Continuous and simultaneous measurement of triple oxygen and hydrogen isotopes of liquid and vapour during evaporation

2020 ◽  
Author(s):  
Matthew Brady ◽  
David Hodell
Keyword(s):  
High Precision ◽  
Standard Error ◽  
Numerical Models ◽  
Hydrogen Isotopes ◽  
Vapour Phase ◽  
Integration Time ◽  
Experimental Conditions ◽  
Liquid Injection ◽  
Oxygen And Hydrogen Isotopes ◽  
The Mean

<p>Here, we describe a system for measuring triple oxygen and hydrogen isotopic ratios of both the liquid and vapour during evaporation of water in a dry gas stream (N2 or dry air) at constant temperature and relative humidity (RH).  The hardware consists of a polymer glove box (COY), peristaltic pump (Ismatec), and Picarro L2140-i cavity ring-down laser spectrometer (CRDS) with Standard Delivery Module (SDM). Liquid water from the evaporation pan is sampled via a closed recirculating loop and syringe pump that delivers a constant rate of water to the vaporizer, maintaining a constant concentration of water vapour in the cell (20,000 ±103, 1 s.d.) over an injection cycle. Liquid measurements alternate with vapour from the glove box which is introduced to the CRDS using a diaphragm gas pump. Important for high-precision measurements, both cavity pressure and outlet valve stability are maintained throughout the liquid injection and subsequent vapour phase. Experiments are bookended by two in-house standards which are calibrated to the SMOW-SLAP scales. An additional drift corrector is introduced periodically.</p><p> </p><p>To test the precision and stability of the liquid injections, we sampled from an isotopically homogeneous volume of water and introduced it to the cavity over a period of ~48h. To minimise the standard deviation derived from noise, we chose an optimum integration time of ~2000s (~33 minutes) based on σ<sub>Allan </sub>minimisation. Therefore, for combined liquid-vapour experiments we use an injection/vapour sampling window of 40-minutes (140ug water is consumed per injection), which provides a data collection period of 33-minutes after a 7-min waiting time for equilibration.</p><p> </p><p>Across a single liquid injection, the mean standard error for d<sup>17</sup>O, d<sup>18</sup>O, and dD is 0.008‰, 0.007‰, and 0.02‰, respectively. For the vapour phase equivalent, the mean standard error for d<sup>17</sup>O, d<sup>18</sup>O, and dD is 0.01‰, 0.009‰, 0.03‰ respectively. For the d-excess in the liquid and the vapour across one 33-minute cycle, the standard error is 0.07‰ and 0.08‰, respectively. For the O17-excess in the liquid and the vapour across one 33-minute cycle, the standard error is 6 per meg and 8 per meg, respectively.</p><p> </p><p>A single evaporation experiment produces in excess of 100,000 measurements each of d<sup>17</sup>O, d<sup>18</sup>O, and dD for both the evaporating liquid and resulting vapour. These measurements result in 95% confidence limits for the slope of ln(d<sup>17</sup>O+1) vs ln(d<sup>18</sup>O+1) of ±0.0002 and ±0.0003 for the liquid and vapour, respectively.  For the slope of ln(dD+1) vs ln(d<sup>18</sup>O+1) we obtain a 95% confidence interval of ±0.001 and ±0.002 for the liquid and vapour, respectively. The experimental method permits measurement of fractionation of triple oxygen and hydrogen isotopes of water under varying experimental conditions (e.g., RH, temperature, turbulence) at very high precision. It will be useful for testing numerical models of evaporation and conducting experiments to simulate evaporation and isotopic equilibration in natural systems. An application to closed-basin lakes will be presented.</p>

Articulatory Behavior Pre and Post Full-Mouth Tooth Extraction and Alveoloplasty

1980 ◽  
Vol 23 (3) ◽  
pp. 630-645 ◽  
Author(s):  
Gerald Zimmermann ◽  
J.A. Scott Kelso ◽  
Larry Lander
Keyword(s):  
Control Subject ◽  
High Speed ◽  
Tooth Extraction ◽  
Kinematic Parameters ◽  
Experimental Conditions ◽  
Mean Values ◽  
Articulatory Movements ◽  
The Mean ◽  
Experimental Subjects ◽  
Normal Speech

High speed cinefluorography was used to track articulatory movements preceding and following full-mouth tooth extraction and alveoloplasty in two subjects. Films also were made of a control subject on two separate days. The purpose of the study was to determine the effects of dramatically altering the structural dimensions of the oral cavity on the kinematic parameters of speech. The results showed that the experimental subjects performed differently pre and postoperatively though the changes were in different directions for the two subjects. Differences in both means and variabilities of kinematic parameters were larger between days for the experimental (operated) subjects than for the control subject. The results for the Control subject also showed significant differences in the mean values of kinematic variables between days though these day-to-day differences could not account for the effects found pre- and postoperatively. The results of the kinematic analysis, particularly the finding that transition time was most stable over the experimental conditions for the operated subjects, are used to speculate about the coordination of normal speech.

Multi-Center Calibration of the Second Reference Material for Thromboplastin, Rabbit, Plain, Coded CRM 149R

1991 ◽  
Vol 65 (03) ◽  
pp. 263-267 ◽  
Author(s):  
A M H P van den Besselaar ◽  
R M Bertina
Keyword(s):  
Reference Material ◽  
Standard Error ◽  
Standard Errors ◽  
Sensitivity Index ◽  
Long Term Stability ◽  
Significant Bias ◽  
The Mean ◽  
The Relationship ◽  
International Sensitivity Index

SummaryIn a collaborative trial of eleven laboratories which was performed mainly within the framework of the European Community Bureau of Reference (BCR), a second reference material for thromboplastin, rabbit, plain, was calibrated against its predecessor RBT/79. This second reference material (coded CRM 149R) has a mean International Sensitivity Index (ISI) of 1.343 with a standard error of the mean of 0.035. The standard error of the ISI was determined by combination of the standard errors of the ISI of RBT/79 and the slope of the calibration line in this trial.The BCR reference material for thromboplastin, human, plain (coded BCT/099) was also included in this trial for assessment of the long-term stability of the relationship with RBT/79. The results indicated that this relationship has not changed over a period of 8 years. The interlaboratory variation of the slope of the relationship between CRM 149R and RBT/79 was significantly lower than the variation of the slope of the relationship between BCT/099 and RBT/79. In addition to the manual technique, a semi-automatic coagulometer according to Schnitger & Gross was used to determine prothrombin times with CRM 149R. The mean ISI of CRM 149R was not affected by replacement of the manual technique by this particular coagulometer.Two lyophilized plasmas were included in this trial. The mean slope of relationship between RBT/79 and CRM 149R based on the two lyophilized plasmas was the same as the corresponding slope based on fresh plasmas. Tlowever, the mean slope of relationship between RBT/79 and BCT/099 based on the two lyophilized plasmas was 4.9% higher than the mean slope based on fresh plasmas. Thus, the use of these lyophilized plasmas induced a small but significant bias in the slope of relationship between these thromboplastins of different species.

scholarly journals Comparison of Bite Force in Patients After Treatment of Mandibular Fractures With 3-Dimensional Locking Miniplate and Standard Miniplates

2019 ◽  
Vol 1 (1) ◽  
pp. 7-10
Author(s):  
Gaurav Singh ◽  
Madan Mishra ◽  
Amit Gaur ◽  
Dhritiman Pathak
Keyword(s):  
Treatment Strategies ◽  
Bite Force ◽  
Mandibular Fractures ◽  
Time Intervals ◽  
Experimental Conditions ◽  
3 Dimensional ◽  
The Mean ◽  
Group 2 ◽  
Drilling Conditions ◽  
Group 1

Background: Fractures of the mandible can be studied and described in anatomic terms, functional considerations, treatment strategies, and outcome measures. The performance of any fixation system depends on multiple factors including plate adaptation, screw placement, bone quality, drilling conditions, and postoperative patient compliance. Bite force assesses masticatory muscle function under clinical and experimental conditions. Method: 30 patients with isolated, noncomminuted mandibular fractures were randomly divided into two equal groups. Group 1 patients were treated using 3-dimensional locking miniplates and group 2 patients were treated with standard miniplates. The bite forces were recorded at definite time intervals: preoperatively, and second week, sixth week, third month, and sixth month postoperatively. Result: At 6 weeks postoperative, 3 month postoperative, and 6 month postoperative, the mean bite force was found to be significantly higher among group 1 patients as compared to those in group 2 in all the sites. While at 2 week postoperative, the mean bite force was found to be significantly higher in Group 2 as compared to Group 1 at incisor region. Conclusion: The overall results of the present study show better performance in bite force for the 3-dimensional locking miniplate when compared with standard miniplates.

An Examination of Language Samples Obtained under Three Experimental Conditions

1982 ◽  
Vol 13 (2) ◽  
pp. 121-128 ◽  
Author(s):  
Louise D. Stalnaker ◽  
Nancy A. Creaghead
Keyword(s):  
Preschool Children ◽  
Head Start ◽  
Experimental Conditions ◽  
Semantic Relationships ◽  
Three Samples ◽  
The Mean ◽  
Mean Length Of Utterance ◽  
Language Sample

Language samples were obtained from 12 Head Start preschool children under the following three experimental conditions: Condition I, Retelling a Story with Toys; Condition II, Playing with Toys; Condition III, Toys with Questions. The quantity and quality of the three samples gathered from each child were compared by analyzing the total number of utterances, the proportion of the total utterances which were sentence fragments, the number of transformations and adverbial expansions, the number of different semantic relationships, and the mean length of utterance (MLU). Results indicated that retelling a story produced the largest MLU, but toys and questions produced more utterances. These findings indicated that questioning children does not inhibit their language and asking them to retell a story may be a fruitful approach to use when gathering a language sample.

Intercomparison of Mesoscale Model Simulations of the Daytime Valley Wind System

2011 ◽  
Vol 139 (5) ◽  
pp. 1389-1409 ◽  
Author(s):  
Juerg Schmidli ◽  
Brian Billings ◽  
Fotini K. Chow ◽  
Stephan F. J. de Wekker ◽  
James Doyle ◽  
...  
Keyword(s):  
Land Surface ◽  
Mesoscale Model ◽  
Numerical Models ◽  
Surface Wind ◽  
Sensible Heat Flux ◽  
Surface Wind Speed ◽  
Time Shift ◽  
Wind System ◽  
Valley Wind ◽  
The Mean

Three-dimensional simulations of the daytime thermally induced valley wind system for an idealized valley–plain configuration, obtained from nine nonhydrostatic mesoscale models, are compared with special emphasis on the evolution of the along-valley wind. The models use the same initial and lateral boundary conditions, and standard parameterizations for turbulence, radiation, and land surface processes. The evolution of the mean along-valley wind (averaged over the valley cross section) is similar for all models, except for a time shift between individual models of up to 2 h and slight differences in the speed of the evolution. The analysis suggests that these differences are primarily due to differences in the simulated surface energy balance such as the dependence of the sensible heat flux on surface wind speed. Additional sensitivity experiments indicate that the evolution of the mean along-valley flow is largely independent of the choice of the dynamical core and of the turbulence parameterization scheme. The latter does, however, have a significant influence on the vertical structure of the boundary layer and of the along-valley wind. Thus, this ideal case may be useful for testing and evaluation of mesoscale numerical models with respect to land surface–atmosphere interactions and turbulence parameterizations.

scholarly journals An alternative to the rejection of observations

1932 ◽  
Vol 137 (831) ◽  
pp. 78-87 ◽  
Keyword(s):  
Standard Deviation ◽  
Continuous Function ◽  
Large Deviations ◽  
Opposite Direction ◽  
Standard Error ◽  
The Other ◽  
Cause Of Error ◽  
The Mean ◽  
Normal Law ◽  
Usual Rule

1. It is widely felt that any method of rejecting observations with large deviations from the mean is open to some suspicion. Suppose that by some criterion, such as Peirce’s and Chauvenet’s, we decide to reject observations with deviations greater than 4 σ, where σ is the standard error, computed from the standard deviation by the usual rule; then we reject an observation deviating by 4·5 σ, and thereby alter the mean by about 4·5 σ/ n , where n is the number of observations, and at the same time we reduce the computed standard error. This may lead to the rejection of another observation deviating from the original mean by less than 4 σ, and if the process is repeated the mean may be shifted so much as to lead to doubt as to whether it is really sufficiently representative of the observations. In many cases, where we suspect that some abnormal cause has affected a fraction of the observations, there is a legitimate doubt as to whether it has affected a particular observation. Suppose that we have 50 observations. Then there is an even chance, according to the normal law, of a deviation exceeding 2·33 σ. But a deviation of 3 σ or more is not impossible, and if we make a mistake in rejecting it the mean of the remainder is not the most probable value. On the other hand, an observation deviating by only 2 σ may be affected by an abnormal cause of error, and then we should err in retaining it, even though no existing rule will instruct us to reject such an observation. It seems clear that the probability that a given observation has been affected by an abnormal cause of error is a continuous function of the deviation; it is never certain or impossible that it has been so affected, and a process that completely rejects certain observations, while retaining with full weight others with comparable deviations, possibly in the opposite direction, is unsatisfactory in principle.

scholarly journals Analyzing Individual Differences in Intervention-Related Changes

2021 ◽  
Vol 4 (1) ◽  
pp. 251524592097917
Author(s):  
Tanja Könen ◽  
Julia Karbach
Keyword(s):  
Individual Differences ◽  
Measurement Invariance ◽  
Educational Psychology ◽  
Intervention Studies ◽  
Regression To The Mean ◽  
Short Introduction ◽  
Experimental Conditions ◽  
Occupational Psychology ◽  
Average Group ◽  
The Mean

Intervention studies can be expensive and time-consuming, which is why it is important to extract as much knowledge as possible. We discuss benefits and limitations of analyzing individual differences in intervention studies in addition to traditional analyses of average group effects. First, we present a short introduction to latent change modeling and measurement invariance in the context of intervention studies. Then, we give an overview on options for analyzing individual differences in intervention-related changes with a focus on how substantive information can be distinguished from methodological artifacts (e.g., regression to the mean). The main topics are benefits and limitations of predicting changes with baseline data and of analyzing correlated change. Both approaches can offer descriptive correlational information about individuals in interventions, which can inform future variations of experimental conditions. Applications increasingly emerge in the literature—from clinical, developmental, and educational psychology to occupational psychology—and demonstrate their potential across all of psychology.

Effects of Elevated Atmospheric CO2 and its Interaction with Temperature and Nitrogen on Yield of Barley (Hordeum vulgare L.): A Meta-analysis

2021 ◽  
Author(s):  
Mekides Woldegiorgis Gardi ◽  
Bettina I.G Haussmann ◽  
Waqas Ahmed Malik ◽  
Petra Högy
Keyword(s):  
Grain Yield ◽  
Nitrogen Fertilizer ◽  
Meta Analysis ◽  
N Fertilization ◽  
Additional Stress ◽  
Hordeum Vulgare L ◽  
Grain Number ◽  
Experimental Conditions ◽  
Elevated Atmospheric Co2 ◽  
The Mean

Abstract AimsThe general aim of this meta-analysis is to synthesize and summarise the mean response of barley yield variables to elevated CO2 (eCO2) and its interaction with temperature and N fertilization. Methods The present study quantitatively synthesized the response of barley to eCO2 and its interaction with temperature, and Nitrogen (N). A meta-analysis procedure was used to analyse five yield variables of barley extracted from 76 articles to determine the effect size and the magnitude in relation to eCO2 and its interaction with temperature and N. Results CO2 enrichment increased biomass (23.8%), grain number (24.8%), grain yield (27.4%), and thousand-grain weight (5.6%). However, responses to eCO2 were affected by genotype, additional stress, and experimental conditions. In comparison, genotype “Anakin” shows the highest response of biomass (47.1%), while “Genebank accessions” had a higher grain number (46.1%) and grain yield (57.1%) under eCO2. The maximal enhancement of barley yield was observed when plants grow under a combination of eCO2 and higher nitrogen fertilizer (>100 kg ha-1). Nevertheless, biomass (-12%), and grain yield (-17%) responses were lower when eCO2 is combined with high temperature (>25 °C). It was further noted the response of barley yield to eCO2 was higher in the growth chamber than in other CO2 exposure methods. Moreover, comparing pot-rooted versus field-rooted barley plants, a higher response of biomass and grain yield was observed for pot-rooted plants. ConclusionsOverall, results suggest that the maximal barley production under eCO2 will be obtained in combination with high nitrogen fertilizer and optimal temperature (21-25 °C).

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