thermodynamic effect
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Polymer ◽  
2022 ◽  
Vol 239 ◽  
pp. 124430
Author(s):  
Long Chen ◽  
Yeqin Shen ◽  
Zhanqiang Liu ◽  
Qinghua Song ◽  
Yanyan Jiang

Author(s):  
Anna Mikheeva ◽  
Igor Kalinnikov

The creepex (creep & explosion) parameter provides information on the relation between low- and high-frequency radiation components in the earthquake source and has become a physically meaningful tool for analyzing various aspects of seismogenesis, in particular, the diagnostics of the preparation processes and the its aftershocks activity of a strong event. This paper investigates the spatial-temporal dynamics of creepex in the focal zones of a number of the major earthquakes from the plate convergence regions, including continental Kashmir earthquake (08.10.2005, MS=7.6) and continental-oceanic Tohoku (11.03.2011, Mw=8.7). One of the goals of this work is to demonstrate the capabilities of the method in studying physically grounded patterns of focal zones development at the first hours after the main shock. Because of this study, the following regularities of the source relaxation process were revealed: the partiality of the aftershock process, positive values of the creepex at its first hours (explained by the influence of the dilatancy process), and abrupt changes in the creepex during deep transitions (explained by the thermodynamic effect and by the increase in pressure with depth).


2021 ◽  
Vol 17 (6) ◽  
pp. 2537-2558
Author(s):  
Zixuan Han ◽  
Qiong Zhang ◽  
Qiang Li ◽  
Ran Feng ◽  
Alan M. Haywood ◽  
...  

Abstract. The mid-Pliocene (∼3 Ma) is one of the most recent warm periods with high CO2 concentrations in the atmosphere and resulting high temperatures, and it is often cited as an analog for near-term future climate change. Here, we apply a moisture budget analysis to investigate the response of the large-scale hydrological cycle at low latitudes within a 13-model ensemble from the Pliocene Model Intercomparison Project Phase 2 (PlioMIP2). The results show that increased atmospheric moisture content within the mid-Pliocene ensemble (due to the thermodynamic effect) results in wetter conditions over the deep tropics, i.e., the Pacific intertropical convergence zone (ITCZ) and the Maritime Continent, and drier conditions over the subtropics. Note that the dynamic effect plays a more important role than the thermodynamic effect in regional precipitation minus evaporation (PmE) changes (i.e., northward ITCZ shift and wetter northern Indian Ocean). The thermodynamic effect is offset to some extent by a dynamic effect involving a northward shift of the Hadley circulation that dries the deep tropics and moistens the subtropics in the Northern Hemisphere (i.e., the subtropical Pacific). From the perspective of Earth's energy budget, the enhanced southward cross-equatorial atmospheric transport (0.22 PW), induced by the hemispheric asymmetries of the atmospheric energy, favors an approximately 1∘ northward shift of the ITCZ. The shift of the ITCZ reorganizes atmospheric circulation, favoring a northward shift of the Hadley circulation. In addition, the Walker circulation consistently shifts westward within PlioMIP2 models, leading to wetter conditions over the northern Indian Ocean. The PlioMIP2 ensemble highlights that an imbalance of interhemispheric atmospheric energy during the mid-Pliocene could have led to changes in the dynamic effect, offsetting the thermodynamic effect and, hence, altering mid-Pliocene hydroclimate.


2021 ◽  
Vol 12 ◽  
Author(s):  
Jessica L. E. Wimmer ◽  
Karl Kleinermanns ◽  
William F. Martin

The possible evolutionary significance of pyrophosphate (PPi) has been discussed since the early 1960s. Lipmann suggested that PPi could have been an ancient currency or a possible environmental source of metabolic energy at origins, while Kornberg proposed that PPi vectorializes metabolism because ubiquitous pyrophosphatases render PPi forming reactions kinetically irreversible. To test those ideas, we investigated the reactions that consume phosphoanhydride bonds among the 402 reactions of the universal biosynthetic core that generates amino acids, nucleotides, and cofactors from H2, CO2, and NH3. We find that 36% of the core’s phosphoanhydride hydrolyzing reactions generate PPi, while no reactions use PPi as an energy currency. The polymerization reactions that generate ~80% of cell mass – protein, RNA, and DNA synthesis – all generate PPi, while none use PPi as an energy source. In typical prokaryotic cells, aminoacyl tRNA synthetases (AARS) underlie ~80% of PPi production. We show that the irreversibility of the AARS reaction is a kinetic, not a thermodynamic effect. The data indicate that PPi is not an ancient energy currency and probably never was. Instead, PPi hydrolysis is an ancient mechanism that imparts irreversibility, as Kornberg suggested, functioning like a ratchet’s pawl to vectorialize the life process toward growth. The two anhydride bonds in nucleoside triphosphates offer ATP-cleaving enzymes an option to impart either thermodynamic control (Pi formation) or kinetic control (PPi formation) upon reactions. This dual capacity explains why nature chose the triphosphate moiety of ATP as biochemistry’s universal energy currency.


2021 ◽  
Vol 11 (19) ◽  
pp. 8853
Author(s):  
Dengwang Wang ◽  
Yong Gao ◽  
Wei Chen ◽  
Jing Zhang ◽  
Sheng Wang

X-ray thermodynamic effect is an important damage mode for spacecraft. Blow-off impulse as the main thermodynamic damage parameter has been widely studied by combining laboratory and numerical simulations. In this paper, most calculations and analyses have been carried out by using the self-developed software RAMA, including the equivalent calculation of blow-off impulse of monoenergetic and blackbody X-ray, and soft/hard blackbody X-ray irradiated at different incidence angles of LY-12 aluminium target. The results show that the characteristic mono-energetic X-ray can be exploited to simulate the blow-off impulse of the blackbody X-ray under certain conditions as a feasible equivalent method for the equal-flux and equal-impulse relations between mono-energetic and intense pulse blackbody of blow-off impulse. Moreover, the equivalent thermodynamic effect can be achieved between the point source radiation and parallel X-ray of X-ray. Furthermore, the cosine distribution of blow-off impulse is conducive to designing and calculating X-ray radiation load of hard aluminium corresponding to 1–5 keV blackbody spectrum. The mentioned results can be referenced for pulse X-ray simulation source and enhance the fidelity of the thermal-mechanical effect by electron beam. It is noteworthy that the study on the thermodynamic effects of intense pulsed X-ray is of high significance.


Author(s):  
Joshua B. Wadler ◽  
David S. Nolan ◽  
Jun A. Zhang ◽  
Lynn K. Shay

AbstractThe thermodynamic effect of downdrafts on the boundary layer and nearby updrafts are explored in idealized simulations of category-3 and category-5 tropical cyclones (Ideal3 and Ideal5). In Ideal5, downdrafts underneath the eyewall pose no negative thermodynamic influence because of eye-eyewall mixing below 2-km altitude. Additionally, a layer of higher θe between 1 and 2 km altitude associated with low-level outflow that extends 40 km outward from the eyewall region creates a “thermodynamic shield” that prevents negative effects from downdrafts. In Ideal3, parcel trajectories from downdrafts directly underneath the eyewall reveal that low-θe air initially moves radially inward allowing for some recovery in the eye, but still enters eyewall updrafts with a mean θe deficit of 5.2 K. Parcels originating in low-level downdrafts often stay below 400 m for over an hour and increase their θe by 10-14 K, showing that air-sea enthalpy fluxes cause sufficient energetic recovery. The most thermodynamically unfavorable downdrafts occur ~5 km radially outward from an updraft and transport low-θe mid-tropospheric air towards the inflow layer. Here, the low-θe air entrains into the updraft in less than five minutes with a mean θe deficit of 8.2 K. In general, θe recovery is a function of minimum parcel altitude such that downdrafts with the most negative influence are those entrained into the top of the inflow layer. With both simulated TCs exposed to environmental vertical wind shear, this study underscores that storm structure and individual downdraft characteristics must be considered when discussing paradigms for TC intensity evolution.


Author(s):  
Anh Dinh Le

In this study, the cavitation in hot water, which implies tight interaction of thermodynamic effect, phase change phenomena, and flow behavior, was studied by a combination of experiment and numerical simulation. The experiment in water up to 90°C was performed in the high temperature and high-pressure water tunnel with NACA0015 as a cavitator. The temperature inside the cavity was measured using the high-accuracy thermistor probe. According to the result, the temperature depression in the cavity was increased proportionally with the increase of freestream temperature. The inverse thermodynamic effect was observed with the increase of cavity length when temperature increased. The maximum temperature depression of about 0.41°C was measured in the water at around 90°C. The temperature drop was reasonably captured in simulation by coupling our simplified thermodynamic model with our cavitation model and governing equations. The tendency of temperature depression in the cavity agreed well with experimental data under different flow conditions.


Author(s):  
Anh Dinh Le

Abstract The flashing flow in a Moby_Dick converging-diverging nozzle under pressurized hot water from 460.5 K to 483.5 K is simulated using a homogeneous compressible water-vapor two-phase flow model. The kinematic and thermodynamic mass transfer are accessed using the cavitation model based on the Hertz-Knudsen-Langmuir equation. Our simplified thermodynamic model is coupled with the governing equations to capture the phase-change heat transfer. This numerical method proved its reliability through a comparison with available experimental data of flow parameters inside the nozzle. Consequently, the present numerical method shows good potential for simulating the flashing flow under pressurized hot water conditions. The satisfying prediction of averaged flow parameters with a slight improvement compared to reference numerical data is reproduced. The results confirm a noticeable impact of the thermodynamic effect on the mechanism of flashing flow, resulting in a considerable decrease in the flow temperature and the saturated vapor pressure. The flashing non-equilibrium is significantly decreased, forcing the flashing flow to be classified as the usual cavitation behavior and better suited to homogeneous model. While the temperature drop is highly dependent on evaporation, the thermodynamic suppression is influenced by the condensation. The suppression effect, unobserved in water at a lower temperature in previous studies, is noticeable for the pressurized hot water flow characterized by the cavitation mechanism. The vapor void fraction decreased considerably in the radial and axial directions as the water temperature rose to 483.5 K in this study.


Author(s):  
Yu Ito

Abstract It is well known that cavitation breakdown, which is a phenomenon in which the pump head suddenly drops with a decrease in the inlet cavitation number, occurs in turbopumps. Especially in cryogenic pumps, cavitation breakdown occurs at a lower inlet cavitation number than that of ordinary fluids such as water. This phenomenon is referred to as a thermodynamic effect, as Stepanoff reported. The thermodynamic properties of the working fluid affect the sizes of cavitation elements, and the sizes affect cavitation breakdown; therefore, experimental flow visualization is an effective approach to realize a more efficient and more reliable cryogenic pump. In 2010, the author and colleagues developed the worldߣs first test facility to enable the visualization of cavitation on a rotating inducer in both cryogenic and ordinary fluids. At that time, only two reports on the flow visualization of a rotating cryogenic impeller had been published: one on flow visualization in liquid hydrogen by NASA in 1967 and the other in liquid nitrogen by JAXA in 2010. The present facility employs a triple-thread helical inducer with a diameter of 65.3 mm and a rotation rate of up to 8000 rpm with both liquid nitrogen and water available as working fluids. Unsteady visualization experiments for cavitation on an inducer in liquid nitrogen and water have revealed the characteristics of tip vortex cavitation, backflow vortex cavitation, and cavitation element size based on comparisons between cryogenic fluids that exhibit a stronger thermodynamic effect and ordinary fluids such as water.


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