A novel high-resolution laser-melting sampler for discrete analyses of ion concentrations and stable water isotopic compositions in firn and ice cores

2021 ◽  
Author(s):  
Yuko Motizuki ◽  
Yoichi Nakai ◽  
Kazuya Takahashi ◽  
Junya Hirose ◽  
Yu Vin Sahoo ◽  
...  
Keyword(s):  
Ice Core ◽  
Ice Cores ◽  
Depth Resolution ◽  
Climatic Changes ◽  
Accumulation Rates ◽  
Laser Melting ◽  
Ion Concentrations ◽  
Annual Layer ◽  
Annual Resolution ◽  
High Depth

<p>Ice cores preserve past climatic changes and, in some cases, astronomical signals. Here we present a newly developed automated ice-core sampler that employs laser melting. A hole in an ice core approximately 3 mm in diameter is melted and heated well below the boiling point by laser irradiation, and the meltwater is simultaneously siphoned by a 2 mm diameter movable evacuation nozzle that also holds the laser fiber. The advantage of sampling by laser melting is that molecular ion concentrations and stable water isotope compositions in ice cores can be measured at high depth resolution, which is advantageous for ice cores with low accumulation rates. This device takes highly discrete samples from ice cores, attaining depth resolution as small as ~3 mm with negligible cross contamination; the resolution can also be set at longer lengths suitable for validating longer-term profiles of various ionic and water isotopic constituents in ice cores. This technique allows the detailed reconstruction of past climatic changes at annual resolution and the investigation of transient ionic and isotopic signals within single annual layers in low-accumulation cores, potentially by annual layer counting.</p>

scholarly journals Annual-layer determinations and 167 year records of past climate of H72 ice core in east Dronning Maud Land, Antarctica

2002 ◽  
Vol 35 ◽  
pp. 471-479 ◽  
Author(s):  
Fumihiko Nishio ◽  
Teruo Furukawa ◽  
Gen Hashida ◽  
Makoto Igarashi ◽  
Takao Kameda ◽  
...  
Keyword(s):  
Mass Balance ◽  
Ice Core ◽  
Ice Cores ◽  
Surface Mass Balance ◽  
Tritium Content ◽  
Surface Mass ◽  
Annual Layer ◽  
Dronning Maud Land ◽  
Annual Resolution ◽  
Continuous Accumulation

AbstractTo determine annual layers for reconstructing the past environment at annual resolution from ice cores, we employed snow-stake data back to 1972, tritium content, solid electrical conductivity measurements (ECM) and stratigraphic properties for the 73m ice core at the H72 site, east Dronning Maud Land, Antarctica. the average annual surface mass balance at H72 is 307 mma–1w.e. during the last 27 years from continuous accumulation data, 317 mma–1 w.e. according to the densification model and 311 mma–1 w.e. according to the average surface mass balance for 167 years based on annual-layer counting. the ECM age is closely coincident with tritium age, and corresponds with the snow-stake record back to AD 1972 from the surface to 15 m depth. the H72 ice core is dated as AD 1831by ECMat 73.16 mdepth.The time series of yearly surface mass balance at H72 shows an almost constant 311 mm a–1 w.e. for the last 167 years. the oxygen-isotope records indicate a significant trend to lower values, with negative gradient of 1.7% (100 years)–1.

scholarly journals Ice core evidence for a recent increase in snow accumulation in coastal Dronning Maud Land, East Antarctica

2016 ◽  
Author(s):  
Morgane Philippe ◽  
Jean-Louis Tison ◽  
Karen Fjøsne ◽  
Bryn Hubbard ◽  
Helle A. Kjær ◽  
...  
Keyword(s):  
Ice Core ◽  
Ice Cores ◽  
Mean Value ◽  
Snow Accumulation ◽  
East Antarctica ◽  
Steady Increase ◽  
Accumulation Rates ◽  
Annual Layer ◽  
Dronning Maud Land ◽  
Δ18o And Δd

Abstract. Ice cores provide temporal records of snow accumulation, a crucial component of Antarctic mass balance. Coastal areas are particularly under-represented in such records, despite their relatively high and sensitive accumulation rates. Here we present records from a 120 m ice core drilled on Derwael Ice Rise, coastal Dronning Maud Land (DML), East Antarctica in 2012. We date the ice core bottom back to 1745 ± 2 AD. δ18O and δD stratigraphy is supplemented by discontinuous major ion profiles, and verified independently by electrical conductivity measurements (ECM) to detect volcanic horizons. The resulting annual layer history is combined with the core density profile to calculate accumulation history, corrected for the influence of ice deformation. The mean long-term accumulation is 0.425 ± 0.035 m water equivalent (w.e.) a−1 (average corrected value). Reconstructed annual accumulation rates show an increase from 1955 onward to a mean value of 0.61 ± 0.02 m w.e. a−1 between 1955 and 2012. This trend is compared to other reported accumulation data in Antarctica, generally showing a high spatial variability. Output of the fully coupled Community Earth System Model demonstrates that sea ice and atmospheric patterns largely explain the accumulation variability. This is the first and longest record from a coastal ice core in East Antarctica showing a steady increase during the 20th and 21st centuries, thereby supporting modelling predictions.

scholarly journals Constituent elements of insoluble and non-volatile particles during the Last Glacial Maximum exhibited in the Dome Fuji (Antarctica) ice core

2009 ◽  
Vol 55 (191) ◽  
pp. 552-562 ◽  
Author(s):  
Yoshinori Iizuka ◽  
Takayuki Miyake ◽  
Motohiro Hirabayashi ◽  
Toshitaka Suzuki ◽  
Sumito Matoba ◽  
...  
Keyword(s):  
Last Glacial Maximum ◽  
Calcium Ion ◽  
Ice Core ◽  
Ice Cores ◽  
Glacial Maximum ◽  
Ion Concentrations ◽  
Last Glacial ◽  
Insoluble Particles ◽  
Almost All ◽  
Constituent Elements

AbstractIn order to find environmental signals based on the dust and calcium-ion concentrations in ice cores, we determine the constituent elements of residue particles obtained after melting ice samples. We have designed a sublimating system that operates at −45°C, below the eutectic temperatures of major salts. This system permits us to obtain a great many non-volatile particles. After studying the non-volatile particles, we immersed them in water to remove soluble particles and compounds. We thereby analyzed a total of 1272 residue particles (from the melted sample), 2418 non-volatile particles (after sublimation) and 1463 insoluble particles taken from five sections of Last Glacial Maximum ice from the Dome Fuji (Antarctica) ice core. Their constituent elements were determined by scanning electron microscopy/energy-dispersive X-ray spectrometry (SEM-EDS) and compared to the dust, calcium-ion and sodium-ion concentrations measured by ion chromatography. Our results indicate that >99.9% of the insoluble particles contain silicon but no sulfur, nitrogen or chlorine. A significant number of the non-volatile particles, however, contain sulfur and chlorine. We conclude that insoluble dust consists mostly of silicate, that almost all calcium ions originate from calcium sulfate and that almost all sodium ions originate from sodium sulfate and sodium chloride.

Reconstructing Antarctic snow accumulation using nitrogen isotopes of nitrate

2021 ◽  
Author(s):  
Pete D. Akers ◽  
Joël Savarino ◽  
Nicolas Caillon ◽  
Mark Curran ◽  
Tas Van Ommen
Keyword(s):  
Nitrogen Isotopes ◽  
Full Range ◽  
Ice Core ◽  
Ice Cores ◽  
Snow Accumulation ◽  
East Antarctica ◽  
Accumulation Rates ◽  
Sea Levels ◽  
Antarctic Snow ◽  
Parallel Reconstruction

<p>Precise Antarctic snow accumulation estimates are needed to understand past and future changes in global sea levels, but standard reconstructions using water isotopes suffer from competing isotopic effects external to accumulation. We present here an alternative accumulation proxy based on the post-depositional photolytic fractionation of nitrogen isotopes (d<sup>15</sup>N) in nitrate. On the high plateau of East Antarctica, sunlight penetrating the uppermost snow layers converts snow-borne nitrate into nitrogen oxide gas that can be lost to the atmosphere. This nitrate loss favors <sup>14</sup>NO<sub>3</sub><sup>-</sup> over <sup>15</sup>NO<sub>3</sub><sup>-</sup>, and thus the d<sup>15</sup>N of nitrate remaining in the snow will steadily increase until the nitrate is eventually buried beneath the reach of light. Because the duration of time until burial is dependent upon the rate of net snow accumulation, sites with lower accumulation rates have a longer burial wait and thus higher d<sup>15</sup>N values. A linear relationship (r<sup>2</sup> = 0.86) between d<sup>15</sup>N and net accumulation<sup>-1</sup> is calculated from over 120 samples representing 105 sites spanning East Antarctica. These sites largely encompass the full range of snow accumulation rates observed in East Antarctica, from 25 kg m-<sup>2</sup> yr<sup>-1</sup> at deep interior sites to >400 kg m-<sup>2</sup> yr<sup>-1</sup> at near coastal sites. We apply this relationship as a transfer function to an Aurora Basin ice core to produce a 700-year record of accumulation changes. Our nitrate-based estimate compares very well with a parallel reconstruction for Aurora Basin that uses volcanic horizons and ice-penetrating radar. Continued improvements to our database may enable precise independent estimates of millennial-scale accumulation changes using deep ice cores such as EPICA Dome C and Beyond EPICA-Oldest Ice.</p>

scholarly journals A 60 000 year Greenland stratigraphic ice core chronology

2008 ◽  
Vol 4 (1) ◽  
pp. 47-57 ◽  
Author(s):  
A. Svensson ◽  
K. K. Andersen ◽  
M. Bigler ◽  
H. B. Clausen ◽  
D. Dahl-Jensen ◽  
...  
Keyword(s):  
North Atlantic ◽  
Time Scale ◽  
Ice Core ◽  
Ice Cores ◽  
The North ◽  
Annual Layer ◽  
Zone Ii ◽  
Absolute Age ◽  
Age Estimates ◽  
New Time

Abstract. The Greenland Ice Core Chronology 2005 (GICC05) is a time scale based on annual layer counting of high-resolution records from Greenland ice cores. Whereas the Holocene part of the time scale is based on various records from the DYE-3, the GRIP, and the NorthGRIP ice cores, the glacial part is solely based on NorthGRIP records. Here we present an 18 ka extension of the time scale such that GICC05 continuously covers the past 60 ka. The new section of the time scale places the onset of Greenland Interstadial 12 (GI-12) at 46.9±1.0 ka b2k (before year AD 2000), the North Atlantic Ash Zone II layer in GI-15 at 55.4±1.2 ka b2k, and the onset of GI-17 at 59.4±1.3 ka b2k. The error estimates are derived from the accumulated number of uncertain annual layers. In the 40–60 ka interval, the new time scale has a discrepancy with the Meese-Sowers GISP2 time scale of up to 2.4 ka. Assuming that the Greenland climatic events are synchronous with those seen in the Chinese Hulu Cave speleothem record, GICC05 compares well to the time scale of that record with absolute age differences of less than 800 years throughout the 60 ka period. The new time scale is generally in close agreement with other independently dated records and reference horizons, such as the Laschamp geomagnetic excursion, the French Villars Cave and the Austrian Kleegruben Cave speleothem records, suggesting high accuracy of both event durations and absolute age estimates.

scholarly journals Crystal growth of air hydrates over 720 ka in Dome Fuji (Antarctica) ice cores: microscopic observations of morphological changes below 2000 m depth

2011 ◽  
Vol 57 (206) ◽  
pp. 1017-1026 ◽  
Author(s):  
Tsutomu Uchida ◽  
Atsushi Miyamoto ◽  
Atsushi Shin’yama ◽  
Takeo Hondoh
Keyword(s):  
Crystal Growth ◽  
Morphological Changes ◽  
Ice Core ◽  
Ice Sheets ◽  
Ice Sheet ◽  
Ice Cores ◽  
Climatic Changes ◽  
Size Distributions ◽  
Number Density ◽  
Average Size

AbstractAir-hydrate crystals store most of the ancient air contained in deep ice sheets. We carried out microscopic observations of air-hydrate crystals below 2000 m depth within the ice core from Dome Fuji, Antarctica, to obtain their number and size distributions. We found that the number density continuously decreased with depth, whereas the average size increased, in contrast to findings from shallower depths. In addition, the characteristic perturbations in both number density and average size distribution with climatic changes almost disappeared, although they are clearly observed in shallow cores. These results indicate that the air-hydrate crystals grow considerably in deeper parts of the ice sheet, and this growth is accompanied by the diffusion of air molecules in the ice. The permeation coefficient of the air molecules in the ice sheet was estimated from the geometric parameters of the air-hydrate distributions. This is the first practical evidence comparable to the previous model estimations. It allows us to evaluate the impacts of the air-molecule migration in the ice sheet on the paleoclimatic information recorded in the deep ice cores.

Dating of ice cores from temperate glaciers - Significant mass loss in the accumulation area of the Adamello glacier indicated by the chronology of a 46 m ice core

2021 ◽  
Author(s):  
Theo Jenk ◽  
Daniela Festi ◽  
Margit Schwikowski ◽  
Valter Maggi ◽  
Klaus Oeggl
Keyword(s):  
Mass Loss ◽  
Ice Core ◽  
Ice Cores ◽  
Italian Alps ◽  
Accumulation Zone ◽  
The Core ◽  
Annual Layer ◽  
Significant Mass Loss ◽  
Carbon Concentrations ◽  
Significant Mass

<p>Dating glaciers is an arduous yet essential task in ice core studies, which becomes even more challenging for the dating of glaciers suffering from mass loss in the accumulation zone as result of climate warming. In this context, we present the dating of a 46 m deep ice core from the Central Italian Alps retrieved in 2016 from the Adamello glacier (Pian di Neve, 3100 m a.s.l.). We will show how the timescale for the core could be obtained by integrating results from the analyses of the radionuclides <sup>210</sup>Pb and <sup>137</sup>Cs with annual layer counting derived from pollen and refractory black carbon concentrations. Our results clearly indicate that the surface of the glacier is older than the drilling date of 2016 by about 20 years and that the 46 m ice core reaches back to around 1944. Despite the severe mass loss affecting this glacier even in the accumulation zone, we show that it is possible to obtain a reliable timescale for such a temperate glacier. These results are very encouraging and open new perspectives on the potential of such glaciers as informative palaeoarchives. We thus consider it important to present our dating approach to a broader audience.</p>

scholarly journals Temperature and mineral dust variability recorded in two low-accumulation Alpine ice cores over the last millennium

2018 ◽  
Vol 14 (1) ◽  
pp. 21-37 ◽  
Author(s):  
Pascal Bohleber ◽  
Tobias Erhardt ◽  
Nicole Spaulding ◽  
Helene Hoffmann ◽  
Hubertus Fischer ◽  
...  
Keyword(s):  
Time Series ◽  
Mineral Dust ◽  
Ice Core ◽  
Ice Cores ◽  
Temperature Reconstruction ◽  
Relative Increase ◽  
Ice Age ◽  
European Alps ◽  
Stable Water Isotopes ◽  
Annual Layer

Abstract. Among ice core drilling sites in the European Alps, Colle Gnifetti (CG) is the only non-temperate glacier to offer climate records dating back at least 1000 years. This unique long-term archive is the result of an exceptionally low net accumulation driven by wind erosion and rapid annual layer thinning. However, the full exploitation of the CG time series has been hampered by considerable dating uncertainties and the seasonal summer bias in snow preservation. Using a new core drilled in 2013 we extend annual layer counting, for the first time at CG, over the last 1000 years and add additional constraints to the resulting age scale from radiocarbon dating. Based on this improved age scale, and using a multi-core approach with a neighbouring ice core, we explore the time series of stable water isotopes and the mineral dust proxies Ca2+ and insoluble particles. Also in our latest ice core we face the already known limitation to the quantitative use of the stable isotope variability based on a high and potentially non-stationary isotope/temperature sensitivity at CG. Decadal trends in Ca2+ reveal substantial agreement with instrumental temperature and are explored here as a potential site-specific supplement to the isotope-based temperature reconstruction. The observed coupling between temperature and Ca2+ trends likely results from snow preservation effects and the advection of dust-rich air masses coinciding with warm temperatures. We find that if calibrated against instrumental data, the Ca2+-based temperature reconstruction is in robust agreement with the latest proxy-based summer temperature reconstruction, including a “Little Ice Age” cold period as well as a medieval climate anomaly. Part of the medieval climate period around AD 1100–1200 clearly stands out through an increased occurrence of dust events, potentially resulting from a relative increase in meridional flow and/or dry conditions over the Mediterranean.

scholarly journals 1000 year ice-core records from Berkner Island, Antarctica

2002 ◽  
Vol 35 ◽  
pp. 45-51 ◽  
Author(s):  
Robert Mulvaney ◽  
Hans Oerter ◽  
David A. Peel ◽  
Wolfgang Graf ◽  
Carol Arrowsmith ◽  
...  
Keyword(s):  
Decadal Variability ◽  
Ice Core ◽  
Ice Cores ◽  
Aerosol Deposition ◽  
Climate History ◽  
Joint Project ◽  
The Past ◽  
Annual Layer ◽  
History Of ◽  
Field Season

AbstractTwo medium-depth ice cores were retrieved from Berkner Island by a joint project between the Alfred-Wegener-Institut and the British Antarctic Survey in the 1994/95 field season. A 151m deep core from the northern dome (Reinwarthhöhe) of Berkner Island spans 700 years, while a 181 m deep core from the southern dome (Thyssenhöhe) spans approximately 1200 years. Both cores display clear seasonal cycles in electrical conductivity measurements, allowing dating by annual-layer counting and the calculation of accumulation profiles. Stable-isotope measurements (both δ18O and δD), together with the accumulation data, allow us to estimate changes in climate for most of the past millennium: the data show multi-decadal variability around a generally stable long-termmean. In addition, a full suite of major chemistry measurements is available to define the history of aerosol deposition at these sites: again, there is little evidence that the chemistry of the sites has changed over the past six centuries. Finally, we suggest that the southern dome, with an ice thickness of 950 m, is an ideal site from which to gain a climate history of the late stages of the last glacial and the deglaciation for comparison with the records from the deep Antarctic ice cores, and with other intermediate-depth cores such as Taylor Dome and Siple Dome.

A multiproxy approach to identify the Tambora volcanic fallout in 1810s from the Styx glacier in Victoria Land, Antarctica

2020 ◽  
Author(s):  
Changhee Han ◽  
Songyi Kim ◽  
Yeongcheol Han ◽  
Jangil Moon ◽  
Sang-Bum Hong ◽  
...  
Keyword(s):  
Inner Core ◽  
Major Ions ◽  
Ice Core ◽  
Ice Cores ◽  
Isotope Ratios ◽  
Depth Interval ◽  
Additional Time ◽  
Aerosol Composition ◽  
Annual Layer ◽  
Victoria Land

<p>Ice cores provide records of past aerosol composition and have been used to reconstruct the relative contribution of different emission sources changing in time. A precise age scale is essential to achieve this goal, for which annual layer counting of seasonal cycles in water stable isotope ratios (δ<sup>18</sup>O and δD) and major ion concentrations have been basically utilized. Introducing additional time markers are helpful for reducing the uncertainty of the depth-age scale, and the fallout of volcanic products has offered useful time markers when they are well-dated. Here, we report lead isotope ratios (<sup>206</sup>Pb/<sup>207</sup>Pb and <sup>208</sup>Pb/<sup>207</sup>Pb) and concentrations of thallium (Tl) and major ions in a shallow ice core from the Styx Glacier (73°51 S, 163°41 E) in the Victoria Land, Antarctica, analyzed for discriminating volcanic products of the 1815 AD Tambora eruption, Indonesia from local volcanic inputs. Mechanically decontaminated 19 inner core pieces between the depth interval 40.8 – 42.4 m were analyzed. The results show that the increases of volcanic SO<sub>4</sub><sup>2-</sup> input are accompanied by either (1) input of more-radiogenic lead (higher <sup>206</sup>Pb/<sup>207</sup>Pb) and Tl or (2) relatively <sup>208</sup>Pb enriched lead. These results suggest that the Tambora volcanic input is overprinted by local volcanic aerosol input and that the isotope-based assessment of the Pb sources can help to discriminate between remote and local components of the volcanic input signals recorded in Victoria Land glaciers.</p>

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