Potential Effect of Halogens on Atmospheric Oxidation in China

Air pollution has been a hazard in China over recent decades threatening the health of half a billion people. Much effort has been devoted to mitigating air pollution in China leading to a tremendous reduction in primary pollutants emissions from 2013 to 2017, while a continuously worsening trend of surface ozone (O3, a secondary pollutant and greenhouse gas) was observed over the same period. Atmospheric oxidation, dominated by daytime reactions involving hydroxyl radicals (OH), is the critical process to convert freshly-emitted compounds into secondary pollutants, and is underestimated in current models of China&#8217;s air pollution. Halogens (chlorine, bromine, and iodine) are known to profoundly influence oxidation chemistry in the marine environment; however, their impact on atmospheric oxidation and air pollution in China is unknown. In the present study, we report for the first time that halogens substantially enhance the total atmospheric oxidation capacity in polluted areas of China, typically 10% to 20% (up to 87% in winter) and mainly by significantly increasing OH level. The enhanced oxidation along the coast is driven by oceanic emissions of bromine and iodine, and that over the inland areas by anthropogenic emission of chlorine. The extent and seasonality of halogen impact are largely explained by the dynamics of Asian monsoon, location and intensity of halogen emissions, and O3 formation regime. The omission of halogen emissions and chemistry may lead to significant errors in historical re-assessments and future projections of the evolution of atmospheric oxidation in polluted regions.

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Beyond megacities: tracking air pollution from urban areas and biomass burning in Brazil

npj Climate and Atmospheric Science ◽

10.1038/s41612-021-00173-y ◽

2021 ◽

Vol 4 (1) ◽

Author(s):

Rafaela Squizzato ◽

Thiago Nogueira ◽

Leila D. Martins ◽

Jorge A. Martins ◽

Rosana Astolfo ◽

...

Keyword(s):

Air Pollution ◽

Biomass Burning ◽

Rural Areas ◽

Urban Areas ◽

Surface Ozone ◽

Mobile Station ◽

Pollutant Emissions ◽

World Population ◽

Hourly Data ◽

Secondary Pollutants

AbstractMost of the world’s population lives in rural areas or small to medium-sized cities (totalling 68% of the world population), all of which are impacted by distant air pollution sources. In Brazil, primary pollutant emissions have decreased in urban centres because of government actions, while secondary pollutants such as surface ozone (O3) increased. In addition, O3 and its precursors can be worsening air quality in areas already affected by biofuels production, especially ethanol. We provide almost 3 months of hourly data (June 7, 2019 to August 25, 2019) for concentrations of O3, CO2 and other priority pollutants from a mobile station positioned to distinguish among pollutant plumes (biomass burning, metropolitan area of São Paulo (MASP) and other cities). Although the concentrations of O3 and CO2 were highest in the plumes from biomass burning, the MASP accounted for up to 80% of the O3 concentration in communities over 200 km away.

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The Zhenhua Case: the emergence of civil environmental public interest litigation in China

The Journal of World Energy Law & Business ◽

10.1093/jwelb/jwab008 ◽

2021 ◽

Vol 14 (2) ◽

pp. 116-128

Author(s):

Wenjun Yan

Keyword(s):

Air Pollution ◽

Environmental Protection ◽

Public Interest ◽

Pollution Control ◽

Environmental Damage ◽

Air Pollution Control ◽

Public Interest Litigation ◽

First Time ◽

Restoration Cost

Abstract In 2015, the All-China Environment Federation v Dezhou Jinghua Group Zhenhua Corporation Limited case was the first civil environmental public interest litigation (CEPIL) against air pollution in China. Constituting a milestone in the field of air pollution control in China, this case (i) confirms the eligibility of a non-governmental organisation (NGO) to file civil public interest litigations; (ii) discusses remedies for the ecological destruction caused by air pollution; (iii) assesses the ecological and environmental damage using the ‘virtual restoration cost’ method; and (iv) uses public apology as an innovative way for Zhenhua to assume liability. By applying and interpreting several important rules under the Environmental Protection Law of China (EPLC) for the first time, this case sets an example for future CEPILs against air pollution in China.

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Specific Seminal Plasma Fractions Are Responsible for the Modulation of Sperm–PMN Binding in the Donkey

Animals ◽

10.3390/ani11051388 ◽

2021 ◽

Vol 11 (5) ◽

pp. 1388

Author(s):

Jordi Miró ◽

Jaime Catalán ◽

Henar Marín ◽

Iván Yánez-Ortiz ◽

Marc Yeste

Keyword(s):

Molecular Weight ◽

Sperm Motility ◽

Seminal Plasma ◽

Potential Effect ◽

Polymorphonuclear Neutrophils ◽

Low Fertility ◽

Plasma Fractions ◽

Complex Fluid ◽

First Time

While artificial insemination (AI) with frozen-thawed sperm results in low fertility rates in donkeys, the addition of seminal plasma, removed during cryopreservation, partially counteracts that reduction. Related to this, an apparent inflammatory reaction in jennies is induced following AI with frozen-thawed sperm, as a high amount of polymorphonuclear neutrophils (PMN) are observed within the donkey uterus six hours after AI. While PMN appear to select the sperm that ultimately reach the oviduct, two mechanisms, phagocytosis and NETosis, have been purported to be involved in that clearance. Remarkably, sperm interacts with PMN, but the presence of seminal plasma reduces that binding. As seminal plasma is a complex fluid made up of different molecules, including proteins, this study aimed to evaluate how different seminal plasma fractions, separated by molecular weight (<3, 3–10, 10–30, 30–50, 50–100, and >100 kDa), affect sperm–PMN binding. Sperm motility, viability, and sperm–PMN binding were evaluated after 0 h, 1 h, 2 h, 3 h, and 4 h of co-incubation at 38 °C. Two seminal plasma fractions, including 30–50 kDa or 50–100 kDa proteins, showed the highest sperm motility and viability. As viability of sperm not bound to PMN after 3 h of incubation was the highest in the presence of 30–50 and 50–100 kDa proteins, we suggest that both fractions are involved in the control of the jenny’s post-breeding inflammatory response. In conclusion, this study has shown for the first time that specific fractions rather than the entire seminal plasma modulate sperm–PMN binding within the donkey uterus. As several proteins suggested to be involved in the control of post-AI endometritis have a molecular weight between 30 and 100 kDa, further studies aimed at determining the identity of these molecules and evaluating their potential effect in vivo are much warranted.

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Analyzing of Coatings on Steel - Reinforced Concrete Elements by Mobile NMR

Archives of Civil Engineering ◽

10.1515/ace-2015-0052 ◽

2016 ◽

Vol 62 (1) ◽

pp. 65-82 ◽

Cited By ~ 2

Author(s):

J. Orlowsky

Keyword(s):

Reinforced Concrete ◽

Potential Effect ◽

Building Site ◽

Steel Reinforced Concrete ◽

Mobile Nmr ◽

The Individual ◽

First Time ◽

Concrete Elements ◽

Non Destructive

Abstract A large number of infrastructural concrete buildings are protected against aggressive environments by coating systems. The functionality of these coating systems is mainly affected by the composition and thickness of the individual polymeric layers. For the first time ever, a mobile nuclear magnetic resonance (NMR) sensor allows a non-destructive determination of these important parameters on the building site. However, before this technique can be used on steel-reinforced concrete elements, the potential effect of the reinforcement on the measurement, i.e. the NMR signal, needs to be studied. The results show a shift of the NMR profile as well as an increase of the signals amplitude in the case of the reinforced samples, while calculating the thickness of concrete coating leading to identical results.

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Particulate matter air pollution offsets ozone damage to global crop production

10.5194/acp-2017-1073 ◽

2017 ◽

Author(s):

Luke D. Schiferl ◽

Colette L. Heald

Keyword(s):

Air Pollution ◽

Particulate Matter ◽

Air Quality ◽

Crop Production ◽

Surface Ozone ◽

Diffuse Radiation ◽

Environmental Pressures ◽

Global Food Security ◽

Negative Effect ◽

Pollution Exposure

Abstract. Ensuring global food security requires a comprehensive understanding of environmental pressures on food production, including the impacts of air quality. Surface ozone damages plants and decreases crop production; this effect has been extensively studied. In contrast, the presence of particulate matter (PM) in the atmosphere can be beneficial to crops given that enhanced light scattering leads to a more even and efficient distribution of photons which can outweigh total incoming radiation loss. This study quantifies the impacts of ozone and PM on the global production of maize, rice, and wheat in 2010 and 2050. We show that accounting for the growing season of these crops is an important factor in determining their air pollution exposure. We find that the effect of PM can offset much, if not all, of the reduction in yield associated with ozone damage. Assuming maximum sensitivity to PM, the current (2010) global net impact of air quality on crop production is positive (+6.0 %, +0.5 %, and +4.9 % for maize, wheat, and rice, respectively). Future emissions scenarios indicate that attempts to improve air quality can result in a net negative effect on crop production in areas dominated by the PM effect. However, we caution that the uncertainty in this assessment is large due to the uncertainty associated with crop response to changes in diffuse radiation; this highlights that more detailed physiological study of this response for common cultivars is crucial.

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PM2.5 and Ozone Air Pollution Levels Have Not Dropped Consistently Across the US Following Societal Covid Response

10.26434/chemrxiv.12275603.v5 ◽

2020 ◽

Author(s):

Bujin Bekbulat ◽

Joshua S. Apte ◽

Dylan B Millet ◽

Allen Robinson ◽

Kelley C. Wells ◽

...

Keyword(s):

Air Pollution ◽

Environmental Protection Agency ◽

Fine Particulate Matter ◽

Pollution Levels ◽

Secondary Pollutants ◽

The Us ◽

Many Sources ◽

Primary Pollutant ◽

Ozone Levels ◽

At Home

Analysis of a large national dataset of fine particulate matter (PM2.5) and ozone air pollution from the US Environmental Protection Agency indicate opposing differences in average concentrations during the covid response period, relative to expected levels. These are the two most important pollutants in terms of public health impacts and regulatory non-attainment in the US. Post-covid response, average PM2.5 levels are slightly higher (~5%) than expected; average ozone levels are slightly lower (~5%). The size of post-response ozone anomaly has decreased with time and by week 6 after the first stay-at-home order was enacted (April 29- May 5, 2020), ozone levels were higher than expected. In addition, no individual US state had lower-than-expected PM2.5 and ozone for all weeks post- covid response. Two non-covid factors, meteorology and regional transport, do not fully explain observed trends. These findings are unexpected given the large reduction in many household’s activities associated with “stay at home” and other covid responses. We hypothesize that this result partly arises from the fact that ozone and the majority of PM2.5 are secondary pollutants formed in the atmosphere from emissions from many sources (i.e., not just traffic). Preliminary analysis of nitrogen dioxide (NO2) data in a few cities reveals substantially lower-than-expected (~30%) concentrations post-covid. NO2 is a primary pollutant and is much more strongly associated with traffic than PM2.5 or ozone.

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Impacts of emission changes in China from 2010 to 2017 on domestic and intercontinental air quality and health effect

10.5194/acp-2021-385 ◽

2021 ◽

Author(s):

Yuqiang Zhang ◽

Drew Shindell ◽

Karl Seltzer ◽

Lu Shen ◽

Jean-Francois Lamarque ◽

...

Keyword(s):

Air Pollution ◽

Air Quality ◽

Air Pollutants ◽

Transport Model ◽

Surface Ozone ◽

Health Effect ◽

Premature Deaths ◽

Concentration Changes ◽

Emission Changes ◽

Related Mortality

Abstract. China has seen dramatic emission changes from 2010, especially after the implementation of Clean Air Action in 2013, with significant air quality and human health benefits observed. Air pollutants, such as PM2.5 and surface ozone, as well as their precursors, have long enough lifetime in the troposphere which can be easily transported downwind. So emission changes in China will not only change the regional air quality domestically, but also affect the air quality in downwind regions. In this study, we use a global chemistry transport model to simulate the influence on both domestic and foreign air quality from the emission change from 2010 to 2017 in China. By applying the health impact functions derived from epidemiology studies, we then quantify the changes in air pollution-related (including both PM2.5 and O3) mortality burdens at regional and global scales. The majority of air pollutants in China reach their peak values around 2012 and 2013. Compared with the year 2010, the population-weighted annual PM2.5 in China increases till 2011 (94.1 μg m−3), and then begins to decrease. In 2017, the population-weighted annual PM2.5 decreases by 17.6 %, compared with the values in 2010 (84.7 μg m−3). The estimated national PM2.5 concentration changes in China are comparable with previous studies using fine-resolution regional models, though our model tends to overestimate PM2.5 from 2013 to 2017 when evaluated with surface observation in China during the same periods. The emission changes in China increased the global PM2.5-related mortality burdens from 2010 to 2013, by 27,700 (95 %CI: 23,900–31, 400) deaths yr−1 in 2011, and 13, 300 (11,400–15,100) deaths yr−1 in 2013, among which at least 93 % occurred in China. The sharp emission decreases after 2013 bring significant benefits for reduced avoided premature mortality in 2017, reaching 108, 800 (92,800–124,800) deaths yr−1 globally, among which 92 % happening in China. Different trend as PM2.5, the annual maximum daily 8-hr ozone in China increased, and also the ozone-related premature deaths, ranging from 3,600 (2,700–4,300) deaths yr−1 in 2011 (75 % of global total increased premature deaths), and 8,500 (6,500–9,900) deaths yr−1 in 2017 (143 % of the global total). Downwind regions, such as South Korea, Japan, and U.S. generally see a decreased O3-related mortality burden after 2013 as a combination of increased export of ozone and decreased export of ozone precursors. In general, we conclude that the sharp emission reductions in China after 2013 bring benefits of improved air quality and reduced premature deaths associated with air pollution at global scale. The benefits are dominated by the PM2.5 decreases since the ozone is shown to actually increase with the emission decrease.

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Simulations over South Asia using the weather research and forecasting model with chemistry (WRF-Chem): chemistry evaluation and initial results

Geoscientific Model Development Discussions ◽

10.5194/gmdd-5-1-2012 ◽

2012 ◽

Vol 5 (1) ◽

pp. 1-66 ◽

Cited By ~ 5

Author(s):

R. Kumar ◽

M. Naja ◽

G. G. Pfister ◽

M. C. Barth ◽

C. Wiedinmyer ◽

...

Keyword(s):

South Asia ◽

Biomass Burning ◽

Surface Ozone ◽

Ozone Production ◽

Weather Research And Forecasting ◽

Northern India ◽

Vertical Distributions ◽

Spatio Temporal ◽

First Time ◽

Vertical Ozone

Abstract. This study presents annual simulations of tropospheric ozone and related species made for the first time using the WRF-Chem model over South Asia for the year 2008. The model simulated ozone, CO, and NOx are evaluated against ground-based, balloon-borne and satellite-borne (TES, OMI and MOPITT) observations. The comparison of model results with surface ozone observations from seven sites and CO and NOx observations from three sites, indicate the model's ability in reproducing seasonal variations of ozone and CO, but show some differences in NOx. The modeled vertical ozone distribution agrees well with the ozone soundings data from two Indian sites. The vertical distributions of TES ozone and MOPITT CO are generally well reproduced, but the model underestimates TES ozone, OMI tropospheric column NO2 and MOPITT total column CO retrievals during all the months except MOPITT retrievals during August–January. Largest differences between modeled and satellite retrieved quantities are found during spring when intense biomass burning activity occurs in this region. The evaluation results indicate large uncertainties in anthropogenic and biomass burning emission estimates, especially for NOx. The model results indicate clear regional differences in the seasonality of surface ozone over South Asia with estimated net ozone production during daytime (11:30–15:30 h) over inland regions of 0–5 ppbv h−1 during all seasons and of 0–2 ppbv h−1 over marine regions during outflow periods. The model results indicate that ozone production in this region is mostly NOx-limited. This study shows that WRF-Chem model captures many important features of the observations and gives confidence to using the model for understanding the spatio-temporal variability of ozone over South Asia. However, improvements of South Asian emission inventories and simulations at finer model resolution, especially over the complex Himalayan terrain in Northern India, are also essential for accurately simulating ozone in this region.

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Atmospheric oxidation capacity in Chinese megacities during photochemical polluted season: radical budget and secondary pollutants formation

10.5194/acp-2018-959 ◽

2018 ◽

Cited By ~ 1

Author(s):

Zhaofeng Tan ◽

Keding Lu ◽

Meiqing Jiang ◽

Rong Su ◽

Hongli Wang ◽

...

Keyword(s):

Fine Particle ◽

Fine Particles ◽

Nox Reduction ◽

Ozone Production ◽

Atmospheric Oxidation ◽

Ozone Pollution ◽

Oxidation Capacity ◽

Radical Chemistry ◽

Budget Analysis ◽

Secondary Pollutants

Abstract. Atmospheric oxidation capacity is the core of converting fresh-emitted substances to secondary pollutants. In this study, we present the in-situ measurements at four Chinese megacities (Beijing, Shanghai, Guangzhou, and Chongqing) in China during photochemical polluted seasons. The atmospheric oxidation capacity is evaluated using an observational-based model with the input of radical chemistry precursor measurements. The radical budget analysis illustrates the importance of HONO and HCHO photolysis, which contribute nearly half of the total radical primary sources. The radical propagation is efficient due to abundant of NO in the urban environments. Hence, the production rate of secondary pollutants, i.e. ozone and fine particle precursors (H2SO4, HNO3, and ELVOCs) is fast resulting in secondary air pollution. The ozone budget demonstrates that strong ozone production occurs in the urban area which results in fast ozone concentration increase locally and further transported to downwind areas. On the other hand, the O3-NOx-VOC sensitivity tests show that ozone production is VOC-limited, among which alkenes and aromatics should be first mitigated for ozone pollution control in the presented four megacities. However, NOx emission control will lead to more server ozone pollution due to the drawback-effect of NOx reduction. For fine particle pollution, the role of HNO3−NO3− partitioning system is investigated with a thermal dynamic model (ISORROPIA2) due to the importance of particulate nitrate during photochemical polluted seasons. The strong nitrate acid production converts efficiently to nitrate particles due to high RH and ammonium-rich conditions during photochemical polluted seasons. This study highlights the efficient radical chemistry maintains the atmospheric oxidation capacity in Chinese megacities, which results in secondary pollutions characterized by ozone and fine particles.

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Sources of Air Pollution

Handbook of Research on Microbial Tools for Environmental Waste Management - Advances in Environmental Engineering and Green Technologies ◽

10.4018/978-1-5225-3540-9.ch011 ◽

2018 ◽

pp. 220-258

Author(s):

Abderrezak Khelfi

Keyword(s):

Air Pollution ◽

Particulate Matter ◽

Adverse Effects ◽

Chemical Reactions ◽

Dust Storms ◽

Pollution Sources ◽

Atmospheric Gases ◽

Secondary Pollutants ◽

Harmful Substances ◽

Life On Earth

This chapter describes how air is a complex natural gaseous system essential to support life on Earth. Air pollution comes from a wide variety of sources, which discharge of harmful substances into the atmosphere, causing adverse effects to humans and the environment. They can be natural or anthropogenic. Natural air pollution sources are multiple and include volcanic eruption, fire, ocean vapors, dust storms and fermentation of organic materials. However, the range and quantities of chemicals discharged into the atmosphere from industry, transport, agriculture, energy production, domestic heating, and many other human activities, have increased dramatically. Some pollutants are emitted directly into the atmosphere and are known as primary pollutants (NOx, SOx, particulate matter, etc.). Others are formed in the air as a result of chemical reactions with other pollutants and atmospheric gases; these are known as secondary pollutants like ozone. This chapter provides an overview on air pollution sources as well as the ways in which pollutants can affect human health and the environment.

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