CFD-DEM Simulation of Spouted Bed Dynamics under High Temperature with an Adhesive Model

Particle adhesion is of great importance to coating processes due to its effect on fluidization. Currently, Computational Fluid Dynamics-Discrete Element Method (CFD-DEM) has become a powerful tool for the study of multiphase flows. Various contact force models have also been proposed. However, particle dynamics in high temperature will be changed with particle surface properties changing. In view of this, an adhesion model is developed based on approaching-loading-unloading-detaching idea and particle surface change under high temperature in this paper. Analyses of the adhesion model are given through two particle collision process and validated by experiment. Effects of inlet gas velocity and adhesion intensity on spouted bed dynamics are investigated. It is concluded that fluidization cycle will be accelerated by adhesion, and intensity of fluidization will be marginally enhanced by slight adhesion. Within a certain range, increasing inlet gas velocity will lead to strong intensity of particle motion. A parameter sensitivity comparison of linear spring-damping model and Hertz-Mindlin Model is given, which shows in case of small overlaps, forces calculated by both models have little distinction, diametrically opposed to that of large overlaps.

Modelling ATR-FTIR Spectra of Dental Bonding Systems to Investigate Composition and Polymerisation Kinetics

Component ratios and kinetics are key to understanding and optimising novel formulations. This warrants investigation of valid methods. Attenuated Total Reflectance Fourier Transform Infra-Red (ATR)-FTIR spectra of separate primers/adhesives were modelled using summed spectra of solvents (water, ethanol), methacrylate monomers (HEMA (hydroxyethyl methacrylate), Bis-GMA (bisphenol A glycidyl methacrylate), and 10-MDP (10-methacryloyloxydecyl dihydrogen phosphate)), and fillers, multiplied by varying fractions. Filler loads were obtained following their separation from the adhesives, by analysing three repetitions (n = 3). Spectral changes during light exposure at 37 °C (20 s, LED 1100–1330 mW/cm2) were used to determine polymerisation kinetics (n = 3). Independent samples T-test was used for statistical analysis (significance level of 5%). FTIR modelling suggested a primer solvent percentage of OBFL (Optibond FL) (30%) was half that of CFSE (Clearfil SE 2) (60%). OBFL included ethanol and water, while CFSE included only water. Monomer peaks were largely those of HEMA with lower levels of phosphate monomers. OBFL/CFSE adhesive model spectra suggested that both contained equal volumes of Bis-GMA/HEMA, with CFSE having 10-MDP. Filler levels and spectra from OBFL (48 wt.%) and CFSE (5 wt.%) were different. Both systems reached a 50% conversion rate within seconds of light exposure. The final conversion for OBFL (74 ± 1%) was lower compared to CFSE (79 ± 2%) (p < 0.05). ATR-FTIR is a useful method to investigate relative levels of main components in bonding systems and their polymerisation kinetics. Such information is valuable to understanding such behaviour.

Advances in Understanding Hydrogel Lubrication

Since their inception, hydrogels have gained popularity among multiple fields, most significantly in biomedical research and industry. Due to their resemblance to biological tribosystems, a significant amount of research has been conducted on hydrogels to elucidate biolubrication mechanisms and their possible applications as replacement materials. This review is focused on lubrication mechanisms and covers friction models that have attempted to quantify the complex frictional characteristics of hydrogels. From models developed on the basis of polymer physics to the concept of hydration lubrication, assumptions and conditions for their applicability are discussed. Based on previous models and our own experimental findings, we propose the viscous-adhesive model for hydrogel friction. This model accounts for the effects of confinement of the polymer network provided by a solid surface and poroelastic relaxation as well as the (non) Newtonian shear of a complex fluid on the frictional force and quantifies the frictional response of hydrogels-solid interfaces. Finally, the review delineates potential areas of future research based on the current knowledge.

Elasto-plastic-adhesive DEM model for simulating hillslope debris flows: cross comparison with field experiments

This paper presents a Discrete Element-based elasto-plastic-adhesive model which is adapted and tested for producing hillslope debris flows. The numerical model produces three phases of particle contacts: elastic, plastic and adhesion. The model capabilities of simulating different types of cohesive granular flows were tested with different ranges of flow velocities and heights. The basic model parameters, being the basal friction (&amp;varphi;b) and normal restitution coefficient (&amp;varepsilon;n), were calibrated using field experiments of hillslope debris flows impacting two sensors. Simulations of 50 m3 of material were carried out on a channelized surface that is 41 m long and 8 m wide. The calibration process was based on measurements of flow height, flow velocity and the pressure applied to a sensor. Results of the numerical model matched well those of the field data in terms of pressure and flow velocity while less agreement was observed for flow height. Those discrepancies in results were due in part to the deposition of material in the field test which are not reproducible in the model. A parametric study was conducted to further investigate that effect of model parameters and inclination angle on flow height, velocity and pressure. Results of best-fit model parameters against selected experimental tests suggested that a link might exist between the model parameters &amp;varphi;b and &amp;varepsilon;n and the initial conditions of the tested granular material (bulk density and water and fine contents). The good performance of the model against the full-scale field experiments encourages further investigation by conducting lab-scale experiments with detailed variation of water and fine content to better understand their link to the model's parameters.

Polymerization capability of simplified dental adhesives with camphorquinone, phenyl-propanedione and bis-alkyl phosphine photoinitiators

Aim: this study aimed to evaluate the degree of conversion (DC) exhibited by novel formulations of dental adhesive systems including camphorquinone (CQ), phenyl-propanedione (PPD), and bis-alkyl phosphine oxide (BAPO) when cured by mono- or polywave light emitting diodes (LEDs). Methods: an adhesive model was formulated by mixing hydroxyethyl methacrylate (HEMA, 40 wt%) and bisphenol A glycidyl dimethacrylate (BisGMA, 60 wt%) in ethanol (30 wt%). Five materials were then formulated by adding the following photoinitiators: CQ (1 mol%), CQ/PPD (0.5/0.5 mol%), CQ/BAPO (0.5/0.5 mol%), PPD (1 mol%), and BAPO (1 mol%). The DC for each material was measured with Fourier transform infrared spectroscopy. Analysis of variance and Tukey’s post-hoc test were used to analyze the data (p < 0.05). Results: Except for CQ, the photoinitiators provided a significantly higher DC in the adhesive systems following photoactivation with a polywave LED. Conclusion: The use of alternative photoinitiators and a polywave LED improved the DC of the adhesive systems examined.

STRAIN EFFICIENCY OF FRP JACKETS IN FRP-CONFINED CONCRETE-FILLED CIRCULAR STEEL TUBES

The confinement of concrete columns using fiber-reinforced polymer (FRP) jackets or wraps is a popular structural retrofitting technique. More recently, the benefits of FRP confinement of concrete-filled steel tubes have also been explored by researchers. Failure of such FRP-confined concrete-filled steel tubes is usually governed by the rupture of the FRP jacket in the hoop direction. However, the observed FRP hoop strain at failure (i.e. the hoop rupture strain) is typically lower than the ultimate tensile strain from a flat coupon test. Many factors may contribute to this phenomenon, one of which is the geometrical discontinuities at both the starting and finishing ends of the wrapping process commonly used to form an FRP jacket. This paper examines the effect of these geometrical discontinuities on the hoop rupture strain of FRP jackets in FRP-confined concrete-filled circular steel tubes. Detailed finite element (FE) analyses conducted using both linear elastic and elastic-perfectly plastic adhesive constitutive models are presented. Comparison between the FE predictions and available test results shows that the hoop rupture strains of FRP jackets predicted by FE analysis using an elastic-perfectly plastic adhesive model are in reasonable agreement with the test results. The influence of parameters such as the FRP thickness, FRP orthotropy, FRP elastic modulus, adhesive yield strength, adhesive thickness, and column size are examined.