Antiferromagnetic alignment of Mn in ferromagnetic MnNi3.5 alloy: state of order dependence

1992 ◽  
Vol 104-107 ◽  
pp. 2015-2016 ◽  
Author(s):  
C. Petrillo ◽  
F. Sacchetti ◽  
M. Scafi
Keyword(s):  
Order Dependence ◽  
Alloy State

Collision Induced Microwave Absorption in N2, CH4, and N2–Ar, N2–CH4 Mixtures at 1.1 and 2.3 cm−1

1974 ◽  
Vol 52 (9) ◽  
pp. 821-829 ◽  
Author(s):  
I. R. Dagg ◽  
G. E. Reesor ◽  
J. L. Urbaniak
Keyword(s):  
Microwave Absorption ◽  
Quadrupole Moment ◽  
Linear Dependence ◽  
Relaxation Times ◽  
High Sensitivity ◽  
Higher Order ◽  
Induced Absorption ◽  
High Q ◽  
Order Dependence

Collision induced microwave absorption is reported in pure N2, N2–Ar, N2–CH4, mixtures, and in pure CH4 in the 35 and 70 GHz regions (1.1 and 2.3 cm−1) at a temperature of 22 °C. The measurements are accomplished using overmoded high Q cavities capable of pressurization of up to 5000 p.s.i.g. The apparatus and method are described. With the high sensitivity attained, the results in pure N2 from 30 → 250 amagat reveal terms in the square and cube of the density from which the relaxation times are calculated. The linear dependence on frequency of the collision induced absorption up to 2.3 cm−1 is established. Higher order dependence on the density is observed in the N2–Ar and N2–CH4 mixtures. Various estimates of the quadrupole moment of N2 are given, making use of earlier results in other frequency regions.

scholarly journals An Order-Independent Algorithm for Learning Chain Graphs

2021 ◽  
Vol 34 (1) ◽  
Author(s):  
Mohammad Ali Javidian ◽  
Marco Valtorta ◽  
Pooyan Jamshidi
Keyword(s):  
Directed Acyclic Graphs ◽  
High Dimensional ◽  
P Values ◽  
Order Dependence ◽  
Error Measures ◽  
Acyclic Graphs ◽  
Simulation Results ◽  
Improved Performance ◽  
Low Dimensional ◽  
Chain Graphs

LWF chain graphs combine directed acyclic graphs and undirected graphs. We propose a PC-like algorithm, called PC4LWF, that finds the structure of chain graphs under the faithfulness assumption to resolve the problem of scalability of the proposed algorithm by Studeny (1997). We prove that PC4LWF is order dependent, in the sense that the output can depend on the order in which the variables are given. This order dependence can be very pronounced in high-dimensional settings. We propose two modifications of the PC4LWF algorithm that remove part or all of this order dependence. Simulation results with different sample sizes, network sizes, and p-values demonstrate the competitive performance of the PC4LWF algorithms in comparison with the LCD algorithm proposed by Ma et al. (2008) in low-dimensional settings and improved performance (with regard to error measures) in high-dimensional settings.

Structural-order dependence of anomalous Hall effect in Co2MnGa topological semimetal thin films

2019 ◽  
Vol 115 (25) ◽  
pp. 252401 ◽  
Author(s):  
Qiang Wang ◽  
Zhenchao Wen ◽  
Takahide Kubota ◽  
Takeshi Seki ◽  
Koki Takanashi
Keyword(s):  
Thin Films ◽  
Hall Effect ◽  
Anomalous Hall Effect ◽  
Order Dependence ◽  
Structural Order ◽  
Topological Semimetal

Isotopic Exchange Between Hydrogen and Water Vapor over Supported Metal Catalysts. Part I. Kinetics of the Exchange

1972 ◽  
Vol 50 (12) ◽  
pp. 1900-1906 ◽  
Author(s):  
J. H. Rolston ◽  
J. W. Goodale
Keyword(s):  
Water Vapor ◽  
Transfer Rate ◽  
Water Vapor Pressure ◽  
Adsorbed Water ◽  
Deuterium Atom ◽  
Supported Metal Catalysts ◽  
Vapor Pressures ◽  
Order Dependence ◽  
Rate Limiting ◽  
Kinetics Of

Some rate data for the transfer of a deuterium atom tracer between hydrogen and water vapor, catalyzed by platinum supported on γ-alumina, are reported. Above 100 °C the transfer rate measured at 1 atm total pressure is shown to be free of mass transfer effects, and obeys an initial first order dependence on water vapor for vapor pressures less than 10 Torr. A near zero order dependence is observed at higher water vapor pressures. At temperatures below 100 °C the transfer rate is essentially independent of water vapor pressure between 5 and 100 Torr suggesting that surface adsorbed water is involved in the rate limiting transfer step.

Kinetics and mechanistic study of the ruthenium(III) catalyzed oxidative deamination and decarboxylation of L-valine by alkaline permanganate

2001 ◽  
Vol 79 (12) ◽  
pp. 1926-1933 ◽  
Author(s):  
Dinesh C Bilehal ◽  
Raviraj M Kulkarni ◽  
Sharanappa T Nandibewoor
Keyword(s):  
Ionic Strength ◽  
Alkaline Medium ◽  
Activation Parameters ◽  
Solvent Polarity ◽  
Mechanistic Study ◽  
Reaction Products ◽  
Order Dependence ◽  
Alkaline Permanganate ◽  
Kinetics Of ◽  
Catalyzed Oxidation

The kinetics of ruthenium(III) catalyzed oxidation of L-valine by permanganate in alkaline medium at a constant ionic strength has been studied spectrophotometrically. The reaction between permanganate and L-valine in alkaline medium exhibits 2:1 stoichiometry (KMnO4:L-valine). The reaction shows first-order dependence on the concentration of permanganate and ruthenium(III) and less than unit-order dependence on the concentrations of L-valine and alkali. The reaction rate increases both with an increase in ionic strength and a decrease in solvent polarity of the medium. Initial addition of reaction products did not significantly affect the rate. A mechanism involving the formation of a complex between catalyst and substrate has been proposed. The activation parameters were computed with respect to the slowest step of the mechanism.Key words: oxidation, L-valine, catalysis, ruthenium(III), kinetics.

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