Study on Performance Optimization of Composite Natural Asphalt Modified Gussasphalt Mix

In order to systematically study and develop a type of gussasphalt (GA) mix with superior performance, namely GA-10; the effect of Qingchuan Rock Asphalt (QRA) and Trinidad Lake asphalt (TLA) on the GA-10 mix was assessed based on the study of composite natural asphalt modified gussasphalt (CNAMGA) binder. Various analytical tests were used to evaluate the engineering properties, thermal stability and microstructure of CNAMGA mix. The results indicate that the stability of QRA modified binder and TLA modified binder in the normal temperature range and the high temperature range have been improved, and the temperature susceptibility is reduced. The optimal asphalt–aggregate ratio of the GA mix is determined to be 9.7%, which has good high-temperature stability, low-temperature crack resistance and construction workability. The QRA mix has better high-temperature stability than the TLA mix, whereas the low-temperature cracking resistance of the TLA mix is better than that of the QRA mix. The two kinds of GA-10 mix have similar construction workability. The fact that the abundant fine aggregates wrapped in binder fill the coarse aggregates surface contributes to the better adhesion of the GA asphalt concrete. The distribution of aggregate and binder is relatively uniform with fewer pores, and the overall proportion of the binder is greater than that of aggregate.

Influence of Waste Cork with Thinner on the Rheological Properties of Asphalt

Over the last two decades, the rapid and continued deterioration of the transportation network has been regarded as a major issue. There are many measures that can be taken to reduce this deterioration and improve road specifications, including improving road design, using higher quality materials, and using more efficient construction methods. This study is concerned with three principles: including investigating the impact of using waste paste on the rheological properties of bitumen; the environmental pollution that is a global problem; and the economic benefits as a result of the reusing of waste materials such as corks to produce new reusable materials like Modified-Asphalt. In this research, cork has been melted by thinner and mixed with asphalt to get a good paste with weight percentages of 1%, 3%, 5%, and 7%. After conducting the necessary tests on the samples, it was found that the addition of waste paste to virgin bitumen has softened the bitumen by decreasing the hardness and adhesiveness of the bitumen by increasing penetration with increasing cork paste content. The findings show that the current procedure can be used in cold regions because it requires less hard asphalt than that used in hot regions. It can also be used with natural asphalt, like natural rock asphalt, in various percent to give asphalt with suitable properties for use in roofing and paving roads.

XPS and structural studies of Fe3O4-PTMS-NAS@Cu as a novel magnetic natural asphalt base network and recoverable nanocatalyst for the synthesis of biaryl compounds

In this research, natural asphalt as a mineral carbonuous material was converted to sodium natural asphalt sulfonate (Na-NAS) and, then, was linked to Fe3O4 MNPs in order to synthesize the magnetic nanocatalyst. Afterwards, Cupper (I) and Cu (II) was grafted on Fe3O4-PTMS-NAS. Moreover, it is worth mentioning that the synthesized the novel magnetic nanocatalyst (Fe3O4-PTMS-NAS@Cu) was successfully used in Suzuki and Stille coupling reactions. The Fe3O4-PTMS-NAS@Cu MNPs were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), thermogravimetric analysis (TGA), vibrating sample magnetometry (VSM), inductively coupled plasma (ICP), BET and X-ray photoelectron spectroscopy (XPS) analysis. Besides, sulfonation of natural asphalt, magnetization of catalyst, grafting of Cu (I) and Cu (II) to NAS and catalyst formation were investigated and proved carefully. This nanocatalyst can be comfortably separated from the reaction medium through an external magnetic field and can also be recovered and reused, while maintaining its catalytic activity.

Performance of Asphalt Mixture with Asbuton Based on Marshall Characteristics Compacted at Hot and Cold Temperatures

The use of natural asphalt is an alternative to meet the high demand for oil asphalt. Asbuton is natural asphalt from Buton Island, Indonesia. However, the use of Asbuton is not as easy as oil asphalt because the asphalt it contains is hard. The asphalt-concrete mixture must go through a rejuvenation process for several days before being compacted. This study aims to determine the performance of asphalt-concrete mixture using Asbuton if it is compacted immediately after mixing, without giving time for the rejuvenation process. Compaction is done when the mixture is hot and after the mixture is cold. Compaction of the asphalt-concrete mixture in hot temperature (150ºC), based on mechanical characteristics (stability, flow, and Marshall Quotient), has better performance than that compacted in cold temperature (30ºC). However, compaction in both hot and cold temperatures, based on their volumetric characteristics, does not meet the requirements for use as road pavements. The performance of the asphalt mixture can be improved by giving time in the process of softening the asphalt content in Asbuton

Experimental Investigation on the Use of Selenice Natural Bitumen as an Additive for Pavement Materials

As a good asphalt modifier, natural asphalt has been the focus of more attention because of its low price and ability to improve the performance of modified asphalt. In this paper, the incorporation of a natural asphalt binder in the production of bituminous materials for pavement application in China was experimentally investigated to evaluate the feasibility of such a process and its potential benefits in terms of performance. For this purpose, an asphalt binder conventionally used in the south of China was blended with various percentages of a hard natural binder obtained from the region of Selenice in Albania. The content of Selenice natural bitumen (SNB) was 80.5%, having high molecular weight and the advantages of good stability and compatibility with virgin asphalt. The physical, rheological, and mechanical properties, as well as the modification mechanism of the binder and corresponding asphalt mixture, were evaluated in the laboratory. It was observed that the hard binder improved the response of the binder blend at high and intermediate temperature; this reflected a better stability, improved moisture susceptibility, and enhanced rutting resistance of the mixture. Fluorescence microscopy showed that after dissolving, the size of the SNB modifier became smaller and its distribution was uneven, presenting three forms, granular, agglomerated, and flocculent properties. Chemical test results showed that the modification mechanism of SNB was mainly related to the enhancement of hydrogen bonds and Van der Waals forces caused by sulfoxide and carbonyl along with the stress concentration caused by silica particles. Molecular composition revealed that the proportion of middle molecules has reduced while the proportion of large molecules has increased. It is considered that SNB is a promising low-priced natural modifier with excellent rutting resistance properties. Future research will be focused on the economic analysis, pavement life cycle assessment of SNB modified asphalt, and its application in perpetual pavements.