scholarly journals Comment on: "Recent revisions of phosphate rock reserves and resources: a critique" by Edixhoven et al. (2014) – clarifying comments and thoughts on key conceptions, conclusions and interpretation to allow for sustainable action

2016 ◽  
Vol 7 (1) ◽  
pp. 103-117 ◽  
Author(s):  
R. W. Scholz ◽  
F.-W. Wellmer

Abstract. Several recent papers deal with concerns about the longevity of the supply of the mineral phosphorus. The paper by Edixhoven et al. (2014), for instance, expresses doubts about whether the upward estimate of reserves by the IFDC (2006, 2010) and the USGS (2010) provides an accurate, reliable, and comparable picture, as it is based on reports that do not clearly differentiate between phosphate ore and phosphate products (i.e., marketable phosphate rock concentrate). Further, the indistinct use of the terms reserves and resources is criticized. Edixhoven et al. (2014) call for a differentiated inventory of world phosphate reserves including "guidelines which determine the appropriate drill hole distances and a detailed granularity". The claim that "humanity is on the safe side" with respect to future phosphate supply is doubted, as the validity of the IFDC's upgrading of the Moroccan data to 50 Gt phosphate is questioned. The main achievement of Edixhoven et al. (2014) is to elaborate that in the literature frequently used data on phosphate rock ore and phosphate concentrate are not properly distinguished, resulting in incorrect summary figures. In addition, it is commendable to raise the question how transparency concerning reserve and resources data and information on the geopotential of phosphate can be achieved because phosphorus is a special element. As fertilizer, it cannot be substituted and there are no unlimited resources as for the other main nutrients potassium in sea water and nitrogen in the air. However, the paper by Edixhoven et al. (2014) contains in the opinion of the authors some incorrect statements. Our comment elaborates first that several statements, such as that the upgrading of the Moroccan data is "solely based" on one scientific paper, are incorrect. Secondly, the paper comments on and illuminates a set of, in our opinion, misleading statements. These include the fact that the dynamic nature of reserves (which depend on price, technology, innovation for exploiting low-grade deposits, etc.) is acknowledged, but the right conclusions are not drawn, including the mixing of finiteness and staticness, and the way in which the critique of the USGS upgrading of the Moroccan reserves has been linked to Peak P. In particular, we clarify that reserves are primarily company data that serve mining companies for their strategic planning and may, by no means, be used as proxy data for providing global Peak P estimates. Likewise, we elaborate that drilling plans for assessing reserves have to be adjusted to site characteristics, in particular, in the case of four plateaus in Morocco and the Western Sahara comprising an area greater than 10 000 km2. We reconstruct the IFDC and USGS estimates and conclude that there is no evidence for considering the somewhat surprising increase to 50 Gt phosphate concentrate to be an unreasonable estimate for Moroccan reserves. However, the partial mixing of different units (e.g., phosphate ore and phosphate concentrate or marketable product) in the USGS data may be avoided by improving the database and using proper conversion factors. When applying these factors and assessing all reserves of marketable Gt of phosphate rock (PR-M), which is a common scale for measuring annual consumption, the magnitude of the 2014 USGS estimates of 67 Gt PR reserves does not change essentially but decreases from 64 (IFDC assessment) to 57.5 Gt PR-M (a worst-case calculation). We agree that a better harmonization of the (national) classification systems is meaningful. The discussion includes several ideas and thoughts that go beyond the paper by Edixhoven et al. (2014). We suggest that the discrepancies in the resource estimates are often caused by missing system understandings, different conceptions of sciences, and diverging world views. Finally, we suggest the establishment of a solidly funded, international standing committee that regularly analyzes global geopotential for assuring long-term supply security.

2015 ◽  
Vol 6 (1) ◽  
pp. 31-80 ◽  
Author(s):  
R. W. Scholz ◽  
F.-W. Wellmer

Abstract. Several recent papers predict a scarcity of phosphate reserves in the near future. The paper by Edixhoven et al. (2014), for instance, expresses the doubts about whether the upward estimate of reserves by the IFDC (2010) and the USGS (2010) provide an accurate, reliable, and comparable picture, as they are based on reports that do not clearly differentiate between phosphate ore and phosphate products (i.e., marketable phosphate rock concentrate). Further the indistinct use of the terms reserves and resources is criticized. Edixhoven et al. ask for a differentiated inventory of world phosphate reserves including "guidelines which determine the appropriate drill hole distances." The claim that humanity is on the safe side with respect to future phosphate is supply is doubted as the validity of the IFDC's upgrading of the Moroccan data to 50 Gt phosphate is questioned. The present paper identifies and discusses basic conceptual errors of the paper by Edixhoven et al. and related papers that predict a short or mid-term phosphorus scarcity. These include the non-acknowledgment of the dynamic nature of reserves (which depends on price, technology, and innovation for exploiting low-grade deposits, etc.), the mixing of finiteness and staticness of the ultimate recoverable resources (i.e., phosphorus that may be mined economically in the long-term future), the improper use of the Hubbert analysis (which, e.g., simply uses the USGS estimates of reserves as a substitute of an estimate of ultimate recoverable resources) and the geostatistical naive/unprofessional demand for fixed drilling plans to assess reserves. We reconstruct the IFDC and USGS estimates and conclude that there is no evidence for considering the 50 Gt phosphate concentrate as an unreasonable estimate for Moroccan reserves. However, the partial mixing of different units (e.g., phosphate ore and phosphate concentrate or marketable product) in the USGS data may be avoided by improving the data base and using proper conversion factors. When applying these factors and assess all reserves in marketable Gt of phosphate rock (PR-M), which is a common scale for measuring annual consumption, the magnitude of the USGS estimates 2014 of 67 Gt PR reserves does not change essentially yet decrease to 64 (IFDC assessment) to 58.3 Gt PR-M (worst case calculation). We argue that, a better harmonization of the (national) classification systems is meaningful. The discussion suggests that the discrepant estimates of resource estimates that can be found in literature are due to different system understandings, different conceptions of sciences, and diverging worldviews. Finally, we discuss in what way an independent and scientifically sound assessment of the phosphate resources can be realized in the long-term. We suggest the establishment of a solidly funded, international standing committee that regularly analyzes global geopotential as the source of future resources and reserves. Such a committee may be hosted by international science associations of geoscientists, given that a comparative assessment with other environmental threats reveals that investments in this field are proportional and meaningful.


Minerals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 253 ◽  
Author(s):  
Ruan ◽  
He ◽  
Chi

Phosphate ore is an important raw material for manufacturing fertilizers and phosphorous chemical products. While most of the phosphate resources cannot be directly treated as feed stock due to the low grade of P2O5 and high content of impurities. In order to obtain a qualified phosphate concentrate, the beneficiation of the low-grade phosphate ore is, hence, of great necessity. Many beneficiation techniques can be employed to upgrade the P2O5 grade of phosphate ores based on their characteristics in chemical composition and texture. The flotation process is most widely applied to balance the P2O5 recovery ratio and cost. In this review, the dominant techniques for the beneficiation of phosphate ores are introduced. Moreover, the factors that affect the flotation of phosphate ore, including the properties of mineralogy, flotation reagents (depressants and collectors) and flotation medium, were systematically analyzed.


2013 ◽  
Vol 699 ◽  
pp. 11-16
Author(s):  
Hua Jun Wang ◽  
Ai Fei Yi ◽  
Hui Mei Yu

Mixed fatty acids collector (JZQ - F7) prepared with catering waste oil applying for recovery of low grade phosphate rock is studied. Research shows that the environmentally friendly collector JZQ - F7 has high selectivity for phosphate ore with good solubility in water. The reagent could upgrade the ore P2O5 content from 2.57% of the run-of-mine to 32.25% of that after a rough and two clean flotation processes with Na2CO3 dosage of 2.1 kg/t, Na2SiO3.9H2O dosage of 2.7 kg/t, JZQ - F7 dosage of 0.7 kg/t. The mesh of grind is 30% minus 200 mesh, and plus 40 mesh (0.45 mm) sizing product is discarded.


Author(s):  
Muhammad Arif Bhatti ◽  
Abdul Ahad ◽  
Kamran Raza Kazmi ◽  
Uzma Zafar ◽  
Athar Amin ◽  
...  

A low-grade siliceous sedimentary phosphate rock assaying 22.05% P205 was upgraded by double float (direct and reverse) technology. The rock contains collophane (carbonate fluorapatite) as the valuable phosphate mineral along with siliceous, carbonaceous and clay minerals. A process was developed which yielded a high-grade phosphate concentrate with improved recovery rate. The developed process consists of three parts. The first part includes wet grinding of ore to liberation point followed by separation of fines (slimes) by cone classifier. The finely ground deslimed ore was floated by direct anionic flotation using oleic acid collector to get rougher phosphate concentrate. It was cleaned once using additional quantity of reagents. In the second part, the fines generated during grinding operation were floated by column flotation to recover phosphate values. The cleaned concentrate and column concentrate were mixed together and washed thoroughly with hot water to remove the attached reagents. The final part comprises of cationic flotation of combined phosphate concentrate with fatty amine collector to float away quartz and silicates and to leave behind phosphate values. The grade of final phosphate concentrate was found to be 32.85% P205 with an overall recovery of 88.14%. The concentrate obtained meets the specifications of fertilizer and acid grade.    


Author(s):  
Guangya Zheng ◽  
Jupei Xia ◽  
Zhengjie Chen

: China primarily contains medium and low-grade phosphorus ores that are used to produce phosphoric acid. Here, we provide an overview of phosphoric acid production processes, including wet, thermal, and kiln methods, as well as the fundamental principles, major equipment, and technological aspects of each process. Progress in the kiln method using lowgrade phosphate rock is described, which involves the KPA and CDK processes. The literature shows that the addition of admixtures adds great competitiveness to kiln phosphate production methods and has considerable development prospects.


2021 ◽  
Vol 10 (1) ◽  
pp. 157-168
Author(s):  
Biwei Luo ◽  
Pengfei Li ◽  
Yan Li ◽  
Jun Ji ◽  
Dongsheng He ◽  
...  

Abstract The feasibility of industrial waste fly ash as an alternative fluxing agent for silica in carbothermal reduction of medium-low-grade phosphate ore was studied in this paper. With a series of single-factor experiments, the reduction rate of phosphate rock under different reaction temperature, reaction time, particle size, carbon excess coefficient, and silicon–calcium molar ratio was investigated with silica and fly ash as fluxing agents. Higher reduction rates were obtained with fly ash fluxing instead of silica. The optimal conditions were derived as: reaction temperature 1,300°C, reaction time 75 min, particle size 48–75 µm, carbon excess coefficient 1.2, and silicon–calcium molar ratio 1.2. The optimized process condition was verified with other two different phosphate rocks and it was proved universally. The apparent kinetics analyses demonstrated that the activation energy of fly ash fluxing is reduced by 31.57 kJ/mol as compared with that of silica. The mechanism of better fluxing effect by fly ash may be ascribed to the fact that the products formed within fly ash increase the amount of liquid phase in the reaction system and promote reduction reaction. Preliminary feasibility about the recycling of industrial waste fly ash in thermal phosphoric acid industry was elucidated in the paper.


Machines ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 124
Author(s):  
Dantam Rao ◽  
Madhan Bagianathan

Currently, permanent-magnet-type traction motors drive most electric vehicles. However, the potential demagnetization of magnets in these motors limits the performance of an electric vehicle. It is well known that during severe duty, the magnets are demagnetized if they operate beyond a ‘knee point’ in the B(H) curve. We show herein that the classic knee point definition can degrade a magnet by up to 4 grades. To prevent consequent excessive loss in performance, this paper defines the knee point k as the point of intersection of the B(H) curve and a parallel line that limits the reduction in its residual flux density to 1%. We show that operating above such a knee point will not be demagnetizing the magnets. It will also prevent a magnet from degenerating to a lower grade. The flux density at such a knee point, termed demag flux density, characterizes the onset of demagnetization. It rightly reflects the value of a magnet, so can be used as a basis to price the magnets. Including such knee points in the purchase specifications also helps avoid the penalty of getting the performance of a low-grade magnet out of a high-grade magnet. It also facilitates an accurate demagnetization analysis of traction motors in the worst-case conditions.


1993 ◽  
Vol 34 (3) ◽  
pp. 217-222 ◽  
Author(s):  
H. �. �zbelge ◽  
T. F. Al-Fariss ◽  
A. M. Abdulrazik
Keyword(s):  

Sexual Health ◽  
2012 ◽  
Vol 9 (6) ◽  
pp. 562 ◽  
Author(s):  
Jennifer Margaret Roberts ◽  
Deborah Ekman

Our understanding of the human papillomavirus (HPV) related cytomorphology and histopathology of the anal canal is underpinned by our knowledge of HPV infection in the cervix. In this review, we utilise cervical reporting of cytological and histological specimens as a foundation for the development of standardised and evidence-based terminology and criteria for reporting of anal specimens. We advocate use of the Australian Modified Bethesda System 2004 for reporting anal cytology. We propose the use of a two-tiered histological reporting system for noninvasive disease – low-grade and high-grade anal intraepithelial neoplasia. These classification systems reflect current understanding of the biology of HPV and enhance diagnostic reproducibility. Biomarkers such as p16INK4A may prove useful in further improving diagnostic accuracy. Standardisation is important because it will increase the value of the data collected as Australian centres develop programs for screening for anal neoplasia.


Author(s):  
Imane Aarab ◽  
Mohammed Derqaoui ◽  
Khalid El Amari ◽  
Abdelrani Yaacoubi ◽  
Abdelmoughit Abidi ◽  
...  
Keyword(s):  

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