Stability of titanium-aluminium nitride (Ti2AlN) at high pressure and high temperatures

2011 ◽  
Vol 26 (5) ◽  
pp. 914-919 ◽  
Author(s):  
Pei An ◽  
Zhilei He ◽  
Jiaqian Qin ◽  
Ziyang Li ◽  
Yongjun Li ◽  
...  

During the researches upon high-pressure explosions of carbonic oxide-air, hydrogen-air, etc., mixtures, which have been described in the previous papers of this series, a mass of data has been accumulated relating to the influence of density and temperature upon the internal energy of gases and the dissociation of steam and carbon dioxide. Some time ago, at Prof. Bone’s request, the author undertook a systematic survey of the data in question, and the present paper summarises some of the principal results thereof, which it is hoped will throw light upon problems interesting alike to chemists, physicists and internal-combustion engineers. The explosion method affords the only means known at present of determining the internal energies of gases at very high temperatures, and it has been used for this purpose for upwards of 50 years. Although by no means without difficulties, arising from uncertainties of some of the assumptions upon which it is based, yet, for want of a better, its results have been generally accepted as being at least provisionally valuable. Amongst the more recent investigations which have attracted attention in this connection should be mentioned those of Pier, Bjerrum, Siegel and Fenning, all of whom worked at low or medium pressures.


1992 ◽  
Vol 06 (19) ◽  
pp. 1153-1158 ◽  
Author(s):  
MANUEL NÚÑEZ-REGUEIRO

The high pressure experiments done on fullerenes are reviewed. C 60 has found to be stable up to about 20 GPa at room temperature and hydrostatic conditions. Application of stronger, or non-hydrostatic, pressures at room temperature can induce the formation of a partially sp3 bonded phase, that apparently conserves the fullerene cage. Extreme non-hydrostatic compressions above about 15 GPa can, though, break down the cage and produce amorphous or cubic diamond. Destruction of the cage at high temperatures has also been observed, but the resulting product is amorphous sp2 material. A preliminary pressure-temperature phase diagram for C 60 is proposed.


Author(s):  
Tohru Suwa ◽  
Tetuko Kurniawan

Due to various reasons, the concepts of thermodynamics are not easy to grasp for undergraduate students. One of the major reasons is that the students are mostly unfamiliar with the thermodynamics devices discussed in the courses. Offering courses with experiments is an effective approach to solve this issue. However, it is not practical or possible for universities to own devices that operate at high temperatures and with high pressure fluids. With the cooperation of a nearby electric company, undergraduate students of a thermodynamics course from the Department of Mechanical Engineering measured thermal performances of a commercial combined cycle and its sub-systems at the President University. After learning about the theory of thermal cycles, the students analyzed the thermal performances of actual thermodynamics cycles. Subsequently, they analyzed the thermal efficiency improvements when reheating or regeneration is applied to the simple Rankine cycle in the combined cycle. At the end of the course, the students gave presentations before the electric company’s management and engineering personnel, akin to professional engineers. This course is structured to familiarize undergraduate students with thermodynamics cycles and devices.


1982 ◽  
Vol 46 (340) ◽  
pp. 329-336 ◽  
Author(s):  
Jørgen Gutzon Larsen

AbstractScattered dunite and lherzolite nodules occur in one of the youngest basanitoid lavas on Ubekendt Ejland. They have protogranular to porphyroclastic textures. The dunites are composed of olivine (Fo93.2−91.9b), enstatite (En93.4−92.8) low in Al2O3 and CaO, and Cr-spinel (61-13% Cr2O3 and 3–55% Al2O3). A solitary lherzolite module has olivine (Fo94.7–94.1), enstatite (En94.7–94.2), Cr-rich spinel, Ti-phlogopite (11% TiO2), and hyalophane. Petrographic evidence suggests that the two latter minerals have not been introduced by magmatic injection from the host in spite of the refractory nature of the coexisting phases, and metasomatic processes prior to the last deformation are therefore indicated. Partial melting of such mantle material would presumably produce small amounts of alkaline liquids even at very high temperatures. Another lherzolite nodule from a lamprophyre dyke has minerals with lower Mg/(Mg + Fe) ratios which, together with its preserved igneous textures, suggest a high-pressure precipitate. The lowest well-esablished equilibrium temperatures of 700–830°C for both dunites and lherzolites indicate a pressure regime of 12-17 kbar, according to the oceanic geotherm, whereas unrealistically high pressure (20–5 kbar) are suggested using the continental shield geotherm.


Crystals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 448
Author(s):  
Vladimir Filonenko ◽  
Pavel Zinin ◽  
Igor Zibrov ◽  
Alexander Anokhin ◽  
Elena Kukueva ◽  
...  

We synthesized star-shaped pentagonal microcrystals of boron carbide with an extremely low carbon content (~5%), from m-carborane under high pressure (7 GPa) and high temperature (1370–1670 K). These crystals have five-fold symmetry and grow in the shape of stars. A 5-fold symmetry in large micron-sized crystals is extremely rare making this a striking observation.


2015 ◽  
Vol 787 ◽  
pp. 664-668 ◽  
Author(s):  
K. Anand ◽  
M.V. Siddharth ◽  
K.S. Vijay Sekar ◽  
S. Suresh Kumar

Composite materials are in-homogenous, anisotropic and cause high tool wear at high cutting speeds in machining. Industrial practices worldwide reveal a need to use high speed machining to achieve the desired material removal rate, surface finish and to reduce cost cutting. In this research work, impact of turning glass fibre reinforced polymer tube with two contrasting turning tool inserts such as titanium aluminium nitride and tungsten carbide have been analysed. The turning was conducted at low to high cutting conditions up to spindle speeds of 2000 rpm and feed rate of 0.446mm/rev. The cutting force, feed force were acquired with a strain gauge based dynamometer, the chip cross section was observed using scanning electron microscopy and the temperature was sensed with a infra red thermo sensor. The advanced titanium aluminium nitride insert shows better machining characteristics across cutting speeds.


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