Magnetostratigraphic evidence for post-depositional distortion of osmium isotopic records in pelagic clay: implications for mineral flux estimates

2021 ◽  
Author(s):  
Yoichi Usui ◽  
Toshitsugu Yamazaki
Keyword(s):  
Accumulation Rate ◽  
Late Eocene ◽  
Main Process ◽  
Mechanical Mixing ◽  
Deep Sea Sediment ◽  
Age Model ◽  
Pelagic Clay ◽  
Isotopic Records ◽  
The Stability ◽  
Age Constraints

<p>Deep-sea sediment sometimes lacks biostratigraphic or radiometric age constraints. Chemical stratigraphy and magnetostratigraphy is useful for dating it. Oxic pelagic clay contains Fe-Mn oxyhydroxides that can retain seawater <sup>187</sup>Os/<sup>188</sup>Os values, and its age can be estimated by fitting the isotopic ratios to the seawater <sup>187</sup>Os/<sup>188</sup>Os curve. On the other hand, the stability of Fe-Mn oxyhydroxides is sensitive to redox change, and it is not clear whether the original <sup>187</sup>Os/<sup>188</sup>Os values are always preserved in sediments. However, due to the lack of independent age constraints, the reliability of <sup>187</sup>Os/<sup>188</sup>Os ages of pelagic clay have never been tested. Magnetostratigraphy is often unsuccessful for pelagic clay older than a few Ma, which has been attributed to diagenesis. Here we report multiple polarity reversals in ca. 35 Ma pelagic clay around Minamitorishima Island, which is inconsistent with a <sup>187</sup>Os/<sup>188</sup>Os age model. In a ~5 m thick interval, previous studies correlated <sup>187</sup>Os/<sup>188</sup>Os data to a brief (<1 million years) isotopic excursion in the late Eocene. Paleomagnetic measurements revealed at least 12 polarity zones in the interval, indicating a >2.9 – 6.9 million years duration. Quartz and feldspars content showed that while the paleomagnetic chronology gives reasonable eolian flux estimates, the <sup>187</sup>Os/<sup>188</sup>Os chronology leads unrealistically high values. These results suggest that the low <sup>187</sup>Os/<sup>188</sup>Os signal has diffused from an original thin layer to the current ~5 m interval, causing an underestimate of the deposition duration. The preservation of the polarity patterns indicates that a mechanical mixing such as bioturbation cannot be the main process for the diffusion, so diagenetic re-distribution of Fe-Mn oxyhydroxides and associated Os may be responsible. The paleomagnetic chronology presented here also demands reconsiderations of the timing, accumulation rate, and origins of the high content of rare-earth elements and yttrium in pelagic clay around Minamitorishima Island. It is also indicated that old oxic pelagic clay can be a faithful paleomagnetic recorder, and success of magnetostratigraphy depends on sedimentation rate and polarity length rather than diagenesis.</p><p>Usui, Y., Yamazaki, T. <em>Earth Planets Space</em> <strong>73, </strong>2 (2021). https://doi.org/10.1186/s40623-020-01338-4</p>

scholarly journals Magnetostratigraphic evidence for post-depositional distortion of osmium isotopic records in pelagic clay and its implications for mineral flux estimates

2021 ◽  
Vol 73 (1) ◽  
Author(s):  
Yoichi Usui ◽  
Toshitsugu Yamazaki
Keyword(s):  
Accumulation Rate ◽  
Late Eocene ◽  
Main Process ◽  
Isotopic Ratios ◽  
Mechanical Mixing ◽  
Redox Change ◽  
Pelagic Clay ◽  
Isotopic Records ◽  
The Stability ◽  
Age Constraints

AbstractChemical stratigraphy is useful for dating deep-sea sediments, which sometimes lack radiometric or biostratigraphic constraints. Oxic pelagic clay contains Fe–Mn oxyhydroxides that can retain seawater 187Os/188Os values, and its age can be estimated by fitting the isotopic ratios to the seawater 187Os/188Os curve. On the other hand, the stability of Fe–Mn oxyhydroxides is sensitive to redox change, and it is not clear whether the original 187Os/188Os values are always preserved in sediments. However, due to the lack of independent age constraints, the reliability of 187Os/188Os ages of pelagic clay has never been tested. Here we report inconsistency between magnetostratigraphic and 187Os/188Os ages in pelagic clay around Minamitorishima Island. In a ~ 5-m-thick interval, previous studies correlated 187Os/188Os data to a brief (< 1 million years) isotopic excursion in the late Eocene. Paleomagnetic measurements revealed at least 12 polarity zones in the interval, indicating a > 2.9–6.9 million years duration. Quartz and feldspars content showed that while the paleomagnetic chronology gives reasonable eolian flux estimates, the 187Os/188Os chronology leads to unrealistically high values. These results suggest that the low 187Os/188Os signal has diffused from an original thin layer to the current ~ 5-m interval, causing an underestimate of the deposition duration. The preservation of the polarity patterns indicates that a mechanical mixing such as bioturbation cannot be the main process for the diffusion, so diagenetic redistribution of Fe–Mn oxyhydroxides and associated Os may be responsible. The paleomagnetic chronology presented here also demands reconsiderations of the timing, accumulation rate, and origins of the high content of rare-earth elements and yttrium in pelagic clay around Minamitorishima Island.

scholarly journals Magnetostratigraphic Evidence for Post-Depositional Distortion of Osmium Isotopic Records in Pelagic Clay and Its Implications for Mineral Flux Estimates

2020 ◽  
Author(s):  
Yoichi Usui ◽  
Toshitsugu Yamazaki
Keyword(s):  
Accumulation Rate ◽  
Late Eocene ◽  
Main Process ◽  
Isotopic Ratios ◽  
Mechanical Mixing ◽  
Redox Change ◽  
Pelagic Clay ◽  
Isotopic Records ◽  
The Stability ◽  
Age Constraints

Abstract Chemical stratigraphy is useful for dating deep sea sediments which sometimes lack radiometric or biostratigraphic constraints. Oxic pelagic clay contains Fe-Mn oxyhydroxides that can retain seawater 187Os/188Os values, and its age can be estimated by fitting the isotopic ratios to the seawater 187Os/188Os curve. On the other hand, the stability of Fe-Mn oxyhydroxides is sensitive to redox change, and it is not clear whether the original 187Os/188Os values are always preserved in sediments. However, due to the lack of independent age constraints, the reliability of 187Os/188Os ages of pelagic clay have never been tested. Here we report inconsistency between magnetostratigraphic and 187Os/188Os ages in pelagic clay around Minamitorishima Island. In a ~ 5 m thick interval, previous studies correlated 187Os/188Os data to a brief (< 2 million years) isotopic excursion in the late Eocene. Paleomagnetic measurements revealed at least 12 polarity zones in the interval, indicating a > 3.3–7.4 million years duration. Quartz and feldspars content showed that while the paleomagnetic chronology gives reasonable eolian flux estimates, the 187Os/188Os chronology leads unrealistically high values. These results suggest that the low 187Os/188Os signal has diffused from an original thin layer to the current ~ 5 m interval, causing an underestimate of the deposition duration. The preservation of the polarity patterns indicates that a mechanical mixing such as bioturbation cannot be the main process for the diffusion, so diagenetic re-distribution of Fe-Mn oxyhydroxides and associated Os may be responsible. The paleomagnetic chronology presented here also demands reconsiderations of the timing, accumulation rate, and origins of the high content of rare-earth elements and yttrium in pelagic clay around Minamitorishima Island.

scholarly journals U-Pb zircon geochronology and depositional age models for the Upper Triassic Chinle Formation (Petrified Forest National Park, Arizona, USA): Implications for Late Triassic paleoecological and paleoenvironmental change

2020 ◽  
Author(s):  
Cornelia Rasmussen ◽  
Roland Mundil ◽  
Randall B. Irmis ◽  
Dominique Geisler ◽  
George E. Gehrels ◽  
...  
Keyword(s):  
National Park ◽  
Accumulation Rate ◽  
Sediment Accumulation ◽  
Upper Triassic ◽  
Sediment Accumulation Rate ◽  
Chinle Formation ◽  
Age Model ◽  
Depositional Age ◽  
Age Constraints ◽  
Petrified Forest

The Upper Triassic Chinle Formation is a critical non-marine archive of low-paleolatitude biotic and environmental change in southwestern North America. The well-studied and highly fossiliferous Chinle strata at Petrified Forest National Park (PFNP), Arizona, preserve a biotic turnover event recorded by vertebrate and palynomorph fossils, which has been alternatively hypothesized to coincide with tectonically driven climate change or with the Manicouagan impact event at ca. 215.5 Ma. Previous outcrop-based geochronologic age constraints are difficult to put in an accurate stratigraphic framework because lateral facies changes and discontinuous outcrops allow for multiple interpretations. A major goal of the Colorado Plateau Coring Project (CPCP) was to retrieve a continuous record in unambiguous superposition designed to remedy this situation. We sampled the 520-m-long core 1A of the CPCP to develop an accurate age model in unquestionable superposition by combining U-Pb zircon ages and magnetostratigraphy. From 13 horizons of volcanic detritus-rich siltstone and sandstone, we screened up to ∼300 zircon crystals per sample using laser ablation−inductively coupled plasma−mass spectrometry and subsequently analyzed up to 19 crystals of the youngest age population using the chemical abrasion−isotope dilution−thermal ionization mass (CA-ID-TIMS) spectrometry method. These data provide new maximum depositional ages for the top of the Moenkopi Formation (ca. 241 Ma), the lower Blue Mesa Member (ca. 222 Ma), and the lower (ca. 218 to 217 Ma) and upper (ca. 213.5 Ma) Sonsela Member. The maximum depositional ages obtained for the upper Chinle Formation fall well within previously proposed age constraints, whereas the maximum depositional ages for the lower Chinle Formation are relatively younger than previously proposed ages from outcrop; however, core to outcrop stratigraphic correlations remain uncertain. By correlating our new ages with the magnetostratigraphy of the core, two feasible age model solutions can be proposed. Model 1 assumes that the youngest, coherent U-Pb age clusters of each sample are representative of the maximum depositional ages and are close to (&lt;1 Ma difference) the true time of deposition throughout the Sonsela Member. This model suggests a significant decrease in average sediment accumulation rate in the mid-Sonsela Member. Hence, the biotic turnover preserved in the mid-Sonsela Member at PFNP is also middle Norian in age, but may, at least partially, be an artifact of a condensed section. Model 2 following the magnetostratigraphic-based age model for the CPCP core 1A suggests instead that the ages from the lower and middle Sonsela Member are inherited populations of zircon crystals that are 1−3 Ma older than the true depositional age of the strata. This results in a model in which no sudden decrease in sediment accumulation rate is necessary and implies that the base of the Sonsela Member is no older than ca. 216 Ma. Independent of these alternatives, both age models agree that none of the preserved Chinle Formation in PFNP is Carnian (&gt;227 Ma) in age, and hence the biotic turnover event cannot be correlated to the Carnian−Norian boundary but is rather a mid-Norian event. Our age models demonstrate the powers, but also the challenges, of integrating detrital CA-ID-TIMS ages with magnetostratigraphic data to properly interpret complex sedimentary sequences.

scholarly journals SEAMUS (v1.0): a Δ<sup>14</sup>C-enabled, single-specimen sediment accumulation simulator

2019 ◽  
Author(s):  
Bryan C. Lougheed
Keyword(s):  
Sediment Core ◽  
Accumulation Rate ◽  
Sediment Accumulation ◽  
Species Abundance ◽  
Depth Interval ◽  
Single Specimen ◽  
14C Dating ◽  
Deep Sea Sediment ◽  
Wide Range ◽  
History Of

Abstract. The systematic bioturbation of single particles (such as foraminifera) within deep-sea sediment archives leads to the apparent smoothing of any temporal signal as record by the downcore, discrete-depth mean signal. This smoothing is the result of the systematic mixing of particles from a wide range of depositional ages into the same discrete depth interval. Previous sediment models that simulate bioturbation have specifically produced an output in the form of a downcore, discrete-depth mean signal. Palaeoceanographers analysing the distribution of single foraminifera specimens from sediment core intervals would be assisted by a model that specifically evaluates the effect of bioturbation upon single specimen populations. Taking advantage of recent increases in computer memory, the single-specimen SEdiment AccuMUlation Simulator (SEAMUS) was created in Matlab, whereby large arrays of single specimens are simulated. This simulation allows researchers to analyse the post-bioturbation age heterogeneity of single specimens contained within discrete-depth sediment core intervals, and how this heterogeneity is influenced by changes in sediment accumulation rate (SAR), bioturbation depth (BD) and species abundance. The simulation also assigns a realistic 14C activity to each specimen, by considering the dynamic Δ14C history of the Earth and temporal changes in reservoir age. This approach allows for the quantification of possible significant artefacts arising when 14C dating multi-specimen samples with heterogeneous 14C activity. Users may also assign additional desired carrier signals to specimens (e.g., stable isotopes, trace elements, temperature, etc.) and consider a second species with an independent abundance. Finally, the model can simulate a virtual palaeoceanographer by randomly picking whole specimens (whereby the user can set the percentage of older, broken specimens) of a prescribed sample size from discrete depths, after which virtual laboratory 14C dating and 14C calibration is carried out within the model.

scholarly journals Influence of optimal conditions of ultrasonic dispersion on the stability of suspensions of finely ground slags

2019 ◽  
Vol 265 ◽  
pp. 01017 ◽  
Author(s):  
Svetlana Samchenko ◽  
Irina Kozlova ◽  
Оlga Zemskova ◽  
Ekaterina Baskakova
Keyword(s):  
Aqueous Dispersion ◽  
Cement Composite ◽  
Cement Stone ◽  
Mechanical Mixing ◽  
Dispersion Parameters ◽  
Ultrasonic Dispersion ◽  
Sedimentation Stability ◽  
Granulated Blast Furnace Slag ◽  
The Stability ◽  
Furnace Slag

The preparation in the jet mill of finely ground slag (FGS) from the waste of metallurgical production granulated blast-furnace slag, the obtaining of slag suspensions, and the behavior of FGS particles in an aqueous dispersion medium are considered in the paper. It was found that FGS particles in the suspension form micelles of two types with negative (micelle 1) and positive (micelle 2) charges of FGS surface. To increase the aggregative and sedimentation stability of FGS particles in suspensions, studies were carried out using ultrasonic dispersion. The results of investigations on the detection of optimal dispersion parameters for slag suspensions are presented. It was found that in the absence of temperature control, the process of coagulation of slag particles is accelerated and aggregative and sedimentation stability of suspensions of FGS is reduced. The slag particles in the suspension form aggregates that lead to a deterioration of the strength characteristics of the cement stone using suspensions of FGS. Optimal parameters of ultrasonic dispersion of slag suspensions are established: the frequency of ultrasonic vibrations is equal to 44 kHz; the dispersion temperature is 25 ± 2 °C; the dispersion time is 15 min. It was found that the application of ultrasonic dispersion to slag suspensions with the observance of dispersion conditions can increase the aggregative and sedimentation stability of FGS suspension by 2-3 times in comparison with the mechanical mixing of suspensions. The strength of samples with suspensions of FGS prepared using UST under the recommended dispersing conditions increased by 19 to 39% in the first day; for 28 days of hardening - by 19 - 36%, which allows using slag suspensions in the production of cement composite materials and concretes based on them.

Global wind-induced change of deep-sea sediment budgets, new ocean production and CO 2 reservoirs ca . 3.3-2.35 Ma BP

1988 ◽  
Vol 318 (1191) ◽  
pp. 487-504 ◽  
Keyword(s):  
Large Scale ◽  
Accumulation Rate ◽  
Sediment Accumulation ◽  
Distribution Patterns ◽  
Trade Wind ◽  
Accumulation Rates ◽  
Deep Sea Sediment ◽  
Late Pliocene ◽  
High Productivity ◽  
Sediment Fraction

The late Pliocene phase of large-scale climatic deterioration about 3.2-2.4 Ma BP is well documented in a number of (benthic) δ 18 O records. To test the global implications of this event, we have mapped the distribution patterns of various sediment variables in the Pacific and Atlantic Oceans during two time slices, 3.4-3.18 and 2.43-2.33 Ma BP. The changes of bulk sedimentation and bulk sediment accumulation rates are largely explained by the variations of CaCO 3 -accumulation rates (and the accumulation rates of the complementary siliciclastic sediment fraction near continents in higher latitudes). During the late Pliocene, the CaCO 3 -accumulation rate increased along the equatorial Pacific and Atlantic and in the northeastern Atlantic, but decreased elsewhere. The accumulation rate of organic carbon (C org ) and net palaeoproductivity also increased below the high-productivity belts along the equator and the eastern continental margins. From these patterns we may conclude that (trade-) wind- induced upwelling zones and upwelling productivity were much enhanced during that time. This change led to an increased transfer of CO 2 from the surface ocean to the ocean deep water and to a reduction of evaporation, which resulted in an aridification of the Saharan desert belt as depicted in the dust sediments off northwest Africa.

Mass accumulation rate and monsoon records from Xifeng, Chinese Loess Plateau, based on a luminescence age model

2016 ◽  
Vol 31 (4) ◽  
pp. 391-405 ◽  
Author(s):  
Thomas Stevens ◽  
Jan-Pieter Buylaert ◽  
Huayu Lu ◽  
Christine Thiel ◽  
Andrew Murray ◽  
...  
Keyword(s):  
Loess Plateau ◽  
Accumulation Rate ◽  
Chinese Loess Plateau ◽  
Chinese Loess ◽  
Mass Accumulation Rate ◽  
Age Model ◽  
Mass Accumulation

A lacustrine record of the early stage of the Miocene Climatic Optimum in Central Europe from the Most Basin, Ohře (Eger) Graben, Czech Republic

2014 ◽  
Vol 151 (6) ◽  
pp. 1013-1033 ◽  
Author(s):  
TOMÁŠ MATYS GRYGAR ◽  
KAREL MACH ◽  
PETR SCHNABL ◽  
PETR PRUNER ◽  
JIŘÍ LAURIN ◽  
...  
Keyword(s):  
Current Knowledge ◽  
Early Stage ◽  
Sedimentary Environment ◽  
Magnetic Polarity ◽  
Early Miocene ◽  
Rift System ◽  
Age Model ◽  
Climatic Optimum ◽  
The Stability ◽  
Lake Deposits

AbstractThis study reports on a ~ 150 m thick macrofossil-barren sequence of siliciclastic sediments from a Burdigalian age (Early Miocene) freshwater lake. The lake was located within an incipient rift system of the Most Basin in the Ohře (Eger) Graben, which was part of the European Cenozoic Rift System, and had an original area of ≈ 1000 km2. Sediments from the HK591 core that cover the entire thickness of the lake deposits and some of the adjacent stratigraphic units were analysed by X-ray fluorescence spectroscopy (a proxy for element composition) and magnetic polarity measurement. The element proxies were subjected to frequency analysis, which provided estimated sedimentation rates, and allowed for sediment dating by magnetostratigraphy and orbital tuning of the age model. Based on the resulting age model and the known biostratigraphy, the lake was present between 17.4 and 16.6 Ma, which includes the onset of the Miocene Climatic Optimum in the latest Early Miocene. The identification of orbital forcing (precession, obliquity and short eccentricity cycles) confirms the stability of the sedimentary environment of the perennial lake in an underfilled basin. The dating allowed the sediment record to be interpreted in the context of the current knowledge of the European climate during that period. The stability of the sedimentary environment confirms that precipitation was relatively stable over the period recorded by the sediments.

scholarly journals The relationship between tectonism and desertification inferred from the provenance and lithofacies changes of the Cenozoic terrestrial sequence of the southwestern Tarim basin

2020 ◽  
Author(s):  
Aki Sakuma ◽  
Ryuji Tada ◽  
Tomohiro Yoshida ◽  
Hitoshi Hasegawa ◽  
Naomi Sugiura ◽  
...  
Keyword(s):  
Tarim Basin ◽  
Global Climate ◽  
Crystallinity Index ◽  
Late Eocene ◽  
Taklimakan Desert ◽  
Tectonic Events ◽  
First Occurrence ◽  
History Of ◽  
Age Model ◽  
Fluvial Sandstone

Abstract The Tarim basin is one of the most arid areas in the world and its major part is occupied by the Taklimakan desert. Although unraveling the history of aridification of Taklimakan desert is important to understand the global climate change during the Cenozoic, the timing and the mechanism of its formation are still controversial. One of the hypotheses is that the uplift of the Pamir locating to the west of the Tarim basin blocked the intrusion of the moist air and induced the aridification in the Tarim basin. In this study, we explored the linkage between the uplift of the Pamir and the desertification in the Tarim basin during the period from the late Eocene to the middle Miocene. Provenance changes of the fluvial deposits along the Aertashi section, which is located in the southwestern edge of the Tarim basin and offers the longest record with the reliable age model, was examined using Electron Spin Resonance (ESR) signal intensity and crystallinity index (CI) of quartz in the sand fraction of fluvial sandstone and the thin section observation to identify the timings of tectonic events in the Pamir from which clastic materials were supplied by rivers. Our results suggest that major provenance changes in the drainage of the river delivering the clasts to the Aertashi section occurred at ca. 26 Ma, 20 Ma, and 15 Ma. These timings are mostly consistent with the timings observed in the previous provenance studies in the Aertashi section and probably reflect tectonic events in the Pamir. On the other hand, the Tarim basin was under the relatively arid condition after ca. 34 Ma based on the first occurrence of sand dune deposit. Hence, our result does not support the hypothesis that the onset of the aridification in the Tarim basin was caused by the uplift of the Pamir and consequent shut down of the moisture supply from the Paratethys Sea although the afterward intensification of tectonic events in the Pamir might be related to the phased uplift.

scholarly journals Stratigraphy and petrophysical characteristics of Lower Paleocene cool-water carbonates, Faxe quarry, Denmark

2021 ◽  
Vol 69 ◽  
pp. 97-121
Author(s):  
Jens Martin Hvid ◽  
Frans van Buchem ◽  
Frank Andreasen ◽  
Emma Sheldon ◽  
Ida Lykke Fabricius
Keyword(s):  
Large Scale ◽  
Accumulation Rate ◽  
Carbonate System ◽  
Cool Water ◽  
Entry Pressure ◽  
Rapid Accumulation ◽  
Basement High ◽  
Capillary Entry Pressure ◽  
Ground Penetrating ◽  
Age Constraints

The Faxe limestone quarry in eastern Denmark exposes Danian (Lower Paleocene) cool-water carbonate deposits. They constitute remnants of an apparent build-up that covers about 12 km2 today. The Danian deposits at Faxe are conspicuous due to their pronounced thickness of coral limestone relative to the regional carbonate system. In the Faxe quarry, scleractinian corals are uniquely exposed in up to 30 m high mounds. The rapid accumulation of scleractinians combined with induration of the mounds may locally have protected the limestone from Quaternary glacial erosion and created a Danian thickness anomaly at Faxe. The position of Faxe above a local fault-bounded basement high and the extent of coral limestone has been better defined by new mapping. A mapped lithostratigraphic surface in the quarry reveals the large-scale organisation of nested bryozoan mounds on three elongated ridges striking NW–SE. The main scleractinian coral mounds are located above this horizon. Data for reservoir characterisation, mainly of the bryozoan mounds, were collected as photographs of the outcrop, petrophysical and petrographical data from cored boreholes, and as ground-penetrating radar sections. Old boreholes and measured sections were used to reconstruct the build-up, and new nannofossil data allow a discussion of stratigraphy and accumulation rate. The petrophysical data show that common mound-building bryozoan packstone has higher permeability and lower capillary entry pressure than chalk, whereas less commonly occurring grain-dominated packstone and grainstone deposits from local higher-energy sites of the mound complex were found to have reduced amounts of coccolith mud, significantly higher permeability and a higher degree of lithification. Based on biostratigraphic age constraints, correlation of flint – limestone couplets and recog-nised hierarchical patterns, we develop a cyclostratigraphy for the middle Danian and suggest that cyclicity in lithology and petrophysical characteristics of bryozoan limestone are controlled by precession and eccentricity of the orbit of the Earth.

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