ChemInform Abstract: High-Temperature Order-Disorder Transition in CoCr2Se4and Trapping Co Disorder in Monoclinic CoCr2Se4: Structural Features of Cu1-xCoxCr2Se4Phases.

ChemInform ◽  
2009 ◽  
Vol 40 (35) ◽  
Author(s):  
Volodymyr Svitlyk ◽  
Yurij Mozharivskyj
2013 ◽  
Vol 197 ◽  
pp. 191-197 ◽  
Author(s):  
Alexey A. Markov ◽  
Elizaveta V. Shalaeva ◽  
Alexander P. Tyutyunnik ◽  
Vasily V. Kuchin ◽  
Mikhail V. Patrakeev ◽  
...  

2021 ◽  
Author(s):  
Xuemei Cheng ◽  
Shuyun Cao

<p>Within orogenic zone and continental extensional area, it often developed metamorphic complex or metamorphic gneiss dome that widely exposed continental mid-lower crustal rocks, which is an ideal place to study exhumation processes of deep-seated metamorphic complex and rheology. The Yuanmou metamorphic complex is located in the south-central part of the "Kangdian Axis" in the western margin of Qiangtang Block and Yangtze Block, which is a part of the anticline of the Sichuan-Yunnan platform. Many research works mainly focus on the discussion of intrusion ages, aeromagnetic anomalies, and polymetallic deposits. However, the exhumation process and mechanism of the Yuanmou metamorphic complex are rarely discussed and still unclear. This study, based on detailed field geological observations, optical microscopy (OM), cathodoluminescence (CL), electron backscatter diffraction (EBSD) and electron probe (EMPA) were performed to illustrate the geological structure features, deformation-metamorphic evolution process and its tectonic significance of Yuanmou metamorphic complex during the exhumation process. All these analysis results indicate that the Yuanmou metamorphic complex generally exhibits a dome structure with deep metamorphic rocks and deformed rocks of varying degrees widely developed. Mylonitic gneiss and granitic intrusions are located in the footwall of the Yuanmou, which have suffered high-temperature shearing. The mylonitic fabrics and mineral stretching lineations in the deformed rock are strongly developed, forming typical S-L or L-shaped structural features. The high-temperature ductile deformation-metamorphism environment is high amphibolite facies, that is, the temperature range is between 620 ~ 690 ℃ and the pressure is between 0.8 ~ 0.95 Gpa. In the deformed rocks closed to the detachment fault, some of the mylonite fabric features are retained, but most of them have experienced a strongly overprinted retrogression metamorphism and deformation. At the top of the detachment fault zone, it is mainly composed of cataclasites and fault gouge. The comprehensive macro- and microstructural characteristics, geometry, kinematics, and mineral (amphibole, quartz and calcite) EBSD textures indicate that the Yuanmou metamorphic complex has undergone a progressive exhumation process during regional extension, obvious high-temperature plastic deformation-metamorphism in the early stage, and superimposed of low-temperature plastic-brittle and brittle deformation in the subsequent stage, which is also accompanied by strong fluid activities during the exhumation process.</p>


2017 ◽  
Vol 87 ◽  
pp. 31-37 ◽  
Author(s):  
Cristina Artini ◽  
Carlo Fanciulli ◽  
Gilda Zanicchi ◽  
Giorgio Andrea Costa ◽  
Riccardo Carlini

1990 ◽  
Vol 45 (7) ◽  
pp. 1084-1090 ◽  
Author(s):  
Klaus Praefcke ◽  
Bernd Kohne ◽  
Andreas Eckert ◽  
Joachim Hempel

Six S,S-dialkyl acetals 2a-f of inosose (1), tripodal in structure, have been synthesized, characterized and investigated by optical microscopy and differential scanning calorimetry (d.s.c.). The four S,S-acetals 2c-f with sufficiently long alkyl chains are thermotropic liquid crystalline; 2 e and 2 f are even dithermomesomorphic. Each of these four inosose derivatives 2c-f exhibits monotropically a most likely cubic mesophase (MI); in addition 2e and 2f show enantiotropically a hexagonal mesophase (Hx) with a non-covalent, supramolecular H-bridge architecture. Whereas the nature of the optically isotropic mesophase MI needs further clarification the stable high temperature mesophase Hx of 2 e and 2 f has been established by a miscibility test using a sugar S,S-dialkyl acetal also tripodal in structure and with a Hx phase proved by X-ray diffraction, but in contrast to 2 with an acyclic hydrophilic part. Similarities of structural features between the Hx-phases of 2e and 2f as well as of other thermotropic and lyotropic liquid crystal systems are discussed briefly.


1993 ◽  
Vol 8 (7) ◽  
pp. 1484-1486 ◽  
Author(s):  
T.R.S. Prasanna ◽  
Alexandra Navrotsky

The heat capacity and the enthalpy associated with the reported oxygen vacancy order-disorder transition in Ba2In2O5 were measured by high temperature step scanning calorimetry. The transition temperature is 1205 ± 2 K. The transition appears first order or nearly so. The enthalpy and entropy of transition are 1.3 kJ/mol and 1.1 J/mol K, respectively. The latter is only 4.8% of the configurational entropy, arising from mixing one vacancy and five oxygens per formula unit, 22.5 J/mol K. This suggests that the transition involves only a small fraction of the oxygen vacancies and implies extensive short-range order, SRO, in the high temperature phase.


2008 ◽  
Vol 403 ◽  
pp. 153-156 ◽  
Author(s):  
Hans Joachim Kleebe ◽  
Heike Störmer

Polymer-derived SiCN glasses with tailored polymer architectures were characterized by TEM and EF-SAED upon pyrolysis at 1000 °C and subsequent annealing. Main emphasis of this work was to verify as to whether the intrinsic amorphous structure of polymer-derived bulk materials exhibits different structural features upon pyrolysis, depending on the functionalities of the pre-ceramic polymer, and whether such characteristic features are maintained upon high-temperature anneal.


2021 ◽  
Vol 7 (5(41)) ◽  
pp. 36-40
Author(s):  
Georgy Yurievich Shahgildyan

Nanoporous glass is a matrix for composite optical materials, in which, by impregnating various activators, it is possible to initiate the appearance of properties uncharacteristic of composite materials. In this case, the main parameter of the structure of nanoporous glass is porosity, which can be controlled by the method of hightemperature sintering. In this work, we have studied the effect of thermal sintering on the structure of porous glass.


1998 ◽  
Vol 180 (2) ◽  
pp. 426-429 ◽  
Author(s):  
Elaine Allan ◽  
Peter Mullany ◽  
Soad Tabaqchali

ABSTRACT Antiserum raised against whole Helicobacter pyloricells identified a novel 94-kDa antigen. The nucleotide sequence of the gene encoding the 94-kDa antigen was determined, and analysis of the deduced amino acid sequence revealed structural features typical of the ClpB ATPase family of stress response proteins. An isogenic H. pylori clpB mutant showed increased sensitivity to high-temperature stress, indicating that the clpB gene product functions as a stress response protein in H. pylori.


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