Ionization mechanism of excitation of heterogeneous chemiluminescence. II

1979 ◽  
Vol 22 (5) ◽  
pp. 519-523 ◽  
Author(s):  
V. V. Styrov ◽  
Yu. I. Tyurin
2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Andreas Kiontke ◽  
Mehrzad Roudini ◽  
Susan Billig ◽  
Amarghan Fakhfouri ◽  
Andreas Winkler ◽  
...  

AbstractMass spectrometry coupled to low-temperature plasma ionization (LTPI) allows for immediate and easy analysis of compounds from the surface of a sample at ambient conditions. The efficiency of this process, however, strongly depends on the successful desorption of the analyte from the surface to the gas phase. Whilst conventional sample heating can improve analyte desorption, heating is not desirable with respect to the stability of thermally labile analytes. In this study using aromatic amines as model compounds, we demonstrate that (1) surface acoustic wave nebulization (SAWN) can significantly improve compound desorption for LTPI without heating the sample. Furthermore, (2) SAWN-assisted LTPI shows a response enhancement up to a factor of 8 for polar compounds such as aminophenols and phenylenediamines suggesting a paradigm shift in the ionization mechanism. Additional assets of the new technique demonstrated here are (3) a reduced analyte selectivity (the interquartile range of the response decreased by a factor of 7)—a significant benefit in non-targeted analysis of complex samples—and (4) the possibility for automated online monitoring using an autosampler. Finally, (5) the small size of the microfluidic SAWN-chip enables the implementation of the method into miniaturized, mobile LTPI probes.


2019 ◽  
Vol 488 (1) ◽  
pp. 803-829 ◽  
Author(s):  
I Moumen ◽  
C Robert ◽  
D Devost ◽  
R P Martin ◽  
L Rousseau-Nepton ◽  
...  

ABSTRACT We present the first optical identification and confirmation of a sample of supernova remnants (SNRs) in the nearby galaxy NGC 3344. Using high spectral and spatial resolution data, obtained with the CFHT imaging Fourier transform spectrograph SITELLE, we identified about 2200 emission line regions, many of which are H ii regions, diffuse ionized gas regions, and also SNRs. Considering the stellar population and diffuse ionized gas background, which are quite important in NGC 3344, we have selected 129 SNR candidates based on four criteria for regions where the emission lines flux ratio [S ii]/H α ≥ 0.4. Emission lines of [O ii] λ3727, H β, [O iii] λλ4959,5007, H α, [N ii] λλ6548,6583, and [S ii] λλ6716,6731 have been measured to study the ionized gas properties of the SNR candidates. We adopted a self-consistent spectroscopic analysis, based on Sabbadin plots and Baldwin, Phillips & Terlevich diagrams, to confirm the shock-heated nature of the ionization mechanism in the candidates sample. With this analysis, we end up with 42 Confirmed SNRs, 45 Probable SNRs, and 42 Less likely SNRs. Using shock models, the confirmed SNRs seem to have a metallicity ranging between Large Magellanic Cloud and 2×solar. We looked for correlations between the size of the confirmed SNRs and their emission lines ratios, their galaxy environment, and their galactocentric distance: We see a trend for a metallicity gradient among the SNR population, along with some evolutionary effects.


2004 ◽  
Vol 22 (3) ◽  
pp. 889-899 ◽  
Author(s):  
S. C. Buchert ◽  
Y. Ogawa ◽  
R. Fujii ◽  
A. P. van Eyken

Abstract. We report on observations of a diverging ion flow along the geomagnetic field that is often seen at the EISCAT Svalbard radar. The flow is upward above the peak of the electron density in the F-region and downward below the peak. We estimate that in such events mass transport along the field line is important for the ionization balance, and that the shape of the F-layer and its ion composition should be strongly influenced by it. Diverging flow typically occurs when there are signatures of direct entry of sheath plasma to the ionosphere in the form of intense soft particle precipitation, and we suggest that it is caused by the ionization and ionospheric electron heating associated with this precipitation. On average, 30% of all events with ion upflow also show significant ion downflow below. Key words.Ionosphere (polar ionosphere; ionization mechanism; plasma temperature and density)


2004 ◽  
Vol 37 (15) ◽  
pp. L297-L304 ◽  
Author(s):  
Lino Ponce ◽  
Richard Taïeb ◽  
Valérie Véniard ◽  
Alfred Maquet
Keyword(s):  

1972 ◽  
Vol 50 (4) ◽  
pp. 474-478 ◽  
Author(s):  
Keith Yates ◽  
Graeme Welch

The pKa values often substituted primary anilines and six substituted tertiary anilines have been determined in 70% DMSO–water. The ΔpKa values relative to those in aqueous solution indicate that DMSO is about 2 log units stronger as a base than H2O. The normal order of basicity (tertiary > primary) is inverted in this solvent system and the Hammett ρ values for the two series provide evidence for a different ionization mechanism than that in water.


2019 ◽  
Vol 35 (S1) ◽  
Author(s):  
Chuping Lee ◽  
Ellen D. Inutan ◽  
Jien Lian Chen ◽  
Mutanu M. Mukeku ◽  
Steffen M. Weidner ◽  
...  

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