Environmental impact on the toxicologically relevant arsenic species in ground water of 2nd aquifer of coal mining area and release in a reservoir: Risk assessment to aquatic life

In present study, the variation in the concentrations of inorganic As species (penta and trivalent) in ground water of coal mining area (2nd aquifer) and its drain outlet/discharge in a reservoir/gorano dam. The water samples were collected from reservoir at four different sites (RW1, RW2, RW3 and RW4. At site four of reservoir (RW4) the fish farming is also carried out, from where a fish species Tilapia (Oreochromis mossambicus) was also collected. The solid phase extraction using titanium dioxide as an adsorbent was applied for the determination of inorganic As. The arsenite (AsIII) was found by an advance extraction method (cloud point extraction) by means of a hydrophobic chelating reagent and the obtained hydrophobic complex was deceived in a surfactant (Triton X-114). Physico-chemical, parameters of all water samples collected from ground water of aquifer 2 of coal mining area (AQ2), drain/discharge outlet (DW) and four sites of reservoir/Gorano dam were carried out. The resulted data indicated that physicochemical parameters (conductivity, total dissolved salt, pH) of all collected samples were surpassed the WHO recommended values for drinking water excluding pH. The different organs (gills, scale, liver and muscles) of O. mossambicus were analyzed for total As. The resulted data designated that accretion of As in various tissues of selected fish species was found in decreasing order as liver > gill > muscles > scale. The bioaccumulation factor was calculated > 28. To evaluate the exposure of As via consuming the fish muscles by people was calculated by daily intake of As (EDI), and found to be significantly higher than the allowable limit (2.1 µg/Kg/day) by food organizations.

Impact of Water Regimes and Amendments on Inorganic Arsenic Exposure to Rice

Rice-based diet faces an important public health concern due to arsenic (As) accumulation in rice grain, which is toxic to humans. Rice crops are prone to assimilate As due to continuously flooded cultivation. In this study, the objective was to determine how water regimes (flooded and aerobic) in rice cultivation impact total As and inorganic As speciation in rice on the basis of a field-scale trial in the post-monsoon season. Iron and silicon with NPK/organic manure were amended in each regime. We hypothesised that aerobic practice receiving amendments would reduce As uptake in rice grain with a subsequent decrease in accumulation of inorganic As species relative to flooded conditions (control). Continuously flooded conditions enhanced soil As availability by 32% compared to aerobic conditions. Under aerobic conditions, total As concentrations in rice decreased by 62% compared to flooded conditions. Speciation analyses revealed that aerobic conditions significantly reduced (p < 0.05) arsenite (68%) and arsenate (61%) accumulation in rice grains. Iron and silicon exhibited significant impact on reducing arsenate and arsenite uptake in rice, respectively. The study indicates that aerobic rice cultivation with minimum use of irrigation water can lead to lower risk of inorganic As exposure to rice relative to flooded practice.

Mechanics of free-standing inorganic and molecular 2D materials

The discovery of graphene has triggered a great interest in inorganic as well as molecular two-dimensional (2D) materials. In this review, we summarize recent progress in the mechanical characterization of...

On-column internal standardisation as an alternative calibration strategy for speciation analysis: feasibility demonstration through analysis of inorganic As in rice

Species-specific isotope dilution mass spectrometry (SS-IDMS) has been the calibration method of choice for high accuracy speciation analysis because it can correct for detector sensitivity drifts, matrix effects, analyte loss...

Cadmium and Lead Levels in Blood and Arsenic Levels in Urine among Schoolchildren Living in Contaminated Glassworks Areas, Sweden

The Kingdom of Crystal, an area in southern Sweden famous for its many glassworks, is historically heavily burdened by pollution from this industry. Glass crust containing cadmium (Cd), lead (Pb), and arsenic (As) has been deposited around the area and used as filling. The purpose of this study was to monitor whether the high levels of metals in the contaminated soil were reflected in blood and urine among school children in this area. Blood and urine samples were collected from 87 children in 2017. The levels of cadmium (Cd-B) and lead (Pb-B) found in blood were determined by inductively coupled plasma mass spectrometry (ICP-MS). The speciation of As in urine (As-U) was performed by ion chromatography. The geometric mean of Cd-B and Pb-B among the children were 0.09 μg/L and 9.9 μg/L respectively. The geometric mean of inorganic As (AsIII and AsV) with metabolites in urine was 6.1 μg/L and 6.94 μg/g creatinine. Children in the study area had blood levels of Pb and Cd that correspond to levels generally found in Swedish children. The levels of inorganic As and its metabolites in urine were low and in the same magnitude as other children in Europe and the U.S.

Arsenic Exposure and Methylation Efficiency in Relation to Oxidative Stress in Semiconductor Workers

This study examined associations between oxidative stress and arsenic (As) exposure and methylation efficiency in semiconductor workers. An As-exposed group (n = 427) and a control group (n = 91) were included. The As-exposure group (n = 427) included 149 maintenance staff members and 278 production staff members representing high As exposure and low As exposure, respectively. The control group included 91 administrative staff members with no or minimal As exposure. An occupational exposure assessment was conducted to assess personal As exposure by measuring As concentrations in urine, hair, and fingernails of the subjects. Urinary As(III), As(V), monomethylarsonic (MMA), and dimethylarsinic acid (DMA) were quantified to assess an internal dose of inorganic As. Urinary 8-hydroxy-2’-deoxyguanosine (8-OHdG) and malondialdehyde (MDA) were measured to asses oxidative DNA damage and lipid peroxidation, respectively. As concentrations in urine, hair, and fingernails significantly increased (p < 0.05) in the As-exposed group in comparison to the control group. Geometric mean urinary concentrations of As, 8-OHdG, and MDA in the As-exposed group significantly exceeded those in the control group. As exposure to As-exposed workers had increased concentrations of 8-OHdG in contrast to those in control subjects. Moreover, urinary 8-OHdG concentrations in the semiconductor workers were positively correlated with urinary total As metabolite (As(III) + As(V) + MMA + DMA) concentrations. Furthermore, urinary excretion of 8-OHdG concentrations in As-exposed workers were positively associated with urinary excretion of MMA concentrations and primary methylation index values (the ration of MMA/inorganic As). However, fingernail and hair samples did not perform as well as urinary samples to measure oxidative stress induced by As exposure. 8-OHdG could serve as a more reliable biomarker for assessing As methylation than MDA did. Occupational exposure to inorganic As was associated with increased oxidative stress among semiconductor workers.

Synthesis, DFT studies, fabrication, and optical characterization of the [ZnCMC]TF polymer (organic/inorganic) as an optoelectronic device

A novel carboxymethyl cellulose zinc thin film [ZnCMC]TF was fabricated using the sol–gel technique.

Rethinking children’s agency: Power, assemblages, freedom and materiality

This article attempts to rethink agency for childhood studies, drawing on Foucault’s theorisations of power, Deleuze and Guattari’s concept of assemblage, Bennett’s vital materialism and Grosz’s account of Bergson’s conception of freedom. I argue that (1) agency is ambivalent, that is, it has no intrinsic ethical value; (2) agency is not a property of individual children but happens within assemblages; (3) it is analytically useful to distinguish between more routine and more inventive tendencies of agency; and (4) agency arises in the relations between the organic and the inorganic, as life actualises the virtual potential of matter for indeterminacy. These ideas contribute to ongoing debates about agency within the field, and connect these debates with wider questions about children’s relations with materials and nonhumans.