scholarly journals A Novel Modeling Approach to Stochastically Evaluate the Impact of Pore Network Geometry, Chemistry and Topology on Fluid Transport

2020 ◽  
Author(s):  
Maria Apostolopoulou ◽  
Michail Stamatakis ◽  
Alberto Striolo ◽  
Ron Dusterhoft ◽  
Rob Hull ◽  
...  
Keyword(s):  
Transport Properties ◽  
Fluid Transport ◽  
Pore Network ◽  
Gas Production ◽  
Systematic Evaluation ◽  
Pore Throat ◽  
Pore Networks ◽  
Throat Width ◽  
Width Distribution ◽  
The Impact

AbstractFine-grained sandstones, siltstones, and shales have become increasingly important to satisfy the ever-growing global energy demands. Of particular current interest are shale rocks, which are mudstones made up of organic and inorganic constituents of varying pore sizes. These materials exhibit high heterogeneity, low porosity, varying chemical composition and low pore connectivity. Due to the complexity and the importance of such materials, many experimental, theoretical and computational efforts have attempted to quantify the impact of rock features on fluids diffusivity and ultimately on permeability. In this study, we introduce a stochastic kinetic Monte Carlo approach developed to simulate fluid transport. The features of this approach allow us to discuss the applicability of 2D vs 3D models for the calculation of transport properties. It is found that a successful model should consider realistic 3D pore networks consisting of pore bodies that communicate via pore throats, which however requires a prohibitive amount of computational resources. To overcome current limitations, we present a rigorous protocol to stochastically generate synthetic 3D pore networks in which pore features can be isolated and varied systematically and individually. These synthetic networks do not correspond to real sample scenarios but are crucial to achieve a systematic evaluation of the pore features on the transport properties. Using this protocol, we quantify the contribution of the pore network’s connectivity, porosity, mineralogy, and pore throat width distribution on the diffusivity of supercritical methane. A sensitivity analysis is conducted to rank the significance of the various network features on methane diffusivity. Connectivity is found to be the most important descriptor, followed by pore throat width distribution and porosity. Based on such insights, recommendations are provided on possible technological approaches to enhance fluid transport through shale rocks and equally complex pore networks. The purpose of this work is to identify the significance of various pore network characteristics using a stochastic KMC algorithm to simulate the transport of fluids. Our findings could be relevant for applications that make use of porous media, ranging from catalysis to radioactive waste management, and from environmental remediation to shale gas production.

scholarly journals Mesoscale structure, mechanics, and transport properties of source rocks’ organic pore networks

2018 ◽  
Vol 115 (49) ◽  
pp. 12365-12370 ◽  
Author(s):  
Jeremie Berthonneau ◽  
Amaël Obliger ◽  
Pierre-Louis Valdenaire ◽  
Olivier Grauby ◽  
Daniel Ferry ◽  
...  
Keyword(s):  
Organic Matter ◽  
Transport Properties ◽  
Fluid Transport ◽  
Lattice Models ◽  
Source Rocks ◽  
Elastic Response ◽  
Limiting Factor ◽  
Pore Networks ◽  
Thermal Maturation ◽  
Hydrocarbon Transport

Organic matter is responsible for the generation of hydrocarbons during the thermal maturation of source rock formation. This geochemical process engenders a network of organic hosted pores that governs the flow of hydrocarbons from the organic matter to fractures created during the stimulation of production wells. Therefore, it can be reasonably assumed that predictions of potentially recoverable confined hydrocarbons depend on the geometry of this pore network. Here, we analyze mesoscale structures of three organic porous networks at different thermal maturities. We use electron tomography with subnanometric resolution to characterize their morphology and topology. Our 3D reconstructions confirm the formation of nanopores and reveal increasingly tortuous and connected pore networks in the process of thermal maturation. We then turn the binarized reconstructions into lattice models including information from atomistic simulations to derive mechanical and confined fluid transport properties. Specifically, we highlight the influence of adsorbed fluids on the elastic response. The resulting elastic energy concentrations are localized at the vicinity of macropores at low maturity whereas these concentrations present more homogeneous distributions at higher thermal maturities, due to pores’ topology. The lattice models finally allow us to capture the effect of sorption on diffusion mechanisms with a sole input of network geometry. Eventually, we corroborate the dominant impact of diffusion occurring within the connected nanopores, which constitute the limiting factor of confined hydrocarbon transport in source rocks.

scholarly journals Comparing organic-hosted and intergranular pore networks: topography and topology in grains, gaps and bubbles

2018 ◽  
Vol 484 (1) ◽  
pp. 241-253 ◽  
Author(s):  
Matthew Andrew
Keyword(s):  
Coordination Number ◽  
Positive Curvature ◽  
Network Connectivity ◽  
Pore Network ◽  
Pore Shape ◽  
Pore Networks ◽  
Geological Processes ◽  
Shale Reservoirs ◽  
Curvature Distribution ◽  
The Impact

AbstractThe relationship between pore structures was examined using a combination of normalized topographical and topological measurements in two qualitatively different pore systems: organic-hosted porosity, common in unconventional shale reservoirs; and intergranular porosity, common in conventional siliciclastic reservoirs. The organic-hosted pore network was found to be less well connected than the intergranular pore network, with volume-weighted coordination numbers of 1.16 and 8.14 for organic-hosted and intergranular pore systems, respectively. This disparity in coordination number was explained by differences in the pore shapes that are caused by variations in the geological processes associated with the generation of the pore network. Measurements of pore shape showed that the pores in the organic-hosted network were both significantly more spherical and had a more positive curvature distribution than the pores present within the intergranular network. The impact of such changes in pore shape on pore-network connectivity was examined by creating a suite of synthetic pore geometries using both erosion/dilation of the existing network and image-guided object-based methods. Coordination number, Euler characteristic and aggregate porosity analyses performed on these synthetic networks showed that organic-type pore networks become connected at much higher aggregate porosities (35–50%) than intergranular-type pore networks (5–10%).

scholarly journals Fast radio burst detection in the presence of coloured noise

2021 ◽  
Vol 503 (4) ◽  
pp. 5223-5231
Author(s):  
C F Zhang ◽  
J W Xu ◽  
Y P Men ◽  
X H Deng ◽  
Heng Xu ◽  
...  
Keyword(s):  
False Alarm ◽  
Radio Burst ◽  
Pulse Width ◽  
False Alarm Probability ◽  
False Positives ◽  
Parameter Distribution ◽  
Correlated Noise ◽  
Width Distribution ◽  
Fast Radio Burst ◽  
The Impact

ABSTRACT In this paper, we investigate the impact of correlated noise on fast radio burst (FRB) searching. We found that (1) the correlated noise significantly increases the false alarm probability; (2) the signal-to-noise ratios (S/N) of the false positives become higher; (3) the correlated noise also affects the pulse width distribution of false positives, and there will be more false positives with wider pulse width. We use 55-h observation for M82 galaxy carried out at Nanshan 26m radio telescope to demonstrate the application of the correlated noise modelling. The number of candidates and parameter distribution of the false positives can be reproduced with the modelling of correlated noise. We will also discuss a low S/N candidate detected in the observation, for which we demonstrate the method to evaluate the false alarm probability in the presence of correlated noise. Possible origins of the candidate are discussed, where two possible pictures, an M82-harboured giant pulse and a cosmological FRB, are both compatible with the observation.

scholarly journals Transport Properties of Natural and Artificial Smart Fabrics Impregnated by Graphite Nanomaterial Stacks

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1018
Author(s):  
Carola Esposito Corcione ◽  
Francesca Ferrari ◽  
Raffaella Striani ◽  
Antonio Greco
Keyword(s):  
Electrical Conductivity ◽  
Transport Properties ◽  
Low Cost ◽  
Empirical Relationship ◽  
Theoretical Models ◽  
Expandable Graphite ◽  
Easy Method ◽  
Textile Materials ◽  
Fabric Materials ◽  
The Impact

In this work, we studied the transport properties (thermal and electrical conductivity) of smart fabric materials treated with graphite nanomaterial stacks–acetone suspensions. An innovative and easy method to produce graphite nanomaterial stacks–acetone-based formulations, starting from a low-cost expandable graphite, is proposed. An original, economical, fast, and easy method to increase the thermal and electrical conductivity of textile materials was also employed for the first time. The proposed method allows the impregnation of smart fabric materials, avoiding pre-coating of the fibers, thus reducing costs and processing time, while obtaining a great increase in the transport properties. Two kinds of textiles, cotton and Lycra®, were selected as they represent the most used natural and artificial fabrics, respectively. The impact of the dimensions of the produced graphite nanomaterial stacks–acetone-based suspensions on both the uniformity of the treatment and the transport properties of the selected textile materials was accurately evaluated using several experimental techniques. An empirical relationship between the two transport properties was also successfully identified. Finally, several theoretical models were applied to predict the transport properties of the developed smart fabric materials, evidencing a good agreement with the experimental data.

scholarly journals A double-blind, placebo-controlled, cross-over study to establish the bifidogenic effect of a very-long-chain inulin extracted from globe artichoke (Cynara scolymus) in healthy human subjects

2010 ◽  
Vol 104 (7) ◽  
pp. 1007-1017 ◽  
Author(s):  
Adele Costabile ◽  
Sofia Kolida ◽  
Annett Klinder ◽  
Eva Gietl ◽  
Michael Bäuerlein ◽  
...  
Keyword(s):  
Gastrointestinal Symptoms ◽  
Gas Production ◽  
Globe Artichoke ◽  
Daily Consumption ◽  
Healthy Human ◽  
Double Blind ◽  
Cynara Scolymus ◽  
The Impact ◽  
Long Chain

There is growing interest in the use of inulins as substrates for the selective growth of beneficial gut bacteria such as bifidobacteria and lactobacilli because recent studies have established that their prebiotic effect is linked to several health benefits. In the present study, the impact of a very-long-chain inulin (VLCI), derived from globe artichoke (Cynara scolymus), on the human intestinal microbiota compared with maltodextrin was determined. A double-blind, cross-over study was carried out in thirty-two healthy adults who were randomised into two groups and consumed 10 g/d of either VLCI or maltodextrin, for two 3-week study periods, separated by a 3-week washout period. Numbers of faecal bifidobacteria and lactobacilli were significantly higher upon VLCI ingestion compared with the placebo. Additionally, levels ofAtopobiumgroup significantly increased, whileBacteroides–Prevotellanumbers were significantly reduced. No significant changes in faecal SCFA concentrations were observed. There were no adverse gastrointestinal symptoms apart from a significant increase in mild and moderate bloating upon VLCI ingestion. These observations were also confirmed byin vitrogas production measurements. In conclusion, daily consumption of VLCI extracted from globe artichoke exerted a pronounced prebiotic effect on the human faecal microbiota composition and was well tolerated by all volunteers.

The impact of porosity on organic matter cycling in a two-dimensional porous medium 

2021 ◽  
Author(s):  
Hanbang Zou ◽  
Pelle Ohlsson ◽  
Edith Hammer
Keyword(s):  
Porous Medium ◽  
Organic Matter ◽  
Carbon Sequestration ◽  
Soil Carbon ◽  
Pore Network ◽  
Pore Scale ◽  
Decomposition Of Organic Matter ◽  
Organic Matter Cycling ◽  
The Impact

<p>Carbon sequestration has been a popular research topic in recent years as the rapid elevation of carbon emission has significantly impacted our climate. Apart from carbon capture and storage in e.g. oil reservoirs, soil carbon sequestration offers a long term and safe solution for the environment and human beings. The net soil carbon budget is determined by the balance between terrestrial ecosystem sink and sources of respiration to atmospheric carbon dioxide. Carbon can be long term stored as organic matters in the soil whereas it can be released from the decomposition of organic matter. The complex pore networks in the soil are believed to be able to "protect" microbial-derived organic matter from decomposition. Therefore, it is important to understand how soil structure impacts organic matter cycling at the pore scale. However, there are limited experimental studies on understanding the mechanism of physical stabilization of organic matter. Hence, my project plan is to create a heterogeneous microfluidic porous microenvironment to mimic the complex soil pore network which allows us to investigate the ability of organisms to access spaces starting from an initial ecophysiological precondition to changes of spatial accessibility mediated by interactions with the microbial community.</p><p>Microfluidics is a powerful tool that enables studies of fundamental physics, rapid measurements and real-time visualisation in a complex spatial microstructure that can be designed and controlled. Many complex processes can now be visualized enabled by the development of microfluidics and photolithography, such as microbial dynamics in pore-scale soil systems and pore network modification mimicking different soil environments – earlier considered impossible to achieve experimentally. The microfluidic channel used in this project contains a random distribution of cylindrical pillars of different sizes so as to mimic the variations found in real soil. The randomness in the design creates various spatial availability for microbes (preferential flow paths with dead-end or continuous flow) as an invasion of liquids proceeds into the pore with the lowest capillary entry pressure. In order to study the impact of different porosity in isolation of varying heterogeneity of the porous medium, different pore size chips that use the same randomly generated pore network is created. Those chips have the same location of the pillars, but the relative size of each pillar is scaled. The experiments will be carried out using sterile cultures of fluorescent bacteria, fungi and protists, synthetic communities of combinations of these, or a whole soil community inoculum. We will quantify the consumption of organic matter from the different areas via fluorescent substrates, and the bio-/necromass produced. We hypothesise that lower porosity will reduce the net decomposition of organic matter as the narrower pore throat limits the access, and that net decomposition rate at the main preferential path will be higher than inside branches</p>

Impact of the Cluster Spacing on Hydraulic Fracture Conductivity and Productivity of a Marcellus Shale Horizontal Well

2021 ◽  
Author(s):  
Mohamed El Sgher ◽  
Kashy Aminian ◽  
Ameri Samuel
Keyword(s):  
Hydraulic Fracture ◽  
Marcellus Shale ◽  
Technical Information ◽  
Gas Production ◽  
Production Performance ◽  
Valuable Insight ◽  
Fracture Conductivity ◽  
Fracture Properties ◽  
Gas Recovery ◽  
The Impact

Abstract The objective of this study was to investigate the impact of the hydraulic fracturing treatment design, including cluster spacing and fracturing fluid volume on the hydraulic fracture properties and consequently, the productivity of a horizontal Marcellus Shale well with multi-stage fractures. The availability of a significant amount of advanced technical information from the Marcellus Shale Energy and Environment Laboratory (MSEEL) provided an opportunity to perform an integrated analysis to gain valuable insight into optimizing fracturing treatment and the gas recovery from Marcellus shale. The available technical information from a horizontal well at MSEEL includes well logs, image logs (both vertical and lateral), diagnostic fracture injection test (DFIT), fracturing treatment data, microseismic recording during the fracturing treatment, production logging data, and production data. The analysis of core data, image logs, and DFIT provided the necessary data for accurate prediction of the hydraulic fracture properties and confirmed the presence and distribution of natural fractures (fissures) in the formation. Furthermore, the results of the microseismic interpretation were utilized to adjust the stress conditions in the adjacent layers. The predicted hydraulic fracture properties were then imported into a reservoir simulation model, developed based on the Marcellus Shale properties, to predict the production performance of the well. Marcellus Shale properties, including porosity, permeability, adsorption characteristics, were obtained from the measurements on the core plugs and the well log data. The Quanta Geo borehole image log from the lateral section of the well was utilized to estimate the fissure distribution s in the shale. The measured and published data were utilized to develop the geomechnical factors to account for the hydraulic fracture conductivity and the formation (matrix and fissure) permeability impairments caused by the reservoir pressure depletion during the production. Stress shadowing and the geomechanical factors were found to play major roles in production performance. Their inclusion in the reservoir model provided a close agreement with the actual production performance of the well. The impact of stress shadowing is significant for Marcellus shale because of the low in-situ stress contrast between the pay zone and the adjacent zones. Stress shadowing appears to have a significant impact on hydraulic fracture properties and as result on the production during the early stages. The geomechanical factors, caused by the net stress changes have a more significant impact on the production during later stages. The cumulative gas production was found to increase as the cluster spacing was decreased (larger number of clusters). At the same time, the stress shadowing caused by the closer cluster spacing resulted in a lower fracture conductivity which in turn diminished the increase in gas production. However, the total fracture volume has more of an impact than the fracture conductivity on gas recovery. The analysis provided valuable insight for optimizing the cluster spacing and the gas recovery from Marcellus shale.

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