Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 581
Author(s):  
Abdulhakim A. Almajid

This study is focused on the deformation mechanism and behavior of naturally aged 7010 aluminum alloy at elevated temperatures. The specimens were naturally aged for 60 days to reach a saturated hardness state. High-temperature tensile tests for the naturally aged sample were conducted at different temperatures of 573, 623, 673, and 723 K at various strain rates ranging from 5 × 10−5 to 10−2 s−1. The dependency of stress on the strain rate showed a stress exponent, n, of ~6.5 for the low two temperatures and ~4.5 for the high two temperatures. The apparent activation energies of 290 and 165 kJ/mol are observed at the low, and high-temperature range, respectively. These values of activation energies are greater than those of solute/solvent self-diffusion. The stress exponents, n, and activation energy observed are rather high and this indicates the presence of threshold stress. This behavior occurred as a result of the dislocation interaction with the second phase particles that are existed in the alloy at the testing temperatures. The threshold stress decreases in an exponential manner as temperature increases. The true activation energy was computed by incorporating the threshold stress in the power-law relation between the stress and the strain. The magnitude of the true activation energy, Qt dropped to 234 and 102 kJ/mol at the low and high-temperature range, respectively. These values are close to that of diffusion of Zinc in Aluminum and diffusion of Magnesium in Aluminum, respectively. The Zener–Hollomon parameter for the alloy was developed as a function of effective stress. The data in each region (low and high-temperature region) coalescence in a segment line in each region.


1956 ◽  
Vol 34 (4) ◽  
pp. 489-501 ◽  
Author(s):  
M. W. Lister

The reaction between sodium hypochlorite and potassium cyanate in the presence of sodium hydroxide has been examined. The main products are chloride, and carbonate ions and nitrogen; but, especially if much hypochlorite is present, some nitrate is formed as well. The rate of reaction is proportional to the cyanate and hypochlorite concentrations, but inversely proportional to the hydroxide concentration: the rate constant is 5.45 × 10−4 min.−1 at 65 °C, at an ionic strength of 2.2. The rate constant increases somewhat as the ionic strength rises from 1.7 to 3.5. The effect of temperature makes the apparent activation energy 25 kcal./gm-molecule. The kinetics of the reaction suggest that the slow step is really a reaction of hypochlorous acid and cyanate ions, and possible intermediate products of this reaction are suggested. Allowing for the different extent of hydrolysis of hypochlorite at different temperatures, the true activation energy is found to be 15 kcal./gm-mol., which is consistent with the observed rate of reaction.


The rate of increase in strength of absorption bands of SO has been measured in shock-heated mixtures of sulphur dioxide and argon. Arrhenius-type plots indicate a unimolecular first step of the order d [SO]/d t = k [SO 2 ] [ M ], where [SO], [SO 2 ] and [ M ] are concentrations of [SO], [SO 2 ] and total gas. The apparent activation energy at around 3500 °K is 56 kcal/mole. It is shown that on unimolecular reaction theory, if four harmonic modes of oscillation in the SO 2 molecules contribute to the energy available for transformation, the true activation energy is 74 kcal/mole. This agrees with the energy of excitation to a known triplet state of SO 2 , and on this basis it is suggested that the first steps in the decomposition are SO 2 + M = SO* 2 + M — 73.6 kcal/mole (1) and SO* 2 + SO 2 = SO 3 + SO + 25.6 kcal/mole. (2) Step (2) is spin-allowed, whereas the more direct reaction SO 2 + SO 2 = SO 3 + SO —48 kcal/ mole is spin-forbidden. This is an unusual type of decomposition mechanism and occurs because of the high dissociation energy of SO 2 , because the direct step of low-energy is spinforbidden, and because there is a favourably situated triplet state of the molecule.


Author(s):  
Abdullah S. Alomari ◽  
Nilesh Kumar ◽  
Korukonda L. Murty

To improve efficiency, safety, and reliability of nuclear reactors, structural materials for Gen-IV reactors are being designed and developed. Alloy 709, a 20Cr-25Ni austenitic stainless steel, has superior mechanical properties to be a preferred candidate material for Sodium Fast Reactor structural application. Creep tensile tests were performed at temperatures of 700 °C, 725 °C and 750 °C and range of stresses from 100 MPa to 250 MPa. The apparent stress exponent and activation energy were found to be 10.3±0.4 and 368.6±14.7 kJ/mol. Linear extrapolation method was used to rationalize the higher stress exponent and activation energy relative to the mechanism in power law creep yielding to a true stress exponent of 7.1 ± 0.3 and a true activation energy of 277 ± 12.8 kJ/mol which is close to the lattice diffusion of iron in Fe-20Cr-25Ni. Hence, the lattice diffusion controlled dislocation climb process is believed to be the rate controlling creep deformation mechanism in this range of stresses and temperatures. The appropriate constitutive equation was developed based on the results; however, microstructural evaluations are under investigation to confirm the rate controlling mechanism. In addition, creep tests at higher temperatures and lower stresses are being conducted to extend the stress and strain-rate ranges to observe possible transition in creep mechanism.


1979 ◽  
Vol 22 (87) ◽  
pp. 237-246
Author(s):  
Charles R. Bently

AbstractElectrical resistivity measurements were carried out at station J9 on the Ross Ice Shelf where temperature measurements were available to a depth exceeding three-quarters of the thickness of the shelf. As in a previously published study at a point about 30 km up-steam (Bentley, 1977), the apparent resistivities fit well to a model based upon a steady-state ice shelf with zero bottom balance-rate and an apparent activation energy in the solid ice of 0.15 to 0.25 eV (14–24. kJ mol−1), with preference for the lower end of the range. This model also fits the observed temperature data almost perfectly. Causes of resistivity variation with depth other than the temperature, such as impurity content, metamorphic history, grain size and crystal orientation, probably do not strongly affect the resistivity depth function. Our conclusion is that the true activation energy in the solid ice is less than 0.25 eV (24 kJ mol−1) and perhaps as small as 0.15 eV (14 kJ mol−1), although a reduction by a factor of two or three in the ionic impurity concentration between 50 and 250 m depth cannot be entirely ruled out as a cause of the low apparent temperature effect. A note added in proof indicates that Herron and Langway (in press) have, in fact, reported a decrease in Na+ concentration with increasing depth by a factor of two or three.


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4071
Author(s):  
Yongtao Zhang ◽  
Peng Luo ◽  
Longjiang Niu ◽  
Zhanpeng Lu ◽  
Haitao Yan ◽  
...  

High-temperature plastic flow of heat-resistant 2.25Cr-1Mo-0.25V steel was investigated by hot tension (at 500–650 °C) on a Gleeble 3800 machine. The strain rate of hot tension was set as 0.001–1 s−1. The constitutive relation of the steel was modeled by the introduction of the parameters termed “true activation energy” and “threshold stress”. Then, the kinetics of high-temperature plastic flow was analyzed based on an Arrhenius equation modified by a “threshold stress”. The stress exponent of the modified equation was equal to 5. True activation energy was estimated to be 132 kJ·mol−1. According to the slip band model, the basic mechanism behind the hot deformation of the steel was considered to be dislocation climbing, which was governed by grain boundary diffusion. This model proved to be successful in its analysis of the experimental results of hot tension tests.


2013 ◽  
Vol 554-557 ◽  
pp. 1217-1223 ◽  
Author(s):  
Juan Daniel Muñoz-Andrade

±Abstract. By applying the new quantum mechanics and relativistic mathematical model, proposed by Muñoz-Andrade, on the experimental results reported previously by Aghaie-khafri and Adhami [5], the true activation energy for hot deformation of 15-5 PH stainless steel is obtained over the temperature range of 900-1150°C and strain rates varying between 0.001 and 0.5s-1. It is interesting to contrast the results of this theoretical work with the main results of the apparent activation energy obtained for the same data, but applying the common methodology. It is shown that the true activation energy increased as the hot deformation is increased. Moreover, the true activation energy decreased as the strain rate is increased. The mean value of the true activation energy (289 kJ/mol) at high strain rate, ξ=0.5s-1, for dynamic recrystallization over the temperature range of 900-1150°C is in a closed agreement with the value of activation energy for self-diffusion in γ iron (280 kJ/mol) in dissimilarity of the result of the apparent activation energy (49221 kJ/mol) obtained beforehand by Aghaie-khafri and Adhami [5]. The results obtained in this work by the quantum mechanics and relativistic mathematical model are widely satisfactory; because essentially they are over the crucial limitations of the common methodology to obtain the activation energy at each thermo-mechanical metalworking condition. Keywords: Activation Energy, Hot Deformation, Dynamic Recrystallization, Quantum Mechanics, Special Relativity Theory.


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