Numerical analysis of an infrared gas sensor utilizing an indium-tin-oxide-based plasmonic slot waveguide

Plasmonic waveguides have attracted much attention owing to the associated high field intensity at the metal–dielectric interface and their ability to confine the modes at the nanometer scale. At the same time, they suffer from relatively high propagation loss, which is due to the presence of metal. Several alternative materials have been introduced to replace noble metals, such as transparent conductive oxides (TCOs). A particularly popular TCO is indium tin oxide (ITO), which is compatible with standard microelectromechanical systems (MEMS) technology. In this work, the feasibility of ITO as an alternative plasmonic material is investigated for infrared absorption sensing applications: we numerically design and optimize an ITO-based plasmonic slot waveguide for a wavelength of 4.26 µm, which is the absorption line of CO2. Our optimization is based on a figure of merit (FOM), which is defined as the confinement factor divided by the imaginary part of the effective mode index (i.e., the intrinsic damping of the mode). The obtained optimal FOM is 3.2, which corresponds to 9 µm and 49 % for the propagation length (characterizing the intrinsic damping) and the confinement factor, respectively.

A Plasmonic Sensor Based on D-Shaped Dual-Core Microchannel Photonic Crystal Fiber

In this paper, a dual-core microchannel-based fiber sensor is studied by using finite element method in the visible and near-infrared bands. Plasmonic material gold (Au) is deposited in microchannel to generate the surface plasmon resonance (SPR) effect, so that sensor can detect the change in RI of its surrounding analyte. Simulation results show that the maximum wavelength sensitivity and resolution are 33600nm/RIU and 2.97×10−6RIU for y polarization in the RI range of 1.33 to 1.44, respectively. The highest figure of merit (FOM) of the sensor is 961 for y polarization. In addition, we study the effects brought by the structural changes of the fiber sensor, and the results show that the design of “microchannel coating” dramatically improves the refractive index detection ability of the sensor. The D-shaped dual-core microchannel-based photonic crystal fiber sensor proposed in this paper has a simple structure, low manufacturing complexity, and high sensitivity. Combined with external sensing technology, this sensor has great application potential in the fields of biotechnology, medical diagnosis, and environmental protection.

Innovative Gold/Cobalt Ferrite Nanocomposite: Physicochemical and Cytotoxicity Properties

The combination of plasmonic material and magnetic metal oxide nanoparticles is widely used in multifunctional nanosystems. Here we propose a method for the fabrication of a gold/cobalt ferrite nanocomposite for biomedical applications. The composite includes gold cores of ~10 nm in diameter coated with arginine, which are surrounded by small cobalt ferrite nanoparticles with diameters of ~5 nm covered with dihydrocaffeic acid. The structure and elemental composition, morphology and dimensions, magnetic and optical properties, and biocompatibility of new nanocomposite were studied. The magnetic properties of the composite are mostly determined by the superparamagnetic state of cobalt ferrite nanoparticles, and optical properties are influenced by the localized plasmon resonance in gold nanoparticles. The cytotoxicity of gold/cobalt ferrite nanocomposite was tested using T-lymphoblastic leukemia and peripheral blood mononuclear cells. Studied composite has selective citotoxic effect on cancerous cells while it has no cytotoxic effect on healtly cells. The results suggest that this material can be explored in the future for combined photothermal treatment and magnetic theranostic.

Comparative study of the highly sensitive plasmonic sensor based on a D-Shaped photonic crystal fiber with silver or gold layers

A highly sensitive D-shaped photonic crystal fiber sensor with circular lattice is proposed for external plasmonic sensing. The proposed design of plasmonic material in a D-shaped form effectively facilitates the excitation of surface plasmons and enhances the sensor performance. As a comparative study, two different plasmonic materials, gold and silver, are applied D-shapely on the fiber and the proposed sensor performance is numerically investigated and evaluated. Moreover, the optimized structural parameters such as air-hole diameters and the thickness of silver and gold layers are selected via simulation results which cause the highest sensitivity of 40000nm/RIU for the gold coated fiber using the wavelength interrogation method. Furthermore, the maximum figure of merit can reach 621.50RIU-1. Analytes with the refractive indices ranging from 1.34 to 1.39 can be detected by double-loss peak that is a more reliable method of simultaneous detection and verification of sensing characteristics. Due to its promising results, the proposed sensor can be widely useful in the area of chemical and biological sensing.

Progress towards the realization of an optical Far-Field Superlens

<p>Conventional optics suffer from a fundamental resolution limit due to the nature of light. The near-field superlens concept was introduced two decades ago, and its theory for enabling high resolution imaging is well-established now. Initially, this superlens, which has a simple setup, became a hot topic given the proposition of overcoming the diffraction limit. It has been demonstrated that a near-field superlens can reconstruct images using evanescent waves emanating from small objects by means of resonant excitations on the surface of the superlens. A modified version of the superlens named the far-field superlens is theorized to be able to project the near-field subwavelength information to the far-field region. By design, the far-field superlens is a near-field superlens with nanostructures added on top of it. These nanostructures, referred to as diffraction gratings help couple object information available in the evanescent waves to the far-field. Work reported in this thesis is divided to two major sections. The first describes the modelling technique that investigates the performance of a far-field superlens. This section focuses on evaluating the impact of the diffraction gratings geometry and the object size on the far-field superlens performance as well as the resulting far-field pattern. It was shown that a far-field superlens with a nanograting having a duty cycle of 40% to 50% produces the maximum intensity and contrast in the far-field interactions. For periodic rectangular objects, an inverse-trapezoidal nanograting was shown to provide the best contrast and intensity for far-field interactions. The minimal simulation domain to model a symmetric far-field superlens design was determined both in 2D and 3D. This input reduced the required modelling time and resources. Finally, a 3D far-field superlens model was proposed, and the effect of light polarization on the far-field pattern was studied. The second section of this thesis contains the experimental study that explores a new material as a potential candidate for the construction of far-field superlens. The material conventionally used for superlens design is silver, as its plasmonic properties are well-established. However, scaling down silver features to the nanoscale introduces fundamental fabrication challenges. Furthermore, silver oxidizes due to its reactions with sulphur compounds at ambient conditions, which means that operating a silver far-field superlens is only possible in a well-controlled environment. This disagrees with our proposed concept of a low-cost and robust superlens imaging device. On the other hand, highly doped semiconductors are emerging candidates for plasmonic applications due to the possibility of tuning their optical and electrical properties during the fabrication process. While the working principle of a superlens is independent of the plasmonic material of choice, every plasmonic material has a particular range of operating wavelengths. The pros and cons of each plasmonic material are usually identified once used experimentally. In this work, aluminium-doped zinc oxide was the proposed material of choice for the far-field superlens design. The second part of this thesis details the characterization results of the optical, electrical and structural properties of this proposed alternative. Our aluminium-doped zinc oxide samples were highly transparent for large parts of the spectrum. Their carrier concentration was of the order of 10+20 cm-3, and a resistivity of about 10-3 Ω.cm was achieved. The modelled dielectric permittivity for the studied samples showed a cross-over frequency in the near-infrared region, with the highest plasma frequency achieved in this study being 4710 cm-1.</p>

Progress towards the realization of an optical Far-Field Superlens

<p>Conventional optics suffer from a fundamental resolution limit due to the nature of light. The near-field superlens concept was introduced two decades ago, and its theory for enabling high resolution imaging is well-established now. Initially, this superlens, which has a simple setup, became a hot topic given the proposition of overcoming the diffraction limit. It has been demonstrated that a near-field superlens can reconstruct images using evanescent waves emanating from small objects by means of resonant excitations on the surface of the superlens. A modified version of the superlens named the far-field superlens is theorized to be able to project the near-field subwavelength information to the far-field region. By design, the far-field superlens is a near-field superlens with nanostructures added on top of it. These nanostructures, referred to as diffraction gratings help couple object information available in the evanescent waves to the far-field. Work reported in this thesis is divided to two major sections. The first describes the modelling technique that investigates the performance of a far-field superlens. This section focuses on evaluating the impact of the diffraction gratings geometry and the object size on the far-field superlens performance as well as the resulting far-field pattern. It was shown that a far-field superlens with a nanograting having a duty cycle of 40% to 50% produces the maximum intensity and contrast in the far-field interactions. For periodic rectangular objects, an inverse-trapezoidal nanograting was shown to provide the best contrast and intensity for far-field interactions. The minimal simulation domain to model a symmetric far-field superlens design was determined both in 2D and 3D. This input reduced the required modelling time and resources. Finally, a 3D far-field superlens model was proposed, and the effect of light polarization on the far-field pattern was studied. The second section of this thesis contains the experimental study that explores a new material as a potential candidate for the construction of far-field superlens. The material conventionally used for superlens design is silver, as its plasmonic properties are well-established. However, scaling down silver features to the nanoscale introduces fundamental fabrication challenges. Furthermore, silver oxidizes due to its reactions with sulphur compounds at ambient conditions, which means that operating a silver far-field superlens is only possible in a well-controlled environment. This disagrees with our proposed concept of a low-cost and robust superlens imaging device. On the other hand, highly doped semiconductors are emerging candidates for plasmonic applications due to the possibility of tuning their optical and electrical properties during the fabrication process. While the working principle of a superlens is independent of the plasmonic material of choice, every plasmonic material has a particular range of operating wavelengths. The pros and cons of each plasmonic material are usually identified once used experimentally. In this work, aluminium-doped zinc oxide was the proposed material of choice for the far-field superlens design. The second part of this thesis details the characterization results of the optical, electrical and structural properties of this proposed alternative. Our aluminium-doped zinc oxide samples were highly transparent for large parts of the spectrum. Their carrier concentration was of the order of 10+20 cm-3, and a resistivity of about 10-3 Ω.cm was achieved. The modelled dielectric permittivity for the studied samples showed a cross-over frequency in the near-infrared region, with the highest plasma frequency achieved in this study being 4710 cm-1.</p>

Near-field Strong Plasmonic Resonances in Bi1.5Sb0.5Te1.8Se1.2 Topological Insulator Film

Topological insulators are a new class of quantum materials with metallic (edge) surface states and insulating bulk states. They exhibit various novel electronic and optical properties that make them highly promising electronic, spintronic, and optoelectronic materials. Our report confirms that the topological insulator Bi 1.5 Sb 0.5 Te 1.8 Se 1.2 (BSTS) is also an effective plasmonic material in the visible and near-infrared range. A BSTS film can effectively control transmission and reflection characteristics by changing the period of the hole array. This study determined that a strong resonant surface plasmonic mode at the resonance peak can confine approximately 80% of the electromagnetic field energy is demonstrated. Higher-order (second- and third-order) resonance peaks were also found, which is critical for controlling electromagnetic waves and research into new optoelectronic devices.

Dual scaled approach SPR-based PCF RI sensor with ultra-low loss

We demonstrate an ultra-low loss photonic crystal fiber (PCF) sensor based on surface plasmon resonance (SPR)in this paper. In this refractive index (RI) sensor, we explored hexagonal-arrangement of airholes and employed only two different sizes of it. The formation of airholes makes the confinement loss (CL) surprisingly low. The maximum CL is as low as 10.71 and 28.58 dB/cm for x and y-pol modes, respectively within a range of refractive indices 1.33-1.40. The maximum gained amplitude sensitivity is -1212 RIU−1 and -2430 RIU−1, and the maximum figure of merit is as high as 583 and 467 respectively for x and y-polarization (pol) modes respectively. In addition to that, we got a maximum wavelength sensitivity, Sw of 14,000nm/RIU for both x and y-pol modes with a minimum sensor resolution of 7.143x10−6. Gold is preferred over other materials as the plasmonic material for its inert behaviour and higher chemical stability. The analysis was carried out using the finite element method (FEM). This sensor, with its elegant configuration, fabrication feasibility, ultra-low loss, stands out to be an effective and eminent prospect in the current burgeoning SPR sensor realm and also prompts further creative exploration in its hexagonal lattice arrangements.

Influence of trap densities in ITO thin film on the optical, electrical, and surface plasmon resonance properties

Indium–tin–oxide (ITO) is a material having metallic behavior in the infra-red spectral range. Its electrical and optical properties are also easily tuned, making it a suitable alternative plasmonic material in the infra-red region. In this work, electrical and optical simulation modeling was performed to study the effect of trap densities in different carrier scattering mechanisms on the mobility in ITO. This study correlates the micro-structural and opto-electronic parameters to the surface plasmon resonance (SPR) behavior in the ITO thin films. The results indicate that low defect density with high carrier concentration can provide better SPR performance in ITO.

Enhanced Photocatalytic Activity of Two Dimensional SrTiO3 Nano Structures for Dye Degradation

The combination of the properties of nanostructures, photocatalytic semiconductors, and plasmonic materials can significantly contribute to improving the performance of the entire photocatalysis process. We tried to produce a unique catalyst by combining these three properties. We have produced a two-dimensional nanostructure which was then coated with gold as a plasmonic material followed by SrTiO3 as semiconductor material. The result was the production of the first catalyst of its kind made in this way, which offered notable results. The degradation ability of the sample was examined with different degrees of pH of rhodamine B dye, where we achieved the highest degradation, 16%, at pH10.