Parameter selection of Polystyrene-Dietilenetriaminepenta acetate Resin Synthesis for the separation of rare Earth Elements by using Plackett-Burman Experimental Design

2021 ◽  
pp. 5629-5634
Author(s):  
Herman Herman ◽  
Bohari Yusuf ◽  
Laode Rijai ◽  
Hadi Kuncoro ◽  
Anni Anggraeni ◽  
...  
Keyword(s):  
Reaction Temperature ◽  
Chemical Properties ◽  
Ammonia Concentration ◽  
Yield Ratio ◽  
Scale Production ◽  
Separation And Purification ◽  
Diethylene Triamine ◽  
Stirring Rate ◽  
Volume Reaction ◽  
Selection Of

The development of the separation method has an essential role in developing science and technology for the separation and purification of an element or compound from other mixtures based on differences in physical and chemical properties. This research is more focused on the selection parameters of polystyrene-based resin production using diethylene triamine penta-acetate (DTPA) light, which used as a prototype for improved scale production. The Plackett-Burman design was used to select variables that have significant influence in Methylaminopolystyrene-Diethylenetriaminepentaacetate (MAP-DTPA) resin synthesis. Eleven variables such as mol ratio of Methylamino Polystyrene and diethylene triamine penta-acetate ligands, solvent volume, reaction time, stirring rate, reaction temperature, total volume, reaction pH, incubation time, ammonia concentration, and the addition of methanol were carried out for the selection of parameters or variables in the process of MAP-DTPA resin synthesis through a statistical approach in studies for design experiments using Software Design Expert 9.0.6.2. Of the eleven variables in resin synthesis obtained, six variables have a positive influence on the yield ratio value (percent yield ratio) of MAP-DTPA resin are the mol ratio of MAP and DTPA, Stirring Rate, reaction temperature, total volume, degree of acidity, and ammonia concentration.

An Overview of Optimization of Spherical Crystallisation Process

2013 ◽  
Vol 6 (4) ◽  
pp. 2203-2209
Author(s):  
N B Bhagat ◽  
A V Yadav ◽  
P R Mastud ◽  
R A Khutale
Keyword(s):  
Physical Phenomenon ◽  
Chemical Properties ◽  
Spherical Shape ◽  
Particle Engineering ◽  
Spherical Crystallization ◽  
Stirring Rate ◽  
Physico Chemical ◽  
Rate Selection ◽  
Pharmaceutical Agents ◽  
Spherical Crystals

In this article we describe the optimizing parameters in the process of spherical crystallisation. Particle engineering of active pharmaceutical agents is an innovative area of research in pharmaceutical industry because of several advantages. Spherical crystallization is one of the particle engineering technique in which drug directly gets crystallized and agglomerated into spherical shape. The spherical crystals can be obtained by different methods like solvent change, Quasi-emulsion droplet, ammonia diffusion and neutralisation. The optimization of process of spherical crystallization is important for obtaining the ideal spherical crystal agglomerates. It includes stirring rate, selection of solvent, pH, temperature etc. which affects on the physico-chemical properties of crystals. These optimizing parameters play its specific role in formation of spherical crystals. Stirring rate affects the shape as well as size of the final agglomerates and solvent selection helps in the formation of maximum amount of agglomerates in the system. The factors like pH and temperature should be maintained in case of drugs which show polymorphism. Apart from this, several others physical phenomenon or parameters like interfacial tension and rate of crystallisation are also important for thorough optimization of process.  

scholarly journals Insights in Behavior of Variably Formulated Alginate-Based Microcapsules for Cell Transplantation

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Pia Montanucci ◽  
Silvia Terenzi ◽  
Claudio Santi ◽  
Ilaria Pennoni ◽  
Vittorio Bini ◽  
...  
Keyword(s):  
Divalent Cations ◽  
Chemical Properties ◽  
Live Cells ◽  
High Performing ◽  
Physical Chemical ◽  
Degenerative Disorders ◽  
Selection Of ◽  
Better Than

Alginate-based microencapsulation of live cells may offer the opportunity to treat chronic and degenerative disorders. So far, a thorough assessment of physical-chemical behavior of alginate-based microbeads remains cloudy. A disputed issue is which divalent cation to choose for a high performing alginate gelling process. Having selected, in our system, high mannuronic (M) enriched alginates, we studied different gelling cations and their combinations to determine their eventual influence on physical-chemical properties of the final microcapsules preparation,in vitroandin vivo. We have shown that used of ultrapure alginate allows for high biocompatibility of the formed microcapsules, regardless of gelation agents, while use of different gelling cations is associated with corresponding variable effects on the capsules’ basic architecture, as originally reported in this work. However, only the final application which the capsules are destined to will ultimately guide the selection of the ideal, specific gelling divalent cations, since in principle there are no capsules that are better than others.

Preparation of Ginger Oil in Water Nanoemulsion Using Phase Inversion Composition Technique: Effects of Stirring and Water Addition Rates on their Physico-Chemical Properties and Stability

2019 ◽  
Vol 0 (0) ◽  
Author(s):  
Ashraf Farshbaf-Sadigh ◽  
Hoda Jafarizadeh-Malmiri ◽  
Navideh Anarjan ◽  
Yahya Najian
Keyword(s):  
Particle Size ◽  
Phase Inversion ◽  
Antimicrobial Properties ◽  
Chemical Properties ◽  
Water Addition ◽  
Chromatography Method ◽  
Stirring Rate ◽  
Physico Chemical ◽  
Oil In Water ◽  
Addition Rate

Abstract Ginger oil in water (O/W) nanoemulsions, were produced using phase inversion composition method and Tween 80, as emulsifier. Effects of processing parameters namely, stirring rate (100 to1000 rpm) and water addition rate (1–10 mL/min) were evaluated on the physico-chemical, morphological, antioxidant and antimicrobial properties of the prepared O/W nanoemulsions using response surface methodology (RSM). Results indicated that well dispersed and spherical ginger nanodroplets were formed in the nanoemulsions with minimum particle size (8.80 nm) and polydispersity index (PDI, 0.285) and maximum zeta potential value (−9.15 mV), using stirring rate and water addition rate of 736 rpm and 8.18 mL/min, respectively. Insignificant differences between predicted and experimental values of the response variables, indicated suitability of fitted models using RSM. Mean particle size of the prepared nanoemulsion using optimum conditions were changed from 8.81 ± 1 to 9.80 ± 1 nm, during 4 weeks of storage, which revealed high stability of the resulted ginger O/W nanoemulsion. High antioxidant activity (55.4%), bactericidal (against Streptococcus mutans) and fungicidal (against Aspergillus niger) activities of the prepared nanoemulsion could be related to the presence of gingerols and shogaols, a group of phenolic alkanones, in the ginger oil, which those were detected by gas chromatography method.

scholarly journals Pratiques de production et caracteristiques physiques et chimiques du shô basi, un couscous de niebe (Vigna unguiculata) produit au Mali

2021 ◽  
Vol 21 (02) ◽  
pp. 17509-17528
Author(s):  
A Timitey ◽  
◽  
L Adinsi ◽  
YE Madodé ◽  
F Cissé ◽  
...  
Keyword(s):  
Vigna Unguiculata ◽  
Large Scale ◽  
Chemical Properties ◽  
Quality Criteria ◽  
Scale Production ◽  
Production Flow ◽  
Cowpea Seeds ◽  
Steam Cooking ◽  
End Products ◽  
Cowpea Varieties

In West Africa, cowpea is processed into several end-products among which the most consumed in Mali is a steamed granulated product known as cowpea couscous or Shô basi, in Bambara. Organoleptic properties ofShô basi are variable, probably as a consequence of the diversity of the practices of production. This study aims at determining these practices, their constraints and the physico-chemical characteristics of Shô basi as sold on Malian markets. A survey using focus group discussions, and involving eighteen (18) Shô basi production cooperatives, each gathering 8 to 32 members, was conducted in South Mali. The information collected was related to cowpea varieties used for production, flow diagrams, constraints of production, and quality criteria of the end-products. Eighteen (18) Shô basi samples were collected from the interviewed groups and used for the determination of the physical and chemical properties of Shô basi. Results showed that most of the processors were married, non or moderately literate and aged between 20 and 59 years women. The main cowpea varieties used for the production are sangaraka and wilibali, both from the species Vigna unguiculata. Both varieties of cowpea are characterized by a white or cream color. Shô basi is produced using a single process with two major technological variants. One involves a wet total dehulling (VDT), whereas the second involves a dry partial dehulling (VDP) of cowpea seeds. Regardless of the technological variant and cowpea variety used, interviewees indicated that a good qualityShô basi must have a light color, a soft mouthfeel texture, a homogeneous granule size and lacking beany flavor. Protein(25,0g/100g) and polyphenol (24,3mg/100g)contents as well as swelling level were similar for Shô basi from both variants. However, Shô basi from technology involving partial dehulling (VDP) was less bright, richer in fiber and minerals, and contained more fine granules thanShô basi involving whole dehulling(VDT). Cowpea dehulling, flour granulation, steam cooking and drying are the mean constraints for quality standardization and large-scale production of Shô basi in Mali.

scholarly journals Experimental and statistical study for leaching of niobium pentoxide from Pakistani ore

2018 ◽  
Vol 24 (1) ◽  
pp. 51-58 ◽  
Author(s):  
Muhammad Irfan ◽  
Muhammad Ahmad ◽  
Sadia Akhtar ◽  
Muhammad Khan ◽  
Muhammad Khan
Keyword(s):  
Particle Size ◽  
Reaction Temperature ◽  
Batch Reactor ◽  
Niobium Pentoxide ◽  
Mass Ratio ◽  
Separation And Purification ◽  
Separation Processes ◽  
Separation Science ◽  
Low Concentration ◽  
Environmentally Friendly Process

The growing demand for niobium pentoxide, based on its use in separation processes, established its prominent significance as a leading candidate in the field of separation science and technology. This study reports the extraction of niobium pentoxide from pyrochlore ore occurring in Sillai Patai, KPK, Pakistan. It is difficult to recover niobium pentoxide from Pakistani ore due to its low concentration. Niobium pentoxide is an important material used in manufacturing industries for different purposes. Most of the commercially employed extraction processes are associated with serious environmental impacts and are not efficient in extracting niobium pentoxide from low concentration pyrochlore. Alkali potash has been used for separation and purification of niobium pentoxide because it is efficient and an environmentally friendly process. The leaching of niobium pentoxide is carried out in a batch reactor using alkali potash as a leachant. Various process parameters, including ore particle size, reaction temperature, reaction time and alkali to ore mass ratio, were examined statistically during the leaching process. It was observed that reaction temperature and ore particle size were more significant compared to other parameters. The maximum percent recovery of niobium pentoxide (95%) was obtained at 280?C in 90 min, while keeping the ore particle size 44 ?m and alkali to ore mass ratio of 7:1.

Improving water use of annual crops and pastures—limitations and opportunities in Western Australia

2001 ◽  
Vol 52 (2) ◽  
pp. 171 ◽  
Author(s):  
David Tennant ◽  
David Tennant ◽  
David Hall ◽  
David Hall
Keyword(s):  
Water Use ◽  
Western Australia ◽  
Chemical Properties ◽  
Farming Systems ◽  
Water Infiltration ◽  
Root Penetration ◽  
Depth Limit ◽  
Annual Crops ◽  
Loamy Sand Soil ◽  
Selection Of

As part of a wider analysis of the potential role for lucerne in farming systems being developed for containing the spread of salinisation, we have reviewed information generated in Western Australia on opportunities for improving the water use of annual crops and pastures. Substantial increases in water use have been shown to be possible in a number of situations and rainfall environments. Best gains, of the order of 40–70 mm, were reported on deep sand and loamy sand soil types. These were achieved from selection of deep-rooted and longer growing crop and pasture species, and from amelioration of widespread traffic pans and subsoil acidity, and/or selection of tolerant species. On more widespread gradational and duplex soils, soil physical and chemical properties that restrict water infiltration and/or root penetration to depth limit the potential to increase water use. Increases in production and water use are still possible, depending on the permeability of the lower horizons of these soils and on rainfall distribution. At best, recorded increases on these soils were of the order of 5–15 mm in short season, low rainfall environments, and around 40 mm in long season, high rainfall environments. These increases in water use were not invariable. Increases in water use were not noted in dry years on all soils and in all years on shallow duplex soils with impermeable B horizons. Seasonality impacts on all outcomes and is a key issue on all soils and in all rainfall environments.

scholarly journals Calcium Phosphate Nanoparticle Precipitation by a Continuous Flow Process: A Design of an Experiment Approach

Crystals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 953
Author(s):  
Lorenzo Degli Esposti ◽  
Alessandro Dotti ◽  
Alessio Adamiano ◽  
Claudia Fabbi ◽  
Eride Quarta ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Flow Rate ◽  
Continuous Flow ◽  
Scale Up ◽  
Chemical Properties ◽  
Chemical Precipitation ◽  
Water Remediation ◽  
Scale Production ◽  
Flow Process ◽  
Process Factors

Calcium phosphate nanoparticles (CaP NPs) are an efficient class of nanomaterials mainly used for biomedical applications but also very promising in other sectors such as cosmetics, catalysis, water remediation, and agriculture. Unfortunately, as in the case of other nanomaterials, their wide application is hindered by the difficulty to control size, morphology, purity and degree of particle aggregation in the translation from laboratory to industrial scale production that is usually carried out in batch or semi-batch systems. In this regard, the use of continuous flow synthesis can help to solve this problem, providing more homogenous reaction conditions and highly reproducible synthesis. In this paper, we have studied with a design of experiment approach the precipitation of citrate functionalized CaP NPs aided by sonication using a continuous flow wet chemical precipitation, and the effect of some of the most relevant process factors (i.e., reactant flow rate, sonication amplitude, and maturation time) on the physico-chemical properties of the NPs were evaluated. From the statistical data analysis, we have found that CaP NP dimensions are influenced by the reactor flow rate, while the crystalline domain dimensions and product purity are influenced by the maturation process. This work provides a deeper understanding of the relationships between reaction process factors and CaP NP properties, and is a relevant contribution for the scale-up production of CaP NPs for nanomedical or other applications.

Identifying ecological barriers to restoration in temperate grassy woodlands: soil changes associated with different degradation states

2002 ◽  
Vol 50 (6) ◽  
pp. 699 ◽  
Author(s):  
Suzanne M. Prober ◽  
Kevin R. Thiele ◽  
Ian D. Lunt
Keyword(s):  
Chemical Properties ◽  
Soil Conditions ◽  
Reference Sites ◽  
Ecosystem Recovery ◽  
Positive Feedbacks ◽  
Ecological Barriers ◽  
Eastern Australia ◽  
Repeated Pattern ◽  
Agricultural Regions ◽  
Selection Of

Temperate grassy woodlands were once the dominant vegetation across many agricultural regions of south-eastern Australia, but most of these are now highly degraded and fragmented. Adequate conservation of these woodlands is dependent on successful ecological restoration; however, ecological barriers often limit ecosystem recovery once degrading processes are removed. To help identify these barriers, we used a state and transition framework to compare topsoils of little-disturbed (reference) and variously degraded remnants of grassy Eucalyptus albens Benth. and E. melliodora Cunn. ex Schauer woodlands. Topsoils of degraded remnants showed a repeated pattern, with the most compacted, most acidic and most depleted topsoils occurring in remnants dominated by Aristida ramosa R.Br. or Austrodanthonia H.P.Linder and Austrostipa scabra (Lindl.) S.W.L.Jacobs & J.Everett; the least compacted and most nutrient rich topsoils in remnants dominated by annual exotics; and generally intermediate topsoils in remnants dominated by Bothriochloa macra (Steud.) S.T.Blake or Austrostipa bigeniculata (Hughes) S.W.L.Jacobs & J.Everett. Surprisingly, topsoils beneath trees in reference sites (supporting Poa sieberiana Spreng.) were similar to topsoils supporting annual exotics for most soil properties. Chemical properties of topsoils from open areas of reference sites [supporting Themeda australis (R.Br.) Stapf] were usually intermediate and similar to Bothriochloa macra and Austrostipa bigeniculata topsoils. The most striking exception to these trends was for soil nitrate, which was extremely low in all reference topsoils and showed a high correlation with annual exotic abundance. We discuss the potential for positive feedbacks between soil nitrogen cycling and understorey composition and the need for intervention to assist possible nitrate-dependent transitions between annual and perennial understorey states. Dominant grasses, trees and annual weed abundance may be useful indicators of soil conditions and could inform selection of target sites, species and techniques for restoration projects.

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