Controllable Synthesis of a Highly Ordered Polymeric Structure Assembled from Cobalt-Cluster-based Racemic Supramolecules

2018 ◽  
Vol 13 (15) ◽  
pp. 1915-1919 ◽  
Author(s):  
Hien Duy Mai ◽  
Inme Lee ◽  
Hyojong Yoo
2019 ◽  
Author(s):  
Amalia Rapakousiou ◽  
Alejandro López-moreno ◽  
Belén Nieto-Ortega ◽  
M. Mar Bernal ◽  
Miguel A. Monclús ◽  
...  

We introduce poly(1,6-pyrene terephthalamide) polymer (PPyrTA) as an aromatic polyamide analogue of poly(p-phenylene terephthalamide) (PPTA), also known as Kevlar®. This work shows that the incorporation of polycyclic aromatic pyrene moieties improves drastically the mechanical properties of the polymeric structure, increasing elastic nanoindentation-determined modulus and hardness by factors of 1.9 and 4.3, respectively. Liquid deprotonated dispersions of PPyrTA nanofibers were used as nanoscale building block for producing large-surface, free-standing polymer macroscopic nanofilms. This 2D assembly leads to further significant improvements in reduced modulus and hardness (more than twice) compared to the starting polymer macroscale fibres, due to a better re-organizational arrangement of the PPyrTA nanofibers in the nanofilms, formed under 2D spatial confinement.


2020 ◽  
Vol 10 (2) ◽  
pp. 53-59
Author(s):  
Bharathi M ◽  
Mullaikodi O ◽  
Rajalingam D ◽  
Gnanasekar N ◽  
Kesavan M

A Microsponge (MS) is an extremely interconnected, permeable, polymeric structure that involves permeable microparticles trapping and discharging through the skin for a considerable time period. Drug delivery system (DDS) offer extended discharge with less degradation, improved physical stability along with better tolerance. The main intend of any DDS is to achieve the required amount of drug in plasma to produce the desired therapeutic and non-poisonous effect over a prolonged period of time. Specific methods for preparing MS were reviewed in this current investigation, and their pharmaceutical implementations were signed. MS have major DDS point of interest. It also improves stability, increased flexibility in formulation and increased elegance. In fact, numerous studies have reported that MS supplies are not allergic, mutagenic, and poisonous. MS creativity is used in products such as sunscreen, prescription, cosmetics, and OTC skin care. This inquiry primarily focuses on the different methods used to identify, plan and exploit MS.


CrystEngComm ◽  
2014 ◽  
Vol 16 (5) ◽  
pp. 858-862 ◽  
Author(s):  
You Wang ◽  
Xuecheng Yan ◽  
Jun Chen ◽  
Jinxia Deng ◽  
Ranbo Yu ◽  
...  

2012 ◽  
Vol 55 ◽  
pp. 18-26 ◽  
Author(s):  
Qiang Wang ◽  
Hui Huang Tay ◽  
Zhanhu Guo ◽  
Luwei Chen ◽  
Yan Liu ◽  
...  

2021 ◽  
Vol 313 ◽  
pp. 110857
Author(s):  
Ye Yang ◽  
Lu Xu ◽  
Yuchao Lyu ◽  
Xinmei Liu ◽  
Zifeng Yan

2021 ◽  
Author(s):  
Shuai Wang ◽  
Zheng Lu ◽  
Yuan Fang ◽  
Tian Zheng ◽  
Zidong Zhang ◽  
...  

Rational construction of self-supporting electrode has been extensively investigated in energy conversion and storage. Herein, hierarchical N-doped carbon encapsulated Ni3S2 grown on 3D porous Ni foam (H-Ni3S2@NC/NF) is controllably synthesized...


Author(s):  
Chunli Liu ◽  
Yang Bai ◽  
Ji Wang ◽  
Ziming Qiu ◽  
Huan Pang

Two-dimensional (2D) materials with structures having diverse features are promising for application in energy conversion and storage. A stronger layered orientation can guarantee fast charge transfer along the 2D planes...


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