scholarly journals Evaluation of fire-retardant properties of edge-jointed lumber from tropical fast-growing woods using cone calorimetry and a standard fire test

2003 ◽  
Vol 49 (3) ◽  
pp. 241-247 ◽  
Author(s):  
Not Available Not Available ◽  
Bambang Subiyanto ◽  
Toshimitsu Hata ◽  
Shuichi Kawai
Keyword(s):  
Fire Test ◽  
Fire Retardant ◽  
Cone Calorimetry ◽  
Fast Growing ◽  
Standard Fire ◽  
Fire Retardant Properties

The fire retardant properties and pyrolysis mechanism of polysulfonamide (PSA) fibers

2017 ◽  
Vol 88 (11) ◽  
pp. 1299-1307 ◽  
Author(s):  
Xiansheng Zhang ◽  
Xiaoning Tang ◽  
Ran Wang ◽  
Rui Wang ◽  
Xiong Yan ◽  
...  
Keyword(s):  
Heat Flux ◽  
Fire Retardant ◽  
Heat Fluxes ◽  
Gas Chromatography Mass Spectrometry ◽  
Cone Calorimetry ◽  
Small Molecular Weight ◽  
Absorption Bands ◽  
Pyrolysis Gas ◽  
Pyrolysis Mechanism ◽  
Fire Retardant Properties

In the present work, the fire retardant properties and pyrolysis mechanism of polysulfonamide (PSA) fibers were investigated by cone calorimetry, scanning electron microscopy, Fourier transform infrared spectroscopy (FTIR), and pyrolysis-gas chromatography-mass spectrometry. The fire retardant behaviors were reflected by the cone calorimeter data under heat fluxes of 35, 50, and 75 kW/m2. This demonstrated that, when exposed to higher heat flux, PSA fibers were ignited easier and burned more completely, indicated by lower time to ignition and higher peak heat release rate. It was further confirmed from the morphology of the residual chars that the original fiber shape can be kept at lower heat flux, but it changed into coherent carbonaceous chars with holes at higher heat flux. In comparison of the FTIR spectra of raw fibers with residual chars, it was noticed that upon heating, the amide linkage was more liable to be broken than that of sulfone groups. Additionally, with elevated heat flux, most of the absorption bands vanished and transformed into the typical feature of carbonaceous material. The pyrolysis products showed that some volatile products with small molecular weight, such as benzene, benzonitrile, and aniline, can be created at high temperature, which can be easily ignited. With this research, the fire retardant properties of PSA fibers are revealed and the corresponding pyrolysis mechanism is proposed, which can guide its application in practice.

scholarly journals PET Foams Surface Treated with Graphene Nanoplatelets: Evaluation of Thermal Resistance and Flame Retardancy

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 501
Author(s):  
Samuele Matta ◽  
Laura Giorgia Rizzi ◽  
Alberto Frache
Keyword(s):  
Fire Retardant ◽  
Graphene Nanoplatelets ◽  
Penetration Test ◽  
Cone Calorimetry ◽  
Sem Images ◽  
Morphological Effect ◽  
Liquid Solutions ◽  
Fire Retardant Properties ◽  
Combustion Tests ◽  
Scanning Electron

In this work, fire-retardant systems consisting of graphene nanoplatelets (GNPs) and dispersant agents were designed and applied on polyethylene terephthalate (PET) foam. Manual deposition from three different liquid solutions was performed in order to create a protective coating on the specimen’s surface. A very low amount of coating, between 1.5 and 3.5 wt%, was chosen for the preparation of coated samples. Flammability, flame penetration, and combustion tests demonstrated the improvement provided to the foam via coating. In particular, specimens with PSS/GNPs coating, compared to neat foam, were able to interrupt the flame during horizontal and vertical flammability tests and led to longer endurance times during the flame penetration test. Furthermore, during cone calorimetry tests, the time to ignition (TTI) increased and the peak of heat release rate (pHRR) was drastically reduced by up to 60% compared to that of the uncoated PET foam. Finally, ageing for 48 and 115 h at 160 °C was performed on coated specimens to evaluate the effect on flammability and combustion behavior. Scanning electron microscopy (SEM) images proved the morphological effect of the heat treatment on the surface, showing that the coating was uniformly distributed. In this case, fire-retardant properties were enhanced, even if fewer GNPs were used.

scholarly journals Layered Clay–Graphene Oxide Nanohybrids for the Reinforcement and Fire-Retardant Properties of Polyurea Matrix

Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 66
Author(s):  
Mădălina Ioana Necolau ◽  
Celina Maria Damian ◽  
Radu Claudiu Fierăscu ◽  
Anita-Laura Chiriac ◽  
George Mihail Vlăsceanu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Great Influence ◽  
Fire Retardant ◽  
Mechanical Analysis ◽  
Cone Calorimetry ◽  
Exchange Method ◽  
Functionalized Graphene Oxide ◽  
Ct Analysis ◽  
Fire Retardant Properties ◽  
Layered Clay

Nanostructures are more and more evolved through extensive research on their functionalities; thus, the aim of this study was to obtain layered clay–graphene oxide nanohybrids with application as reinforcing agents in polyurea nanocomposites with enhanced thermal–mechanical and fire-retardant properties. Montmorillonite (MMT) was combined with graphene oxide (GO) and amine functionalized graphene oxide (GOD) through a new cation exchange method; the complex nanostructures were analyzed through FTIR and XPS to assess ionic interactions between clay layers and GO sheets by C1s deconvolution and specific C sp3, respective/ly, C-O secondary peaks appearance. The thermal decomposition of nanohybrids showed a great influence of MMT layers in TGA, while the XRD patterns highlighted mutual MMT and GO sheets crystalline-structure disruption by the d (002) shift 2θ = 6.29° to lower values. Furthermore, the nanohybrids were embedded in the polyurea matrix, and the thermo-mechanical analysis gave information about the stiffness of MMT–GO nanocomposites, while GOD insertion within the MMT layers resulted in a 30 °C improvement in the Tg of hard domains, as shown in the DSC study. The micro CT analysis show good dispersion of inorganic structures within the polyurea, while the SEM fracture images revealed smooth surfaces. Cone calorimetry was used to evaluate fire-retardant properties through limiting the oxygen index, and MMT–GOD based nanocomposites showed a 35.4% value.

scholarly journals Experimental Study on Delaying the Failure Time of In-Service Cables in Trays by Using Fire-Retardant Coatings

2021 ◽  
Vol 11 (6) ◽  
pp. 2521
Author(s):  
Feng Jiang ◽  
Jianyong Liu ◽  
Wei Yuan ◽  
Jianbo Yan ◽  
Lin Wang ◽  
...  
Keyword(s):  
Fire Resistance ◽  
Failure Time ◽  
Fire Retardant ◽  
Resistance Test ◽  
Control Group ◽  
Engineering Practice ◽  
Standard Fire ◽  
Oil Storage ◽  
Fire Resistance Test ◽  
Test Furnace

Improving the fire resistance of the key cables connected to firefighting and safety equipment is of great importance. Based on the engineering practice of an oil storage company, this study proposes a modification scheme that entails spraying fire-retardant coatings on the outer surface of a cable tray to delay the failure times of the cables in the tray. To verify the effect, 12 specimens were processed using five kinds of fire-retardant coatings and two kinds of fire-resistant cotton to coat the cable tray. The specimens were installed in the vertical fire resistance test furnace. For the ISO 834 standard fire condition, a fire resistance test was carried out on the specimens. The data for the surface temperature and the insulation resistance of the cables in trays were collected, and the fireproof effect was analyzed. The results showed that compared with the control group, the failure time of the cable could be delayed by 1.57–14.86 times, and the thicker the fire-retardant coatings were, the better the fireproof effect was. In general, the fire protection effect of the fire-retardant coating was better than that of the fire-resistant cotton.

The Use of Sol-Gel Method for Obtaining Fire-Resistant Elastic Coatings on Cotton Fabrics

2021 ◽  
Vol 1038 ◽  
pp. 468-479
Author(s):  
Olga Skorodumova ◽  
Olena Tarakhno ◽  
Olena Chebotaryova ◽  
Oleg Bezuglov ◽  
Fatih Mehmet Emen
Keyword(s):  
Thin Layer ◽  
Fire Protection ◽  
Sol Gel ◽  
Fire Retardant ◽  
Cotton Fabrics ◽  
Covalent Bonds ◽  
Silica Coatings ◽  
Factors Influencing ◽  
Fire Retardant Properties ◽  
Main Factors

Based on the generalization of research results on the processes of obtaining SiO2 sols using tetraethoxysilane and ethyl silicates, the main factors influencing the elasticity of silica coatings on cotton fabrics and their fire-retardant properties are considered. The possibility of forming covalent bonds between the functional groups of cellulose, gel coating and flame retardant layer is considered, which explains the strong fixation of a thin layer of coating on the fibers of the fabric and improve its fire protection. The use of the developed compositions for fire-retardant elastic coatings based on ethyl silicate allows to increase the time of complete burning of cotton from 30s (untreated fabric) to 600s (treated with binary coating).

Performance of CHS T-joints in a standard fire test

2012 ◽  
pp. 599-606 ◽  
Author(s):  
M Nguyen ◽  
K Tan ◽  
T Fung
Keyword(s):  
Fire Test ◽  
T Joints ◽  
Standard Fire

scholarly journals Enhancement of Wood Biological Resistance and Fire Retardant Properties after Laccase Assisted Enzymatic Grafting

Forests ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 1102
Author(s):  
Cristian Bolaño ◽  
Sabrina Palanti ◽  
Luigi Benni ◽  
Diego Moldes
Keyword(s):  
Silver Nanoparticles ◽  
Flame Retardant ◽  
Toxic Substance ◽  
Treated Wood ◽  
Fire Retardant ◽  
Wood Preservative ◽  
Decay Resistance ◽  
Kraft Lignin ◽  
Fire Retardant Properties ◽  
Wood Surfaces

Several treatments of wood, based on laccase assisted grafting, were evaluated in this paper. Firstly, the efficacy of lignosulfonate and kraft lignin from Eucalyptus spp. as a wood preservative was assessed. Both ligno products were anchored to wood surfaces via laccase treatment in order to avoid leaching. Moreover, some of these wood preservative treatments were completed with the addition of silver nanoparticles. For comparison, a commercial product was also analyzed in terms of its fungal decay resistance during surface application, in accordance to use class 3, CEN EN 335. Secondly, the anchoring of a flame retardant based on tetrabromobisphenol-A (TBBPA) was attempted, to limit the dispersion of this toxic substance from treated wood. In both cases, kraft lignin and lignosulfonate showed an improvement in wood durability, even after leaching. However, the addition of silver nanoparticles did not improve the efficacy. On the other hand, the efficacy of TBBPA as a flame retardant was not improved by grafting it with laccase treatment or by adding O2, a co-factor of laccase.

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