scholarly journals Corrosion Resistance, Evaluation Methods, and Surface Treatments of Stainless Steels

2022 ◽  
Author(s):  
Temitope Olumide Olugbade

Stainless steels are widely recognized and find applications in many engineering industries and companies due to their excellent properties including high resistance to corrosion as a result of their minimum 10.5% chromium content, exceptional strength and durability, temperature resistance, high recyclability, and easy formability. In the present book chapter, the basic concepts of stainless steel including its applications, classifications, and corrosion properties will first be discussed. Thereafter, their corrosion behaviour will then be explained. The various methods by which the corrosion resistance behaviour can be significantly improved including surface treatments such as coatings/electrodepositions, alloying, mechanical treatment, and others will be discussed in detail.

CORROSION ◽  
10.5006/3813 ◽  
2021 ◽  
Author(s):  
Donovan Verkens ◽  
Reynier Revilla ◽  
Mert Günyüz ◽  
Cemil Işıksaçan ◽  
Herman Terryn ◽  
...  

The AA3003 alloy is widely used as fin material in heat exchangers. The life time of these heat exchangers is mostly determined by their corrosion properties. Twin roll casting (TRC) of AA3003 material is known to often result in the formation of a macrosegregation area of alloying elements towards the centre plane of the casted strip (centre line segregation = CLS). Considering the potential exposure of cross-sectional areas of TRC material in the heat exchanger fin application, and the relatively high corrosion susceptibility of the CLS, the study of this region is of key importance to understand the microstructural effects on the resulting corrosion mechanisms and kinetics for these materials. Typically the alloys are homogenized to bring the microstructures closer to an equilibrium state, but the impact of this heat treatment on the corrosion properties is insufficiently studied. Therefore, this study investigates the effect of different homogenization procedures on the corrosion properties of the CLS and the interaction of the intermetallic particles with the surrounding aluminium matrix. This work shows that the pitting corrosion resistance is greatly dependent on the homogenization temperature, with better corrosion resistance obtained with higher temperature, especially near the CLS. This difference in corrosion behaviour is completely attributed to a difference in microstructure and not to an oxide layer effect. Furthermore, it is observed that not only temperature will have a large influence on the corrosion resistance, but duration of the heat treatment as well.


2017 ◽  
Vol 11 (2) ◽  
pp. 91-95 ◽  
Author(s):  
Eliza Romańczuk ◽  
Zbigniew Oksiuta

AbstractIn this work two austenitic stainless steels, REX734 and 316LV were tested in terms of their microstructure and corrosion properties. The REX734 is a newer generation stainless steel, with modified chemical composition, in comparison to the 316LV grade. Potentiodynamic study of corrosion resistance was conducted in physiological saline solution (0.9% NaCl solution). In spite of the similarities of microstructure, grain size and phase structure in both materials, the corrosion tests revealed that the REX734, with lower nickel and higher nitrogen content, had better corrosion resistance than 316LV. Repassivation potential in the REX734 was almost six times higher than for the 316LV steel. Superior corrosion resistance of the REX734 steel was also confirmed by surface observations of both materials, since bigger and more densely distributed pits were detected in 316LV alloy.


2019 ◽  
Vol 121 ◽  
pp. 01011
Author(s):  
Olga Parmenova ◽  
Svetlana Mushnikova ◽  
Vitaliy Bobyr ◽  
Evgeniy Samodelkin

This paper presents the results of comparative corrosion resistance studies of stainless steels manufactured by selective laser melting (SLM) in the initial state with subsequent heat treatment and machining. Pitting corrosion tests are carried out, according to ASTM G48 method A in 10% FeCl3·6H2O solution at elevated temperature and exposure time for 5h. The studies were performed on the AISI 321 and AISI 316L stainless steels manufactured by SLM. It was obtained that laser scanning speed decrease led to density rise by other SLM parameters being equal. Porosity affected to the stainless steel corrosion behaviour significant. Metal density decrease resulted to corrosion rate rise. Microstructure examination showed that pitting corrosion development depended on surface steel condition.


2006 ◽  
Vol 530-531 ◽  
pp. 105-110
Author(s):  
Renato Altobelli Antunes ◽  
Wagner S. Wiggers ◽  
Maysa Terada ◽  
Paulo A.P. Vendhausen ◽  
Isolda Costa

The use of AISI 316L stainless steels for biomedical applications as implants is widespread due to a combination of low cost and easy formability. However, wrought 316L steel is prone to localized corrosion. Coating deposition is commonly used to overcome this problem. Ceramic hard coatings, like titanium nitride, are used to improve both corrosion and wear resistance of stainless steels. Powder injection moulding (PIM) is an attractive method to manufacture complex, near net-shape components. Stainless steels obtained from this route have shown mechanical and corrosion properties similar to wrought materials. The literature on the use of PIM 316L steel, either coated or not, as implants is still very scarce. The aim of the present work was to study the corrosion behaviour of PIM 316L in two conditions: TiN-coated and bare. Electrochemical investigations were performed using EIS and potentiodynamic polarization techniques.


2007 ◽  
Vol 23 ◽  
pp. 261-264
Author(s):  
Brandusa Ghiban

In the present paper there are presented results concerning comparative corrosion resistance of some austenitic stainless steels, with or without silicon content. The silicon content is varying in the range of 1-5 %, in a matrix of alloyed austenite, containing 20% Cr and 15-18%Ni and with very low carbon contents (lower than 0,03% C). There are investigated different types of corrosion resistance: intergranular corrosion in nitrogen media, stress corrosion resistance in chloride media, and transpassive behaviour in sulphuric media. The testing media contained nitrogen, as it follows: Huey test (65% HNO3, at boiling temperature, 244 hours maintain), and 5N HNO3 +1g/l Cr6+ (144 h, at boiling temperature). The media containing chloride is 45% MgCl2 at boiling temperature, with a period of 1000 hours. The transpassive behaviour is tested in 10% HSO4. The investigations were made by optic and electronic microscope, and the corroded surfaces were examined by scanning electron microscopy.


2019 ◽  
Vol 25 (25) ◽  
pp. 43-46
Author(s):  
Viera Zatkalíková ◽  
Lenka Markovičová

Abstract Temperature is considered a complicated external factor of the susceptibility of stainless steels to the pitting. This paper deals with the corrosion behaviour of AISI 316Ti stainless steel in temperature range 22 - 80°C in aggressive chloride environments (3 and 5% FeCl3 solutions). The corrosion resistance of tested steel is evaluated on the base of results of exposure immersion tests and cyclic potentiodynamic tests. According to the obtained results the resistance of AISI 316Ti to the pitting is markedly affected by temperature changes in the range 22 – 80°C. Intensity of corrosion attack increases with the rise of Cl− concentration. Gentle changes of temperature and Cl− concentration cause significant differences in character of local damage. The appearance of pitted surfaces changes with the rise of the temperature (a density of pitting increases, a size of pits decreases). The strongest change in appearance is observed between 40 and 50ºC.


2019 ◽  
Vol 25 (4) ◽  
pp. 217
Author(s):  
Andrea Di Schino

<p class="AMSmaintext1"><span lang="EN-GB">Following nickel and molybdenum significant price increase, nowadays the stainless steel market is moving toward an increasing use of ferritic stainless steel instead of austenitic stainless and therefore to the development of advanced ferritic stainless steels grades aimed to substitute the more expensive austenitic materials in all applications allowing it. Super-ferritic stainless steels are higher chromium (Cr) and molybdenum (Mo) steels with properties similar to those of standard ferritic alloys. Such elements increase high temperature and corrosion resistance in strong environment. This paper deal about the corrosion resistance of super-ferritic stainless steels with a Cr content ranging from 21% to 24%. </span></p>


2019 ◽  
Vol 813 ◽  
pp. 298-303 ◽  
Author(s):  
Luca Pezzato ◽  
Manuele Dabalà ◽  
Katya Brunelli

Aluminum alloys are one of the main materials employed in aerospace and automotive applications. One of the problems that affect these alloys in certain application is the poor corrosion resistance that can, however, be enhanced with proper surface treatments, such as anodizing. Among these treatments, Plasma Electrolytic Oxidation (PEO) is one of the most promising and the production of PEO coatings on traditional aluminum alloy was extensively studied in literature. Recently, the production of a lot of components is going into the direction of using innovative manufacturing systems and customized components, with improved mechanical and physical properties, can be manufactured by additive manufacturing (AM) techniques. Among the AM methods, laser-based AM has an immense potential for producing fully dense metallic structures, using a variety of available metal powders and has attracted more and more attention. The resulting AM samples are characterized by different microstructures in comparison with the conventionally manufactured ones and this can cause differences also in the production of PEO coatings and other surface treatments. Objective of the present work is to produce PEO coatings on AM samples in order to increase the corrosion and wear performances of the samples. PEO coating were produced on the samples testing different parameters and the coatings were characterized, in terms of microstructure and composition, with SEM analysis. The corrosion resistance of the samples was also evaluated with electrochemical tests. The results were compared with the ones obtained on traditionally manufactured samples. PEO coatings were successfully produced on AM samples obtaining samples with good coatings thickness and improved corrosion performances compared to the untreated ones.


2012 ◽  
Vol 326-328 ◽  
pp. 620-625 ◽  
Author(s):  
Joanna Michalska

Hydrogen entering into steel affects its electrochemical properties and may enhance the susceptibility to environmental degradation. The present work has been aimed at further clarifying the effect of hydrogenation on the corrosion behaviour and passivity of highly-alloyed stainless steels. The results were discussed by taking into account hydrogen charged samples and without hydrogen. The corrosion resistance to pitting was qualified with the cyclic polarization curves. The conclusion is that hydrogen may deteriorated the passive film stability and corrosion resistance to pitting of highly-alloyed stainless steel. Furthermore, the presence of hydrogen in passive films increases corrosion current density, decreasing the potential of the film breakdown and repassivation potential. It was also found that the degree of susceptibility to hydrogen-enhanced pitting corrosion was dependent on the type of steel.


Coatings ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1542
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Dumitru-Doru Burduhos-Nergis ◽  
Costica Bejinariu

Worker safety is one of the main aspects to be taken into account in any activity carried out at work. When we talk about the safety of the worker at activities carried out at height, the condition and characteristics of the personal protective equipment against falling from a height are one of the main causes of work accidents resulting in serious injuries or death. Carabiners are the main components of the safety system; their role is to connect the other components of the system or to make the connection between the system and the anchor point. Therefore, to be used safely, the carabiners’ material must have high corrosion resistance in different environments. This paper is part of a complex study that aims to improve the corrosion properties of carbon steel used in the manufacture of carabiners. Previous studies have shown that the corrosion resistance of carbon steel in various corrosive environments has been improved by the deposition of different types of phosphate layers, as well as other subsequently deposited layers. The aim of this paper is to study the galvanic corrosion evaluation between different galvanic couples (duralumin-coated samples, aluminium bronze-coated samples, and carbon steel-coated samples) tested in three different corrosive media. Moreover, the study approaches for the first time the galvanic corrosion of systems that can be formed between the materials used in the manufacture of carabiners. Accordingly, it was observed that, overall, the samples coated with a Zn phosphate layer exhibited the best performance in all the corrosive environments (saltwater and fire extinguishing solution).


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