Effect of maleic anhydride and liquid natural rubber as compatibilizers on the mechanical properties and impact resistance of the NR-NBR blend

2004 ◽  
Vol 15 (4) ◽  
pp. 209-213 ◽  
Author(s):  
Ahmed Mounir ◽  
Nabila A. Darwish ◽  
Adel Shehata
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Natural Rubber ◽  
Impact Resistance ◽  
Liquid Natural Rubber

Phase Morphology, Thermal and Mechanical Properties of Compatibilized Nylon12/Natural Rubber Blends Using PS/MNR

2013 ◽  
Vol 844 ◽  
pp. 53-56
Author(s):  
Saravalee Saengthaveep ◽  
Sadhan C. Jana ◽  
Rathanawan Magaraphan
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Moisture Absorption ◽  
Rubber Particle ◽  
Impact Resistance ◽  
Phase Morphology ◽  
Thermal And Mechanical Properties ◽  
Binary Blend ◽  
Polyamide 12 ◽  
The Impact

To produce a tough material for application demanding high impact resistance and low moisture absorption, melt blending of Nylon12 (Polyamide 12, PA12) and natural rubber (NR) was carried out in a brabender plasticorder at 210 °C with rotor speed of 70 rpm in the presence of polystyrene/maleated natural rubber (PS/MNR) blend as a compatibilizer. The effect of compatibilizer content (1, 3, 5, 7 and 10 phr) on phase morphology, thermal, and mechanical properties of [Nylon12/NR]/[PS/MNR] blends was investigated by using SEM, DSC, and Izod impact tester, respectively. The result revealed that PS/MNR blend improved the compatibility of Nylon12/NR blends efficiently due to the presence of amide linkage at the interfaces from the reaction between the reactive groups of MNR and the NH2 end groups of Nylon12 during mixing. A fine phase morphology (good dispersion and small dispersed phase size of NR domains in Nylon12 matrix) of [Nylon12/NR]/[PS/MNR] blends was observed at the optimum compatibilizer content of 7 phr, relating to the improvement of mechanical property. The impact energy of [Nylon12/NR]/[PS/MNR] blends was 503 J/m higher than that of neat Nylon12 (115 J/m) and Nylon12/NR binary blend (241 J/m) due to the toughening effect of rubber and proper morphology. The melting temperature of all blends did not change obviously from thermal analysis. However, the presence of rubber particle obstructed the crystallization of Nylon12 phase, leading to the decreasing of %crystallinity from 93% to around 70%.

Mechanical Properties of Kenaf Core Sandwich Panel Toughened with Modified Epoxy

2015 ◽  
Vol 1115 ◽  
pp. 275-278
Author(s):  
J.N. Hasnidawani ◽  
Noor Azlina Hassan ◽  
H. Norita ◽  
Zahurin Halim ◽  
A. Zuraida
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Sandwich Panel ◽  
Drop Impact ◽  
Main Element ◽  
Kenaf Fiber ◽  
Kenaf Core ◽  
Liquid Natural Rubber ◽  
Impact Modifier ◽  
Modified Epoxy

Kenaf-core sandwich panels were prepared by hand lay-up method with the optimum characteristics. The aim of this study is to determine the effects of modified epoxy on the mechanical properties of the sandwich panel. Mechanical test such as flexural, drop impact and tensile test were performed to investigate the optimum system of kenaf-core sandwich panel within 0-5wt% of kenaf fiber content. It revealed that the optimum loading of kenaf fiber was at 3wt%. Furthermore, this system was studied with the incorporation of liquid natural rubber (LNR) as impact modifier. All tests have been carried out according to the ASTM 365, C297, C393, and D1736. Each final data point is an average value that has been obtained based on a statistical sampling of four specimens. The main element of core structure is kenaf and the skin used in this study is aluminium type 1100. According to compression, flatwise tensile, three point bending and drop impact tests, 3wt% of LNR content exhibit as an excellent impact modifier, in modifying the mechanical properties due to rubber toughening. In addition of too much liquid natural rubber more than 5wt% was substantially interrupted the system.

Toughening Studies of an Unsaturated Polyester Resin Using Maleated Elastomers

2001 ◽  
Vol 17 (4) ◽  
pp. 205-224 ◽  
Author(s):  
A. Benny Cherian ◽  
Eby Thomas Thachil
Keyword(s):  
Mechanical Properties ◽  
Maleic Anhydride ◽  
Polyester Resin ◽  
Unsaturated Polyester ◽  
Impact Resistance ◽  
Physical Method ◽  
Unsaturated Polyester Resin ◽  
Polyester Resins ◽  
Reinforced Plastic ◽  
Physical And Chemical

Unsaturated polyester resins are extensively used in the fibre-reinforced plastic industry. The fracture toughness and impact resistance of rigid unsaturated polyester can be improved by the incorporation of elastomers by physical and chemical methods. In the physical method, two strategies are adopted. In the first, various masticated elastomers are dissolved in styrene and blended with unsaturated polyester resin. In this study, the mechanical properties of cured blends are compared with the unmodified resin and the performance of nitrile rubber is found to be far superior to all other rubbers considered. In the second approach, elastomers are modified by grafting with maleic anhydride. These maleated elastomers are then dissolved in styrene and blended with polyester resin. Maleic anhydride modified elastomers are found to improve the mechanical properties such as toughness, impact resistance and tensile strength of the cured resin to a greater extent compared to unmodified elastomers.

Mechanical Properties and Environmental Stress Cracking Resistance of Rubber Toughened Polyester/Clay Composite

2012 ◽  
Vol 576 ◽  
pp. 318-321 ◽  
Author(s):  
Bonnia Noor Najmi ◽  
Sahrim Haji Ahmad ◽  
Surip Siti Norasmah ◽  
S.S. Nurul ◽  
Noor Azlina Hassan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Natural Rubber ◽  
Stress Cracking ◽  
Rubber Toughened ◽  
Environmental Stress Cracking ◽  
Liquid Natural Rubber ◽  
Polyester Composite ◽  
Polyester Matrix ◽  
The Impact

Crosslinked polyester clay nanocomposites were prepared by dispersing originically modified montmorillonite in prepromoted polyester resin and subsequently crosslinked using methyl ethyl ketone peroxide catalyst at different clay concentration. Cure process and the mechanical properties of rubber toughened polyester clay composite have been studied. Rubber toughened thermoset polyester composite were prepared by adding 3 per hundred rubber (phr) of liquid natural rubber (LNR) was used in the mixing of producing this composite. Modification of polyester matrix was done due to the brittle problem of polyester composite. Addition of LNR will increase the toughness of composite and produce ductile polyester. Two types of composites were produced which is clay-lnr polyester composite and clay polyester composite. Addition of liquid natural rubber significantly increased the impact strength and flexural properties. Result shows that addition of 6% of clay-lnr composite give good properties on impact, strength and flexural. From the ESCR test, both composites showed good resistance to environmental.

Studies on reinforcing effect of industrial nano silica in chloroprene vulcanizates containing carboxy-terminated liquid natural rubber

2021 ◽  
pp. 009524432110635
Author(s):  
Gopika Sudhakaran ◽  
Shanti A Avirah
Keyword(s):  
Maleic Anhydride ◽  
Natural Rubber ◽  
Cost Effective ◽  
Cross Linking ◽  
Nano Silica ◽  
Rubber Content ◽  
Reinforcing Effect ◽  
Bound Rubber ◽  
Liquid Natural Rubber ◽  
Rubber Filler

Maleic anhydride was chemically attached to depolymerized natural rubber, and the product was named as carboxy-terminated liquid natural rubber (CTNR). The CTNR can act as a potential plasticizer in chloroprene (CR) vulcanizates. This paper describes the use of commercial nano silica (NS) as a promising cost-effective filler, which can enhance the tensile properties and ageing resistance of the CR vulcanizates incorporated with CTNR (CR-CTNR). The enhancement in properties may be attributed to the increased bound-rubber content owing to the large surface area of the nano-sized filler. The characteristics of the NS-filled CR vulcanizates containing CTNR (NS CR-CTNR) were compared with those containing amorphous silica. The NS CR-CTNR vulcanizates showed superior ageing and oil resistance due to the finer rubber filler interaction modified by ionic cross linking.

Effect of Carbon Nanotube on the Mechanical Properties of Compatibilized Polylactic Acid/Natural Rubber Blend

2014 ◽  
Vol 695 ◽  
pp. 273-276 ◽  
Author(s):  
Nor Nisa Balqis Mohammad ◽  
Agus Arsad ◽  
Abdul Razak Rahmat ◽  
S.Z. Mat Des ◽  
Nur Syazana Abdullah Sani
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotube ◽  
Maleic Anhydride ◽  
Impact Strength ◽  
Natural Rubber ◽  
Polylactic Acid ◽  
High Performance ◽  
Flexural Modulus ◽  
Rubber Blend ◽  
Blend Nanocomposites

Polylactic acid (PLA)/ Natural rubber (NR) in the presence of PLA grafted Maleic Anhydride (PLAGMA) as compatibilizer was prepared by the melting blend method. In attempt to achieve high performance of the blend, nanocomposites were formed by incorporating different ratio of carbon nanotube (CNT) in PLA/NR/PLAGMA blend. The effect of CNT content on mechanical properties was investigated. With increasing CNT content, Young’s modulus and flexural modulus were increased firstly and then decreased as CNT was further added. In other hand, impact strength was dropped as expected as the CNT loading was increased.

Physical and Mechanical Properties of Thermoplastic Natural Rubber (TPNR) Nanocomposites

2012 ◽  
Vol 576 ◽  
pp. 394-397 ◽  
Author(s):  
Noor Azlina Hassan ◽  
Hassan Norita ◽  
Sahrim Haji Ahmad ◽  
Rozaidi Rasid ◽  
Hazleen Anuar ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Maleic Anhydride ◽  
Natural Rubber ◽  
Physical And Mechanical Properties ◽  
Melt Blending ◽  
Mixing Parameters ◽  
Blending Method ◽  
Thermoplastic Natural Rubber ◽  
Internal Mixer

Thermoplastic natural rubber (TPNR) nanocomposites were prepared by melt blending method with the optimum mixing parameters (140oC, 100 rpm, 12 min) using internal mixer (Haake 600 P). The aim of this work is to study the effects of organo-montmorillonite (OMMT) on the physical and mechanical properties of TPNR with and without coupling agent (maleic anhydride grafted polyethylene, MA-PE). Significant improvement in tensile strength and modulus of TPNR nanocomposites were obtained with the presence of MA-PE.

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