scholarly journals Ultrasonic oscillations induced property development of water-bentonite suspension containing sulfonated wood coal

2021 ◽  
Vol 11 (5) ◽  
pp. 2179-2190
Author(s):  
Wen-Yu Guo ◽  
Bo Peng

AbstractDuring drilling fluid preparation, ultrasonic oscillations were introduced into water-bentonite suspension incorporating sulfonated wood coal (SMC) by a specially designed device. The influences of ultrasonic oscillations on fluid loss and rheological performances of the drilling fluid as well as mechanism of ultrasonic action were investigated. The experimental results showed that the filtrate volume decreased with the increase of ultrasonic time till a certain extent and then leveled off. In the presence of ultrasound, shorter time of 15 min and mild intensity of 250 W could lead to a satisfactory result in fluid loss properties, including the reasonable filtrate volume and thin and compact filter cakes. With increasing ultrasonic intensity, the fluid loss properties changed relatively little but various rheological data of the drilling fluids always increased. Adsorption tests through total organic carbon, infrared spectrum and thermogravimetic analyses as well as clay particle size analysis confirmed that as compared with the conventional agitation, ultrasound-assisted mud preparation could not only increase adsorbed amount of SMC on bentonite but also decrease average clay particle diameter attributed to acoustic cavitation. A plausible mechanism based on sonochemical thermodynamics is proposed to explain the improvement of the colloidal structure and performances of drilling fluid.

1969 ◽  
Vol 9 (04) ◽  
pp. 403-411 ◽  
Author(s):  
B.K. Sinha ◽  
Harvey T. Kennedy

Abstract Recommendations are made for obtaining consistent and reproducible test data on drilling fluids having identical composition. Previously, such a procedure has been difficult to accomplish even when the fluids were mixed in similar equipment. A survey of work in this area indicates that previous methods have been unsatisfactory because previous methods have been unsatisfactory because (1) the muds are extremely sensitive to the duration and violence of agitation during a normal mixing routine, and (2) gelling of the muds occurs before the properties can reach constant values. This gelling is caused by water evaporation resulting from the increase in temperature associated with the agitation. The work shows that these problems largely can be overcome by (1) agitating the constituents of the drilling fluid more vigorously, (2) maintaining a fairly constant temperature, and(3) Protecting the fluid from evaporation. When these steps are followed, the fluid properties approach asymptotic values that do not change by prolonged or accelerated agitation or by aging for a month. The time required to reach asymptotic values or a stabilized state is from 2 to 6 hours and is a function of the mud composition. Introduction Preparation of drilling fluids in the laboratory to determine their suitability to meet specific drilling requirements or to serve as a base fluid to evaluate the effectiveness of thinners, dispersants or other additives normally begins with combining measured quantities of the constituents and stirring them for a short time in a low-speed mixer. This is done to obtain a uniform mixture and to hydrate clays. Then the fluid is further agitated in a higher-speed device (Hamilton Beach mixer or Waring blender) to disperse more thoroughly and clay particles The biggest obstacle in the laboratory investigation of drilling fluids has been the lack of a method of producing a mixture by which reproducible results of the measured properties could be obtained. Numerous investigators have encountered this difficulty. Prior to 1929, density was the only property of mud that customarily was measured. The use of Wyoming bentonite on a large scale after 1929 was mainly responsible for the development of more elaborate testing procedures and for the application of the principles of colloid chemistry to the drilling fluids. Ambrose and Loomis in 1931 were among the first to recognize the plastic flow characteristics of drilling fluids, although Bingham in 1916 had observed The same phenomenon with dilute clay suspensions. Marsh introduced the Marsh funnel for field testing in 1931. By this time, non-Newtonian characteristics of drilling fluids were established. The Stormer and MacMichael viscometers were used to study the rheological properties of the fluids. In the 1930's and early 1940's, the work conducted by several investigators contributed toward a better understanding of drilling fluids. In the mid 1930's, fluid-loss and the associated mud-cake-forming properties of drilling fluids were recognized as important to the behavior of these fluids. The other properties of drilling fluids, including gel strength, pH, and sand content soon were recognized. In 1937, API published its first recommended procedure for test methods. Since that time, these procedures have been revised periodically. The latest edition, RP-13B, was published in 1961 However, in spite of the recognized need for a method of mixing that provides drilling fluids with stabilized properties, no such method previously has been described. SPEJ P. 403


2015 ◽  
Vol 820 ◽  
pp. 65-70
Author(s):  
I.D.S. Pereira ◽  
V.N.F. Lisboa ◽  
I.A. Silva ◽  
J.M.R. Figueirêdo ◽  
G.A. Neves ◽  
...  

Bentonite exhibt a range of industrial applications moving millions of dollars on the market per year. Among several applications if highlights it is use for petroleum drilling fluids. Thus, this work aims to characterize physical, mineralogical and technologically, the bentonitics clays of Sossego County, Paraíba, Brazil. Mineralogical characterization of clays was done through the following techniques: particle size analysis by laser diffraction, thermogravimetric and differential thermal analysis, chemical analysis and x-ray diffraction. The clays were turned in by treatment with sodium in Na2CO3 and then determined whether the apparent viscosity, plastic and volume of filtrate of clay-water dispersions. The results showed that the samples are of polycationic, showing levels of MgO, CaO and K2O, similar to those from Boa Vista County, Paraíba, Brazil, and consist of clay mineral kaolinite, quartz and esmec. The clays showed rheological properties that indicate potential for use in drilling fluids.


2018 ◽  
Author(s):  
Ζήσης Βρύζας

Η γεώτρηση αποτελεί την πλέον δαπανηρή εργασία σε μια καμπάνια εξεύρεσης και παραγωγής υδρογονανθράκων. Πέραν αυτού συνιστά και την μοναδική διεργασία που δίνει τη δυνατότητα ακριβούς προσδιορισμού των αποθεμάτων στο υπέδαφος. Ο πολφός (γεωτρητικά ρευστά) είναι το ‘αίμα’ της γεώτρησης: παρέχει πίεση, μεταφορά τριμμάτων/θραυσμάτων από τον πυθμένα του φρέατος, ψύξη και λίπανση κοπτικού και στήλης, καθώς επίσης διατηρεί τα θραύσματα εν αιωρήσει όταν υπάρχει διακοπή της κυκλοφορίας. Ως ρευστό γεώτρησης (drilling fluid) χρησιμοποιείται συνήθως ένα αιώρημα πηλού και άλλων υλικών σε νερό. Τα ρευστά διάτρησης με βάση το νερό αποτελούνται από α) νερό, το οποίο αποτελεί την συνεχή φάση και παρέχει το αρχικό ιξώδες (φρέσκο ή θαλασσινό), β) ενεργά στερεά για την ενίσχυση του ιξώδους και του σημείου διαρροής (μπεντονίτης, που συνιστάται στην περίπτωση του φρέσκου νερού και ατταπουλγίτης, αμίαντος ή σιπιόλιθος, που συνιστώνται στην περίπτωση του θαλασσινού νερού), και γ) αδρανή στερεά για την επίτευξη της απαιτούμενης πυκνότητας (βαρύτης, θειούχος μόλυβδος, σιδηρομεταλλεύματα ή χαλαζιακά υλικά).Τα γεωτρητικά ρευστά αποτελούν το 10-20% του συνολικού κόστους κατά την διάρκεια μιας γεώτρησης. Ποσοστό πολύ υψηλό όταν μιλάμε για επενδύσεις εκκατομυρίων δολλαρίων. Λόγω των ολοένα πιο βαθιών αλλά και περίπλοκων γεωλογικών σχηματισμών υπάρχει τεράστια ανάγκη από την πετρελαική βιομηχανία για καινούργια και περισσότερο αποδοτικά γεωτρητικά ρευστά τα οποία θα μπορούν να ανταπεξέλθουν στα ολοένα και πιο απαιτητικά περβάλλοντα θερμοκρασίας και πίεσης. Τα σημαντικότερα ζητήματα τα οποία καλούνται να ανταποκριθούν τα ρευστά είναι οι ολοένα αυξανόμενες συνθήκες πίεσης και θερμοκρασίας στο υπέδαφος που είναι απόροια της αναζήτησης υδρογονανθράκων σε πλέον δύσβατες περιοχές με μεγαλύτερα βάθη που αυξάνουν τους κινδύνους και το κόστος για μια γεώτρηση. Η απώλεια ρευστού κυκλοφορίας (fluid loss) είναι ένα από τα σημαντικότερα και πλέον δαπανηρά προβλήματα κατά την διαδικασία μιας γεώτρησης. Ως απώλεια ρευστού κυκλοφορίας ορίζεται η συνολική ή μερική απώλεια των ρευστών της γεώτρησης σε εξαιρετικά διαπερατές ζώνες (porous sands), σε σπηλαιώδεις σχηματισμούς (cavernous zones), σε φυσικές ρηγματώσεις (natural fractures) και σε ρηγματώσεις προκαλούμενες κατά τη διάτρηση (induced fractures). Τα τελευταία χρόνια έχουν γίνει αρκετές προσπάθειες για την βελτίωση των γεωτρητικών ρευστών με την χρήση νανοσωματιδίων, τα οποία έχουν τη δυνατότητα να βελτιώσουν τις ιδιότητες των γεωτρητικών ρευστών όταν προστίθενται ακόμα και σε χαμηλές συγκεντρώσεις (<1 wt%). Οι μοναδικές τους ιδιότητες σχετίζονται με το μικρό τους μέγεθος και επομένως τον εξαιρετικά μεγάλο λόγο επιφάνειας προς όγκο.Σε αυτή την εργασία, εξετάστηκαν διάφορα εμπορικά νανοσωματίδια (Fe2O3, Fe3O4, SiO2) καθώς επίσης συντέθηκαν, με την μέθοδο της συγκαταβύθισης, νανοσωματιδία μαγνητίτη (custom-made Fe3O4), με και χωρίς επικάλυψη κιτρικού οξέος, τα οποία ερευνήθηκαν ως προς την ικανότητα τους να βελτιώσουν τις ρεολογικές ιδιότητες και την απώλεια ρευστών σε αιωρήματα μπετονίτη. Προκειμένου να χαρακτηρισθούν φυσικοχημικά τα αιωρήματα υπέστησαν ξήρανση με κοκκοποίηση σε θερμοκρασία υγρού Ν2 και κρυοξήρανση. Η μορφολογία, η κρυσταλλική δομή και οι επιφανειακές ομάδες των ξηρών κόνεων εξετάσθηκαν με ηλεκτρονική μικροσκοπία HR-TΕM, περίθλαση ακτίνων Χ (XRD), φυσική ρόφηση Ν2 και φασματοσκοπία FTIR. Οι αλληλεπιδράσεις των σωματιδίων μπετονίτη με τα νανοσωματίδια και οι διάφορες δομές που δημιουργούνται και πως τελικά αυτές επηρεάζουν τις ρεολογικές ιδιότητες των αιωρημάτων εξετάστηκαν με το HR-TEM στους 25°C και 60°C. Με βάση τις εικόνες από το HR-TEM, ένα μοντέλο αλληλεπιδράσεων μεταξύ των διαφορετικών τύπων νανοσωματιδίων και σωματιδίων μπετονίτη δημιουργήθηκε για πρώτη φορά για τέτοια αιωρήματα. Οι ρεολογικές ιδιότητες των παραγόμενων δειγμάτων εξετάστηκαν και σε συνθήκες ατμοσφαιρικής πίεσης (μέχρι 70°C) με την χρήση περιστροφικού ιξωδόμετρου (Grace M3600-Couette type geometry) αλλά και σε συνθήκες υψηλής πίεσης και θερμοκρασίας (69 bar-121°C) (Chandler 7600 HPHT viscometer). Το μοντέλο Herschel-Bulkley χρησιμοποιήθηκε για να περιγράψει τη μεταβολή του ιξώδους με τη μεταβολή των ρεολογικών παραμέτρων δείχνοντας εξαιρετική εφαρμογή για τις διαφορετικές πειραματικές μετρήσεις με συντελεστές συσχέτισης (R2) >0.99 σε όλες τις περιπτώσεις. Οι ρεολογικές μετρήσεις έδειξαν ότι η προσθήκη των νανοσωματιδίων βελτιώνει σημαντικά τις ρεολογικές ιδιότητες των αιωρημάτων μπετονίτη στις διάφορες συνθήκες πίεσης και θερμοκρασίας. Οι απώλειες ρευστών (fluid loss) εξετάστηκαν με φιλτροπρέσες υψηλής πίεσης και θερμοκρασίας (20.7 bar και 121°C) οι οποίες υπολογίζουν τον ρυθμό διήθησης του πολφού μέσω του χρησιμοποιούμενου φίλτρου (κεραμικός δίσκος). Η μεγαλύτερη μείωση στην απώλεια ρευστών επιτεύχθηκε για το δείγμα που περιείχε 0.5 wt% custom-made Fe3O4 με μείωση -40% σε σχέση με το αρχικό δείγμα μπετονίτη που δείχνει την τεράστια ικανότητα των νανοσωματιδίων να βελτιώσουν σημαντικά τις απώλειες ρευστών ακόμα και σε τόσο μικρές συγκεντρώσεις. Τέλος, εξετάστηκε η ικανότητα των παραγόμενων ρευστών να αλλάζουν τις ρεολογικές τους ιδιότητες υπό την επίδραση διάφορων μαγνητικών πεδίων (μέχρι 0.7 Tesla). Τα αποτελέσματα έδειξαν ότι τα καινούργια γεωτρητικά ρευστά έχουν την ικανότητα να αυξάνουν την τάση διολίσθησης (yield stress) έως και 300% σε σχέση με αυτή που μετρήθηκε χωρίς την εφαρμογή μαγνητικού πεδίου. Αυτό είναι κάτι πολύ σημαντικό που επιτρέπει την χρήση έξυπνων ρευστών (smart drilling fluids) τα οποία μπορούν να εξοικονομήσουν και χρόνο αλλά και κόστη κατά την διάρκεια μιας γεώτρησης.Τα νανοσωματίδια δείχνουν πολλές ελπιδοφόρες δυνατότητες σε εφαρμογές γεωτρήσεων αφού έχουν τη δυνατότητα να βελτιώσουν ή και να λύσουν το πρόβλημα της απώλειας ρευστών, όταν προστίθενται ακόμα και σε χαμηλές συγκεντρώσεις (>0.5 wt%), ενώ ταυτόχρονα βελτιστοποιούν τις ρεολογικές ιδιότητες των γεωτρητικών ρευστών. Η χρήση τους για την ανάπτυξη βελτιωμένων γεωτρητικών ρευστών υπόσχεται να αλλάξει την βιομηχανία των γεωτρήσεων και να την βοηθήσει να εξορυχθούν πολύπλοκοι γεωλογικοί σχηματισμοί πιο αποδοτικά αλλά και οικονομικά.


Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4877
Author(s):  
Mobeen Murtaza ◽  
Sulaiman A. Alarifi ◽  
Muhammad Shahzad Kamal ◽  
Sagheer A. Onaizi ◽  
Mohammed Al-Ajmi ◽  
...  

Drilling issues such as shale hydration, high-temperature tolerance, torque and drag are often resolved by applying an appropriate drilling fluid formulation. Oil-based drilling fluid (OBDF) formulations are usually composed of emulsifiers, lime, brine, viscosifier, fluid loss controller and weighting agent. These additives sometimes outperform in extended exposure to high pressure high temperature (HPHT) conditions encountered in deep wells, resulting in weighting material segregation, high fluid loss, poor rheology and poor emulsion stability. In this study, two additives, oil wetter and rheology modifier were incorporated into the OBDF and their performance was investigated by conducting rheology, fluid loss, zeta potential and emulsion stability tests before and after hot rolling at 16 h and 32 h. Extending the hot rolling period beyond what is commonly used in this type of experiment is necessary to ensure the fluid’s stability. It was found that HPHT hot rolling affected the properties of drilling fluids by decreasing the rheology parameters and emulsion stability with the increase in the hot rolling time to 32 h. Also, the fluid loss additive’s performance degraded as rolling temperature and time increased. Adding oil wetter and rheology modifier additives resulted in a slight loss of rheological profile after 32 h and maintained flat rheology profile. The emulsion stability was slightly decreased and stayed close to the recommended value (400 V). The fluid loss was controlled by optimizing the concentration of fluid loss additive and oil wetter. The presence of oil wetter improved the carrying capacity of drilling fluids and prevented the barite sag problem. The zeta potential test confirmed that the oil wetter converted the surface of barite from water to oil and improved its dispersion in the oil.


2013 ◽  
Vol 66 (4) ◽  
pp. 485-491 ◽  
Author(s):  
Isabelle A. Silva ◽  
Julliana Marques R. Costa ◽  
Romualdo R. Menezes ◽  
Heber S. Ferreira ◽  
Gelmires de A. Neves ◽  
...  

New bentonite clay deposits have recently been discovered in the state of Paraíba, mainly in the municipalities of Cubati and Pedra Lavrada, creating great expectations in view of the possibility of expanding industrial production using these new reserves. The aim of this study was to study the new occurrences of bentonite clay in Paraíba, particularly in the municipality of Pedra Lavrada, for use in water based drilling fluids. The mineralogical properties of the clays were characterized by particle size analysis using laser diffraction, and thermogravimetric and differential thermal analysis, and its chemical composition was analyzed by X-ray fluorescence, X-ray diffraction, cation exchange capacity and specific surface area. The bentonite clays were treated with sodium carbonate at concentrations of 75, 100, 125, 150 and 175mEq/100g of dry clay, to transform them from polycationic to sodium form. For the technological characterization, drilling fluids were prepared according to the standards of Petrobras. The results indicated that the mineralogical composition of the samples consisted of montmorillonite, kaolinite and quartz. As for their rheological properties, the samples were found to partially meet the rheological requirements of the Petrobras standard.


Author(s):  
Erfan Veisi ◽  
Mastaneh Hajipour ◽  
Ebrahim Biniaz Delijani

Cooling the drill bit is one of the major functions of drilling fluids, especially in high temperature deep drilling operations. Designing stable drilling fluids with proper thermal properties is a great challenge. Identifying appropriate additives for the drilling fluid can mitigate drill-bit erosion or deformation caused by induced thermal stress. The unique advantages of nanoparticles may enhance thermal characteristics of drilling fluids. The impacts of nanoparticles on the specific heat capacity, thermal conductivity, rheological, and filtration control characteristics of water‐based drilling fluids were experimentally investigated and compared in this study. Al2O3, CuO, and Cu nanoparticles were used to prepare the water-based drilling nanofluid samples with various concentrations, using the two-step method. Transmission Electron Microscopy (TEM) and X-Ray Diffraction (XRD) were utilized to study the nanoparticle samples. The nanofluids stability and particle size distribution were, furthermore, examined using Dynamic Light Scattering (DLS). The experimental results indicated that thermal and rheological characteristics are enhanced in the presence of nanoparticles. The best enhancement in drilling fluid heat capacity and thermal conductivity was obtained as 15.6% and 12%, respectively by adding 0.9 wt% Cu nanoparticles. Furthermore, significant improvement was observed in the rheological characteristics such as the apparent and plastic viscosities, yield point, and gel strength of the drilling nanofluids compared to the base drilling fluid. Addition of nanoparticles resulted in reduced fluid loss and formation damage. The permeability of filter cakes decreased with increasing the nanoparticles concentration, but no significant effect in filter cake thickness was observed. The results reveal that the application of nanoparticles may reduce drill-bit replacement costs by improving the thermal and drilling fluid rheological characteristics and decrease the formation damage due to mud filtrate invasion.


2020 ◽  
Vol 10 (8) ◽  
pp. 3449-3466
Author(s):  
Atul Kumar Patidar ◽  
Anjali Sharma ◽  
Dev Joshi

Abstract The hydrocarbon extraction and exploitation using state-of-the-art modern drilling technologies urge the use of biodegradable, environment-friendly drilling fluid and drilling fluid additives to protect the environment and humanity. As more environmental laws are enacted and new safety rules implemented to oust the usage of toxic chemicals as fluid additives, it becomes inevitable that we re-evaluate our choice of drilling fluid additives. Drilling fluids and its additives play a crucial role in drilling operations as well as project costing; hence, it is needed that we develop cost-effective environment-friendly drilling fluid additives that meet the requirements for smooth functioning in geologically complex scenarios as well as have a minimal ecological impact. The current research work demonstrates key outcomes of investigations carried out on the formulation of a sustainable drilling fluid system, where groundnut husk is used as a fluid loss additive and a rheological modifier having no toxicity and high biodegradability. Cellulose was generated from groundnut husk at two varying particle sizes using mesh analysis, which was then compared with the commercially available PAC at different concentrations to validate its properties as a comparable fluid loss retarder additive as well as a rheological modifier. In the present work, various controlling characteristics of proposed groundnut husk additive are discussed, where comparison at different concentrations with a commercially available additive, PAC, is also validated. The API filtration losses demonstrated by the (63–74) µm and the (250–297) µm proposed additive showed a decrease of 91.88% and 82.31%, respectively, from the base mud at 4% concentration. The proposed husk additives acted as a filtrate retarder additive without much deviation from base rheology and with considerably higher pH than the base mud. This investigation indicates that the proposed fluid loss additive and rheological modifier can minimize the environmental hazards and have proved to be a cost-effective eco-friendly alternative in this challenging phase of the hydrocarbon exploration industry.


2020 ◽  
Author(s):  
Xian-Bin Huang ◽  
Jin-Sheng Sun ◽  
Yi Huang ◽  
Bang-Chuan Yan ◽  
Xiao-Dong Dong ◽  
...  

Abstract High-performance water-based drilling fluids (HPWBFs) are essential to wellbore stability in shale gas exploration and development. Laponite is a synthetic hectorite clay composed of disk-shaped nanoparticles. This paper analyzed the application potential of laponite in HPWBFs by evaluating its shale inhibition, plugging and lubrication performances. Shale inhibition performance was studied by linear swelling test and shale recovery test. Plugging performance was analyzed by nitrogen adsorption experiment and scanning electron microscope (SEM) observation. Extreme pressure lubricity test was used to evaluate the lubrication property. Experimental results show that laponite has good shale inhibition property, which is better than commonly used shale inhibitors, such as polyamine and KCl. Laponite can effectively plug shale pores. It considerably decreases the surface area and pore volume of shale, and SEM results show that it can reduce the porosity of shale and form a seamless nanofilm. Laponite is beneficial to increase lubricating property of drilling fluid by enhancing the drill pipes/wellbore interface smoothness and isolating the direct contact between wellbore and drill string. Besides, laponite can reduce the fluid loss volume. According to mechanism analysis, the good performance of laponite nanoparticles is mainly attributed to the disk-like nanostructure and the charged surfaces.


SPE Journal ◽  
2020 ◽  
Vol 25 (05) ◽  
pp. 2220-2233
Author(s):  
Weian Huang ◽  
Ming Lei ◽  
Jingwen Wang ◽  
Kaihe Lv ◽  
Lin Jiang ◽  
...  

Summary The rheology of drilling fluid is commonly regulated by chemical methods. In this work, a physical method of a high-frequency and high-voltage alternating current (AC) electric field to regulate the rheological properties of water-based drilling fluid is established. The effects of the electric field on the continuous phase and dispersed phase, as well as two kinds of water-based drilling fluids, were investigated, and the response relationship among rheological properties modeled by Bingham and Herschel-Bulkley (H-B) models and electric-field parameters was explored. Results showed that water conductivity increased when voltage reached 4 kV, whereas it was restored to the original state after 3 hours in the absence of an electric field, showing a memory effect. The effect was also observed on bentonite suspension, whose plastic viscosity increased with the aid of an electric field and decreased over time. Voltage showed the greatest effect on bentonite-suspension viscosity, followed by frequency and pulse-width ratio. Under the condition of voltage of 5 kV, frequency of 5 kHz, and pulse-width ratio of 80%, there was a maximum increase of 50% in viscosity. The addition of salts caused bentonite-suspension flocculation, and electric field reduced the consistency coefficient and relieved flocculation state. When polymers were incorporated in bentonite suspension, the electric field could decrease the adsorption amount between clay particles and polymeric additives such as amphoteric and acrylamide-based polymers. For two typical drilling fluids, the voltage of an introduced electric field was the main controlling factor to change the rheological properties; their plastic viscosity and consistency coefficient both started to increase when voltage reached 4 kV.


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