Reflection Characteristics of Airy Beams Impinging on Graphene-Substrate Surfaces

In this work, we analytically and numerically investigate the reflection characteristics of the airy beams impinging on graphene-substrate surfaces. The explicit analytical expressions for the electric and magnetic field components of the airy beams reflected from a graphene-substrate interface are derived. The local-field amplitude, Poynting vector, and spin and orbital angular momentum of the reflected airy beams with different graphene structure and beam parameters are presented and discussed. The results show that the reflection properties of the airy beams can be flexibly tuned by modulating the Fermi energy of the graphene and have a strong dependence on the incident angle and polarization state. These results may have potential applications in the modulation of airy beams and precise measurement of graphene structure parameters.

Self-Assembly Strategy for Reducing Non-Specific Adsorption on Substrates and Application for Quantitative Immunoassay

Background The development of functionalized surfaces with low non-specific adsorption is important for biomedical applications. To inhibit non-specific adsorption on a substrate, we prepared a novel optical biochip based on a quantum dot fluorescence immunosorbent assay (QD-FLISA), specifically by modifying a layer of dense negatively charged film (SO32−) on the glass substrate surface via self-assembly. Results Using optimized conditions, we constructed a biochip on functionalized glass substrates to achieve quantitative detection of C-reactive protein (CRP). We subsequently achieved quantitative determination of CRP in the range of 1-1,000 ng/mL, with a limit of detection (LOD) of 1.26 ng/mL or 5.17 ng/mL, using poly(styrene sulfonic acid) sodium salt (PSS) or meso-tetra (4-sulfonatophenyl) porphine dihydrochloride (TSPP) on individually modified glass substrate biochips. The experimental protocol was further optimized and the LOD achieved a sensitivity of 0.69 ng/mL using functionalized TSPP and PSS co-treated glass substrate surfaces for the quantitative detection of CRP. Conclusions This work demonstrated an effective and convenient strategy to obtain biochips with low non-specific adsorption properties on functionalized surfaces, thus providing a new approach for creating ultra-high sensitivity microchannels or microarrays on glass substrates.

Facile and scalable preparation of ZIF-67 decorated cotton fibers as recoverable and efficient adsorbents for removal of malachite green

Recently, metal–organic frameworks (MOFs) have received considerable attention as highly efficient adsorbents for dye wastewater remediation. However, the immobilization of MOFs on the substrate surfaces to fabricate easy recyclable adsorbents via a facile route is still a challenge. In this work, ZIF-67/cotton fibers as adsorbents for dye removal were prepared in a large-scale using a simple coordination replication method. The successful fabrication of the ZIF-67/cotton fibers was confirmed by FTIR, XRD, XPS, SEM and BET analysis, respectively. As expected, the as-prepared ZIF-67/cotton fibers exhibited high adsorption capacity of 3787 mg/g towards malachite green (MG). Meanwhile, the adsorption kinetics and isotherm obeyed the pseudo-second-order kinetics and Langmuir model, respectively. Moreover, its removal efficiency towards MG was not significantly influenced by the pH and ionic strength of aqueous solution. Most importantly, the ZIF-67/cotton fibers can remove MG from synthetic effluents, and it can be easily regenerated without filtration or centrifugation processes, with the regeneration efficiency remaining over 90% even after 10 cycles. Additionally, the ZIF-67/cotton fibers presented excellent antimicrobial performance against E. coli and S. aureus. Hence, the distinctive features of the as-prepared ZIF-67/cotton fibers make it promisingly applicable for the colored wastewater treatment.

Cold Gas Spray of Copper on Aluminum Nitride as Substrate for Power Electronics

Ceramic substrates for electronic packaging of high-power applications are growing in demand due to their robustness as power and thermal requirements increase. Aluminum nitride (AlN) has excellent thermal and electrical properties with copper currently being bonded to AlN via a direct bond copper (DBC) technique. However, substrates fabricated by DBC are subjected to thermo-mechanical fatigue during fabrication processes and power cycling. DBC substrate’s reliability is negatively affected by the large mismatch in coefficient of thermal expansion that hinders the possibility of thicker substrates, therefore limiting its use for applications above 20 kV. This work employed cold gas spraying (CGS) to mechanically bond Cu on AlN. CGS is a low-temperature additive manufacturing method that accelerates powder particles at near-supersonic velocities to impact a surface causing plastic deformation and mechanical bonding. On ceramic-metal systems CGS has not been widely studied owing to ceramics’ inability to deform plastically, therefore, surface functionalization was performed to enhance the mechanical interlocking mechanism. A factorial design of experiments (DOE) was used to assess the effect of factors: temperature, pressure, stand-off distance, angle of deposition, and travel speed on various substrate surfaces in the CGS fabrication process. These experiments resulted in a successful deposition of copper on AlN.

Effective Properties of Semitransparent Radiative Cooling Materials With Spectrally Variable Properties

Radiation cooling is a promising solid-state, non-vapor-compression technology for passive refrigeration and air conditioning. Although this phenomenon occurs naturally, achieving a significant amount of cooling to make it a technically and economically viable technology requires highly engineered, spectrally selective radiative surfaces. These characteristics make radiation cooling difficult to estimate, particularly when it is integrated with other systems such as photovoltaic panels or building envelopes. The complexity further increases when the substrate also participates in the radiative cooling (along with the radiative coating). Energy estimation is becoming increasingly critical because of the recent focus on the semitransparent radiative coatings that transmit a variety of colors to enhance the aesthetic appeal of the system. Here, we propose a simple iterative method to calculate the effective radiative properties, which provide the same net radiative cooling that would be observed using the spectral properties at both the coating and substrate surfaces. Compared to traditional methods that rely on either computationally expensive full spectral analysis or methods for averaging each radiative surface parameter locally, our proposed method focuses on calculating effective properties that provide the same the net cooling effect as a full spectral analysis by accounting the emissivity, absorptivity, and transmissivity collectively, thereby providing an overall estimation error of less than 0.2%. We believe that this study will be beneficial to the engineering communities that employ complex simulation codes and require lumped solar and thermal radiation related parameters.

Effect of Different Surface Treatments of Lithium Disilicate on the Adhesive Properties of Resin Cements

The aim of the current study was to evaluate the influence of hydrofluoric (HF) acid concentration and conditioning time on the shear bond strength (SBS) of dual cure resin cement to pressed lithium disilicate ceramic compared to treatment with an Etch and Prime self-etching glass-ceramic primer (EP). A total of 100 samples of pressed lithium disilicate (IPS e.max Press, Ivoclar Vivadent) were randomly divided into five groups (n = 20) according to surface treatment: two different concentrations of HF (5% or 9%), for different durations (20 or 90 s), or treatment with EP. Adhesion of light-cured resin cement to the treated surface was tested by the SBS test. The substrate surfaces of the specimen after failures were examined by SEM. Data were analyzed using Weibull distribution. The highest cumulative failure probability of 63.2% of the shear bond strength (η parameter) values was in the 9% HF −90 s group (17.71 MPa), while the lowest values were observed in the 5% HF −20 s group (7.94 MPa). SBS values were not affected significantly by the conditioning time (20 s or 90 s). However, compared to treatment with 5% HF, surface treatment with 9% HF showed a significantly higher η (MPa) as well as β (reliability parameter). Moreover, while compared to 9% HF for 20 s, EP treatment did not differ significantly in SBS values. Examination of the failure mode revealed a mixed mode of failure in all the groups. Within the limits of this study, it is possible to assume that IPS e.max Press surface treatment with 9% HF acid for only 20 s will provide a better bonding strength with resin cement than using 5% HF acid.

Tunable Adhesive Self-Cleaning Coating with Superhydrophobicity and Photocatalytic Activity

Superhydrophobic coatings with intelligent properties have attracted much attention because of their wide application in many fields. However, there is a limited amount of literature on superhydrophobic coatings whose wettability and adhesion can be adjusted by UV irradiation and calcination at the same time. In this study, amorphous SiO2 microspheres (A-SiO2) and nano-TiO2 particles (N-TiO2) were used to fabricate A-SiO2/N-TiO2 composites by wet grinding, and then, they were modified with polydimethylsiloxane (PDMS) and sprayed onto substrate surfaces to obtain a tunable adhesive superhydrophobic A-SiO2/N-TiO2@PDMS coating. It is worth noting that the wettability and adhesion of the coating to water droplets could be adjusted by UV irradiation and calcination. The mechanisms of the aforementioned phenomena were studied. Moreover, methyl orange solution could be degraded by the coating due to its photocatalysis. The as-prepared coating had good adaptation to different substrates and outdoor environments. Moreover, the surfaces of these coatings exhibited the same liquid repellency towards different droplets. This research provides an environmental strategy to prepare advanced self-cleaning coatings.

Interfacial Modeling of Fibrinogen Adsorption onto LiNbO3 Single Crystal–Single Domain Surfaces

For the development of next-generation protein-based biosensor surfaces, it is important to understand how functional proteins, such as fibrinogen (FBG), interact with polar substrate surfaces in order to prepare highly sensitive points of medical care diagnostics. FBG, which is a fibrous protein with an extracellular matrix, has both positively and negatively charged regions on its 3-dimensional surface, which makes interpreting how it effectively binds to polarized surfaces challenging. In this study, single-crystal LiNbO3 (LNO) substrates that have surface charges were used to investigate the adsorption of FBG protruding polar fragments on the positively and negatively charged LNO surfaces. We performed a combination of experiments and multi-scale molecular modeling to understand the binding of FBG in vacuum and water-solvated surfaces of LNO. XPS measurements showed that the FBG adsorption on LNO increased with increment in solution concentration on surfaces independent of charges. Multi-scale molecular modeling employing Quantum Mechanics, Monte Carlo, and Molecular Mechanics addressed the phenomenon of FBG fragment bonding on LNO surfaces. The binding simulation validated the experimental observation using zeta potential measurements which showed presence of solvated medium influenced the adsorption phenomenon due to the negative surface potential.