Physical Properties of Two O-Ring Compounds after Exposure to Reactor Radiation
Abstract Two commercial O-ring compounds, NBR and SBR, specially formulated for radiation resistance were irradiated by means of a nuclear reactor to six gamma-dose levels in the range from 4.9×108 to 15×1011ergs/gm(C). O-rings and compression-set buttons of both materials were irradiated in air at near room temperature; O-rings of NBR were also irradiated in oil. Tensile properties, hardness, and compression set were measured as a function of radiation dose. Fifteen O-rings and five compression buttons were used for each experimental condition to provide statistically valid results. Analytical procedures were used to compute molecular weight between crosslinks and network-chain ratio as a function of dose. The wide dose range provided an accurate assessment of degradation produced by radiation. The highest dose resulted in complete loss of useful mechanical properties. Properties most adversely affected at lower doses were ultimate elongation, hardness, and compression set. While compression set was 50% at a dose of 3×109ergs/gm(C), tensile properties of both materials remained relatively good at a gamma dose of 1.2×1010 ergs/gm(C).