozone burden. Analysis of these simulations confirms that the characterization of ozone outside the regional-scale modeling domain can have a profound impact on simulated regional-scale ozone. This was further investigated by using data from four hemispheric or global modeling systems (Chemistry – Integrated Forecasting Model (C-IFS), CMAQ extended for hemispheric applications (H-CMAQ), the Goddard Earth Observing System model coupled to chemistry (GEOS-Chem), and AM3) to derive alternate boundary conditions for the regional-scale CMAQ simulations. The regional-scale CMAQ simulations using these four different boundary conditions showed that the largest ozone abundance in the upper layers was simulated when using boundary conditions from GEOS-Chem, followed by the simulations using C-IFS, AM3, and H-CMAQ boundary conditions, consistent with the analysis of the ozone fields from the global models along the CMAQ boundaries. Using boundary conditions from AM3 yielded higher springtime ozone columns burdens in the middle and lower troposphere compared to boundary conditions from the other models. For surface ozone, the differences between the AM3-driven CMAQ simulations and the CMAQ simulations driven by other large-scale models are especially pronounced during spring and winter where they can reach more than 10 ppb for seasonal mean ozone mixing ratios and as much as 15 ppb for domain-averaged daily maximum 8 h average ozone on individual days. In contrast, the differences between the C-IFS-, GEOS-Chem-, and H-CMAQ-driven regional-scale CMAQ simulations are typically smaller. Comparing simulated surface ozone mixing ratios to observations and computing seasonal and regional model performance statistics revealed that boundary conditions can have a substantial impact on model performance. Further analysis showed that boundary conditions can affect model performance across the entire range of the observed distribution, although the impacts tend to be lower during summer and for the very highest observed percentiles. The results are discussed in the context of future model development and analysis opportunities.

Transport into the upper troposphere-lower stratosphere over North America

2020 ◽  
Author(s):  
Xinyue Wang ◽  
William Randel ◽  
Yutian Wu
Keyword(s):  
Gulf Of Mexico ◽  
Large Scale ◽  
Lower Stratosphere ◽  
Climate Model ◽  
Deep Convection ◽  
Vertical Diffusion ◽  
Dynamical Mechanism ◽  
Upper Troposphere ◽  
The North ◽  
Budget Analysis

&lt;p&gt;We study fast transport of air from the surface into the North American upper troposphere-lower stratosphere (UTLS) during northern summer with a large ensemble of Boundary Impulse Response (BIR) idealized tracers. Specifically, we implement 90 pulse tracers at the Northern Hemisphere surface and release them during July and August months in the fully coupled Whole Atmosphere Community Climate Model (WACCM) version 5. We focus on the most efficient transport cases above southern U.S. (10&amp;#176;-40&amp;#176;N, 60&amp;#176;-140&amp;#176;W) at 100 hPa with modal ages fall below 10th percentile. We examine transport-related terms, including resolved dynamics computed inside model transport scheme and parameterized processes (vertical diffusion and convective parameterization), to pin down the dominant dynamical mechanism. Our results show during the fastest transport, air parcels enter ULTS directly above the Gulf of Mexico. The budget analysis indicates that strong deep convection over the Gulf of Mexico fast uplift the tracer into 200 hPa, and then is vertically advected into 100 hPa and circulated by the enhanced large-scale anticyclone.&amp;#160;&lt;/p&gt;

scholarly journals The relative importance of various source regions on East Asian surface ozone

2010 ◽  
Vol 10 (4) ◽  
pp. 9077-9120 ◽  
Author(s):  
T. Nagashima ◽  
T. Ohara ◽  
K. Sudo ◽  
H. Akimoto
Keyword(s):  
East Asia ◽  
Korean Peninsula ◽  
Transport Model ◽  
Surface Ozone ◽  
East Asian ◽  
Large Contribution ◽  
Chemical Transport Model ◽  
Substantial Impact ◽  
Source Regions ◽  
Surface O3

Abstract. The Source-Receptor (S-R) relationship for surface O3 in East Asia is estimated for recent years in this study utilizing the tagged tracer method with a global chemical transport model. The estimation shows the importance of intra-continental transport of O3 inside East Asia as well as the transport of O3 from distant source regions. The model well simulated the absolute concentration and seasonal variation of surface O3 in the East Asian region, and demonstrated significant seasonal difference in the origin of surface O3. More than half of surface O3 is attributable to the O3 transported from distant sources outside of East Asia in the cold season (October to March). In the warm season (April to September), most of the surface O3 is attributed to O3 created within East Asia in most areas of East Asia. The contribution of domestically-created O3 accounts for 20% of surface O3 in Japan and the Korean Peninsula, 40% in North China Plain and around 50% in the southern part of China in spring, which increase greatly in summer. The contribution of China and the Korean Peninsula to Japan are estimated at about 10% and 5%, respectively. A large contribution (20%) of China to the Korean Peninsula is also demonstrated. In the northern and southern part of China, large contribution of over 10% from East Siberia and the Indochina Peninsula are identified, respectively. The contribution of intercontinental transport increases with latitude; it is 21% in Northeast China and 13% in Japan and the Korean Peninsula in spring. As for one-hourly mean surface O3, domestically-created O3 is the main contributor in most areas of East Asia, except for the low O3 class (<30 ppbv), and accounts for more than 50% in very high O3 class (>90 ppbv). The mean relative contribution of China to central Japan was about 10% in every class, but that from the Korean Peninsula is important in all expect the low O3 class. Substantial impact of foreign sources on the exceedance of Japan's AAQS is identified in the high O3 class (60–90 ppbv) in spring.

Sign in / Sign up

Export Citation Format

Share Document