scholarly journals Inferences from geochemical characteristics of the upper part of the Middle Pleistocene interglacial deposits in Lithuania

Baltica ◽  
2015 ◽  
Vol 28 (2) ◽  
pp. 89-108 ◽  
Author(s):  
Valentinas Baltrūnas ◽  
Bronislavas Karmaza ◽  
Rimantė Zinkutė ◽  
Valentas Katinas ◽  
Stasys Paškauskas ◽  
...  

The study presents geochemical characteristics of deposits from the reference sections of the Middle Pleistocene interglacials: 2 from the Butėnai Interglacial and 2 from the problematic Snaigupėlė Interglacial. Geochemical data (the contents of 29 chemical elements, percentages of sediment components) are related to magnetic susceptibility (MS), bedding, lithology and previous palaeobotanical results. Higher content of carbonates and clay in sections of the Snaigupėlė Interglacial can be explained by warmer climate and calmer depositional environment, though the influence of chemical composition of the provenance and underlying tills is also obvious. The influence of oxic-anoxic sedimentary environment fluctuations on MS and on the separation between P-Fe and S-Mn is demonstrated. Many geochemical differences between deposits from the intervals of the Snaigupėlė-705 borehole and the Snaigupėlė outcrop sections which presumably include pollen zone S6 Carpinus-Quercus enable to speculate that these deposits were formed during different interglacials.

2021 ◽  
Vol 40 (5) ◽  
pp. 104-114
Author(s):  
G.A. Chelnokov ◽  
◽  
I.V. Bragin ◽  
N.A. Kharitonova ◽  
◽  
...  

The article presents the results of isotope-chemical research of the Tavatum thermal water deposit (coast of the Sea of Okhotsk, Magadanskaya Oblast), as well as surrounding underground and surface waters. For the first time, data on the content of isotopes of oxygen and hydrogen in the underground and surface waters were obtained, and the analysis of trace elements was performed. The results show that the chloride sodium-calcium mesohalinous thermal waters of the Tavatum deposit are atmogenic; two processes can be considered as the main processes of the chemical composition formation: 1) involvement of deep brines (including cryopeg waters) and 2) cationic exchange in the interaction of sea waters (buried during marine transgressions in the Holocene) with rocks. In the chemical composition of thermal waters, there are indicator chemical elements reflecting the impact of deep high-temperature processes. The temperature of the deep fluid estimated by different geothermometers is 117 to 128°C, and the depth of formation is at least three kilometers.


2011 ◽  
Vol 20 (1) ◽  
Author(s):  
G. Barisevišius ◽  
G. Tautvaišienė ◽  
S. Berdyugina ◽  
Y. Chorniy ◽  
I. Ilyin

AbstractAbundances of 22 chemical elements, including the key elements and isotopes such as


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Rasa Zalakeviciute ◽  
Katiuska Alexandrino ◽  
Yves Rybarczyk ◽  
Alexis Debut ◽  
Karla Vizuete ◽  
...  

Abstract Particulate matter (PM) is one of the key pollutants causing health risks worldwide. While the preoccupation for increased concentrations of these particles mainly depends on their sources and thus chemical composition, some regions are yet not well investigated. In this work the composition of chemical elements of atmospheric PM10 (particles with aerodynamic diameters ≤ 10 µm), collected at the urban and suburban sites in high elevation tropical city, were chemically analysed during the dry and wet seasons of 2017–2018. A large fraction (~ 68%) of PM10 composition in Quito, Ecuador is accounted for by water-soluble ions and 16 elements analysed using UV/VIS spectrophotometer and Inductively Coupled Plasma—Optical Emission Spectroscopy (ICP-OES). Hierarchical clustering analysis was performed to study a correlation between the chemical composition of urban pollution and meteorological parameters. The suburban area displays an increase in PM10 concentrations and natural elemental markers during the dry (increased wind intensity, resuspension of soil dust) season. Meanwhile, densely urbanized area shows increased total PM10 concentrations and anthropogenic elemental markers during the wet season, which may point to the worsened combustion and traffic conditions. This might indicate the prevalence of cardiovascular and respiratory problems in motorized areas of the cities in the developing world.


2010 ◽  
Vol 119 (6) ◽  
pp. 853-860 ◽  
Author(s):  
Ömer Elitok ◽  
Züheyr Kamaci ◽  
M. Nuri Dolmaz ◽  
Kamil Yılmaz ◽  
Meltem Şener

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2949
Author(s):  
Juan I. Burneo ◽  
Ángel Benítez ◽  
James Calva ◽  
Pablo Velastegui ◽  
Vladimir Morocho

Chemical compositions of plants are affected by the initial nutrient contents in the soil and climatic conditions; thus, we analyzed for the first time the effects of soil and leaf nutrients on the compositions of the essential oils (EOs) of Siparuna muricata in four different localities in Ecuador. EOs were obtained by hydrodistillation and analyzed by gas chromatography/mass spectrometry (GC/MS) and a gas chromatography/flame ionization detector (GC/FID). Enantiomeric distribution by GC/MS was determined, modifying the enantiomeric separation of β-pinene, limonene, δ-elemene, β-bourbonene, cis-cadina-1 (6), 4-diene and atractylone. A total of 44 compounds were identified. The most representative for L1 were guaiol, atractylone and 4-diene; for L2, cis-cadina-1(6),4-diene and myrcene; for L3, atractylone, myrcene and germacrene B; and finally, L4 germacrene B, myrcene and cis-cadina-1(6),4-diene. Correlations between soil- leaf chemical elements such as Al, Ca, Fe, Mg, Mn, N and Si in the different localities were significant with chemical composition of the essential oil of Siparuna muricata; however, correlations between soil and leaf K, P, and Na were not significant. Cluster and NMDS analysis showed high dissimilarity values of secondary metabolites between four localities related with changes in soil- leaf nutrients. Thus, the SIMPER routine revealed that not all secondary metabolites contribute equally to establishing the differences in the four localities, and the largest contributions are due to differences in guaiol, cis-cadina-1(6),4-diene, atractylone and germacrene. Our investigation showed for the first time the influences of altitude and soil- leaf chemical elements in the chemical composition of the EOs of S. muricata.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Ilse Valenzuela Matus ◽  
Jorge Lino Alves ◽  
Joaquim Góis ◽  
Augusto Barata da Rocha ◽  
Rui Neto ◽  
...  

Purpose The purpose of this paper is to prove and qualify the influence of textured surface substrates morphology and chemical composition on the growth and propagation of transplanted corals. Use additive manufacturing and silicone moulds for converting three-dimensional samples into limestone mortar with white Portland cement substrates for coral growth. Design/methodology/approach Tiles samples were designed and printed with different geometries and textures inspired by nature marine environment. Commercial coral frag tiles were analysed through scanning electron microscopy (SEM) to identify the main chemical elements. Raw materials and coral species were selected. New base substrates were manufactured and deployed into a closed-circuit aquarium to monitor the coral weekly evolution process and analyse the results obtained. Findings Experimental results provided positive statistical parameters for future implementation tests, concluding that the intensity of textured surface, interfered favourably in the coralline algae biofilm growth. The chemical composition and design of the substrates were determinant factors for successful coral propagation. Recesses and cavities mimic the natural rocks aspect and promoted the presence and interaction of other species that favour the richness of the ecosystem. Originality/value Additive manufacturing provided an innovative method of production for ecology restoration areas, allowing rapid prototyping of substrates with high complexity morphologies, a critical and fundamental attribute to guarantee coral growth and Crustose Coralline Algae. The result of this study showed the feasibility of this approach using three-dimensional printing technologies.


2021 ◽  
Vol 316 ◽  
pp. 521-526
Author(s):  
Vladimir A. Nosenko ◽  
Alexander V. Fetisov ◽  
Semen P. Kuznetsov

The article summarizes the results of the of the titanium alloy surface morphology and chemical composition study after grinding with a wheel of cubic boron nitride on a ceramic bond. The titanium alloy was treated using the method of cut-in grinding in the finishing mode using a synthetic water-soluble lubricant-cooling liquid that does not contain mineral oil. The research was carried out using the FEI Versa 3D LoVac electron microscope. Digital photos of the titanium alloy surface at different magnifications are given. Individual objects’ morphology allows us to identify them as wear products of abrasive tools. The chemical composition of the selected objects was studied by local x-ray spectral analysis. CBN crystals are partially or completely pressed into the treated surface and covered with a layer of the treated material. On the surface of CBN crystals, there are chemical elements that are part of the abrasive tool bond.


2021 ◽  
pp. 51-56
Author(s):  
Yu. B. Sazonov ◽  
D. Yu. Ozherelkov ◽  
R. Sh. Latypov ◽  
E. E. Gorshkov

Possibility of determination of the fragments and articles made of different grades of steel aluminium and copper alloys and their affiliation to the common melt was examined via the methods of photoelectric spectral analysis based on composition of micro-impurities. Chemical elements with micro-impurities were revealed; they allow to determine affiliation of metal fragments to one melt. Ultimately possible deviations of micro-impurities within one melt were obtained. The technique allowing to establish affiliation of fragments to the common melt based on their elementary composition of micro-impurities with minimal amount of measurements was suggested based on the obtained results. The minimal geometric size of a sample available for analysis was determined; it allows to classify the examined fragments to one melt based on the results of investigation of expanded elementary composition of micro-impurities. Practical opportunities of this technique were displayed on the example of the alloys with different chemical composition.


Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 444 ◽  
Author(s):  
Pavlína Hájková

This work describes the role of chemical composition and curing conditions in geopolymer strength, leachability of chemical elements and porosity. The study focuses on geopolymer material prepared from calcined kaolinite claystone, which is not studied frequently as a raw material for geopolymer production, although it has a high application potential as it is easily commercially available and allows preparation of geopolymers with low viscosity. The composition of geopolymers and their curing methods were selected considering their ease of use in the praxis. Therefore, the potassium water glass itself was used as alkali activator without any KOH or NaOH addition. Chemical composition was changed only by the density of water glass in the range of 1.2 to 1.6 g·cm−3. Geopolymers were cured at a temperature within the range of 5 °C–70 °C to speed up the solidification process as well as by microwave radiation. High compressive strengths were obtained for geopolymers with the highest densities of the water glass (1.5 and 1.6 g·cm−3) in dependence on various curing conditions. Higher strengths were achieved in the case of samples where the solidification was not accelerated. The samples cured at lower temperatures (5 °C) showed lower porosity compared to the other curing types. The lowest leachability of Si and alkalis was reached for the samples with water glass density 1.5 g·cm−3.


1969 ◽  
Vol 35 ◽  
pp. 51-54 ◽  
Author(s):  
Christian Knudsen ◽  
Bodil W. Lauridsen

The chemical composition of chalk and marl reflects the mixture of carbonate particles and clastic input deposited on the seabed together with growth of authigenic minerals and diagenesis. The Rørdal quarry in Jylland (Fig. 1) is known for its alternating chalk–marl succession (Surlyk et al. 2010) and the aim of this article is to investigate how this cyclicity is reflected in the geochemical signature of the sequence and test if this has implications for the interpretation of the depositional environment as well as the chemostratigraphy in the chalk.


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